Using device 0 (rank 0, local rank 0, local size 4) : Tesla V100-PCIE-16GB
Using device 2 (rank 2, local rank 2, local size 4) : Tesla V100-PCIE-16GB
Using device 3 (rank 3, local rank 3, local size 4) : Tesla V100-PCIE-16GB
Using device 1 (rank 1, local rank 1, local size 4) : Tesla V100-PCIE-16GB
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on    1 cores,    4 groups
  
 *******************************************************************************
  You are running the GPU port of VASP! When publishing results obtained with
  this version, please cite:
   - M. Hacene et al., http://dx.doi.org/10.1002/jcc.23096
   - M. Hutchinson and M. Widom, http://dx.doi.org/10.1016/j.cpc.2012.02.017
  
  in addition to the usual required citations (see manual).
  
  GPU developers: A. Anciaux-Sedrakian, C. Angerer, and M. Hutchinson.
 *******************************************************************************
  
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     Please note that VASP has recently been ported to GPU by means of       |
|     OpenACC. You are running the CUDA-C GPU-port of VASP, which is          |
|     deprecated and no longer actively developed, maintained, or             |
|     supported. In the near future, the CUDA-C GPU-port of VASP will be      |
|     dropped completely. We encourage you to switch to the OpenACC           |
|     GPU-port of VASP as soon as possible.                                   |
|                                                                             |
 -----------------------------------------------------------------------------

 vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 POSCAR found type information on POSCAR SiO C H 
 POSCAR found :  4 types and      22 ions
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 LDA part: xc-table for Pade appr. of Perdew
  
 WARNING: The GPU port of VASP has been extensively
 tested for: ALGO=Normal, Fast, and VeryFast.
 Other algorithms may produce incorrect results or
 yield suboptimal performance. Handle with care!
  
 POSCAR, INCAR and KPOINTS ok, starting setup
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
 FFT: planning ...
 WAVECAR not read
 entering main loop
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1     0.426661704682E+03    0.42666E+03   -0.16908E+04   712   0.804E+02 
DAV:   2    -0.746897727218E+01   -0.43413E+03   -0.41856E+03   968   0.208E+02 
DAV:   3    -0.118457907474E+03   -0.11099E+03   -0.11025E+03   768   0.116E+02 
DAV:   4    -0.123713686051E+03   -0.52558E+01   -0.52233E+01   832   0.296E+01 
DAV:   5    -0.123831589271E+03   -0.11790E+00   -0.11765E+00   944   0.407E+00    0.191E+01
DAV:   6    -0.114452708508E+03    0.93789E+01   -0.24440E+01   832   0.190E+01    0.983E+00
DAV:   7    -0.113075773016E+03    0.13769E+01   -0.27686E+00   888   0.841E+00    0.478E+00
DAV:   8    -0.112682049829E+03    0.39372E+00   -0.83625E-01   832   0.451E+00    0.156E+00
DAV:   9    -0.112611460173E+03    0.70590E-01   -0.13899E-01   920   0.193E+00    0.566E-01
DAV:  10    -0.112603887133E+03    0.75730E-02   -0.20597E-02   816   0.696E-01    0.311E-01
DAV:  11    -0.112604408093E+03   -0.52096E-03   -0.27423E-02   768   0.703E-01    0.258E-01
DAV:  12    -0.112606006668E+03   -0.15986E-02   -0.10568E-02   848   0.605E-01    0.110E-01
DAV:  13    -0.112611237782E+03   -0.52311E-02   -0.34708E-03   704   0.257E-01    0.726E-02
DAV:  14    -0.112616176842E+03   -0.49391E-02   -0.83899E-04   760   0.115E-01    0.356E-02
DAV:  15    -0.112620453376E+03   -0.42765E-02   -0.61085E-04   752   0.876E-02    0.250E-02
DAV:  16    -0.112622324018E+03   -0.18706E-02   -0.25693E-04   912   0.698E-02    0.165E-02
DAV:  17    -0.112623041751E+03   -0.71773E-03   -0.67754E-05   712   0.288E-02    0.100E-02
DAV:  18    -0.112623467686E+03   -0.42593E-03   -0.57242E-05   672   0.285E-02    0.567E-03
DAV:  19    -0.112623580807E+03   -0.11312E-03   -0.11853E-05   600   0.135E-02    0.216E-03
DAV:  20    -0.112623646694E+03   -0.65887E-04   -0.10480E-05   536   0.936E-03    0.216E-03
DAV:  21    -0.112623660376E+03   -0.13682E-04   -0.16726E-06   608   0.480E-03    0.102E-03
DAV:  22    -0.112623668688E+03   -0.83120E-05   -0.14700E-06   520   0.407E-03 
   1 F= -.11262367E+03 E0= -.11260498E+03  d E =-.112624E+03
 curvature:   0.00 expect dE= 0.000E+00 dE for cont linesearch  0.000E+00
 trial: gam= 0.00000 g(F)=  0.234E+01 g(S)=  0.000E+00 ort = 0.000E+00 (trialstep = 0.100E+01)
 search vector abs. value=  0.234E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.112508405975E+03    0.11525E+00   -0.45682E+02   640   0.116E+02    0.745E+00
DAV:   2    -0.114237414413E+03   -0.17290E+01   -0.18201E+01   856   0.198E+01    0.365E+00
DAV:   3    -0.114059557421E+03    0.17786E+00   -0.44146E-01   896   0.432E+00    0.203E+00
DAV:   4    -0.114027644695E+03    0.31913E-01   -0.37251E-01   832   0.357E+00    0.703E-01
DAV:   5    -0.114029216567E+03   -0.15719E-02   -0.87241E-02   768   0.172E+00    0.492E-01
DAV:   6    -0.114027540758E+03    0.16758E-02   -0.20575E-02   864   0.873E-01    0.111E-01
DAV:   7    -0.114028025089E+03   -0.48433E-03   -0.50131E-03   792   0.347E-01    0.127E-01
DAV:   8    -0.114028144880E+03   -0.11979E-03   -0.40462E-04   784   0.128E-01    0.570E-02
DAV:   9    -0.114028417994E+03   -0.27311E-03   -0.50282E-04   768   0.134E-01    0.177E-02
DAV:  10    -0.114028718991E+03   -0.30100E-03   -0.10532E-04   760   0.515E-02    0.171E-02
DAV:  11    -0.114028965885E+03   -0.24689E-03   -0.49721E-05   648   0.319E-02    0.171E-02
DAV:  12    -0.114029085677E+03   -0.11979E-03   -0.28272E-05   576   0.264E-02    0.712E-03
DAV:  13    -0.114029131178E+03   -0.45501E-04   -0.15358E-05   624   0.189E-02    0.323E-03
DAV:  14    -0.114029175427E+03   -0.44248E-04   -0.78039E-06   528   0.111E-02    0.441E-03
DAV:  15    -0.114029190941E+03   -0.15515E-04   -0.24197E-06   616   0.569E-03    0.363E-03
DAV:  16    -0.114029197442E+03   -0.65001E-05   -0.15076E-06   576   0.626E-03 
   2 F= -.11402920E+03 E0= -.11401051E+03  d E =-.140553E+01
 trial-energy change:   -1.405529  1 .order   -1.347552   -2.342705   -0.352398
 step:   1.1475(harm=  1.1771)  dis= 0.15291  next Energy=  -114.055369 (dE=-0.143E+01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.114033976956E+03   -0.47860E-02   -0.10231E+01   640   0.175E+01    0.115E+00
DAV:   2    -0.114057801193E+03   -0.23824E-01   -0.26687E-01   896   0.251E+00    0.424E-01
DAV:   3    -0.114055040981E+03    0.27602E-02   -0.69101E-03   896   0.554E-01    0.229E-01
DAV:   4    -0.114054686998E+03    0.35398E-03   -0.45456E-03   832   0.390E-01    0.718E-02
DAV:   5    -0.114054743268E+03   -0.56271E-04   -0.89703E-04   832   0.178E-01    0.423E-02
DAV:   6    -0.114054760065E+03   -0.16797E-04   -0.94417E-05   800   0.568E-02    0.221E-02
DAV:   7    -0.114054769210E+03   -0.91446E-05   -0.37045E-05   704   0.331E-02 
   3 F= -.11405477E+03 E0= -.11403608E+03  d E =-.143110E+01
 curvature:  -0.57 expect dE=-0.925E+00 dE for cont linesearch -0.162E-04
 trial: gam= 0.69372 g(F)=  0.162E+01 g(S)=  0.000E+00 ort =-0.814E-02 (trialstep = 0.882E+00)
 search vector abs. value=  0.273E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.113265542719E+03    0.78922E+00   -0.31893E+02   640   0.984E+01    0.846E+00
DAV:   2    -0.114200647731E+03   -0.93511E+00   -0.10737E+01   832   0.157E+01    0.281E+00
DAV:   3    -0.114066303812E+03    0.13434E+00   -0.30783E-01   832   0.373E+00    0.154E+00
DAV:   4    -0.114038278247E+03    0.28026E-01   -0.21502E-01   832   0.280E+00    0.520E-01
DAV:   5    -0.114039245620E+03   -0.96737E-03   -0.36607E-02   856   0.111E+00    0.314E-01
DAV:   6    -0.114039582693E+03   -0.33707E-03   -0.61074E-03   840   0.402E-01    0.144E-01
DAV:   7    -0.114039606105E+03   -0.23412E-04   -0.98907E-04   808   0.183E-01    0.117E-01
DAV:   8    -0.114039831930E+03   -0.22582E-03   -0.34363E-04   744   0.108E-01    0.417E-02
DAV:   9    -0.114039974362E+03   -0.14243E-03   -0.19329E-04   832   0.949E-02    0.145E-02
DAV:  10    -0.114040271027E+03   -0.29667E-03   -0.14083E-04   712   0.705E-02    0.279E-02
DAV:  11    -0.114040449621E+03   -0.17859E-03   -0.56662E-05   728   0.478E-02    0.201E-02
DAV:  12    -0.114040570307E+03   -0.12069E-03   -0.51354E-05   760   0.398E-02    0.104E-02
DAV:  13    -0.114040618342E+03   -0.48034E-04   -0.99780E-06   616   0.190E-02    0.305E-03
DAV:  14    -0.114040669692E+03   -0.51350E-04   -0.57477E-06   544   0.101E-02    0.271E-03
DAV:  15    -0.114040686349E+03   -0.16657E-04   -0.15524E-06   584   0.491E-03    0.263E-03
DAV:  16    -0.114040695108E+03   -0.87589E-05   -0.11392E-06   560   0.472E-03 
   4 F= -.11404070E+03 E0= -.11402197E+03  d E =0.140741E-01
 trial-energy change:    0.014074  1 .order    0.075569   -1.421928    1.573066
 step:   0.4461(harm=  0.4189)  dis= 0.05038  next Energy=  -114.422153 (dE=-0.367E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.114274118396E+03   -0.23343E+00   -0.78431E+01   640   0.487E+01    0.380E+00
DAV:   2    -0.114452133187E+03   -0.17801E+00   -0.23008E+00   848   0.746E+00    0.122E+00
DAV:   3    -0.114425170499E+03    0.26963E-01   -0.58620E-02   832   0.144E+00    0.686E-01
DAV:   4    -0.114420290207E+03    0.48803E-02   -0.53940E-02   832   0.124E+00    0.184E-01
DAV:   5    -0.114420684903E+03   -0.39470E-03   -0.12529E-02   816   0.618E-01    0.190E-01
DAV:   6    -0.114420851577E+03   -0.16667E-03   -0.83612E-04   792   0.149E-01    0.114E-01
DAV:   7    -0.114420970990E+03   -0.11941E-03   -0.16431E-04   784   0.841E-02    0.666E-02
DAV:   8    -0.114421144540E+03   -0.17355E-03   -0.18661E-04   744   0.675E-02    0.285E-02
DAV:   9    -0.114421261935E+03   -0.11740E-03   -0.86729E-05   800   0.668E-02    0.860E-03
DAV:  10    -0.114421402111E+03   -0.14018E-03   -0.50268E-05   752   0.367E-02    0.184E-02
DAV:  11    -0.114421469584E+03   -0.67473E-04   -0.14288E-05   616   0.219E-02    0.123E-02
DAV:  12    -0.114421534000E+03   -0.64416E-04   -0.18692E-05   576   0.200E-02    0.387E-03
DAV:  13    -0.114421564472E+03   -0.30472E-04   -0.51842E-06   600   0.941E-03    0.199E-03
DAV:  14    -0.114421580293E+03   -0.15821E-04   -0.25334E-06   576   0.639E-03    0.808E-04
DAV:  15    -0.114421589041E+03   -0.87485E-05   -0.13329E-06   560   0.397E-03 
   5 F= -.11442159E+03 E0= -.11440288E+03  d E =-.366820E+00
 curvature:  -0.35 expect dE=-0.269E+00 dE for cont linesearch -0.124E-08
 trial: gam= 0.30678 g(F)=  0.761E+00 g(S)=  0.000E+00 ort =-0.977E-04 (trialstep = 0.795E+00)
 search vector abs. value=  0.102E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.114727421217E+03   -0.30584E+00   -0.43460E+01   640   0.360E+01    0.196E+00
DAV:   2    -0.114824409864E+03   -0.96989E-01   -0.12348E+00   816   0.529E+00    0.107E+00
DAV:   3    -0.114810498890E+03    0.13911E-01   -0.40186E-02   880   0.123E+00    0.577E-01
DAV:   4    -0.114809540018E+03    0.95887E-03   -0.19430E-02   824   0.776E-01    0.212E-01
DAV:   5    -0.114809673095E+03   -0.13308E-03   -0.45224E-03   792   0.409E-01    0.844E-02
DAV:   6    -0.114809686603E+03   -0.13508E-04   -0.47389E-04   760   0.119E-01    0.483E-02
DAV:   7    -0.114809678974E+03    0.76292E-05   -0.25753E-04   728   0.958E-02    0.272E-02
DAV:   8    -0.114809677818E+03    0.11553E-05   -0.57974E-05   864   0.575E-02 
   6 F= -.11480968E+03 E0= -.11479092E+03  d E =-.388089E+00
 trial-energy change:   -0.388089  1 .order   -0.383148   -0.604826   -0.161471
 step:   1.0610(harm=  1.0848)  dis= 0.06594  next Energy=  -114.836858 (dE=-0.415E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.114827874443E+03   -0.18195E-01   -0.49170E+00   640   0.121E+01    0.674E-01
DAV:   2    -0.114838395173E+03   -0.10521E-01   -0.14160E-01   808   0.177E+00    0.365E-01
DAV:   3    -0.114836841220E+03    0.15540E-02   -0.48008E-03   880   0.420E-01    0.199E-01
DAV:   4    -0.114836713463E+03    0.12776E-03   -0.20788E-03   824   0.262E-01    0.715E-02
DAV:   5    -0.114836743730E+03   -0.30267E-04   -0.56257E-04   792   0.138E-01    0.291E-02
DAV:   6    -0.114836748827E+03   -0.50969E-05   -0.49297E-05   792   0.401E-02 
   7 F= -.11483675E+03 E0= -.11481798E+03  d E =-.415160E+00
 curvature:  -0.72 expect dE=-0.677E+00 dE for cont linesearch -0.967E-06
 trial: gam= 1.17820 g(F)=  0.939E+00 g(S)=  0.000E+00 ort =-0.117E-02 (trialstep = 0.368E+00)
 search vector abs. value=  0.235E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115070456349E+03   -0.23371E+00   -0.17021E+01   640   0.220E+01    0.105E+00
DAV:   2    -0.115097601321E+03   -0.27145E-01   -0.38336E-01   864   0.303E+00    0.662E-01
DAV:   3    -0.115093950807E+03    0.36505E-02   -0.15412E-02   888   0.700E-01    0.356E-01
DAV:   4    -0.115093729331E+03    0.22148E-03   -0.53950E-03   768   0.421E-01    0.108E-01
DAV:   5    -0.115093832415E+03   -0.10308E-03   -0.80931E-04   832   0.168E-01    0.476E-02
DAV:   6    -0.115093883256E+03   -0.50841E-04   -0.34589E-04   776   0.107E-01    0.288E-02
DAV:   7    -0.115093906036E+03   -0.22781E-04   -0.50748E-05   792   0.470E-02    0.144E-02
DAV:   8    -0.115093969629E+03   -0.63592E-04   -0.41654E-05   736   0.342E-02    0.653E-03
DAV:   9    -0.115094005332E+03   -0.35704E-04   -0.44664E-06   608   0.162E-02    0.444E-03
DAV:  10    -0.115094062860E+03   -0.57528E-04   -0.11698E-05   536   0.217E-02    0.363E-03
DAV:  11    -0.115094094229E+03   -0.31369E-04   -0.55652E-06   584   0.117E-02    0.286E-03
DAV:  12    -0.115094108287E+03   -0.14058E-04   -0.21610E-06   576   0.712E-03    0.162E-03
DAV:  13    -0.115094117424E+03   -0.91371E-05   -0.15672E-06   560   0.630E-03 
   8 F= -.11509412E+03 E0= -.11507534E+03  d E =-.257369E+00
 trial-energy change:   -0.257369  1 .order   -0.256787   -0.344555   -0.169018
 step:   0.7085(harm=  0.7216)  dis= 0.07667  next Energy=  -115.172947 (dE=-0.336E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115154032839E+03   -0.59925E-01   -0.14733E+01   640   0.205E+01    0.980E-01
DAV:   2    -0.115176522399E+03   -0.22490E-01   -0.32735E-01   856   0.282E+00    0.617E-01
DAV:   3    -0.115173352157E+03    0.31702E-02   -0.14605E-02   880   0.682E-01    0.328E-01
DAV:   4    -0.115173122836E+03    0.22932E-03   -0.44428E-03   768   0.389E-01    0.102E-01
DAV:   5    -0.115173201130E+03   -0.78295E-04   -0.68065E-04   872   0.157E-01    0.429E-02
DAV:   6    -0.115173237053E+03   -0.35922E-04   -0.30272E-04   776   0.104E-01    0.272E-02
DAV:   7    -0.115173256680E+03   -0.19627E-04   -0.44883E-05   768   0.421E-02    0.153E-02
DAV:   8    -0.115173313712E+03   -0.57032E-04   -0.36326E-05   728   0.323E-02    0.555E-03
DAV:   9    -0.115173356594E+03   -0.42882E-04   -0.54525E-06   576   0.163E-02    0.493E-03
DAV:  10    -0.115173409118E+03   -0.52525E-04   -0.95810E-06   536   0.203E-02    0.354E-03
DAV:  11    -0.115173442468E+03   -0.33350E-04   -0.77620E-06   592   0.144E-02    0.337E-03
DAV:  12    -0.115173457742E+03   -0.15274E-04   -0.22701E-06   552   0.681E-03    0.235E-03
DAV:  13    -0.115173465177E+03   -0.74349E-05   -0.12267E-06   592   0.562E-03 
   9 F= -.11517347E+03 E0= -.11515468E+03  d E =-.336716E+00
 curvature:  -0.90 expect dE=-0.739E+00 dE for cont linesearch -0.481E-05
 trial: gam= 0.82142 g(F)=  0.818E+00 g(S)=  0.000E+00 ort = 0.354E-02 (trialstep = 0.425E+00)
 search vector abs. value=  0.241E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115360356393E+03   -0.18690E+00   -0.18821E+01   640   0.239E+01    0.159E+00
DAV:   2    -0.115388896799E+03   -0.28540E-01   -0.45355E-01   848   0.341E+00    0.795E-01
DAV:   3    -0.115381524698E+03    0.73721E-02   -0.21464E-02   936   0.941E-01    0.454E-01
DAV:   4    -0.115380910028E+03    0.61467E-03   -0.15536E-02   800   0.725E-01    0.154E-01
DAV:   5    -0.115380709984E+03    0.20004E-03   -0.30418E-03   864   0.363E-01    0.882E-02
DAV:   6    -0.115380755025E+03   -0.45041E-04   -0.89593E-04   776   0.151E-01    0.493E-02
DAV:   7    -0.115380737497E+03    0.17528E-04   -0.16432E-04   784   0.841E-02    0.300E-02
DAV:   8    -0.115380754630E+03   -0.17133E-04   -0.62712E-05   736   0.448E-02    0.165E-02
DAV:   9    -0.115380768954E+03   -0.14324E-04   -0.18121E-05   552   0.388E-02    0.761E-03
DAV:  10    -0.115380800746E+03   -0.31792E-04   -0.49053E-05   672   0.417E-02    0.128E-02
DAV:  11    -0.115380817199E+03   -0.16452E-04   -0.22381E-05   632   0.309E-02    0.292E-03
DAV:  12    -0.115380829208E+03   -0.12009E-04   -0.45642E-06   576   0.115E-02    0.184E-03
DAV:  13    -0.115380840505E+03   -0.11297E-04   -0.13441E-06   528   0.511E-03    0.135E-03
DAV:  14    -0.115380849150E+03   -0.86446E-05   -0.92970E-07   536   0.357E-03 
  10 F= -.11538085E+03 E0= -.11536207E+03  d E =-.207384E+00
 trial-energy change:   -0.207384  1 .order   -0.209066   -0.348955   -0.069176
 step:   0.5350(harm=  0.5300)  dis= 0.05757  next Energy=  -115.389779 (dE=-0.216E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115388426792E+03   -0.75863E-02   -0.12576E+00   648   0.616E+00    0.401E-01
DAV:   2    -0.115390306132E+03   -0.18793E-02   -0.29804E-02   832   0.877E-01    0.202E-01
DAV:   3    -0.115389820018E+03    0.48611E-03   -0.14319E-03   904   0.243E-01    0.114E-01
DAV:   4    -0.115389799474E+03    0.20544E-04   -0.10721E-03   800   0.189E-01    0.404E-02
DAV:   5    -0.115389783470E+03    0.16003E-04   -0.23031E-04   888   0.100E-01    0.226E-02
DAV:   6    -0.115389787128E+03   -0.36580E-05   -0.62252E-05   760   0.387E-02 
  11 F= -.11538979E+03 E0= -.11537101E+03  d E =-.216322E+00
 curvature:  -0.78 expect dE=-0.221E+00 dE for cont linesearch -0.279E-06
 trial: gam= 0.34132 g(F)=  0.285E+00 g(S)=  0.000E+00 ort =-0.930E-03 (trialstep = 0.447E+00)
 search vector abs. value=  0.565E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115460141628E+03   -0.70358E-01   -0.86870E+00   672   0.160E+01    0.107E+00
DAV:   2    -0.115477700558E+03   -0.17559E-01   -0.23268E-01   816   0.234E+00    0.470E-01
DAV:   3    -0.115474498696E+03    0.32019E-02   -0.79103E-03   856   0.556E-01    0.272E-01
DAV:   4    -0.115474125517E+03    0.37318E-03   -0.65876E-03   816   0.469E-01    0.933E-02
DAV:   5    -0.115474120061E+03    0.54556E-05   -0.13558E-03   832   0.211E-01    0.574E-02
DAV:   6    -0.115474143850E+03   -0.23789E-04   -0.28692E-04   768   0.825E-02    0.273E-02
DAV:   7    -0.115474145495E+03   -0.16448E-05   -0.32928E-05   784   0.377E-02 
  12 F= -.11547415E+03 E0= -.11545536E+03  d E =-.843584E-01
 trial-energy change:   -0.084358  1 .order   -0.084455   -0.127336   -0.041575
 step:   0.6636(harm=  0.6636)  dis= 0.03191  next Energy=  -115.484320 (dE=-0.945E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115480842536E+03   -0.66987E-02   -0.20412E+00   672   0.778E+00    0.525E-01
DAV:   2    -0.115484947956E+03   -0.41054E-02   -0.54598E-02   816   0.114E+00    0.226E-01
DAV:   3    -0.115484187240E+03    0.76072E-03   -0.18763E-03   872   0.270E-01    0.130E-01
DAV:   4    -0.115484118202E+03    0.69038E-04   -0.14682E-03   816   0.223E-01    0.435E-02
DAV:   5    -0.115484126176E+03   -0.79734E-05   -0.31070E-04   840   0.101E-01    0.275E-02
DAV:   6    -0.115484139921E+03   -0.13746E-04   -0.62355E-05   752   0.393E-02    0.133E-02
DAV:   7    -0.115484148119E+03   -0.81978E-05   -0.70631E-06   584   0.182E-02 
  13 F= -.11548415E+03 E0= -.11546537E+03  d E =-.943610E-01
 curvature:  -0.66 expect dE=-0.139E+00 dE for cont linesearch -0.669E-06
 trial: gam= 0.71949 g(F)=  0.211E+00 g(S)=  0.000E+00 ort =-0.758E-03 (trialstep = 0.490E+00)
 search vector abs. value=  0.503E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115551596244E+03   -0.67456E-01   -0.63670E+00   640   0.133E+01    0.741E-01
DAV:   2    -0.115559324852E+03   -0.77286E-02   -0.12138E-01   848   0.179E+00    0.425E-01
DAV:   3    -0.115557735067E+03    0.15898E-02   -0.54259E-03   824   0.434E-01    0.230E-01
DAV:   4    -0.115557665183E+03    0.69884E-04   -0.32500E-03   696   0.327E-01    0.665E-02
DAV:   5    -0.115557637281E+03    0.27903E-04   -0.53110E-04   800   0.144E-01    0.375E-02
DAV:   6    -0.115557639869E+03   -0.25879E-05   -0.21099E-04   736   0.729E-02    0.216E-02
DAV:   7    -0.115557642533E+03   -0.26646E-05   -0.24359E-05   664   0.339E-02 
  14 F= -.11555764E+03 E0= -.11553886E+03  d E =-.734944E-01
 trial-energy change:   -0.073494  1 .order   -0.073487   -0.103420   -0.043555
 step:   0.8470(harm=  0.8470)  dis= 0.03607  next Energy=  -115.573479 (dE=-0.893E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115570482318E+03   -0.12842E-01   -0.33718E+00   640   0.968E+00    0.541E-01
DAV:   2    -0.115574403844E+03   -0.39215E-02   -0.63737E-02   840   0.130E+00    0.309E-01
DAV:   3    -0.115573551472E+03    0.85237E-03   -0.28932E-03   848   0.317E-01    0.167E-01
DAV:   4    -0.115573492000E+03    0.59472E-04   -0.17120E-03   792   0.239E-01    0.486E-02
DAV:   5    -0.115573488751E+03    0.32487E-05   -0.28012E-04   920   0.104E-01    0.272E-02
DAV:   6    -0.115573504758E+03   -0.16007E-04   -0.10072E-04   760   0.510E-02    0.151E-02
DAV:   7    -0.115573518821E+03   -0.14063E-04   -0.10422E-05   592   0.226E-02    0.765E-03
DAV:   8    -0.115573552498E+03   -0.33677E-04   -0.21217E-05   584   0.244E-02    0.630E-03
DAV:   9    -0.115573569227E+03   -0.16729E-04   -0.39484E-06   608   0.165E-02    0.306E-03
DAV:  10    -0.115573594290E+03   -0.25063E-04   -0.79834E-06   512   0.162E-02    0.374E-03
DAV:  11    -0.115573605600E+03   -0.11310E-04   -0.19260E-06   600   0.823E-03    0.185E-03
DAV:  12    -0.115573613615E+03   -0.80147E-05   -0.13557E-06   520   0.520E-03 
  15 F= -.11557361E+03 E0= -.11555483E+03  d E =-.894655E-01
 curvature:  -1.01 expect dE=-0.192E+00 dE for cont linesearch -0.276E-06
 trial: gam= 0.91934 g(F)=  0.190E+00 g(S)=  0.000E+00 ort = 0.371E-03 (trialstep = 0.458E+00)
 search vector abs. value=  0.616E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115630576018E+03   -0.56970E-01   -0.49355E+00   640   0.115E+01    0.655E-01
DAV:   2    -0.115636564808E+03   -0.59888E-02   -0.90936E-02   832   0.148E+00    0.417E-01
DAV:   3    -0.115634995892E+03    0.15689E-02   -0.57123E-03   856   0.463E-01    0.198E-01
DAV:   4    -0.115634913870E+03    0.82022E-04   -0.18629E-03   768   0.247E-01    0.666E-02
DAV:   5    -0.115634891634E+03    0.22235E-04   -0.46838E-04   824   0.137E-01    0.264E-02
DAV:   6    -0.115634898792E+03   -0.71575E-05   -0.66501E-05   768   0.454E-02 
  16 F= -.11563490E+03 E0= -.11561612E+03  d E =-.612852E-01
 trial-energy change:   -0.061285  1 .order   -0.061455   -0.087429   -0.035481
 step:   0.7824(harm=  0.7716)  dis= 0.03624  next Energy=  -115.647374 (dE=-0.738E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115645129836E+03   -0.10238E-01   -0.24655E+00   640   0.812E+00    0.459E-01
DAV:   2    -0.115648160133E+03   -0.30303E-02   -0.45714E-02   816   0.105E+00    0.294E-01
DAV:   3    -0.115647389074E+03    0.77106E-03   -0.27968E-03   872   0.325E-01    0.141E-01
DAV:   4    -0.115647358497E+03    0.30577E-04   -0.96024E-04   760   0.178E-01    0.467E-02
DAV:   5    -0.115647357568E+03    0.92919E-06   -0.23675E-04   776   0.987E-02    0.191E-02
DAV:   6    -0.115647369997E+03   -0.12429E-04   -0.35634E-05   752   0.324E-02    0.105E-02
DAV:   7    -0.115647387719E+03   -0.17721E-04   -0.87533E-06   544   0.179E-02    0.466E-03
DAV:   8    -0.115647407634E+03   -0.19915E-04   -0.29150E-06   536   0.112E-02    0.273E-03
DAV:   9    -0.115647432450E+03   -0.24816E-04   -0.64868E-06   536   0.174E-02    0.334E-03
DAV:  10    -0.115647442838E+03   -0.10388E-04   -0.27730E-06   576   0.105E-02    0.250E-03
DAV:  11    -0.115647447113E+03   -0.42748E-05   -0.10177E-06   560   0.554E-03 
  17 F= -.11564745E+03 E0= -.11562867E+03  d E =-.738335E-01
 curvature:  -1.25 expect dE=-0.205E+00 dE for cont linesearch -0.246E-07
 trial: gam= 0.88211 g(F)=  0.164E+00 g(S)=  0.000E+00 ort =-0.110E-03 (trialstep = 0.501E+00)
 search vector abs. value=  0.644E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115691608093E+03   -0.44165E-01   -0.80610E+00   640   0.146E+01    0.895E-01
DAV:   2    -0.115702583564E+03   -0.10975E-01   -0.15513E-01   816   0.198E+00    0.485E-01
DAV:   3    -0.115700341346E+03    0.22422E-02   -0.55154E-03   832   0.463E-01    0.262E-01
DAV:   4    -0.115700128656E+03    0.21269E-03   -0.42884E-03   784   0.369E-01    0.638E-02
DAV:   5    -0.115700104426E+03    0.24230E-04   -0.70935E-04   832   0.169E-01    0.429E-02
DAV:   6    -0.115700115930E+03   -0.11504E-04   -0.21741E-04   792   0.781E-02    0.235E-02
DAV:   7    -0.115700116105E+03   -0.17560E-06   -0.42481E-05   776   0.434E-02 
  18 F= -.11570012E+03 E0= -.11568134E+03  d E =-.526690E-01
 trial-energy change:   -0.052669  1 .order   -0.052731   -0.082326   -0.023136
 step:   0.6966(harm=  0.6966)  dis= 0.03425  next Energy=  -115.704700 (dE=-0.573E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115703321933E+03   -0.32060E-02   -0.12313E+00   640   0.572E+00    0.351E-01
DAV:   2    -0.115705003911E+03   -0.16820E-02   -0.23792E-02   824   0.776E-01    0.188E-01
DAV:   3    -0.115704660643E+03    0.34327E-03   -0.85148E-04   848   0.179E-01    0.100E-01
DAV:   4    -0.115704639166E+03    0.21478E-04   -0.65070E-04   800   0.144E-01    0.245E-02
DAV:   5    -0.115704641934E+03   -0.27689E-05   -0.10555E-04   832   0.645E-02    0.172E-02
DAV:   6    -0.115704652094E+03   -0.10159E-04   -0.37063E-05   720   0.338E-02    0.916E-03
DAV:   7    -0.115704656189E+03   -0.40957E-05   -0.56688E-06   624   0.162E-02 
  19 F= -.11570466E+03 E0= -.11568588E+03  d E =-.572091E-01
 curvature:  -1.36 expect dE=-0.193E+00 dE for cont linesearch -0.123E-07
 trial: gam= 0.85119 g(F)=  0.142E+00 g(S)=  0.000E+00 ort = 0.761E-04 (trialstep = 0.540E+00)
 search vector abs. value=  0.608E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115745349518E+03   -0.40697E-01   -0.89565E+00   640   0.156E+01    0.881E-01
DAV:   2    -0.115758991292E+03   -0.13642E-01   -0.17626E-01   800   0.207E+00    0.509E-01
DAV:   3    -0.115756811875E+03    0.21794E-02   -0.70425E-03   848   0.543E-01    0.274E-01
DAV:   4    -0.115756540684E+03    0.27119E-03   -0.35476E-03   736   0.328E-01    0.720E-02
DAV:   5    -0.115756568373E+03   -0.27689E-04   -0.73196E-04   776   0.167E-01    0.354E-02
DAV:   6    -0.115756571763E+03   -0.33896E-05   -0.80153E-05   752   0.503E-02 
  20 F= -.11575657E+03 E0= -.11573779E+03  d E =-.519156E-01
 trial-energy change:   -0.051916  1 .order   -0.051821   -0.076460   -0.027182
 step:   0.8379(harm=  0.8379)  dis= 0.04174  next Energy=  -115.763974 (dE=-0.593E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115760784906E+03   -0.42165E-02   -0.27221E+00   640   0.860E+00    0.487E-01
DAV:   2    -0.115764891507E+03   -0.41066E-02   -0.53424E-02   808   0.114E+00    0.278E-01
DAV:   3    -0.115764240355E+03    0.65115E-03   -0.21038E-03   840   0.297E-01    0.149E-01
DAV:   4    -0.115764164565E+03    0.75791E-04   -0.10806E-03   768   0.181E-01    0.391E-02
DAV:   5    -0.115764178103E+03   -0.13539E-04   -0.22458E-04   776   0.942E-02    0.193E-02
DAV:   6    -0.115764186368E+03   -0.82646E-05   -0.24025E-05   656   0.280E-02 
  21 F= -.11576419E+03 E0= -.11574540E+03  d E =-.595302E-01
 curvature:  -1.80 expect dE=-0.225E+00 dE for cont linesearch -0.135E-05
 trial: gam= 0.88165 g(F)=  0.125E+00 g(S)=  0.000E+00 ort = 0.674E-03 (trialstep = 0.600E+00)
 search vector abs. value=  0.599E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115793669257E+03   -0.29491E-01   -0.87979E+00   656   0.154E+01    0.852E-01
DAV:   2    -0.115803831820E+03   -0.10163E-01   -0.15104E-01   872   0.193E+00    0.501E-01
DAV:   3    -0.115801940015E+03    0.18918E-02   -0.51643E-03   776   0.413E-01    0.255E-01
DAV:   4    -0.115801696439E+03    0.24358E-03   -0.37885E-03   744   0.317E-01    0.517E-02
DAV:   5    -0.115801680343E+03    0.16095E-04   -0.52249E-04   824   0.132E-01    0.388E-02
DAV:   6    -0.115801695000E+03   -0.14657E-04   -0.24641E-04   728   0.900E-02    0.227E-02
DAV:   7    -0.115801708211E+03   -0.13211E-04   -0.36453E-05   792   0.409E-02    0.136E-02
DAV:   8    -0.115801746532E+03   -0.38322E-04   -0.32768E-05   640   0.356E-02    0.560E-03
DAV:   9    -0.115801786124E+03   -0.39591E-04   -0.86648E-06   544   0.186E-02    0.594E-03
DAV:  10    -0.115801840206E+03   -0.54083E-04   -0.11468E-05   512   0.233E-02    0.329E-03
DAV:  11    -0.115801869787E+03   -0.29580E-04   -0.89499E-06   576   0.150E-02    0.399E-03
DAV:  12    -0.115801881519E+03   -0.11732E-04   -0.17365E-06   568   0.778E-03    0.208E-03
DAV:  13    -0.115801891542E+03   -0.10023E-04   -0.24630E-06   544   0.809E-03    0.130E-03
DAV:  14    -0.115801897570E+03   -0.60275E-05   -0.74697E-07   544   0.355E-03 
  22 F= -.11580190E+03 E0= -.11578311E+03  d E =-.377112E-01
 trial-energy change:   -0.037711  1 .order   -0.037818   -0.075241   -0.000394
 step:   0.6027(harm=  0.6027)  dis= 0.03056  next Energy=  -115.802005 (dE=-0.378E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115801901117E+03   -0.95749E-05   -0.24511E-04   752   0.812E-02    0.459E-03
DAV:   2    -0.115801901686E+03   -0.56934E-06   -0.39540E-06   632   0.105E-02 
  23 F= -.11580190E+03 E0= -.11578312E+03  d E =-.377153E-01
 curvature:  -1.44 expect dE=-0.127E+00 dE for cont linesearch -0.224E-09
 trial: gam= 0.70890 g(F)=  0.884E-01 g(S)=  0.000E+00 ort =-0.965E-05 (trialstep = 0.600E+00)
 search vector abs. value=  0.389E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115820435984E+03   -0.18535E-01   -0.75339E+00   640   0.145E+01    0.731E-01
DAV:   2    -0.115833086494E+03   -0.12651E-01   -0.15732E-01   792   0.196E+00    0.460E-01
DAV:   3    -0.115831091416E+03    0.19951E-02   -0.45771E-03   848   0.434E-01    0.254E-01
DAV:   4    -0.115830837754E+03    0.25366E-03   -0.47774E-03   792   0.382E-01    0.670E-02
DAV:   5    -0.115830792063E+03    0.45692E-04   -0.80122E-04   816   0.179E-01    0.383E-02
DAV:   6    -0.115830800608E+03   -0.85452E-05   -0.19579E-04   784   0.707E-02    0.196E-02
DAV:   7    -0.115830804196E+03   -0.35879E-05   -0.18014E-05   568   0.303E-02 
  24 F= -.11583080E+03 E0= -.11581202E+03  d E =-.289025E-01
 trial-energy change:   -0.028903  1 .order   -0.029113   -0.053024   -0.005202
 step:   0.6675(harm=  0.6655)  dis= 0.02777  next Energy=  -115.831095 (dE=-0.292E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115830983858E+03   -0.18325E-03   -0.95231E-02   672   0.164E+00    0.827E-02
DAV:   2    -0.115831145639E+03   -0.16178E-03   -0.20669E-03   832   0.227E-01    0.521E-02
DAV:   3    -0.115831125148E+03    0.20491E-04   -0.65016E-05   840   0.508E-02    0.293E-02
DAV:   4    -0.115831132863E+03   -0.77140E-05   -0.64173E-05   752   0.456E-02 
  25 F= -.11583113E+03 E0= -.11581235E+03  d E =-.292312E-01
 curvature:  -1.46 expect dE=-0.690E-01 dE for cont linesearch -0.146E-05
 trial: gam= 0.54219 g(F)=  0.471E-01 g(S)=  0.000E+00 ort =-0.622E-03 (trialstep = 0.614E+00)
 search vector abs. value=  0.161E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115841185389E+03   -0.10060E-01   -0.37091E+00   640   0.103E+01    0.500E-01
DAV:   2    -0.115847059738E+03   -0.58743E-02   -0.78535E-02   864   0.139E+00    0.310E-01
DAV:   3    -0.115846211637E+03    0.84810E-03   -0.25636E-03   848   0.312E-01    0.168E-01
DAV:   4    -0.115846100887E+03    0.11075E-03   -0.16210E-03   728   0.244E-01    0.413E-02
DAV:   5    -0.115846093266E+03    0.76215E-05   -0.31743E-04   800   0.110E-01    0.252E-02
DAV:   6    -0.115846087644E+03    0.56213E-05   -0.93425E-05   736   0.532E-02 
  26 F= -.11584609E+03 E0= -.11582730E+03  d E =-.149548E-01
 trial-energy change:   -0.014955  1 .order   -0.014903   -0.028688   -0.001118
 step:   0.6382(harm=  0.6385)  dis= 0.01702  next Energy=  -115.846110 (dE=-0.150E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115846103519E+03   -0.10253E-04   -0.60791E-03   760   0.419E-01    0.225E-02
DAV:   2    -0.115846117850E+03   -0.14331E-04   -0.13390E-04   808   0.582E-02    0.131E-02
DAV:   3    -0.115846123089E+03   -0.52388E-05   -0.49793E-06   552   0.196E-02 
  27 F= -.11584612E+03 E0= -.11582734E+03  d E =-.149902E-01
 curvature:  -1.10 expect dE=-0.433E-01 dE for cont linesearch -0.125E-06
 trial: gam= 0.84534 g(F)=  0.394E-01 g(S)=  0.000E+00 ort = 0.135E-03 (trialstep = 0.619E+00)
 search vector abs. value=  0.155E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115855999940E+03   -0.98821E-02   -0.31797E+00   640   0.963E+00    0.489E-01
DAV:   2    -0.115860859413E+03   -0.48595E-02   -0.71736E-02   848   0.131E+00    0.302E-01
DAV:   3    -0.115860107795E+03    0.75162E-03   -0.28365E-03   848   0.320E-01    0.170E-01
DAV:   4    -0.115860048430E+03    0.59365E-04   -0.18200E-03   728   0.235E-01    0.551E-02
DAV:   5    -0.115860020917E+03    0.27513E-04   -0.28645E-04   952   0.122E-01    0.238E-02
DAV:   6    -0.115860027452E+03   -0.65351E-05   -0.12115E-04   736   0.612E-02    0.148E-02
DAV:   7    -0.115860029066E+03   -0.16139E-05   -0.15371E-05   584   0.279E-02 
  28 F= -.11586003E+03 E0= -.11584124E+03  d E =-.139060E-01
 trial-energy change:   -0.013906  1 .order   -0.013890   -0.024469   -0.003312
 step:   0.7154(harm=  0.7154)  dis= 0.01806  next Energy=  -115.860272 (dE=-0.141E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115860205325E+03   -0.17787E-03   -0.78241E-02   656   0.151E+00    0.774E-02
DAV:   2    -0.115860325662E+03   -0.12034E-03   -0.18233E-03   856   0.210E-01    0.467E-02
DAV:   3    -0.115860310219E+03    0.15443E-04   -0.72266E-05   792   0.500E-02    0.269E-02
DAV:   4    -0.115860312640E+03   -0.24217E-05   -0.50993E-05   712   0.396E-02 
  29 F= -.11586031E+03 E0= -.11584153E+03  d E =-.141896E-01
 curvature:  -1.40 expect dE=-0.325E-01 dE for cont linesearch -0.106E-05
 trial: gam= 0.59818 g(F)=  0.232E-01 g(S)=  0.000E+00 ort =-0.342E-03 (trialstep = 0.638E+00)
 search vector abs. value=  0.781E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115862471140E+03   -0.21609E-02   -0.25285E+00   640   0.863E+00    0.506E-01
DAV:   2    -0.115867097581E+03   -0.46264E-02   -0.60220E-02   848   0.121E+00    0.241E-01
DAV:   3    -0.115866410713E+03    0.68687E-03   -0.18346E-03   800   0.263E-01    0.138E-01
DAV:   4    -0.115866289712E+03    0.12100E-03   -0.14610E-03   736   0.230E-01    0.396E-02
DAV:   5    -0.115866284964E+03    0.47482E-05   -0.27359E-04   824   0.103E-01    0.248E-02
DAV:   6    -0.115866284803E+03    0.16062E-06   -0.87081E-05   752   0.489E-02 
  30 F= -.11586628E+03 E0= -.11584750E+03  d E =-.597216E-02
 trial-energy change:   -0.005972  1 .order   -0.005845   -0.014683    0.002994
 step:   0.5337(harm=  0.5299)  dis= 0.00906  next Energy=  -115.866529 (dE=-0.622E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115866419929E+03   -0.13497E-03   -0.67228E-02   656   0.141E+00    0.786E-02
DAV:   2    -0.115866547618E+03   -0.12769E-03   -0.16392E-03   840   0.201E-01    0.401E-02
DAV:   3    -0.115866532554E+03    0.15063E-04   -0.50566E-05   824   0.433E-02    0.235E-02
DAV:   4    -0.115866536626E+03   -0.40717E-05   -0.48807E-05   728   0.409E-02 
  31 F= -.11586654E+03 E0= -.11584775E+03  d E =-.622399E-02
 curvature:  -0.90 expect dE=-0.129E-01 dE for cont linesearch -0.260E-05
 trial: gam= 0.60137 g(F)=  0.144E-01 g(S)=  0.000E+00 ort = 0.475E-03 (trialstep = 0.617E+00)
 search vector abs. value=  0.432E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115870549601E+03   -0.40170E-02   -0.11354E+00   640   0.574E+00    0.249E-01
DAV:   2    -0.115872485353E+03   -0.19358E-02   -0.23355E-02   840   0.751E-01    0.158E-01
DAV:   3    -0.115872277296E+03    0.20806E-03   -0.59986E-04   824   0.148E-01    0.881E-02
DAV:   4    -0.115872262027E+03    0.15269E-04   -0.48603E-04   744   0.130E-01    0.204E-02
DAV:   5    -0.115872264136E+03   -0.21086E-05   -0.88886E-05   872   0.522E-02 
  32 F= -.11587226E+03 E0= -.11585348E+03  d E =-.572751E-02
 trial-energy change:   -0.005728  1 .order   -0.005767   -0.009049   -0.002485
 step:   0.8507(harm=  0.8507)  dis= 0.01013  next Energy=  -115.872774 (dE=-0.624E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115872501605E+03   -0.23958E-03   -0.16288E-01   640   0.217E+00    0.963E-02
DAV:   2    -0.115872790680E+03   -0.28907E-03   -0.34181E-03   840   0.287E-01    0.595E-02
DAV:   3    -0.115872763051E+03    0.27629E-04   -0.80514E-05   808   0.560E-02    0.337E-02
DAV:   4    -0.115872763728E+03   -0.67732E-06   -0.78845E-05   752   0.524E-02 
  33 F= -.11587276E+03 E0= -.11585398E+03  d E =-.622710E-02
 curvature:  -1.25 expect dE=-0.227E-01 dE for cont linesearch -0.128E-05
 trial: gam= 1.27220 g(F)=  0.181E-01 g(S)=  0.000E+00 ort =-0.210E-03 (trialstep = 0.328E+00)
 search vector abs. value=  0.875E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115876716273E+03   -0.39532E-02   -0.55408E-01   640   0.405E+00    0.210E-01
DAV:   2    -0.115877746609E+03   -0.10303E-02   -0.12827E-02   768   0.551E-01    0.114E-01
DAV:   3    -0.115877649528E+03    0.97081E-04   -0.32562E-04   840   0.116E-01    0.673E-02
DAV:   4    -0.115877647578E+03    0.19492E-05   -0.43745E-04   712   0.127E-01    0.225E-02
DAV:   5    -0.115877642684E+03    0.48945E-05   -0.79083E-05   840   0.538E-02 
  34 F= -.11587764E+03 E0= -.11585886E+03  d E =-.487896E-02
 trial-energy change:   -0.004879  1 .order   -0.004798   -0.005851   -0.003745
 step:   0.7153(harm=  0.9102)  dis= 0.01210  next Energy=  -115.879991 (dE=-0.723E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115879191949E+03   -0.15444E-02   -0.77250E-01   640   0.478E+00    0.247E-01
DAV:   2    -0.115880672995E+03   -0.14810E-02   -0.18235E-02   768   0.657E-01    0.134E-01
DAV:   3    -0.115880529098E+03    0.14390E-03   -0.44943E-04   824   0.138E-01    0.801E-02
DAV:   4    -0.115880517892E+03    0.11206E-04   -0.65388E-04   712   0.154E-01    0.285E-02
DAV:   5    -0.115880509339E+03    0.85537E-05   -0.11498E-04   848   0.654E-02    0.223E-02
DAV:   6    -0.115880504662E+03    0.46770E-05   -0.63801E-05   728   0.442E-02 
  35 F= -.11588050E+03 E0= -.11586172E+03  d E =-.774093E-02
 curvature:  -1.98 expect dE=-0.309E-01 dE for cont linesearch -0.260E-03
 ZBRENT: extrapolating
 opt :   0.8789  next Energy=  -115.880782 (dE=-0.802E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115880549640E+03   -0.40301E-04   -0.13793E-01   640   0.202E+00    0.105E-01
DAV:   2    -0.115880814343E+03   -0.26470E-03   -0.32258E-03   800   0.276E-01    0.570E-02
DAV:   3    -0.115880787257E+03    0.27086E-04   -0.75259E-05   808   0.569E-02    0.335E-02
DAV:   4    -0.115880785760E+03    0.14973E-05   -0.10368E-04   736   0.612E-02    0.110E-02
DAV:   5    -0.115880785543E+03    0.21647E-06   -0.18298E-05   688   0.276E-02 
  36 F= -.11588079E+03 E0= -.11586200E+03  d E =-.802181E-02
 curvature:  -2.11 expect dE=-0.478E-01 dE for cont linesearch -0.639E-08
 trial: gam= 1.26098 g(F)=  0.227E-01 g(S)=  0.000E+00 ort =-0.163E-04 (trialstep = 0.237E+00)
 search vector abs. value=  0.162E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115884409653E+03   -0.36239E-02   -0.54590E-01   640   0.397E+00    0.181E-01
DAV:   2    -0.115885331027E+03   -0.92137E-03   -0.11337E-02   824   0.516E-01    0.110E-01
DAV:   3    -0.115885258937E+03    0.72090E-04   -0.29572E-04   792   0.108E-01    0.636E-02
DAV:   4    -0.115885266593E+03   -0.76559E-05   -0.32931E-04   704   0.106E-01    0.202E-02
DAV:   5    -0.115885262354E+03    0.42387E-05   -0.52349E-05   816   0.448E-02 
  37 F= -.11588526E+03 E0= -.11586648E+03  d E =-.447681E-02
 trial-energy change:   -0.004477  1 .order   -0.004442   -0.005362   -0.003522
 step:   0.6905(harm=  0.6905)  dis= 0.01621  next Energy=  -115.888599 (dE=-0.781E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115885613968E+03   -0.34737E-03   -0.19998E+00   640   0.759E+00    0.348E-01
DAV:   2    -0.115888971503E+03   -0.33575E-02   -0.41629E-02   824   0.989E-01    0.211E-01
DAV:   3    -0.115888692840E+03    0.27866E-03   -0.10636E-03   808   0.205E-01    0.122E-01
DAV:   4    -0.115888695894E+03   -0.30545E-05   -0.12132E-03   736   0.202E-01    0.387E-02
DAV:   5    -0.115888676782E+03    0.19112E-04   -0.18768E-04   864   0.842E-02    0.251E-02
DAV:   6    -0.115888674730E+03    0.20515E-05   -0.10236E-04   768   0.559E-02    0.913E-03
DAV:   7    -0.115888675745E+03   -0.10153E-05   -0.70586E-06   576   0.168E-02 
  38 F= -.11588868E+03 E0= -.11586989E+03  d E =-.789020E-02
 curvature:  -2.47 expect dE=-0.411E-01 dE for cont linesearch -0.384E-07
 trial: gam= 0.71440 g(F)=  0.167E-01 g(S)=  0.000E+00 ort = 0.502E-04 (trialstep = 0.328E+00)
 search vector abs. value=  0.993E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115891710005E+03   -0.30353E-02   -0.78764E-01   640   0.478E+00    0.240E-01
DAV:   2    -0.115892998726E+03   -0.12887E-02   -0.16050E-02   776   0.618E-01    0.125E-01
DAV:   3    -0.115892875428E+03    0.12330E-03   -0.48322E-04   856   0.127E-01    0.707E-02
DAV:   4    -0.115892847802E+03    0.27626E-04   -0.31126E-04   752   0.109E-01    0.175E-02
DAV:   5    -0.115892848641E+03   -0.83809E-06   -0.62219E-05   808   0.472E-02 
  39 F= -.11589285E+03 E0= -.11587407E+03  d E =-.417290E-02
 trial-energy change:   -0.004173  1 .order   -0.004167   -0.005473   -0.002861
 step:   0.6866(harm=  0.6866)  dis= 0.01305  next Energy=  -115.894410 (dE=-0.573E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115892999613E+03   -0.15181E-03   -0.94471E-01   640   0.524E+00    0.265E-01
DAV:   2    -0.115894562129E+03   -0.15625E-02   -0.19327E-02   776   0.678E-01    0.137E-01
DAV:   3    -0.115894411832E+03    0.15030E-03   -0.55783E-04   864   0.138E-01    0.773E-02
DAV:   4    -0.115894379137E+03    0.32696E-04   -0.39000E-04   752   0.122E-01    0.196E-02
DAV:   5    -0.115894379853E+03   -0.71631E-06   -0.78704E-05   840   0.536E-02 
  40 F= -.11589438E+03 E0= -.11587560E+03  d E =-.570411E-02
 curvature:  -2.04 expect dE=-0.286E-01 dE for cont linesearch -0.642E-06
 trial: gam= 0.86820 g(F)=  0.140E-01 g(S)=  0.000E+00 ort =-0.177E-03 (trialstep = 0.399E+00)
 search vector abs. value=  0.886E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115896458650E+03   -0.20795E-02   -0.99363E-01   640   0.542E+00    0.243E-01
DAV:   2    -0.115898368657E+03   -0.19100E-02   -0.23327E-02   800   0.730E-01    0.142E-01
DAV:   3    -0.115898234502E+03    0.13415E-03   -0.48248E-04   816   0.130E-01    0.842E-02
DAV:   4    -0.115898213018E+03    0.21485E-04   -0.51362E-04   688   0.143E-01    0.234E-02
DAV:   5    -0.115898211014E+03    0.20036E-05   -0.97541E-05   808   0.584E-02 
  41 F= -.11589821E+03 E0= -.11587943E+03  d E =-.383116E-02
 trial-energy change:   -0.003831  1 .order   -0.003817   -0.005546   -0.002088
 step:   0.6406(harm=  0.6406)  dis= 0.01180  next Energy=  -115.898827 (dE=-0.445E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115898195289E+03    0.17728E-04   -0.36262E-01   640   0.327E+00    0.147E-01
DAV:   2    -0.115898907272E+03   -0.71198E-03   -0.86753E-03   792   0.445E-01    0.856E-02
DAV:   3    -0.115898854680E+03    0.52592E-04   -0.17229E-04   792   0.803E-02    0.515E-02
DAV:   4    -0.115898844643E+03    0.10037E-04   -0.21581E-04   704   0.938E-02    0.159E-02
DAV:   5    -0.115898844497E+03    0.14577E-06   -0.40429E-05   792   0.378E-02 
  42 F= -.11589884E+03 E0= -.11588006E+03  d E =-.446464E-02
 curvature:  -2.04 expect dE=-0.231E-01 dE for cont linesearch -0.509E-07
 trial: gam= 0.77824 g(F)=  0.113E-01 g(S)=  0.000E+00 ort =-0.470E-04 (trialstep = 0.448E+00)
 search vector abs. value=  0.649E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115901122850E+03   -0.22782E-02   -0.89334E-01   640   0.512E+00    0.224E-01
DAV:   2    -0.115902838831E+03   -0.17160E-02   -0.20481E-02   752   0.687E-01    0.140E-01
DAV:   3    -0.115902715358E+03    0.12347E-03   -0.50041E-04   856   0.140E-01    0.850E-02
DAV:   4    -0.115902719593E+03   -0.42352E-05   -0.65816E-04   704   0.155E-01    0.291E-02
DAV:   5    -0.115902709395E+03    0.10199E-04   -0.11137E-04   824   0.678E-02    0.201E-02
DAV:   6    -0.115902709968E+03   -0.57374E-06   -0.67039E-05   712   0.452E-02 
  43 F= -.11590271E+03 E0= -.11588393E+03  d E =-.386547E-02
 trial-energy change:   -0.003865  1 .order   -0.003825   -0.005034   -0.002616
 step:   0.8545(harm=  0.9319)  dis= 0.01385  next Energy=  -115.903929 (dE=-0.508E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115902803210E+03   -0.93815E-04   -0.73828E-01   640   0.466E+00    0.205E-01
DAV:   2    -0.115904207716E+03   -0.14045E-02   -0.16799E-02   760   0.622E-01    0.127E-01
DAV:   3    -0.115904106927E+03    0.10079E-03   -0.41139E-04   864   0.125E-01    0.764E-02
DAV:   4    -0.115904106972E+03   -0.45603E-07   -0.49626E-04   704   0.133E-01    0.250E-02
DAV:   5    -0.115904099086E+03    0.78863E-05   -0.82685E-05   816   0.589E-02 
  44 F= -.11590410E+03 E0= -.11588532E+03  d E =-.525459E-02
 curvature:  -2.62 expect dE=-0.346E-01 dE for cont linesearch -0.328E-04
 trial: gam= 1.13395 g(F)=  0.132E-01 g(S)=  0.000E+00 ort = 0.901E-03 (trialstep = 0.348E+00)
 search vector abs. value=  0.987E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115906499877E+03   -0.23929E-02   -0.87424E-01   640   0.503E+00    0.209E-01
DAV:   2    -0.115907971676E+03   -0.14718E-02   -0.17507E-02   776   0.639E-01    0.133E-01
DAV:   3    -0.115907871104E+03    0.10057E-03   -0.41497E-04   800   0.125E-01    0.766E-02
DAV:   4    -0.115907868981E+03    0.21225E-05   -0.41642E-04   728   0.119E-01    0.213E-02
DAV:   5    -0.115907864497E+03    0.44845E-05   -0.71330E-05   848   0.520E-02 
  45 F= -.11590786E+03 E0= -.11588908E+03  d E =-.376541E-02
 trial-energy change:   -0.003765  1 .order   -0.003728   -0.004953   -0.002504
 step:   0.7034(harm=  0.7034)  dis= 0.01405  next Energy=  -115.909107 (dE=-0.501E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115907790212E+03    0.78769E-04   -0.91441E-01   640   0.514E+00    0.214E-01
DAV:   2    -0.115909323188E+03   -0.15330E-02   -0.18281E-02   792   0.653E-01    0.136E-01
DAV:   3    -0.115909217962E+03    0.10523E-03   -0.43288E-04   880   0.126E-01    0.780E-02
DAV:   4    -0.115909213274E+03    0.46886E-05   -0.41018E-04   728   0.119E-01    0.206E-02
DAV:   5    -0.115909210148E+03    0.31253E-05   -0.71255E-05   848   0.518E-02 
  46 F= -.11590921E+03 E0= -.11589043E+03  d E =-.511106E-02
 curvature:  -2.44 expect dE=-0.305E-01 dE for cont linesearch -0.127E-05
 trial: gam= 1.07871 g(F)=  0.125E-01 g(S)=  0.000E+00 ort = 0.226E-03 (trialstep = 0.323E+00)
 search vector abs. value=  0.128E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115911119839E+03   -0.19066E-02   -0.97701E-01   640   0.533E+00    0.225E-01
DAV:   2    -0.115912827421E+03   -0.17076E-02   -0.19985E-02   752   0.668E-01    0.131E-01
DAV:   3    -0.115912754071E+03    0.73351E-04   -0.46913E-04   856   0.117E-01    0.763E-02
DAV:   4    -0.115912748146E+03    0.59241E-05   -0.31823E-04   704   0.112E-01    0.152E-02
DAV:   5    -0.115912751060E+03   -0.29134E-05   -0.68382E-05   840   0.458E-02 
  47 F= -.11591275E+03 E0= -.11589397E+03  d E =-.354091E-02
 trial-energy change:   -0.003541  1 .order   -0.003505   -0.004126   -0.002885
 step:   1.0753(harm=  1.0753)  dis= 0.02381  next Energy=  -115.916070 (dE=-0.686E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115907536176E+03    0.52120E-02   -0.52785E+00   640   0.124E+01    0.522E-01
DAV:   2    -0.115916755301E+03   -0.92191E-02   -0.10812E-01   752   0.155E+00    0.305E-01
DAV:   3    -0.115916311151E+03    0.44415E-03   -0.26040E-03   856   0.275E-01    0.178E-01
DAV:   4    -0.115916207927E+03    0.10322E-03   -0.16790E-03   728   0.259E-01    0.344E-02
DAV:   5    -0.115916222591E+03   -0.14664E-04   -0.36812E-04   840   0.106E-01    0.300E-02
DAV:   6    -0.115916219260E+03    0.33310E-05   -0.86911E-05   752   0.528E-02 
  48 F= -.11591622E+03 E0= -.11589744E+03  d E =-.700911E-02
 curvature:  -5.39 expect dE=-0.101E+00 dE for cont linesearch -0.603E-05
 trial: gam= 1.39102 g(F)=  0.187E-01 g(S)=  0.000E+00 ort = 0.378E-03 (trialstep = 0.227E+00)
 search vector abs. value=  0.267E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115917934053E+03   -0.17115E-02   -0.10282E+00   640   0.547E+00    0.235E-01
DAV:   2    -0.115919831014E+03   -0.18970E-02   -0.21989E-02   736   0.705E-01    0.133E-01
DAV:   3    -0.115919764097E+03    0.66916E-04   -0.52138E-04   840   0.121E-01    0.775E-02
DAV:   4    -0.115919758282E+03    0.58157E-05   -0.34125E-04   720   0.118E-01    0.170E-02
DAV:   5    -0.115919761944E+03   -0.36627E-05   -0.71643E-05   816   0.483E-02 
  49 F= -.11591976E+03 E0= -.11590098E+03  d E =-.354268E-02
 trial-energy change:   -0.003543  1 .order   -0.003535   -0.004364   -0.002707
 step:   0.5970(harm=  0.5970)  dis= 0.01766  next Energy=  -115.921965 (dE=-0.575E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115917294899E+03    0.24634E-02   -0.27390E+00   640   0.892E+00    0.381E-01
DAV:   2    -0.115922335435E+03   -0.50405E-02   -0.58651E-02   728   0.115E+00    0.215E-01
DAV:   3    -0.115922137734E+03    0.19770E-03   -0.14087E-03   848   0.200E-01    0.127E-01
DAV:   4    -0.115922091829E+03    0.45905E-04   -0.10016E-03   736   0.201E-01    0.309E-02
DAV:   5    -0.115922093238E+03   -0.14093E-05   -0.20165E-04   848   0.826E-02    0.263E-02
DAV:   6    -0.115922090755E+03    0.24829E-05   -0.82256E-05   760   0.523E-02 
  50 F= -.11592209E+03 E0= -.11590331E+03  d E =-.587149E-02
 curvature:  -4.14 expect dE=-0.589E-01 dE for cont linesearch -0.935E-05
 trial: gam= 0.72361 g(F)=  0.142E-01 g(S)=  0.000E+00 ort = 0.776E-03 (trialstep = 0.301E+00)
 search vector abs. value=  0.155E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115923858378E+03   -0.17651E-02   -0.10948E+00   640   0.564E+00    0.232E-01
DAV:   2    -0.115925861445E+03   -0.20031E-02   -0.23413E-02   760   0.732E-01    0.138E-01
DAV:   3    -0.115925775321E+03    0.86123E-04   -0.61890E-04   864   0.137E-01    0.817E-02
DAV:   4    -0.115925775479E+03   -0.15808E-06   -0.50806E-04   712   0.136E-01    0.255E-02
DAV:   5    -0.115925771675E+03    0.38045E-05   -0.84025E-05   792   0.567E-02 
  51 F= -.11592577E+03 E0= -.11590699E+03  d E =-.368092E-02
 trial-energy change:   -0.003681  1 .order   -0.003662   -0.004445   -0.002880
 step:   0.8542(harm=  0.8542)  dis= 0.01732  next Energy=  -115.928402 (dE=-0.631E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115922151224E+03    0.36243E-02   -0.37036E+00   640   0.104E+01    0.425E-01
DAV:   2    -0.115928960722E+03   -0.68095E-02   -0.79710E-02   760   0.135E+00    0.254E-01
DAV:   3    -0.115928641570E+03    0.31915E-03   -0.21257E-03   864   0.256E-01    0.152E-01
DAV:   4    -0.115928621044E+03    0.20526E-04   -0.19004E-03   768   0.262E-01    0.508E-02
DAV:   5    -0.115928597473E+03    0.23571E-04   -0.31097E-04   832   0.110E-01    0.383E-02
DAV:   6    -0.115928589892E+03    0.75817E-05   -0.24740E-04   760   0.893E-02    0.147E-02
DAV:   7    -0.115928589276E+03    0.61604E-06   -0.22244E-05   640   0.311E-02 
  52 F= -.11592859E+03 E0= -.11590981E+03  d E =-.649852E-02
 curvature:  -4.48 expect dE=-0.642E-01 dE for cont linesearch -0.716E-05
 trial: gam= 1.00158 g(F)=  0.143E-01 g(S)=  0.000E+00 ort = 0.498E-03 (trialstep = 0.373E+00)
 search vector abs. value=  0.171E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115929391537E+03   -0.80165E-03   -0.19932E+00   640   0.764E+00    0.314E-01
DAV:   2    -0.115933066223E+03   -0.36747E-02   -0.42293E-02   752   0.977E-01    0.181E-01
DAV:   3    -0.115932906073E+03    0.16015E-03   -0.10296E-03   864   0.168E-01    0.106E-01
DAV:   4    -0.115932849191E+03    0.56882E-04   -0.58062E-04   744   0.161E-01    0.210E-02
DAV:   5    -0.115932858245E+03   -0.90536E-05   -0.14295E-04   816   0.652E-02    0.205E-02
DAV:   6    -0.115932855001E+03    0.32443E-05   -0.38821E-05   704   0.367E-02 
  53 F= -.11593286E+03 E0= -.11591407E+03  d E =-.426572E-02
 trial-energy change:   -0.004266  1 .order   -0.004279   -0.005530   -0.003029
 step:   0.8258(harm=  0.8258)  dis= 0.01777  next Energy=  -115.934703 (dE=-0.611E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115929545922E+03    0.33123E-02   -0.29256E+00   640   0.925E+00    0.382E-01
DAV:   2    -0.115934958356E+03   -0.54124E-02   -0.62199E-02   744   0.118E+00    0.219E-01
DAV:   3    -0.115934715395E+03    0.24296E-03   -0.14863E-03   864   0.202E-01    0.129E-01
DAV:   4    -0.115934622855E+03    0.92541E-04   -0.86075E-04   728   0.197E-01    0.251E-02
DAV:   5    -0.115934635500E+03   -0.12646E-04   -0.21395E-04   840   0.799E-02    0.250E-02
DAV:   6    -0.115934630812E+03    0.46881E-05   -0.56478E-05   768   0.440E-02 
  54 F= -.11593463E+03 E0= -.11591585E+03  d E =-.604154E-02
 curvature:  -4.77 expect dE=-0.878E-01 dE for cont linesearch -0.127E-06
 trial: gam= 1.37057 g(F)=  0.184E-01 g(S)=  0.000E+00 ort = 0.674E-04 (trialstep = 0.233E+00)
 search vector abs. value=  0.340E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115935554297E+03   -0.91880E-03   -0.15436E+00   640   0.672E+00    0.277E-01
DAV:   2    -0.115938468302E+03   -0.29140E-02   -0.32818E-02   736   0.853E-01    0.156E-01
DAV:   3    -0.115938348581E+03    0.11972E-03   -0.70394E-04   824   0.139E-01    0.929E-02
DAV:   4    -0.115938311356E+03    0.37225E-04   -0.48012E-04   720   0.146E-01    0.178E-02
DAV:   5    -0.115938318417E+03   -0.70613E-05   -0.12005E-04   848   0.592E-02    0.180E-02
DAV:   6    -0.115938317109E+03    0.13082E-05   -0.18595E-05   600   0.255E-02 
  55 F= -.11593832E+03 E0= -.11591953E+03  d E =-.368630E-02
 trial-energy change:   -0.003686  1 .order   -0.003708   -0.004320   -0.003097
 step:   0.8245(harm=  0.8245)  dis= 0.02288  next Energy=  -115.942259 (dE=-0.763E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115924488902E+03    0.13830E-01   -0.98902E+00   640   0.170E+01    0.699E-01
DAV:   2    -0.115943241995E+03   -0.18753E-01   -0.21102E-01   712   0.216E+00    0.396E-01
DAV:   3    -0.115942436351E+03    0.80564E-03   -0.46408E-03   832   0.357E-01    0.237E-01
DAV:   4    -0.115942137585E+03    0.29877E-03   -0.32170E-03   744   0.376E-01    0.471E-02
DAV:   5    -0.115942172448E+03   -0.34863E-04   -0.80111E-04   856   0.154E-01    0.468E-02
DAV:   6    -0.115942152722E+03    0.19726E-04   -0.15226E-04   776   0.709E-02    0.233E-02
DAV:   7    -0.115942151120E+03    0.16020E-05   -0.36156E-05   760   0.349E-02 
  56 F= -.11594215E+03 E0= -.11592337E+03  d E =-.752031E-02
 curvature:  -7.57 expect dE=-0.139E+00 dE for cont linesearch -0.542E-05
 trial: gam= 0.90981 g(F)=  0.183E-01 g(S)=  0.000E+00 ort = 0.493E-03 (trialstep = 0.352E+00)
 search vector abs. value=  0.300E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115941661880E+03    0.49084E-03   -0.29718E+00   640   0.927E+00    0.375E-01
DAV:   2    -0.115947349345E+03   -0.56875E-02   -0.64335E-02   728   0.119E+00    0.225E-01
DAV:   3    -0.115947114152E+03    0.23519E-03   -0.13501E-03   848   0.203E-01    0.136E-01
DAV:   4    -0.115947080551E+03    0.33601E-04   -0.13716E-03   744   0.224E-01    0.415E-02
DAV:   5    -0.115947074156E+03    0.63950E-05   -0.24425E-04   848   0.902E-02    0.359E-02
DAV:   6    -0.115947064824E+03    0.93316E-05   -0.11182E-04   760   0.622E-02    0.131E-02
DAV:   7    -0.115947067229E+03   -0.24045E-05   -0.15832E-05   640   0.224E-02 
  57 F= -.11594707E+03 E0= -.11592828E+03  d E =-.491611E-02
 trial-energy change:   -0.004916  1 .order   -0.004958   -0.006601   -0.003314
 step:   0.7775(harm=  0.7062)  dis= 0.02167  next Energy=  -115.949000 (dE=-0.685E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115940889438E+03    0.61754E-02   -0.43611E+00   640   0.112E+01    0.455E-01
DAV:   2    -0.115949262935E+03   -0.83735E-02   -0.94966E-02   728   0.144E+00    0.274E-01
DAV:   3    -0.115948891668E+03    0.37127E-03   -0.20080E-03   848   0.248E-01    0.166E-01
DAV:   4    -0.115948832010E+03    0.59658E-04   -0.20803E-03   728   0.275E-01    0.516E-02
DAV:   5    -0.115948818479E+03    0.13531E-04   -0.36526E-04   840   0.111E-01    0.444E-02
DAV:   6    -0.115948799212E+03    0.19267E-04   -0.17528E-04   752   0.786E-02    0.160E-02
DAV:   7    -0.115948799884E+03   -0.67249E-06   -0.26214E-05   648   0.281E-02 
  58 F= -.11594880E+03 E0= -.11593002E+03  d E =-.664876E-02
 curvature:  -5.42 expect dE=-0.119E+00 dE for cont linesearch -0.254E-04
 trial: gam= 1.25273 g(F)=  0.219E-01 g(S)=  0.000E+00 ort =-0.119E-02 (trialstep = 0.268E+00)
 search vector abs. value=  0.490E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115948300171E+03    0.49904E-03   -0.28724E+00   640   0.911E+00    0.359E-01
DAV:   2    -0.115953676744E+03   -0.53766E-02   -0.61109E-02   760   0.115E+00    0.217E-01
DAV:   3    -0.115953438785E+03    0.23796E-03   -0.13417E-03   856   0.201E-01    0.129E-01
DAV:   4    -0.115953390232E+03    0.48552E-04   -0.11001E-03   752   0.202E-01    0.342E-02
DAV:   5    -0.115953385058E+03    0.51747E-05   -0.21366E-04   848   0.874E-02    0.272E-02
DAV:   6    -0.115953381830E+03    0.32273E-05   -0.97951E-05   744   0.565E-02 
  59 F= -.11595338E+03 E0= -.11593460E+03  d E =-.458195E-02
 trial-energy change:   -0.004582  1 .order   -0.004631   -0.005459   -0.003803
 step:   0.8820(harm=  0.8820)  dis= 0.03307  next Energy=  -115.957795 (dE=-0.900E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115930110029E+03    0.23275E-01   -0.15110E+01   640   0.209E+01    0.830E-01
DAV:   2    -0.115958836997E+03   -0.28727E-01   -0.32714E-01   752   0.266E+00    0.497E-01
DAV:   3    -0.115957601622E+03    0.12354E-02   -0.72080E-03   856   0.463E-01    0.298E-01
DAV:   4    -0.115957303802E+03    0.29782E-03   -0.59629E-03   792   0.477E-01    0.810E-02
DAV:   5    -0.115957268959E+03    0.34844E-04   -0.11639E-03   808   0.202E-01    0.662E-02
DAV:   6    -0.115957237267E+03    0.31691E-04   -0.52389E-04   768   0.130E-01    0.260E-02
DAV:   7    -0.115957236199E+03    0.10680E-05   -0.49940E-05   656   0.439E-02 
  60 F= -.11595724E+03 E0= -.11593846E+03  d E =-.843631E-02
 curvature: -10.60 expect dE=-0.330E+00 dE for cont linesearch -0.277E-04
 trial: gam= 1.26457 g(F)=  0.311E-01 g(S)=  0.000E+00 ort =-0.113E-02 (trialstep = 0.236E+00)
 search vector abs. value=  0.813E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115955957806E+03    0.12795E-02   -0.39813E+00   640   0.108E+01    0.429E-01
DAV:   2    -0.115963497879E+03   -0.75401E-02   -0.84751E-02   744   0.136E+00    0.245E-01
DAV:   3    -0.115963185965E+03    0.31191E-03   -0.17660E-03   864   0.222E-01    0.146E-01
DAV:   4    -0.115963044505E+03    0.14146E-03   -0.10279E-03   736   0.219E-01    0.227E-02
DAV:   5    -0.115963068840E+03   -0.24335E-04   -0.31209E-04   856   0.922E-02    0.250E-02
DAV:   6    -0.115963064589E+03    0.42517E-05   -0.19941E-05   560   0.277E-02 
  61 F= -.11596306E+03 E0= -.11594428E+03  d E =-.582839E-02
 trial-energy change:   -0.005828  1 .order   -0.005795   -0.006988   -0.004602
 step:   0.6903(harm=  0.6903)  dis= 0.03491  next Energy=  -115.967469 (dE=-0.102E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115940736387E+03    0.22332E-01   -0.14789E+01   640   0.207E+01    0.828E-01
DAV:   2    -0.115968999308E+03   -0.28263E-01   -0.31819E-01   744   0.263E+00    0.471E-01
DAV:   3    -0.115967876945E+03    0.11224E-02   -0.66651E-03   864   0.428E-01    0.282E-01
DAV:   4    -0.115967296171E+03    0.58077E-03   -0.38232E-03   768   0.423E-01    0.440E-02
DAV:   5    -0.115967376947E+03   -0.80777E-04   -0.11412E-03   848   0.177E-01    0.492E-02
DAV:   6    -0.115967355527E+03    0.21420E-04   -0.96943E-05   768   0.574E-02    0.288E-02
DAV:   7    -0.115967349223E+03    0.63043E-05   -0.30488E-05   688   0.340E-02 
  62 F= -.11596735E+03 E0= -.11594857E+03  d E =-.101130E-01
 curvature:  -9.46 expect dE=-0.212E+00 dE for cont linesearch -0.342E-06
 trial: gam= 0.60416 g(F)=  0.224E-01 g(S)=  0.000E+00 ort =-0.171E-03 (trialstep = 0.327E+00)
 search vector abs. value=  0.319E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115966858364E+03    0.49716E-03   -0.31130E+00   640   0.952E+00    0.376E-01
DAV:   2    -0.115972923646E+03   -0.60653E-02   -0.68075E-02   744   0.123E+00    0.218E-01
DAV:   3    -0.115972645193E+03    0.27845E-03   -0.13766E-03   864   0.196E-01    0.131E-01
DAV:   4    -0.115972540229E+03    0.10496E-03   -0.93281E-04   760   0.203E-01    0.231E-02
DAV:   5    -0.115972562897E+03   -0.22668E-04   -0.26178E-04   816   0.853E-02    0.237E-02
DAV:   6    -0.115972564325E+03   -0.14279E-05   -0.28177E-05   632   0.308E-02 
  63 F= -.11597256E+03 E0= -.11595378E+03  d E =-.521510E-02
 trial-energy change:   -0.005215  1 .order   -0.005237   -0.007293   -0.003182
 step:   0.5794(harm=  0.5794)  dis= 0.01836  next Energy=  -115.973818 (dE=-0.647E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115970398828E+03    0.21641E-02   -0.18667E+00   640   0.737E+00    0.295E-01
DAV:   2    -0.115974030900E+03   -0.36321E-02   -0.41000E-02   744   0.953E-01    0.168E-01
DAV:   3    -0.115973885022E+03    0.14588E-03   -0.82605E-04   864   0.152E-01    0.101E-01
DAV:   4    -0.115973828545E+03    0.56477E-04   -0.54530E-04   776   0.156E-01    0.181E-02
DAV:   5    -0.115973841685E+03   -0.13139E-04   -0.15281E-04   816   0.656E-02    0.184E-02
DAV:   6    -0.115973842648E+03   -0.96298E-06   -0.16702E-05   560   0.241E-02 
  64 F= -.11597384E+03 E0= -.11595506E+03  d E =-.649342E-02
 curvature:  -4.14 expect dE=-0.648E-01 dE for cont linesearch -0.622E-06
 trial: gam= 0.67928 g(F)=  0.157E-01 g(S)=  0.000E+00 ort = 0.219E-03 (trialstep = 0.377E+00)
 search vector abs. value=  0.163E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115974624242E+03   -0.78256E-03   -0.20630E+00   640   0.777E+00    0.329E-01
DAV:   2    -0.115978891720E+03   -0.42675E-02   -0.47866E-02   760   0.103E+00    0.181E-01
DAV:   3    -0.115978725516E+03    0.16620E-03   -0.96657E-04   848   0.179E-01    0.110E-01
DAV:   4    -0.115978711869E+03    0.13646E-04   -0.10469E-03   768   0.202E-01    0.363E-02
DAV:   5    -0.115978704216E+03    0.76536E-05   -0.20114E-04   856   0.838E-02    0.303E-02
DAV:   6    -0.115978698110E+03    0.61061E-05   -0.10146E-04   760   0.580E-02    0.999E-03
DAV:   7    -0.115978699295E+03   -0.11857E-05   -0.10500E-05   624   0.183E-02 
  65 F= -.11597870E+03 E0= -.11595992E+03  d E =-.485665E-02
 trial-energy change:   -0.004857  1 .order   -0.004845   -0.005965   -0.003724
 step:   1.0038(harm=  1.0038)  dis= 0.02293  next Energy=  -115.981780 (dE=-0.794E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115970760312E+03    0.79378E-02   -0.56894E+00   640   0.129E+01    0.545E-01
DAV:   2    -0.115982515963E+03   -0.11756E-01   -0.13178E-01   752   0.171E+00    0.301E-01
DAV:   3    -0.115982031329E+03    0.48463E-03   -0.27243E-03   864   0.299E-01    0.184E-01
DAV:   4    -0.115981956656E+03    0.74672E-04   -0.29375E-03   816   0.339E-01    0.609E-02
DAV:   5    -0.115981928709E+03    0.27947E-04   -0.55634E-04   808   0.141E-01    0.492E-02
DAV:   6    -0.115981911233E+03    0.17476E-04   -0.29112E-04   760   0.975E-02    0.168E-02
DAV:   7    -0.115981912047E+03   -0.81408E-06   -0.28683E-05   664   0.300E-02 
  66 F= -.11598191E+03 E0= -.11596313E+03  d E =-.806940E-02
 curvature:  -5.17 expect dE=-0.787E-01 dE for cont linesearch -0.502E-05
 trial: gam= 1.04290 g(F)=  0.152E-01 g(S)=  0.000E+00 ort = 0.398E-03 (trialstep = 0.424E+00)
 search vector abs. value=  0.193E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115979617780E+03    0.22935E-02   -0.32328E+00   640   0.979E+00    0.416E-01
DAV:   2    -0.115986446331E+03   -0.68286E-02   -0.76076E-02   768   0.130E+00    0.218E-01
DAV:   3    -0.115986164406E+03    0.28192E-03   -0.15121E-03   856   0.224E-01    0.134E-01
DAV:   4    -0.115986090676E+03    0.73731E-04   -0.14016E-03   760   0.250E-01    0.358E-02
DAV:   5    -0.115986092367E+03   -0.16914E-05   -0.34200E-04   840   0.107E-01    0.317E-02
DAV:   6    -0.115986083101E+03    0.92664E-05   -0.10546E-04   744   0.583E-02    0.127E-02
DAV:   7    -0.115986082935E+03    0.16540E-06   -0.10174E-05   632   0.190E-02 
  67 F= -.11598608E+03 E0= -.11596730E+03  d E =-.417089E-02
 trial-energy change:   -0.004171  1 .order   -0.004143   -0.006616   -0.001669
 step:   0.5667(harm=  0.5667)  dis= 0.01698  next Energy=  -115.986336 (dE=-0.442E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115985628143E+03    0.45496E-03   -0.36844E-01   640   0.331E+00    0.140E-01
DAV:   2    -0.115986401267E+03   -0.77312E-03   -0.86570E-03   768   0.438E-01    0.734E-02
DAV:   3    -0.115986367671E+03    0.33596E-04   -0.17359E-04   872   0.758E-02    0.450E-02
DAV:   4    -0.115986357284E+03    0.10387E-04   -0.15546E-04   752   0.852E-02    0.114E-02
DAV:   5    -0.115986359216E+03   -0.19319E-05   -0.41502E-05   848   0.368E-02 
  68 F= -.11598636E+03 E0= -.11596758E+03  d E =-.444717E-02
 curvature:  -3.51 expect dE=-0.267E-01 dE for cont linesearch -0.689E-06
 trial: gam= 0.57057 g(F)=  0.760E-02 g(S)=  0.000E+00 ort =-0.195E-03 (trialstep = 0.452E+00)
 search vector abs. value=  0.703E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115986246739E+03    0.11054E-03   -0.13692E+00   640   0.634E+00    0.250E-01
DAV:   2    -0.115988936234E+03   -0.26895E-02   -0.30048E-02   736   0.814E-01    0.141E-01
DAV:   3    -0.115988824499E+03    0.11173E-03   -0.63384E-04   848   0.136E-01    0.851E-02
DAV:   4    -0.115988787072E+03    0.37428E-04   -0.43845E-04   768   0.142E-01    0.175E-02
DAV:   5    -0.115988794128E+03   -0.70568E-05   -0.12591E-04   832   0.610E-02    0.167E-02
DAV:   6    -0.115988792590E+03    0.15388E-05   -0.14724E-05   568   0.229E-02 
  69 F= -.11598879E+03 E0= -.11597001E+03  d E =-.243337E-02
 trial-energy change:   -0.002433  1 .order   -0.002426   -0.003389   -0.001463
 step:   0.7959(harm=  0.7959)  dis= 0.01242  next Energy=  -115.989341 (dE=-0.298E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115987901555E+03    0.89257E-03   -0.79130E-01   640   0.482E+00    0.190E-01
DAV:   2    -0.115989460886E+03   -0.15593E-02   -0.17448E-02   744   0.621E-01    0.108E-01
DAV:   3    -0.115989393028E+03    0.67858E-04   -0.36566E-04   848   0.103E-01    0.651E-02
DAV:   4    -0.115989370122E+03    0.22906E-04   -0.25341E-04   760   0.107E-01    0.131E-02
DAV:   5    -0.115989374758E+03   -0.46356E-05   -0.72792E-05   816   0.464E-02 
  70 F= -.11598937E+03 E0= -.11597059E+03  d E =-.301554E-02
 curvature:  -3.74 expect dE=-0.346E-01 dE for cont linesearch -0.743E-06
 trial: gam= 1.14295 g(F)=  0.926E-02 g(S)=  0.000E+00 ort = 0.118E-03 (trialstep = 0.361E+00)
 search vector abs. value=  0.101E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115989634509E+03   -0.26439E-03   -0.12834E+00   640   0.612E+00    0.250E-01
DAV:   2    -0.115992140087E+03   -0.25056E-02   -0.28447E-02   744   0.787E-01    0.134E-01
DAV:   3    -0.115992062142E+03    0.77945E-04   -0.57770E-04   832   0.127E-01    0.809E-02
DAV:   4    -0.115992035016E+03    0.27126E-04   -0.38552E-04   704   0.128E-01    0.163E-02
DAV:   5    -0.115992040121E+03   -0.51056E-05   -0.98372E-05   840   0.543E-02 
  71 F= -.11599204E+03 E0= -.11597326E+03  d E =-.266536E-02
 trial-energy change:   -0.002665  1 .order   -0.002646   -0.003395   -0.001896
 step:   0.8187(harm=  0.8187)  dis= 0.01268  next Energy=  -115.993220 (dE=-0.385E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115989390978E+03    0.26440E-02   -0.20558E+00   640   0.775E+00    0.317E-01
DAV:   2    -0.115993414156E+03   -0.40232E-02   -0.45777E-02   744   0.998E-01    0.169E-01
DAV:   3    -0.115993282115E+03    0.13204E-03   -0.92812E-04   848   0.161E-01    0.102E-01
DAV:   4    -0.115993220215E+03    0.61901E-04   -0.62624E-04   712   0.163E-01    0.214E-02
DAV:   5    -0.115993227996E+03   -0.77814E-05   -0.16009E-04   864   0.697E-02    0.208E-02
DAV:   6    -0.115993226258E+03    0.17381E-05   -0.29033E-05   696   0.314E-02 
  72 F= -.11599323E+03 E0= -.11597444E+03  d E =-.385150E-02
 curvature:  -4.42 expect dE=-0.504E-01 dE for cont linesearch -0.585E-06
 trial: gam= 1.27229 g(F)=  0.114E-01 g(S)=  0.000E+00 ort = 0.116E-03 (trialstep = 0.261E+00)
 search vector abs. value=  0.176E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115993608300E+03   -0.38030E-03   -0.11138E+00   640   0.570E+00    0.223E-01
DAV:   2    -0.115995813877E+03   -0.22056E-02   -0.24801E-02   760   0.727E-01    0.126E-01
DAV:   3    -0.115995756464E+03    0.57413E-04   -0.49666E-04   856   0.119E-01    0.764E-02
DAV:   4    -0.115995751621E+03    0.48429E-05   -0.36379E-04   704   0.120E-01    0.179E-02
DAV:   5    -0.115995754890E+03   -0.32689E-05   -0.82526E-05   832   0.506E-02 
  73 F= -.11599575E+03 E0= -.11597697E+03  d E =-.252863E-02
 trial-energy change:   -0.002529  1 .order   -0.002513   -0.003018   -0.002009
 step:   0.7815(harm=  0.7815)  dis= 0.01755  next Energy=  -115.997742 (dE=-0.452E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115989406175E+03    0.63454E-02   -0.44164E+00   640   0.114E+01    0.445E-01
DAV:   2    -0.115998167565E+03   -0.87614E-02   -0.99132E-02   760   0.145E+00    0.250E-01
DAV:   3    -0.115997918074E+03    0.24949E-03   -0.19919E-03   856   0.238E-01    0.153E-01
DAV:   4    -0.115997877351E+03    0.40722E-04   -0.15497E-03   768   0.248E-01    0.386E-02
DAV:   5    -0.115997878301E+03   -0.94943E-06   -0.33843E-04   832   0.103E-01    0.322E-02
DAV:   6    -0.115997873190E+03    0.51109E-05   -0.96768E-05   768   0.539E-02 
  74 F= -.11599787E+03 E0= -.11597909E+03  d E =-.464693E-02
 curvature:  -5.95 expect dE=-0.637E-01 dE for cont linesearch -0.780E-05
 trial: gam= 0.84445 g(F)=  0.107E-01 g(S)=  0.000E+00 ort = 0.480E-03 (trialstep = 0.365E+00)
 search vector abs. value=  0.137E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115997764847E+03    0.11345E-03   -0.16199E+00   640   0.688E+00    0.283E-01
DAV:   2    -0.116000972121E+03   -0.32073E-02   -0.35963E-02   760   0.880E-01    0.156E-01
DAV:   3    -0.116000865857E+03    0.10626E-03   -0.68957E-04   824   0.145E-01    0.945E-02
DAV:   4    -0.116000839664E+03    0.26193E-04   -0.56115E-04   696   0.153E-01    0.227E-02
DAV:   5    -0.116000840178E+03   -0.51347E-06   -0.13009E-04   864   0.667E-02    0.186E-02
DAV:   6    -0.116000839017E+03    0.11608E-05   -0.31850E-05   688   0.321E-02 
  75 F= -.11600084E+03 E0= -.11598206E+03  d E =-.296583E-02
 trial-energy change:   -0.002966  1 .order   -0.002995   -0.004058   -0.001931
 step:   0.6969(harm=  0.6969)  dis= 0.01563  next Energy=  -116.001745 (dE=-0.387E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.115999189768E+03    0.16504E-02   -0.13363E+00   640   0.625E+00    0.256E-01
DAV:   2    -0.116001826323E+03   -0.26366E-02   -0.29632E-02   752   0.799E-01    0.142E-01
DAV:   3    -0.116001727899E+03    0.98424E-04   -0.57249E-04   848   0.132E-01    0.862E-02
DAV:   4    -0.116001696438E+03    0.31461E-04   -0.47228E-04   752   0.140E-01    0.209E-02
DAV:   5    -0.116001697048E+03   -0.61006E-06   -0.10943E-04   848   0.614E-02    0.169E-02
DAV:   6    -0.116001696610E+03    0.43850E-06   -0.26549E-05   704   0.294E-02 
  76 F= -.11600170E+03 E0= -.11598292E+03  d E =-.382342E-02
 curvature:  -4.29 expect dE=-0.445E-01 dE for cont linesearch -0.107E-07
 trial: gam= 0.99854 g(F)=  0.104E-01 g(S)=  0.000E+00 ort = 0.184E-04 (trialstep = 0.402E+00)
 search vector abs. value=  0.147E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116001165387E+03    0.53166E-03   -0.19999E+00   640   0.765E+00    0.306E-01
DAV:   2    -0.116004957157E+03   -0.37918E-02   -0.43112E-02   776   0.967E-01    0.180E-01
DAV:   3    -0.116004801376E+03    0.15578E-03   -0.87516E-04   864   0.163E-01    0.108E-01
DAV:   4    -0.116004773264E+03    0.28112E-04   -0.59016E-04   736   0.151E-01    0.198E-02
DAV:   5    -0.116004779461E+03   -0.61964E-05   -0.13679E-04   848   0.650E-02    0.156E-02
DAV:   6    -0.116004780077E+03   -0.61619E-06   -0.12536E-05   560   0.202E-02 
  77 F= -.11600478E+03 E0= -.11598600E+03  d E =-.308347E-02
 trial-energy change:   -0.003083  1 .order   -0.003067   -0.004178   -0.001957
 step:   0.7565(harm=  0.7565)  dis= 0.01580  next Energy=  -116.005626 (dE=-0.393E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116002849524E+03    0.19299E-02   -0.15523E+00   640   0.674E+00    0.270E-01
DAV:   2    -0.116005782348E+03   -0.29328E-02   -0.33473E-02   776   0.852E-01    0.158E-01
DAV:   3    -0.116005665860E+03    0.11649E-03   -0.67550E-04   872   0.143E-01    0.948E-02
DAV:   4    -0.116005640675E+03    0.25185E-04   -0.46035E-04   736   0.134E-01    0.176E-02
DAV:   5    -0.116005645577E+03   -0.49019E-05   -0.10662E-04   864   0.573E-02    0.140E-02
DAV:   6    -0.116005646714E+03   -0.11370E-05   -0.10109E-05   576   0.183E-02 
  78 F= -.11600565E+03 E0= -.11598686E+03  d E =-.395010E-02
 curvature:  -5.35 expect dE=-0.416E-01 dE for cont linesearch -0.410E-08
 trial: gam= 0.76618 g(F)=  0.778E-02 g(S)=  0.000E+00 ort = 0.106E-04 (trialstep = 0.473E+00)
 search vector abs. value=  0.941E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116005180965E+03    0.46461E-03   -0.16019E+00   640   0.686E+00    0.292E-01
DAV:   2    -0.116008203943E+03   -0.30230E-02   -0.34562E-02   744   0.869E-01    0.166E-01
DAV:   3    -0.116008075232E+03    0.12871E-03   -0.74952E-04   840   0.148E-01    0.969E-02
DAV:   4    -0.116008043480E+03    0.31753E-04   -0.44851E-04   752   0.131E-01    0.173E-02
DAV:   5    -0.116008048438E+03   -0.49583E-05   -0.10511E-04   808   0.562E-02    0.134E-02
DAV:   6    -0.116008048979E+03   -0.54062E-06   -0.70692E-06   576   0.142E-02 
  79 F= -.11600805E+03 E0= -.11598927E+03  d E =-.240226E-02
 trial-energy change:   -0.002402  1 .order   -0.002390   -0.003684   -0.001096
 step:   0.6734(harm=  0.6734)  dis= 0.01217  next Energy=  -116.008269 (dE=-0.262E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116007782133E+03    0.26631E-03   -0.28789E-01   640   0.291E+00    0.124E-01
DAV:   2    -0.116008327743E+03   -0.54561E-03   -0.62326E-03   768   0.369E-01    0.705E-02
DAV:   3    -0.116008304997E+03    0.22746E-04   -0.13357E-04   848   0.628E-02    0.411E-02
DAV:   4    -0.116008301096E+03    0.39006E-05   -0.80445E-05   776   0.564E-02 
  80 F= -.11600830E+03 E0= -.11598952E+03  d E =-.265438E-02
 curvature:  -4.07 expect dE=-0.270E-01 dE for cont linesearch -0.486E-05
 trial: gam= 0.84208 g(F)=  0.664E-02 g(S)=  0.000E+00 ort =-0.335E-03 (trialstep = 0.513E+00)
 search vector abs. value=  0.728E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116007889578E+03    0.41542E-03   -0.13776E+00   640   0.635E+00    0.268E-01
DAV:   2    -0.116010537417E+03   -0.26478E-02   -0.30658E-02   792   0.818E-01    0.158E-01
DAV:   3    -0.116010413479E+03    0.12394E-03   -0.76317E-04   848   0.153E-01    0.905E-02
DAV:   4    -0.116010394207E+03    0.19272E-04   -0.29610E-04   736   0.103E-01    0.185E-02
DAV:   5    -0.116010400869E+03   -0.66619E-05   -0.68980E-05   816   0.433E-02 
  81 F= -.11601040E+03 E0= -.11599162E+03  d E =-.209977E-02
 trial-energy change:   -0.002100  1 .order   -0.002015   -0.003264   -0.000767
 step:   0.6389(harm=  0.6707)  dis= 0.01174  next Energy=  -116.010496 (dE=-0.220E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116010353157E+03    0.41050E-04   -0.82742E-02   656   0.156E+00    0.671E-02
DAV:   2    -0.116010516162E+03   -0.16301E-03   -0.18691E-03   816   0.202E-01    0.377E-02
DAV:   3    -0.116010510752E+03    0.54095E-05   -0.40423E-05   784   0.362E-02 
  82 F= -.11601051E+03 E0= -.11599173E+03  d E =-.220966E-02
 curvature:  -3.68 expect dE=-0.178E-01 dE for cont linesearch -0.137E-05
 trial: gam= 0.71760 g(F)=  0.484E-02 g(S)=  0.000E+00 ort = 0.164E-03 (trialstep = 0.538E+00)
 search vector abs. value=  0.426E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116011102994E+03   -0.58683E-03   -0.87014E-01   640   0.503E+00    0.221E-01
DAV:   2    -0.116012583927E+03   -0.14809E-02   -0.17914E-02   768   0.634E-01    0.129E-01
DAV:   3    -0.116012496416E+03    0.87511E-04   -0.46160E-04   872   0.122E-01    0.725E-02
DAV:   4    -0.116012486844E+03    0.95714E-05   -0.23753E-04   712   0.878E-02    0.147E-02
DAV:   5    -0.116012489204E+03   -0.23595E-05   -0.51256E-05   832   0.414E-02 
  83 F= -.11601249E+03 E0= -.11599371E+03  d E =-.197845E-02
 trial-energy change:   -0.001978  1 .order   -0.001966   -0.002669   -0.001263
 step:   1.0218(harm=  1.0218)  dis= 0.01101  next Energy=  -116.013044 (dE=-0.253E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116011867497E+03    0.61935E-03   -0.70468E-01   640   0.453E+00    0.199E-01
DAV:   2    -0.116013100671E+03   -0.12332E-02   -0.14794E-02   768   0.576E-01    0.115E-01
DAV:   3    -0.116013031943E+03    0.68728E-04   -0.37084E-04   880   0.109E-01    0.651E-02
DAV:   4    -0.116013022963E+03    0.89809E-05   -0.19354E-04   712   0.793E-02    0.132E-02
DAV:   5    -0.116013025303E+03   -0.23400E-05   -0.41713E-05   816   0.373E-02 
  84 F= -.11601303E+03 E0= -.11599424E+03  d E =-.251455E-02
 curvature:  -4.38 expect dE=-0.354E-01 dE for cont linesearch -0.690E-06
 trial: gam= 1.75142 g(F)=  0.807E-02 g(S)=  0.000E+00 ort =-0.818E-04 (trialstep = 0.195E+00)
 search vector abs. value=  0.138E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116013729049E+03   -0.70609E-03   -0.38384E-01   640   0.335E+00    0.145E-01
DAV:   2    -0.116014394284E+03   -0.66524E-03   -0.78907E-03   744   0.418E-01    0.822E-02
DAV:   3    -0.116014368718E+03    0.25566E-04   -0.17352E-04   848   0.746E-02    0.475E-02
DAV:   4    -0.116014370683E+03   -0.19644E-05   -0.11124E-04   728   0.618E-02    0.933E-03
DAV:   5    -0.116014371693E+03   -0.10098E-05   -0.21244E-05   680   0.288E-02 
  85 F= -.11601437E+03 E0= -.11599559E+03  d E =-.134639E-02
 trial-energy change:   -0.001346  1 .order   -0.001329   -0.001548   -0.001111
 step:   0.6918(harm=  0.6918)  dis= 0.01376  next Energy=  -116.015766 (dE=-0.274E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116011837984E+03    0.25327E-02   -0.24795E+00   640   0.851E+00    0.366E-01
DAV:   2    -0.116016126999E+03   -0.42890E-02   -0.51327E-02   744   0.106E+00    0.210E-01
DAV:   3    -0.116015935613E+03    0.19139E-03   -0.11381E-03   872   0.193E-01    0.123E-01
DAV:   4    -0.116015912653E+03    0.22960E-04   -0.79699E-04   744   0.166E-01    0.255E-02
DAV:   5    -0.116015910918E+03    0.17352E-05   -0.15897E-04   808   0.768E-02    0.165E-02
DAV:   6    -0.116015913045E+03   -0.21271E-05   -0.32279E-05   744   0.289E-02 
  86 F= -.11601591E+03 E0= -.11599713E+03  d E =-.288774E-02
 curvature:  -6.04 expect dE=-0.425E-01 dE for cont linesearch -0.794E-05
 trial: gam= 0.72709 g(F)=  0.703E-02 g(S)=  0.000E+00 ort = 0.426E-03 (trialstep = 0.295E+00)
 search vector abs. value=  0.808E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116016725548E+03   -0.81463E-03   -0.52697E-01   640   0.393E+00    0.168E-01
DAV:   2    -0.116017673121E+03   -0.94757E-03   -0.11231E-02   768   0.497E-01    0.984E-02
DAV:   3    -0.116017628368E+03    0.44753E-04   -0.27100E-04   800   0.906E-02    0.567E-02
DAV:   4    -0.116017624123E+03    0.42456E-05   -0.16059E-04   736   0.756E-02    0.117E-02
DAV:   5    -0.116017625240E+03   -0.11175E-05   -0.34000E-05   784   0.347E-02 
  87 F= -.11601763E+03 E0= -.11599885E+03  d E =-.171219E-02
 trial-energy change:   -0.001712  1 .order   -0.001697   -0.002163   -0.001232
 step:   0.6844(harm=  0.6844)  dis= 0.00985  next Energy=  -116.018425 (dE=-0.251E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116016929091E+03    0.69503E-03   -0.92185E-01   640   0.519E+00    0.220E-01
DAV:   2    -0.116018588750E+03   -0.16597E-02   -0.19699E-02   776   0.658E-01    0.130E-01
DAV:   3    -0.116018501767E+03    0.86983E-04   -0.45116E-04   856   0.118E-01    0.757E-02
DAV:   4    -0.116018487094E+03    0.14672E-04   -0.30706E-04   768   0.103E-01    0.161E-02
DAV:   5    -0.116018487641E+03   -0.54633E-06   -0.63334E-05   856   0.474E-02 
  88 F= -.11601849E+03 E0= -.11599971E+03  d E =-.257460E-02
 curvature:  -3.77 expect dE=-0.170E-01 dE for cont linesearch -0.116E-05
 trial: gam= 0.70028 g(F)=  0.451E-02 g(S)=  0.000E+00 ort = 0.158E-03 (trialstep = 0.373E+00)
 search vector abs. value=  0.443E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116018909825E+03   -0.42273E-03   -0.50279E-01   640   0.383E+00    0.163E-01
DAV:   2    -0.116019813337E+03   -0.90351E-03   -0.10726E-02   760   0.487E-01    0.940E-02
DAV:   3    -0.116019772447E+03    0.40890E-04   -0.24244E-04   832   0.838E-02    0.544E-02
DAV:   4    -0.116019760532E+03    0.11915E-04   -0.13544E-04   712   0.703E-02    0.892E-03
DAV:   5    -0.116019762449E+03   -0.19173E-05   -0.28427E-05   696   0.306E-02 
  89 F= -.11601976E+03 E0= -.11600098E+03  d E =-.127481E-02
 trial-energy change:   -0.001275  1 .order   -0.001262   -0.001721   -0.000804
 step:   0.6994(harm=  0.6994)  dis= 0.00702  next Energy=  -116.020102 (dE=-0.161E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116019488998E+03    0.27153E-03   -0.38698E-01   640   0.336E+00    0.143E-01
DAV:   2    -0.116020182012E+03   -0.69301E-03   -0.82429E-03   768   0.427E-01    0.824E-02
DAV:   3    -0.116020148516E+03    0.33496E-04   -0.18697E-04   848   0.736E-02    0.477E-02
DAV:   4    -0.116020137563E+03    0.10953E-04   -0.10357E-04   736   0.614E-02    0.786E-03
DAV:   5    -0.116020139448E+03   -0.18852E-05   -0.21949E-05   728   0.270E-02 
  90 F= -.11602014E+03 E0= -.11600136E+03  d E =-.165181E-02
 curvature:  -3.36 expect dE=-0.170E-01 dE for cont linesearch -0.264E-06
 trial: gam= 1.09631 g(F)=  0.505E-02 g(S)=  0.000E+00 ort = 0.591E-04 (trialstep = 0.332E+00)
 search vector abs. value=  0.585E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116020663140E+03   -0.52558E-03   -0.53100E-01   640   0.394E+00    0.164E-01
DAV:   2    -0.116021615395E+03   -0.95225E-03   -0.11184E-02   760   0.496E-01    0.965E-02
DAV:   3    -0.116021572936E+03    0.42459E-04   -0.24175E-04   864   0.859E-02    0.564E-02
DAV:   4    -0.116021566438E+03    0.64975E-05   -0.16455E-04   752   0.749E-02    0.107E-02
DAV:   5    -0.116021567814E+03   -0.13755E-05   -0.33008E-05   776   0.337E-02 
  91 F= -.11602157E+03 E0= -.11600279E+03  d E =-.142837E-02
 trial-energy change:   -0.001428  1 .order   -0.001399   -0.001699   -0.001100
 step:   0.9421(harm=  0.9421)  dis= 0.01133  next Energy=  -116.022549 (dE=-0.241E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116019539603E+03    0.20268E-02   -0.17907E+00   640   0.723E+00    0.302E-01
DAV:   2    -0.116022746911E+03   -0.32073E-02   -0.37717E-02   760   0.911E-01    0.178E-01
DAV:   3    -0.116022592773E+03    0.15414E-03   -0.82739E-04   864   0.159E-01    0.104E-01
DAV:   4    -0.116022564872E+03    0.27901E-04   -0.56588E-04   760   0.138E-01    0.202E-02
DAV:   5    -0.116022566859E+03   -0.19865E-05   -0.11372E-04   856   0.622E-02    0.142E-02
DAV:   6    -0.116022567202E+03   -0.34318E-06   -0.17869E-05   640   0.235E-02 
  92 F= -.11602257E+03 E0= -.11600379E+03  d E =-.242775E-02
 curvature:  -5.38 expect dE=-0.269E-01 dE for cont linesearch -0.106E-05
 trial: gam= 1.05462 g(F)=  0.500E-02 g(S)=  0.000E+00 ort =-0.107E-03 (trialstep = 0.380E+00)
 search vector abs. value=  0.698E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116022718138E+03   -0.15128E-03   -0.77252E-01   640   0.475E+00    0.212E-01
DAV:   2    -0.116024061108E+03   -0.13430E-02   -0.16033E-02   752   0.595E-01    0.121E-01
DAV:   3    -0.116023983097E+03    0.78010E-04   -0.34952E-04   848   0.108E-01    0.704E-02
DAV:   4    -0.116023970136E+03    0.12962E-04   -0.27553E-04   760   0.978E-02    0.144E-02
DAV:   5    -0.116023969328E+03    0.80784E-06   -0.56079E-05   848   0.465E-02 
  93 F= -.11602397E+03 E0= -.11600519E+03  d E =-.140213E-02
 trial-energy change:   -0.001402  1 .order   -0.001394   -0.001859   -0.000929
 step:   0.7605(harm=  0.7605)  dis= 0.01175  next Energy=  -116.024426 (dE=-0.186E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116023159907E+03    0.81023E-03   -0.77119E-01   640   0.474E+00    0.212E-01
DAV:   2    -0.116024512839E+03   -0.13529E-02   -0.16095E-02   760   0.596E-01    0.121E-01
DAV:   3    -0.116024431597E+03    0.81242E-04   -0.35247E-04   856   0.110E-01    0.705E-02
DAV:   4    -0.116024417323E+03    0.14274E-04   -0.28429E-04   792   0.993E-02    0.150E-02
DAV:   5    -0.116024416296E+03    0.10268E-05   -0.58610E-05   856   0.485E-02 
  94 F= -.11602442E+03 E0= -.11600564E+03  d E =-.184909E-02
 curvature:  -5.43 expect dE=-0.334E-01 dE for cont linesearch -0.844E-07
 trial: gam= 1.17302 g(F)=  0.615E-02 g(S)=  0.000E+00 ort =-0.329E-04 (trialstep = 0.312E+00)
 search vector abs. value=  0.102E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116024929861E+03   -0.51254E-03   -0.67223E-01   640   0.441E+00    0.199E-01
DAV:   2    -0.116026025293E+03   -0.10954E-02   -0.13363E-02   768   0.545E-01    0.118E-01
DAV:   3    -0.116025951777E+03    0.73516E-04   -0.35248E-04   872   0.110E-01    0.667E-02
DAV:   4    -0.116025945711E+03    0.60664E-05   -0.21379E-04   744   0.839E-02    0.133E-02
DAV:   5    -0.116025946142E+03   -0.43154E-06   -0.43731E-05   848   0.421E-02 
  95 F= -.11602595E+03 E0= -.11600717E+03  d E =-.152985E-02
 trial-energy change:   -0.001530  1 .order   -0.001533   -0.001905   -0.001160
 step:   0.7977(harm=  0.7977)  dis= 0.01318  next Energy=  -116.026852 (dE=-0.244E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116024424211E+03    0.15215E-02   -0.16287E+00   640   0.687E+00    0.310E-01
DAV:   2    -0.116027062151E+03   -0.26379E-02   -0.32269E-02   768   0.847E-01    0.184E-01
DAV:   3    -0.116026875955E+03    0.18620E-03   -0.85817E-04   872   0.170E-01    0.104E-01
DAV:   4    -0.116026856570E+03    0.19385E-04   -0.50791E-04   768   0.130E-01    0.204E-02
DAV:   5    -0.116026856860E+03   -0.29018E-06   -0.10297E-04   864   0.638E-02    0.129E-02
DAV:   6    -0.116026858953E+03   -0.20929E-05   -0.14919E-05   640   0.207E-02 
  96 F= -.11602686E+03 E0= -.11600808E+03  d E =-.244266E-02
 curvature:  -6.67 expect dE=-0.439E-01 dE for cont linesearch -0.195E-06
 trial: gam= 1.07508 g(F)=  0.658E-02 g(S)=  0.000E+00 ort = 0.546E-04 (trialstep = 0.335E+00)
 search vector abs. value=  0.125E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116027585874E+03   -0.72901E-03   -0.84682E-01   640   0.495E+00    0.225E-01
DAV:   2    -0.116028832493E+03   -0.12466E-02   -0.15635E-02   736   0.593E-01    0.135E-01
DAV:   3    -0.116028750982E+03    0.81511E-04   -0.45603E-04   856   0.117E-01    0.697E-02
DAV:   4    -0.116028751549E+03   -0.56735E-06   -0.18768E-04   712   0.773E-02    0.113E-02
DAV:   5    -0.116028755070E+03   -0.35210E-05   -0.32011E-05   728   0.306E-02 
  97 F= -.11602876E+03 E0= -.11600997E+03  d E =-.189612E-02
 trial-energy change:   -0.001896  1 .order   -0.001873   -0.002223   -0.001523
 step:   1.0632(harm=  1.0632)  dis= 0.01747  next Energy=  -116.030387 (dE=-0.353E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116025023760E+03    0.37278E-02   -0.39978E+00   640   0.108E+01    0.486E-01
DAV:   2    -0.116030931729E+03   -0.59080E-02   -0.74118E-02   736   0.129E+00    0.292E-01
DAV:   3    -0.116030512873E+03    0.41886E-03   -0.21695E-03   872   0.254E-01    0.152E-01
DAV:   4    -0.116030478672E+03    0.34201E-04   -0.90492E-04   744   0.169E-01    0.244E-02
DAV:   5    -0.116030489447E+03   -0.10774E-04   -0.15712E-04   840   0.669E-02    0.190E-02
DAV:   6    -0.116030491161E+03   -0.17142E-05   -0.13894E-05   584   0.237E-02 
  98 F= -.11603049E+03 E0= -.11601171E+03  d E =-.363221E-02
 curvature:  -9.99 expect dE=-0.909E-01 dE for cont linesearch -0.773E-06
 trial: gam= 1.43740 g(F)=  0.910E-02 g(S)=  0.000E+00 ort = 0.982E-04 (trialstep = 0.224E+00)
 search vector abs. value=  0.267E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116031058367E+03   -0.56892E-03   -0.82057E-01   640   0.489E+00    0.223E-01
DAV:   2    -0.116032322841E+03   -0.12645E-02   -0.15496E-02   752   0.591E-01    0.133E-01
DAV:   3    -0.116032240586E+03    0.82254E-04   -0.38510E-04   824   0.114E-01    0.718E-02
DAV:   4    -0.116032243195E+03   -0.26087E-05   -0.23984E-04   744   0.873E-02    0.131E-02
DAV:   5    -0.116032244788E+03   -0.15934E-05   -0.40611E-05   744   0.386E-02 
  99 F= -.11603224E+03 E0= -.11601346E+03  d E =-.175363E-02
 trial-energy change:   -0.001754  1 .order   -0.001729   -0.002074   -0.001385
 step:   0.6751(harm=  0.6751)  dis= 0.02005  next Energy=  -116.033611 (dE=-0.312E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116028984181E+03    0.32590E-02   -0.33065E+00   640   0.981E+00    0.448E-01
DAV:   2    -0.116034066286E+03   -0.50821E-02   -0.62712E-02   736   0.119E+00    0.266E-01
DAV:   3    -0.116033709247E+03    0.35704E-03   -0.15584E-03   848   0.230E-01    0.145E-01
DAV:   4    -0.116033686862E+03    0.22385E-04   -0.99678E-04   744   0.178E-01    0.269E-02
DAV:   5    -0.116033685670E+03    0.11920E-05   -0.17496E-04   840   0.804E-02    0.180E-02
DAV:   6    -0.116033687948E+03   -0.22780E-05   -0.36611E-05   768   0.319E-02 
 100 F= -.11603369E+03 E0= -.11601490E+03  d E =-.319679E-02
 curvature:  -9.76 expect dE=-0.787E-01 dE for cont linesearch -0.767E-07
 trial: gam= 0.89035 g(F)=  0.807E-02 g(S)=  0.000E+00 ort = 0.458E-04 (trialstep = 0.315E+00)
 search vector abs. value=  0.220E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116033861263E+03   -0.17559E-03   -0.13913E+00   640   0.636E+00    0.295E-01
DAV:   2    -0.116036020505E+03   -0.21592E-02   -0.26561E-02   736   0.775E-01    0.172E-01
DAV:   3    -0.116035863604E+03    0.15690E-03   -0.58899E-04   856   0.146E-01    0.962E-02
DAV:   4    -0.116035850787E+03    0.12817E-04   -0.51324E-04   736   0.131E-01    0.201E-02
DAV:   5    -0.116035848115E+03    0.26714E-05   -0.96192E-05   872   0.603E-02 
 101 F= -.11603585E+03 E0= -.11601706E+03  d E =-.216017E-02
 trial-energy change:   -0.002160  1 .order   -0.002143   -0.002551   -0.001734
 step:   0.9824(harm=  0.9824)  dis= 0.02831  next Energy=  -116.037671 (dE=-0.398E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116028906952E+03    0.69438E-02   -0.62662E+00   640   0.135E+01    0.624E-01
DAV:   2    -0.116038718645E+03   -0.98117E-02   -0.12056E-01   720   0.165E+00    0.365E-01
DAV:   3    -0.116037965047E+03    0.75360E-03   -0.26858E-03   856   0.314E-01    0.207E-01
DAV:   4    -0.116037885699E+03    0.79348E-04   -0.24256E-03   744   0.285E-01    0.446E-02
DAV:   5    -0.116037866202E+03    0.19497E-04   -0.45294E-04   864   0.133E-01    0.298E-02
DAV:   6    -0.116037866299E+03   -0.97446E-07   -0.11898E-04   752   0.584E-02    0.154E-02
DAV:   7    -0.116037865510E+03    0.78931E-06   -0.93270E-06   608   0.206E-02 
 102 F= -.11603787E+03 E0= -.11601908E+03  d E =-.417756E-02
 curvature: -13.32 expect dE=-0.159E+00 dE for cont linesearch -0.131E-04
 trial: gam= 1.36621 g(F)=  0.119E-01 g(S)=  0.000E+00 ort = 0.465E-03 (trialstep = 0.233E+00)
 search vector abs. value=  0.424E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116038384985E+03   -0.51869E-03   -0.14338E+00   640   0.644E+00    0.290E-01
DAV:   2    -0.116040571513E+03   -0.21865E-02   -0.27239E-02   712   0.779E-01    0.172E-01
DAV:   3    -0.116040433387E+03    0.13813E-03   -0.69779E-04   848   0.145E-01    0.930E-02
DAV:   4    -0.116040421226E+03    0.12161E-04   -0.37997E-04   728   0.114E-01    0.154E-02
DAV:   5    -0.116040425958E+03   -0.47317E-05   -0.69531E-05   832   0.470E-02 
 103 F= -.11604043E+03 E0= -.11602164E+03  d E =-.256045E-02
 trial-energy change:   -0.002560  1 .order   -0.002509   -0.002921   -0.002098
 step:   0.5480(harm=  0.8257)  dis= 0.02126  next Energy=  -116.041976 (dE=-0.411E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116038754218E+03    0.16670E-02   -0.26337E+00   640   0.872E+00    0.392E-01
DAV:   2    -0.116042829082E+03   -0.40749E-02   -0.50007E-02   712   0.105E+00    0.232E-01
DAV:   3    -0.116042579309E+03    0.24977E-03   -0.12435E-03   864   0.195E-01    0.126E-01
DAV:   4    -0.116042554799E+03    0.24510E-04   -0.69686E-04   752   0.153E-01    0.209E-02
DAV:   5    -0.116042559533E+03   -0.47337E-05   -0.12554E-04   856   0.638E-02    0.163E-02
DAV:   6    -0.116042560835E+03   -0.13021E-05   -0.26171E-05   672   0.302E-02 
 104 F= -.11604256E+03 E0= -.11602377E+03  d E =-.469532E-02
 curvature: -10.87 expect dE=-0.559E-01 dE for cont linesearch -0.496E-03
 ZBRENT: increasing intervall
 opt :   1.1789  next Energy=  -116.042420 (dE=-0.455E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116026666750E+03    0.15893E-01   -0.10521E+01   640   0.174E+01    0.784E-01
DAV:   2    -0.116042950236E+03   -0.16283E-01   -0.19996E-01   712   0.211E+00    0.466E-01
DAV:   3    -0.116041878194E+03    0.10720E-02   -0.51680E-03   864   0.393E-01    0.253E-01
DAV:   4    -0.116041735078E+03    0.14312E-03   -0.26859E-03   752   0.303E-01    0.409E-02
DAV:   5    -0.116041759020E+03   -0.23941E-04   -0.48891E-04   856   0.124E-01    0.322E-02
DAV:   6    -0.116041761543E+03   -0.25234E-05   -0.97529E-05   744   0.582E-02 
 105 F= -.11604176E+03 E0= -.11602297E+03  d E =-.389603E-02
 curvature:   3.09 expect dE= 0.838E-01 dE for cont linesearch  0.286E-03
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   0.8085  next Energy=  -116.043134 (dE=-0.527E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116037978109E+03    0.37809E-02   -0.36256E+00   640   0.102E+01    0.456E-01
DAV:   2    -0.116043493694E+03   -0.55156E-02   -0.68858E-02   696   0.124E+00    0.273E-01
DAV:   3    -0.116043125683E+03    0.36801E-03   -0.17375E-03   840   0.232E-01    0.150E-01
DAV:   4    -0.116043077320E+03    0.48363E-04   -0.10710E-03   728   0.189E-01    0.270E-02
DAV:   5    -0.116043081446E+03   -0.41254E-05   -0.19132E-04   832   0.785E-02    0.203E-02
DAV:   6    -0.116043081186E+03    0.25948E-06   -0.46218E-05   736   0.388E-02 
 106 F= -.11604308E+03 E0= -.11602429E+03  d E =-.521568E-02
 curvature:  -6.21 expect dE=-0.641E-01 dE for cont linesearch -0.333E-05
 trial: gam= 1.04982 g(F)=  0.103E-01 g(S)=  0.000E+00 ort =-0.476E-03 (trialstep = 0.309E+00)
 search vector abs. value=  0.476E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116041035977E+03    0.20455E-02   -0.28805E+00   640   0.914E+00    0.399E-01
DAV:   2    -0.116045610003E+03   -0.45740E-02   -0.55983E-02   696   0.111E+00    0.240E-01
DAV:   3    -0.116045328518E+03    0.28149E-03   -0.13551E-03   840   0.203E-01    0.132E-01
DAV:   4    -0.116045288824E+03    0.39694E-04   -0.84132E-04   768   0.168E-01    0.254E-02
DAV:   5    -0.116045288916E+03   -0.91693E-07   -0.14410E-04   856   0.707E-02    0.184E-02
DAV:   6    -0.116045288360E+03    0.55567E-06   -0.44292E-05   792   0.384E-02 
 107 F= -.11604529E+03 E0= -.11602650E+03  d E =-.220717E-02
 trial-energy change:   -0.002207  1 .order   -0.002204   -0.003042   -0.001365
 step:   0.5611(harm=  0.5611)  dis= 0.02566  next Energy=  -116.045840 (dE=-0.276E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116042901546E+03    0.23874E-02   -0.19077E+00   640   0.744E+00    0.328E-01
DAV:   2    -0.116045954225E+03   -0.30527E-02   -0.37184E-02   688   0.908E-01    0.196E-01
DAV:   3    -0.116045786000E+03    0.16823E-03   -0.89828E-04   832   0.164E-01    0.106E-01
DAV:   4    -0.116045765138E+03    0.20862E-04   -0.50934E-04   784   0.130E-01    0.194E-02
DAV:   5    -0.116045766821E+03   -0.16835E-05   -0.88765E-05   864   0.552E-02 
 108 F= -.11604577E+03 E0= -.11602698E+03  d E =-.268564E-02
 curvature: -13.58 expect dE=-0.752E-01 dE for cont linesearch -0.121E-04
 trial: gam= 0.39365 g(F)=  0.554E-02 g(S)=  0.000E+00 ort =-0.650E-03 (trialstep = 0.360E+00)
 search vector abs. value=  0.788E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116045669699E+03    0.95439E-04   -0.77153E-01   640   0.476E+00    0.221E-01
DAV:   2    -0.116047074507E+03   -0.14048E-02   -0.16669E-02   768   0.616E-01    0.123E-01
DAV:   3    -0.116046972131E+03    0.10238E-03   -0.34024E-04   864   0.114E-01    0.726E-02
DAV:   4    -0.116046947764E+03    0.24367E-04   -0.36198E-04   736   0.116E-01    0.190E-02
DAV:   5    -0.116046944070E+03    0.36939E-05   -0.76891E-05   872   0.555E-02 
 109 F= -.11604694E+03 E0= -.11602816E+03  d E =-.117725E-02
 trial-energy change:   -0.001177  1 .order   -0.001171   -0.001900   -0.000442
 step:   0.4690(harm=  0.4690)  dis= 0.00880  next Energy=  -116.047005 (dE=-0.124E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116046882955E+03    0.64809E-04   -0.71121E-02   640   0.145E+00    0.684E-02
DAV:   2    -0.116047016608E+03   -0.13365E-03   -0.15839E-03   776   0.190E-01    0.375E-02
DAV:   3    -0.116047006366E+03    0.10242E-04   -0.30914E-05   744   0.364E-02    0.223E-02
DAV:   4    -0.116047004447E+03    0.19191E-05   -0.40017E-05   688   0.393E-02 
 110 F= -.11604700E+03 E0= -.11602822E+03  d E =-.123763E-02
 curvature:  -3.50 expect dE=-0.871E-02 dE for cont linesearch -0.491E-05
 trial: gam= 0.43576 g(F)=  0.249E-02 g(S)=  0.000E+00 ort =-0.333E-03 (trialstep = 0.382E+00)
 search vector abs. value=  0.172E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116047342573E+03   -0.33621E-03   -0.20796E-01   640   0.246E+00    0.117E-01
DAV:   2    -0.116047695730E+03   -0.35316E-03   -0.42779E-03   792   0.313E-01    0.641E-02
DAV:   3    -0.116047666303E+03    0.29427E-04   -0.99262E-05   872   0.619E-02    0.367E-02
DAV:   4    -0.116047664738E+03    0.15651E-05   -0.90010E-05   728   0.562E-02 
 111 F= -.11604766E+03 E0= -.11602888E+03  d E =-.660291E-03
 trial-energy change:   -0.000660  1 .order   -0.000588   -0.000894   -0.000283
 step:   0.4756(harm=  0.5583)  dis= 0.00356  next Energy=  -116.047701 (dE=-0.696E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116047720724E+03   -0.54421E-04   -0.12916E-02   656   0.613E-01    0.325E-02
DAV:   2    -0.116047744351E+03   -0.23627E-04   -0.28397E-04   784   0.809E-02    0.170E-02
DAV:   3    -0.116047743323E+03    0.10277E-05   -0.63406E-06   608   0.173E-02 
 112 F= -.11604774E+03 E0= -.11602895E+03  d E =-.738876E-03
 curvature:  -1.60 expect dE=-0.147E-02 dE for cont linesearch -0.414E-04
 ZBRENT: increasing intervall
 opt :   0.6637  next Energy=  -116.047855 (dE=-0.850E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116047723082E+03    0.21268E-04   -0.49828E-02   640   0.121E+00    0.575E-02
DAV:   2    -0.116047803083E+03   -0.80000E-04   -0.98177E-04   800   0.150E-01    0.310E-02
DAV:   3    -0.116047797114E+03    0.59689E-05   -0.21438E-05   720   0.283E-02 
 113 F= -.11604780E+03 E0= -.11602901E+03  d E =-.792667E-03
 curvature:  -4.30 expect dE=-0.618E-02 dE for cont linesearch -0.542E-06
 trial: gam= 0.59897 g(F)=  0.144E-02 g(S)=  0.000E+00 ort =-0.465E-04 (trialstep = 0.438E+00)
 search vector abs. value=  0.754E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048040796E+03   -0.23771E-03   -0.99688E-02   640   0.172E+00    0.816E-02
DAV:   2    -0.116048218816E+03   -0.17802E-03   -0.22619E-03   808   0.228E-01    0.463E-02
DAV:   3    -0.116048204798E+03    0.14019E-04   -0.67510E-05   856   0.481E-02    0.258E-02
DAV:   4    -0.116048203316E+03    0.14813E-05   -0.35919E-05   672   0.377E-02 
 114 F= -.11604820E+03 E0= -.11602941E+03  d E =-.406202E-03
 trial-energy change:   -0.000406  1 .order   -0.000384   -0.000617   -0.000151
 step:   0.5800(harm=  0.5800)  dis= 0.00268  next Energy=  -116.048206 (dE=-0.409E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048223998E+03   -0.19200E-04   -0.10719E-02   656   0.562E-01    0.284E-02
DAV:   2    -0.116048243941E+03   -0.19943E-04   -0.25973E-04   824   0.777E-02    0.156E-02
DAV:   3    -0.116048242130E+03    0.18103E-05   -0.63153E-06   600   0.169E-02 
 115 F= -.11604824E+03 E0= -.11602945E+03  d E =-.445016E-03
 curvature:  -1.55 expect dE=-0.125E-02 dE for cont linesearch -0.372E-05
 trial: gam= 0.43935 g(F)=  0.807E-03 g(S)=  0.000E+00 ort = 0.134E-03 (trialstep = 0.466E+00)
 search vector abs. value=  0.238E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048445477E+03   -0.20154E-03   -0.36938E-02   640   0.105E+00    0.531E-02
DAV:   2    -0.116048527820E+03   -0.82343E-04   -0.96905E-04   840   0.148E-01    0.294E-02
DAV:   3    -0.116048520061E+03    0.77589E-05   -0.19252E-05   616   0.297E-02 
 116 F= -.11604852E+03 E0= -.11602973E+03  d E =-.277931E-03
 trial-energy change:   -0.000278  1 .order   -0.000283   -0.000404   -0.000162
 step:   0.7777(harm=  0.7777)  dis= 0.00203  next Energy=  -116.048579 (dE=-0.337E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048530772E+03   -0.29520E-05   -0.15907E-02   720   0.691E-01    0.361E-02
DAV:   2    -0.116048561641E+03   -0.30869E-04   -0.37741E-04   872   0.927E-02    0.193E-02
DAV:   3    -0.116048558715E+03    0.29257E-05   -0.73073E-06   576   0.178E-02 
 117 F= -.11604856E+03 E0= -.11602977E+03  d E =-.316585E-03
 curvature:  -1.07 expect dE=-0.960E-03 dE for cont linesearch -0.841E-06
 trial: gam= 1.26742 g(F)=  0.899E-03 g(S)=  0.000E+00 ort =-0.433E-04 (trialstep = 0.273E+00)
 search vector abs. value=  0.461E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048733595E+03   -0.17195E-03   -0.20251E-02   640   0.772E-01    0.370E-02
DAV:   2    -0.116048761920E+03   -0.28326E-04   -0.38262E-04   880   0.945E-02    0.217E-02
DAV:   3    -0.116048758644E+03    0.32763E-05   -0.10038E-05   616   0.210E-02 
 118 F= -.11604876E+03 E0= -.11602997E+03  d E =-.199929E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000200  1 .order   -0.000205   -0.000230   -0.000179
 step:   1.0913(harm=  1.2243)  dis= 0.00404  next Energy=  -116.049075 (dE=-0.517E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116048794403E+03   -0.32482E-04   -0.18389E-01   640   0.232E+00    0.110E-01
DAV:   2    -0.116049063669E+03   -0.26927E-03   -0.36051E-03   840   0.290E-01    0.654E-02
DAV:   3    -0.116049031465E+03    0.32204E-04   -0.97119E-05   912   0.625E-02    0.364E-02
DAV:   4    -0.116049030779E+03    0.68620E-06   -0.97089E-05   728   0.589E-02 
 119 F= -.11604903E+03 E0= -.11603024E+03  d E =-.472064E-03
 curvature:  -3.28 expect dE=-0.493E-02 dE for cont linesearch -0.702E-05
 trial: gam= 1.27996 g(F)=  0.150E-02 g(S)=  0.000E+00 ort =-0.994E-04 (trialstep = 0.229E+00)
 search vector abs. value=  0.880E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049255220E+03   -0.22375E-03   -0.27858E-02   640   0.900E-01    0.483E-02
DAV:   2    -0.116049301745E+03   -0.46525E-04   -0.67873E-04   848   0.128E-01    0.267E-02
DAV:   3    -0.116049297277E+03    0.44679E-05   -0.21054E-05   696   0.292E-02 
 120 F= -.11604930E+03 E0= -.11603051E+03  d E =-.266498E-03
 trial-energy change:   -0.000266  1 .order   -0.000258   -0.000314   -0.000202
 step:   0.6410(harm=  0.6410)  dis= 0.00322  next Energy=  -116.049471 (dE=-0.440E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049295285E+03    0.64596E-05   -0.88615E-02   640   0.161E+00    0.850E-02
DAV:   2    -0.116049429076E+03   -0.13379E-03   -0.19441E-03   856   0.216E-01    0.465E-02
DAV:   3    -0.116049414135E+03    0.14941E-04   -0.65098E-05   800   0.463E-02    0.262E-02
DAV:   4    -0.116049410827E+03    0.33080E-05   -0.43641E-05   656   0.423E-02 
 121 F= -.11604941E+03 E0= -.11603062E+03  d E =-.380048E-03
 curvature:  -2.05 expect dE=-0.243E-02 dE for cont linesearch -0.393E-04
 ZBRENT: interpolating
 opt :   0.5102  next Energy=  -116.049438 (dE=-0.407E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049413810E+03    0.32508E-06   -0.89013E-03   672   0.511E-01    0.245E-02
DAV:   2    -0.116049428245E+03   -0.14435E-04   -0.19363E-04   848   0.679E-02    0.143E-02
DAV:   3    -0.116049426811E+03    0.14343E-05   -0.54903E-06   568   0.137E-02 
 122 F= -.11604943E+03 E0= -.11603064E+03  d E =-.396032E-03
 curvature:  -1.40 expect dE=-0.961E-03 dE for cont linesearch -0.562E-06
 trial: gam= 0.46997 g(F)=  0.685E-03 g(S)=  0.000E+00 ort = 0.594E-04 (trialstep = 0.285E+00)
 search vector abs. value=  0.269E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049582919E+03   -0.15467E-03   -0.15288E-02   640   0.673E-01    0.297E-02
DAV:   2    -0.116049609018E+03   -0.26099E-04   -0.34969E-04   792   0.910E-02    0.174E-02
DAV:   3    -0.116049606475E+03    0.25432E-05   -0.88237E-06   600   0.203E-02 
 123 F= -.11604961E+03 E0= -.11603082E+03  d E =-.179664E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000180  1 .order   -0.000180   -0.000203   -0.000157
 step:   1.1400(harm=  1.2645)  dis= 0.00317  next Energy=  -116.049878 (dE=-0.451E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049663861E+03   -0.54843E-04   -0.13508E-01   640   0.200E+00    0.928E-02
DAV:   2    -0.116049868675E+03   -0.20481E-03   -0.29186E-03   824   0.264E-01    0.520E-02
DAV:   3    -0.116049849282E+03    0.19392E-04   -0.92582E-05   832   0.584E-02    0.303E-02
DAV:   4    -0.116049846840E+03    0.24422E-05   -0.81990E-05   680   0.591E-02 
 124 F= -.11604985E+03 E0= -.11603106E+03  d E =-.420029E-03
 curvature:  -2.34 expect dE=-0.252E-02 dE for cont linesearch -0.455E-05
 trial: gam= 1.68026 g(F)=  0.108E-02 g(S)=  0.000E+00 ort =-0.722E-04 (trialstep = 0.145E+00)
 search vector abs. value=  0.842E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116049971757E+03   -0.12247E-03   -0.11468E-02   640   0.576E-01    0.315E-02
DAV:   2    -0.116049990996E+03   -0.19239E-04   -0.31702E-04   784   0.881E-02    0.175E-02
DAV:   3    -0.116049989175E+03    0.18207E-05   -0.90270E-06   592   0.215E-02 
 125 F= -.11604999E+03 E0= -.11603120E+03  d E =-.142335E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000142  1 .order   -0.000135   -0.000139   -0.000131
 step:   0.5820(harm=  2.5350)  dis= 0.00317  next Energy=  -116.051059 (dE=-0.121E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050074603E+03   -0.83608E-04   -0.10074E-01   640   0.171E+00    0.824E-02
DAV:   2    -0.116050232260E+03   -0.15766E-03   -0.23053E-03   776   0.234E-01    0.477E-02
DAV:   3    -0.116050219133E+03    0.13127E-04   -0.60741E-05   848   0.498E-02    0.291E-02
DAV:   4    -0.116050220641E+03   -0.15083E-05   -0.94582E-05   728   0.605E-02 
 126 F= -.11605022E+03 E0= -.11603143E+03  d E =-.373801E-03
 curvature:  -3.70 expect dE=-0.208E-02 dE for cont linesearch -0.134E-06
 trial: gam= 0.40117 g(F)=  0.561E-03 g(S)=  0.000E+00 ort = 0.175E-04 (trialstep = 0.233E+00)
 search vector abs. value=  0.193E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050332767E+03   -0.11363E-03   -0.59738E-03   656   0.414E-01    0.248E-02
DAV:   2    -0.116050342955E+03   -0.10189E-04   -0.18443E-04   816   0.694E-02    0.146E-02
DAV:   3    -0.116050341506E+03    0.14494E-05   -0.82107E-06   560   0.196E-02 
 127 F= -.11605034E+03 E0= -.11603155E+03  d E =-.120865E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000121  1 .order   -0.000119   -0.000132   -0.000106
 step:   0.9312(harm=  1.1600)  dis= 0.00299  next Energy=  -116.050550 (dE=-0.330E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050399521E+03   -0.56566E-04   -0.52206E-02   640   0.123E+00    0.640E-02
DAV:   2    -0.116050478039E+03   -0.78518E-04   -0.11222E-03   840   0.165E-01    0.390E-02
DAV:   3    -0.116050465380E+03    0.12659E-04   -0.40657E-05   800   0.422E-02    0.224E-02
DAV:   4    -0.116050465289E+03    0.91565E-07   -0.49237E-05   712   0.398E-02 
 128 F= -.11605047E+03 E0= -.11603168E+03  d E =-.244647E-03
 curvature:  -1.85 expect dE=-0.124E-02 dE for cont linesearch -0.209E-04
 ZBRENT: interpolating
 opt :   0.7598  next Energy=  -116.050478 (dE=-0.257E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050465404E+03   -0.24340E-07   -0.30729E-03   688   0.298E-01    0.136E-02
DAV:   2    -0.116050469403E+03   -0.39984E-05   -0.54971E-05   816   0.370E-02 
 129 F= -.11605047E+03 E0= -.11603168E+03  d E =-.248762E-03
 curvature:  -1.12 expect dE=-0.440E-03 dE for cont linesearch -0.125E-05
 trial: gam= 0.81161 g(F)=  0.393E-03 g(S)=  0.000E+00 ort = 0.464E-04 (trialstep = 0.338E+00)
 search vector abs. value=  0.174E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050560127E+03   -0.94723E-04   -0.12793E-02   640   0.617E-01    0.292E-02
DAV:   2    -0.116050586316E+03   -0.26189E-04   -0.30117E-04   808   0.845E-02    0.148E-02
DAV:   3    -0.116050584305E+03    0.20114E-05   -0.63118E-06   560   0.169E-02 
 130 F= -.11605058E+03 E0= -.11603180E+03  d E =-.114902E-03
 trial-energy change:   -0.000115  1 .order   -0.000118   -0.000146   -0.000089
 step:   0.8749(harm=  0.8749)  dis= 0.00247  next Energy=  -116.050658 (dE=-0.188E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050599705E+03   -0.13389E-04   -0.31671E-02   656   0.970E-01    0.487E-02
DAV:   2    -0.116050654490E+03   -0.54785E-04   -0.67812E-04   840   0.127E-01    0.252E-02
DAV:   3    -0.116050649388E+03    0.51022E-05   -0.15863E-05   608   0.254E-02 
 131 F= -.11605065E+03 E0= -.11603186E+03  d E =-.179985E-03
 curvature:  -1.77 expect dE=-0.870E-03 dE for cont linesearch -0.104E-07
 trial: gam= 1.29473 g(F)=  0.492E-03 g(S)=  0.000E+00 ort = 0.321E-05 (trialstep = 0.227E+00)
 search vector abs. value=  0.342E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050735475E+03   -0.80985E-04   -0.89114E-03   664   0.510E-01    0.240E-02
DAV:   2    -0.116050748550E+03   -0.13075E-04   -0.17269E-04   840   0.638E-02    0.138E-02
DAV:   3    -0.116050747965E+03    0.58569E-06   -0.59046E-06   552   0.139E-02 
 132 F= -.11605075E+03 E0= -.11603196E+03  d E =-.985764E-04
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000099  1 .order   -0.000099   -0.000113   -0.000086
 step:   0.9074(harm=  0.9617)  dis= 0.00362  next Energy=  -116.050888 (dE=-0.239E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116050764792E+03   -0.16242E-04   -0.82134E-02   640   0.155E+00    0.690E-02
DAV:   2    -0.116050898805E+03   -0.13401E-03   -0.16935E-03   800   0.199E-01    0.401E-02
DAV:   3    -0.116050890296E+03    0.85086E-05   -0.44474E-05   856   0.378E-02 
 133 F= -.11605089E+03 E0= -.11603210E+03  d E =-.240908E-03
 curvature:  -3.29 expect dE=-0.186E-02 dE for cont linesearch -0.143E-05
 trial: gam= 0.93856 g(F)=  0.566E-03 g(S)=  0.000E+00 ort = 0.385E-04 (trialstep = 0.340E+00)
 search vector abs. value=  0.365E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051030134E+03   -0.13133E-03   -0.22277E-02   640   0.800E-01    0.390E-02
DAV:   2    -0.116051060983E+03   -0.30849E-04   -0.44275E-04   848   0.104E-01    0.229E-02
DAV:   3    -0.116051058576E+03    0.24066E-05   -0.21337E-05   648   0.289E-02 
 134 F= -.11605106E+03 E0= -.11603227E+03  d E =-.168280E-03
 trial-energy change:   -0.000168  1 .order   -0.000168   -0.000205   -0.000131
 step:   0.9509(harm=  0.9509)  dis= 0.00415  next Energy=  -116.051177 (dE=-0.286E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051068724E+03   -0.77414E-05   -0.73019E-02   640   0.144E+00    0.671E-02
DAV:   2    -0.116051180984E+03   -0.11226E-03   -0.14783E-03   848   0.187E-01    0.404E-02
DAV:   3    -0.116051170483E+03    0.10501E-04   -0.50946E-05   832   0.451E-02    0.221E-02
DAV:   4    -0.116051169447E+03    0.10360E-05   -0.26605E-05   528   0.328E-02 
 135 F= -.11605117E+03 E0= -.11603238E+03  d E =-.279151E-03
 curvature:  -2.88 expect dE=-0.231E-02 dE for cont linesearch -0.264E-05
 trial: gam= 1.57405 g(F)=  0.803E-03 g(S)=  0.000E+00 ort =-0.579E-04 (trialstep = 0.175E+00)
 search vector abs. value=  0.966E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051268326E+03   -0.97842E-04   -0.15376E-02   640   0.662E-01    0.315E-02
DAV:   2    -0.116051292376E+03   -0.24050E-04   -0.30533E-04   792   0.838E-02    0.179E-02
DAV:   3    -0.116051290838E+03    0.15384E-05   -0.73229E-06   600   0.192E-02 
 136 F= -.11605129E+03 E0= -.11603250E+03  d E =-.121390E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000121  1 .order   -0.000117   -0.000124   -0.000110
 step:   0.6981(harm=  1.5359)  dis= 0.00523  next Energy=  -116.051716 (dE=-0.547E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051299266E+03   -0.68896E-05   -0.13685E-01   640   0.198E+00    0.906E-02
DAV:   2    -0.116051505479E+03   -0.20621E-03   -0.25888E-03   768   0.244E-01    0.523E-02
DAV:   3    -0.116051490165E+03    0.15313E-04   -0.74772E-05   864   0.536E-02    0.297E-02
DAV:   4    -0.116051489221E+03    0.94448E-06   -0.54504E-05   688   0.467E-02 
 137 F= -.11605149E+03 E0= -.11603270E+03  d E =-.319773E-03
 curvature:  -6.47 expect dE=-0.507E-02 dE for cont linesearch -0.432E-06
 trial: gam= 0.62642 g(F)=  0.783E-03 g(S)=  0.000E+00 ort = 0.254E-04 (trialstep = 0.279E+00)
 search vector abs. value=  0.461E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051651604E+03   -0.16144E-03   -0.19349E-02   656   0.749E-01    0.365E-02
DAV:   2    -0.116051689138E+03   -0.37533E-04   -0.47256E-04   848   0.104E-01    0.206E-02
DAV:   3    -0.116051686457E+03    0.26804E-05   -0.11402E-05   544   0.225E-02 
 138 F= -.11605169E+03 E0= -.11603290E+03  d E =-.197237E-03
 trial-energy change:   -0.000197  1 .order   -0.000191   -0.000223   -0.000160
 step:   0.9867(harm=  0.9867)  dis= 0.00523  next Energy=  -116.051883 (dE=-0.394E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051609815E+03    0.79323E-04   -0.12230E-01   672   0.188E+00    0.871E-02
DAV:   2    -0.116051842465E+03   -0.23265E-03   -0.28312E-03   864   0.253E-01    0.509E-02
DAV:   3    -0.116051823684E+03    0.18781E-04   -0.74888E-05   824   0.522E-02    0.290E-02
DAV:   4    -0.116051820236E+03    0.34479E-05   -0.36484E-05   720   0.392E-02 
 139 F= -.11605182E+03 E0= -.11603303E+03  d E =-.331015E-03
 curvature:  -2.84 expect dE=-0.379E-02 dE for cont linesearch -0.354E-04
 ZBRENT: interpolating
 opt :   0.7782  next Energy=  -116.051845 (dE=-0.356E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051815132E+03    0.85525E-05   -0.10628E-02   640   0.557E-01    0.233E-02
DAV:   2    -0.116051836889E+03   -0.21758E-04   -0.25326E-04   848   0.761E-02    0.149E-02
DAV:   3    -0.116051835578E+03    0.13117E-05   -0.59224E-06   576   0.150E-02 
 140 F= -.11605184E+03 E0= -.11603305E+03  d E =-.346357E-03
 curvature:  -2.01 expect dE=-0.146E-02 dE for cont linesearch -0.580E-06
 trial: gam= 1.08967 g(F)=  0.729E-03 g(S)=  0.000E+00 ort = 0.365E-04 (trialstep = 0.278E+00)
 search vector abs. value=  0.628E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116051987341E+03   -0.15045E-03   -0.19835E-02   640   0.748E-01    0.350E-02
DAV:   2    -0.116052020260E+03   -0.32918E-04   -0.39803E-04   776   0.961E-02    0.212E-02
DAV:   3    -0.116052017500E+03    0.27593E-05   -0.13262E-05   576   0.229E-02 
 141 F= -.11605202E+03 E0= -.11603323E+03  d E =-.181923E-03
 trial-energy change:   -0.000182  1 .order   -0.000180   -0.000214   -0.000147
 step:   0.8928(harm=  0.8928)  dis= 0.00575  next Energy=  -116.052179 (dE=-0.343E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052053425E+03   -0.33166E-04   -0.95357E-02   640   0.164E+00    0.805E-02
DAV:   2    -0.116052198336E+03   -0.14491E-03   -0.18051E-03   744   0.204E-01    0.476E-02
DAV:   3    -0.116052186322E+03    0.12015E-04   -0.68160E-05   856   0.475E-02    0.252E-02
DAV:   4    -0.116052184931E+03    0.13909E-05   -0.27619E-05   592   0.336E-02 
 142 F= -.11605218E+03 E0= -.11603340E+03  d E =-.349353E-03
 curvature:  -3.65 expect dE=-0.258E-02 dE for cont linesearch -0.444E-06
 trial: gam= 0.94823 g(F)=  0.708E-03 g(S)=  0.000E+00 ort =-0.276E-04 (trialstep = 0.400E+00)
 search vector abs. value=  0.630E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052350311E+03   -0.16399E-03   -0.43066E-02   640   0.110E+00    0.534E-02
DAV:   2    -0.116052413739E+03   -0.63429E-04   -0.80482E-04   832   0.138E-01    0.304E-02
DAV:   3    -0.116052408126E+03    0.56136E-05   -0.16249E-05   616   0.271E-02 
 143 F= -.11605241E+03 E0= -.11603362E+03  d E =-.223195E-03
 trial-energy change:   -0.000223  1 .order   -0.000221   -0.000273   -0.000170
 step:   1.0618(harm=  1.0618)  dis= 0.00724  next Energy=  -116.052547 (dE=-0.362E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052353831E+03    0.59908E-04   -0.11669E-01   640   0.182E+00    0.866E-02
DAV:   2    -0.116052516830E+03   -0.16300E-03   -0.20758E-03   832   0.221E-01    0.492E-02
DAV:   3    -0.116052503762E+03    0.13068E-04   -0.46622E-05   848   0.417E-02    0.274E-02
DAV:   4    -0.116052502750E+03    0.10120E-05   -0.47424E-05   744   0.414E-02 
 144 F= -.11605250E+03 E0= -.11603371E+03  d E =-.317819E-03
 curvature:  -4.90 expect dE=-0.750E-02 dE for cont linesearch -0.310E-04
 ZBRENT: interpolating
 opt :   0.8503  next Energy=  -116.052524 (dE=-0.339E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052494854E+03    0.89080E-05   -0.11854E-02   640   0.579E-01    0.256E-02
DAV:   2    -0.116052511436E+03   -0.16583E-04   -0.20284E-04   840   0.694E-02    0.160E-02
DAV:   3    -0.116052510223E+03    0.12138E-05   -0.45672E-06   544   0.139E-02 
 145 F= -.11605251E+03 E0= -.11603372E+03  d E =-.325292E-03
 curvature:  -3.34 expect dE=-0.317E-02 dE for cont linesearch -0.106E-05
 trial: gam= 1.26403 g(F)=  0.950E-03 g(S)=  0.000E+00 ort = 0.446E-04 (trialstep = 0.277E+00)
 search vector abs. value=  0.111E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052701766E+03   -0.19033E-03   -0.35487E-02   640   0.999E-01    0.456E-02
DAV:   2    -0.116052758328E+03   -0.56562E-04   -0.68093E-04   800   0.125E-01    0.273E-02
DAV:   3    -0.116052753403E+03    0.49247E-05   -0.15499E-05   608   0.241E-02 
 146 F= -.11605275E+03 E0= -.11603396E+03  d E =-.243181E-03
 trial-energy change:   -0.000243  1 .order   -0.000242   -0.000279   -0.000206
 step:   1.0593(harm=  1.0593)  dis= 0.00990  next Energy=  -116.053043 (dE=-0.533E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052640719E+03    0.11761E-03   -0.27825E-01   640   0.280E+00    0.131E-01
DAV:   2    -0.116053055710E+03   -0.41499E-03   -0.51338E-03   776   0.343E-01    0.762E-02
DAV:   3    -0.116053022383E+03    0.33327E-04   -0.13333E-04   808   0.658E-02    0.412E-02
DAV:   4    -0.116053015583E+03    0.68002E-05   -0.84504E-05   728   0.554E-02 
 147 F= -.11605302E+03 E0= -.11603423E+03  d E =-.505360E-03
 curvature:  -5.86 expect dE=-0.724E-02 dE for cont linesearch -0.161E-04
 ZBRENT: interpolating
 opt :   0.9103  next Energy=  -116.053029 (dE=-0.518E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116052998542E+03    0.23842E-04   -0.99702E-03   640   0.530E-01    0.226E-02
DAV:   2    -0.116053012919E+03   -0.14377E-04   -0.17540E-04   792   0.639E-02    0.146E-02
DAV:   3    -0.116053012106E+03    0.81318E-06   -0.50862E-06   576   0.134E-02 
 148 F= -.11605301E+03 E0= -.11603422E+03  d E =-.501883E-03
 curvature:  -4.74 expect dE=-0.400E-02 dE for cont linesearch -0.471E-05
 trial: gam= 0.93871 g(F)=  0.843E-03 g(S)=  0.000E+00 ort = 0.105E-03 (trialstep = 0.404E+00)
 search vector abs. value=  0.108E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116053221814E+03   -0.20889E-03   -0.67130E-02   640   0.137E+00    0.634E-02
DAV:   2    -0.116053317526E+03   -0.95713E-04   -0.12049E-03   752   0.167E-01    0.381E-02
DAV:   3    -0.116053309830E+03    0.76966E-05   -0.48857E-05   856   0.382E-02 
 149 F= -.11605331E+03 E0= -.11603452E+03  d E =-.297724E-03
 trial-energy change:   -0.000298  1 .order   -0.000292   -0.000380   -0.000203
 step:   0.8659(harm=  0.8659)  dis= 0.00820  next Energy=  -116.053420 (dE=-0.408E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116053338217E+03   -0.20691E-04   -0.86473E-02   640   0.155E+00    0.758E-02
DAV:   2    -0.116053450697E+03   -0.11248E-03   -0.14642E-03   760   0.184E-01    0.447E-02
DAV:   3    -0.116053442817E+03    0.78795E-05   -0.65442E-05   856   0.442E-02 
 150 F= -.11605344E+03 E0= -.11603465E+03  d E =-.430712E-03
 curvature:  -4.98 expect dE=-0.450E-02 dE for cont linesearch -0.153E-06
 trial: gam= 1.15772 g(F)=  0.902E-03 g(S)=  0.000E+00 ort = 0.183E-04 (trialstep = 0.348E+00)
 search vector abs. value=  0.155E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116053647104E+03   -0.19641E-03   -0.65431E-02   640   0.134E+00    0.668E-02
DAV:   2    -0.116053729659E+03   -0.82555E-04   -0.10783E-03   760   0.158E-01    0.393E-02
DAV:   3    -0.116053724015E+03    0.56437E-05   -0.32676E-05   688   0.332E-02 
 151 F= -.11605372E+03 E0= -.11603494E+03  d E =-.281198E-03
 trial-energy change:   -0.000281  1 .order   -0.000274   -0.000321   -0.000227
 step:   1.1893(harm=  1.1893)  dis= 0.01396  next Energy=  -116.053992 (dE=-0.549E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116053496951E+03    0.23271E-03   -0.38517E-01   640   0.326E+00    0.155E-01
DAV:   2    -0.116054012171E+03   -0.51522E-03   -0.65414E-03   752   0.387E-01    0.915E-02
DAV:   3    -0.116053975418E+03    0.36754E-04   -0.19802E-04   832   0.810E-02    0.491E-02
DAV:   4    -0.116053975164E+03    0.25396E-06   -0.12885E-04   744   0.680E-02    0.120E-02
DAV:   5    -0.116053973644E+03    0.15200E-05   -0.21147E-05   720   0.300E-02 
 152 F= -.11605397E+03 E0= -.11603519E+03  d E =-.530827E-03
 curvature:  -9.97 expect dE=-0.210E-01 dE for cont linesearch -0.785E-05
 trial: gam= 2.40320 g(F)=  0.210E-02 g(S)=  0.000E+00 ort =-0.110E-03 (trialstep = 0.878E-01)
 search vector abs. value=  0.910E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116054101427E+03   -0.12626E-03   -0.24024E-02   640   0.810E-01    0.374E-02
DAV:   2    -0.116054136609E+03   -0.35183E-04   -0.41621E-04   760   0.973E-02    0.233E-02
DAV:   3    -0.116054134450E+03    0.21592E-05   -0.11933E-05   592   0.243E-02 
 153 F= -.11605413E+03 E0= -.11603535E+03  d E =-.160806E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000161  1 .order   -0.000156   -0.000162   -0.000151
 step:   0.3512(harm=  1.3283)  dis= 0.01020  next Energy=  -116.055195 (dE=-0.122E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116054250069E+03   -0.11346E-03   -0.21403E-01   640   0.242E+00    0.112E-01
DAV:   2    -0.116054524244E+03   -0.27418E-03   -0.34961E-03   768   0.283E-01    0.686E-02
DAV:   3    -0.116054503840E+03    0.20404E-04   -0.10032E-04   856   0.593E-02    0.358E-02
DAV:   4    -0.116054505973E+03   -0.21330E-05   -0.74479E-05   752   0.505E-02 
 154 F= -.11605451E+03 E0= -.11603572E+03  d E =-.532329E-03
 curvature: -12.47 expect dE=-0.168E-01 dE for cont linesearch -0.691E-04
 ZBRENT: increasing intervall
 opt :   0.8780  next Energy=  -116.054349 (dE=-0.376E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116053688918E+03    0.81492E-03   -0.86307E-01   640   0.485E+00    0.226E-01
DAV:   2    -0.116054835766E+03   -0.11468E-02   -0.14514E-02   728   0.577E-01    0.138E-01
DAV:   3    -0.116054747571E+03    0.88195E-04   -0.42111E-04   864   0.127E-01    0.741E-02
DAV:   4    -0.116054754340E+03   -0.67682E-05   -0.34522E-04   728   0.109E-01    0.218E-02
DAV:   5    -0.116054747000E+03    0.73398E-05   -0.55253E-05   872   0.492E-02 
 155 F= -.11605475E+03 E0= -.11603596E+03  d E =-.773356E-03
 curvature:  28.27 expect dE= 0.576E-01 dE for cont linesearch  0.198E-04
 trial: gam= 0.67767 g(F)=  0.204E-02 g(S)=  0.000E+00 ort =-0.252E-03 (trialstep = 0.246E+00)
 search vector abs. value=  0.435E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116054981084E+03   -0.22674E-03   -0.96934E-02   640   0.163E+00    0.741E-02
DAV:   2    -0.116055120931E+03   -0.13985E-03   -0.16867E-03   784   0.197E-01    0.453E-02
DAV:   3    -0.116055113630E+03    0.73018E-05   -0.43295E-05   664   0.391E-02 
 156 F= -.11605511E+03 E0= -.11603633E+03  d E =-.366630E-03
 trial-energy change:   -0.000367  1 .order   -0.000364   -0.000459   -0.000270
 step:   0.5957(harm=  0.5957)  dis= 0.01221  next Energy=  -116.055303 (dE=-0.556E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116055081294E+03    0.39637E-04   -0.19412E-01   640   0.231E+00    0.107E-01
DAV:   2    -0.116055331237E+03   -0.24994E-03   -0.31730E-03   792   0.272E-01    0.647E-02
DAV:   3    -0.116055319727E+03    0.11511E-04   -0.11457E-04   832   0.580E-02    0.318E-02
DAV:   4    -0.116055320699E+03   -0.97184E-06   -0.37705E-05   704   0.395E-02 
 157 F= -.11605532E+03 E0= -.11603653E+03  d E =-.573699E-03
 curvature:  -6.94 expect dE=-0.101E-01 dE for cont linesearch -0.252E-05
 trial: gam= 0.62536 g(F)=  0.146E-02 g(S)=  0.000E+00 ort =-0.126E-03 (trialstep = 0.316E+00)
 search vector abs. value=  0.183E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116055604516E+03   -0.28479E-03   -0.68671E-02   640   0.139E+00    0.670E-02
DAV:   2    -0.116055700935E+03   -0.96419E-04   -0.12274E-03   760   0.171E-01    0.392E-02
DAV:   3    -0.116055693790E+03    0.71444E-05   -0.54055E-05   808   0.405E-02 
 158 F= -.11605569E+03 E0= -.11603691E+03  d E =-.373092E-03
 trial-energy change:   -0.000373  1 .order   -0.000348   -0.000436   -0.000260
 step:   0.7799(harm=  0.7799)  dis= 0.01065  next Energy=  -116.055859 (dE=-0.539E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116055703173E+03   -0.22385E-05   -0.14677E-01   640   0.203E+00    0.999E-02
DAV:   2    -0.116055899022E+03   -0.19585E-03   -0.25339E-03   768   0.246E-01    0.596E-02
DAV:   3    -0.116055879136E+03    0.19886E-04   -0.11941E-04   832   0.613E-02    0.291E-02
DAV:   4    -0.116055876897E+03    0.22386E-05   -0.27174E-05   608   0.366E-02 
 159 F= -.11605588E+03 E0= -.11603709E+03  d E =-.556198E-03
 curvature:  -5.17 expect dE=-0.477E-02 dE for cont linesearch -0.446E-05
 trial: gam= 0.80124 g(F)=  0.923E-03 g(S)=  0.000E+00 ort =-0.126E-03 (trialstep = 0.409E+00)
 search vector abs. value=  0.125E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116056102657E+03   -0.22352E-03   -0.66252E-02   640   0.133E+00    0.655E-02
DAV:   2    -0.116056178059E+03   -0.75402E-04   -0.97299E-04   760   0.150E-01    0.399E-02
DAV:   3    -0.116056171180E+03    0.68792E-05   -0.34289E-05   752   0.364E-02 
 160 F= -.11605617E+03 E0= -.11603738E+03  d E =-.294283E-03
 trial-energy change:   -0.000294  1 .order   -0.000288   -0.000336   -0.000239
 step:   1.4140(harm=  1.4140)  dis= 0.01671  next Energy=  -116.056458 (dE=-0.581E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116056024808E+03    0.15325E-03   -0.39902E-01   640   0.327E+00    0.161E-01
DAV:   2    -0.116056468389E+03   -0.44358E-03   -0.58072E-03   760   0.365E-01    0.982E-02
DAV:   3    -0.116056422832E+03    0.45557E-04   -0.20901E-04   856   0.885E-02    0.504E-02
DAV:   4    -0.116056422998E+03   -0.16578E-06   -0.11602E-04   720   0.588E-02    0.125E-02
DAV:   5    -0.116056420694E+03    0.23038E-05   -0.20383E-05   616   0.320E-02 
 161 F= -.11605642E+03 E0= -.11603763E+03  d E =-.543798E-03
 curvature: -10.72 expect dE=-0.159E-01 dE for cont linesearch -0.861E-05
 trial: gam= 1.53651 g(F)=  0.149E-02 g(S)=  0.000E+00 ort =-0.100E-03 (trialstep = 0.248E+00)
 search vector abs. value=  0.306E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116056638756E+03   -0.21576E-03   -0.62625E-02   640   0.130E+00    0.626E-02
DAV:   2    -0.116056720204E+03   -0.81448E-04   -0.98678E-04   768   0.151E-01    0.380E-02
DAV:   3    -0.116056714252E+03    0.59517E-05   -0.28023E-05   648   0.343E-02 
 162 F= -.11605671E+03 E0= -.11603793E+03  d E =-.293558E-03
 trial-energy change:   -0.000294  1 .order   -0.000289   -0.000331   -0.000247
 step:   0.9812(harm=  0.9812)  dis= 0.01859  next Energy=  -116.057074 (dE=-0.653E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116056441132E+03    0.27907E-03   -0.54195E-01   640   0.382E+00    0.184E-01
DAV:   2    -0.116057106188E+03   -0.66506E-03   -0.83744E-03   728   0.441E-01    0.111E-01
DAV:   3    -0.116057045555E+03    0.60633E-04   -0.24230E-04   800   0.953E-02    0.581E-02
DAV:   4    -0.116057045594E+03   -0.38838E-07   -0.17090E-04   744   0.743E-02    0.132E-02
DAV:   5    -0.116057043429E+03    0.21642E-05   -0.28649E-05   760   0.354E-02 
 163 F= -.11605704E+03 E0= -.11603826E+03  d E =-.622735E-03
 curvature: -11.29 expect dE=-0.249E-01 dE for cont linesearch -0.592E-05
 trial: gam= 1.46843 g(F)=  0.221E-02 g(S)=  0.000E+00 ort =-0.127E-03 (trialstep = 0.178E+00)
 search vector abs. value=  0.679E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116057290995E+03   -0.24540E-03   -0.70811E-02   640   0.138E+00    0.663E-02
DAV:   2    -0.116057382764E+03   -0.91769E-04   -0.11537E-03   704   0.164E-01    0.393E-02
DAV:   3    -0.116057377346E+03    0.54179E-05   -0.38809E-05   744   0.371E-02 
 164 F= -.11605738E+03 E0= -.11603859E+03  d E =-.333917E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000334  1 .order   -0.000325   -0.000360   -0.000290
 step:   0.7127(harm=  0.9110)  dis= 0.02040  next Energy=  -116.057965 (dE=-0.921E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116057203127E+03    0.17964E-03   -0.63327E-01   640   0.413E+00    0.200E-01
DAV:   2    -0.116057976891E+03   -0.77376E-03   -0.10081E-02   728   0.485E-01    0.118E-01
DAV:   3    -0.116057920125E+03    0.56766E-04   -0.33835E-04   872   0.105E-01    0.609E-02
DAV:   4    -0.116057922477E+03   -0.23526E-05   -0.14851E-04   744   0.672E-02    0.128E-02
DAV:   5    -0.116057922278E+03    0.19933E-06   -0.26038E-05   728   0.308E-02 
 165 F= -.11605792E+03 E0= -.11603913E+03  d E =-.878849E-03
 curvature: -14.17 expect dE=-0.172E-01 dE for cont linesearch -0.265E-04
 ZBRENT: extrapolating
 opt :   0.8626  next Energy=  -116.057949 (dE=-0.906E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116057895738E+03    0.26739E-04   -0.50101E-02   640   0.116E+00    0.563E-02
DAV:   2    -0.116057961555E+03   -0.65817E-04   -0.81926E-04   760   0.138E-01    0.331E-02
DAV:   3    -0.116057958138E+03    0.34170E-05   -0.26217E-05   696   0.308E-02 
 166 F= -.11605796E+03 E0= -.11603917E+03  d E =-.914709E-03
 curvature: -14.28 expect dE=-0.219E-01 dE for cont linesearch -0.150E-06
 trial: gam= 0.62864 g(F)=  0.154E-02 g(S)=  0.000E+00 ort = 0.267E-04 (trialstep = 0.315E+00)
 search vector abs. value=  0.284E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116058282588E+03   -0.32103E-03   -0.10219E-01   640   0.167E+00    0.819E-02
DAV:   2    -0.116058410147E+03   -0.12756E-03   -0.17181E-03   728   0.199E-01    0.465E-02
DAV:   3    -0.116058402423E+03    0.77236E-05   -0.57790E-05   856   0.426E-02 
 167 F= -.11605840E+03 E0= -.11603961E+03  d E =-.444285E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000444  1 .order   -0.000433   -0.000490   -0.000376
 step:   1.2602(harm=  1.3621)  dis= 0.02376  next Energy=  -116.059016 (dE=-0.106E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116057971481E+03    0.43867E-03   -0.92285E-01   640   0.503E+00    0.245E-01
DAV:   2    -0.116059145695E+03   -0.11742E-02   -0.15761E-02   728   0.604E-01    0.140E-01
DAV:   3    -0.116059063322E+03    0.82373E-04   -0.49751E-04   872   0.126E-01    0.762E-02
DAV:   4    -0.116059056301E+03    0.70210E-05   -0.25156E-04   712   0.909E-02    0.151E-02
DAV:   5    -0.116059057200E+03   -0.89929E-06   -0.47021E-05   840   0.378E-02 
 168 F= -.11605906E+03 E0= -.11604027E+03  d E =-.109906E-02
 curvature: -12.33 expect dE=-0.242E-01 dE for cont linesearch -0.103E-04
 trial: gam= 1.24946 g(F)=  0.196E-02 g(S)=  0.000E+00 ort = 0.154E-03 (trialstep = 0.307E+00)
 search vector abs. value=  0.467E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116059345801E+03   -0.28950E-03   -0.16775E-01   640   0.217E+00    0.105E-01
DAV:   2    -0.116059588799E+03   -0.24300E-03   -0.31109E-03   752   0.271E-01    0.602E-02
DAV:   3    -0.116059570945E+03    0.17853E-04   -0.87048E-05   776   0.581E-02    0.344E-02
DAV:   4    -0.116059573741E+03   -0.27958E-05   -0.73603E-05   736   0.529E-02 
 169 F= -.11605957E+03 E0= -.11604078E+03  d E =-.516541E-03
 trial-energy change:   -0.000517  1 .order   -0.000466   -0.000662   -0.000270
 step:   0.4100(harm=  0.5177)  dis= 0.01000  next Energy=  -116.059621 (dE=-0.564E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116059647533E+03   -0.76587E-04   -0.19390E-02   656   0.737E-01    0.387E-02
DAV:   2    -0.116059677476E+03   -0.29943E-04   -0.38539E-04   784   0.949E-02    0.210E-02
DAV:   3    -0.116059676424E+03    0.10517E-05   -0.94700E-06   592   0.205E-02 
 170 F= -.11605968E+03 E0= -.11604089E+03  d E =-.619223E-03
 curvature:  -4.14 expect dE=-0.272E-02 dE for cont linesearch -0.603E-04
 ZBRENT: increasing intervall
 opt :   0.6167  next Energy=  -116.059835 (dE=-0.778E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116059674536E+03    0.29398E-05   -0.75382E-02   640   0.145E+00    0.710E-02
DAV:   2    -0.116059774616E+03   -0.10008E-03   -0.13307E-03   768   0.177E-01    0.402E-02
DAV:   3    -0.116059766940E+03    0.76761E-05   -0.38455E-05   760   0.382E-02 
 171 F= -.11605977E+03 E0= -.11604098E+03  d E =-.709739E-03
 curvature: -10.92 expect dE=-0.133E-01 dE for cont linesearch -0.811E-06
 trial: gam= 0.72680 g(F)=  0.121E-02 g(S)=  0.000E+00 ort = 0.589E-04 (trialstep = 0.369E+00)
 search vector abs. value=  0.260E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116060078143E+03   -0.30353E-03   -0.11104E-01   640   0.173E+00    0.879E-02
DAV:   2    -0.116060192344E+03   -0.11420E-03   -0.16222E-03   760   0.192E-01    0.518E-02
DAV:   3    -0.116060180771E+03    0.11573E-04   -0.53953E-05   776   0.442E-02    0.266E-02
DAV:   4    -0.116060182804E+03   -0.20331E-05   -0.38799E-05   672   0.357E-02 
 172 F= -.11606018E+03 E0= -.11604139E+03  d E =-.415864E-03
 trial-energy change:   -0.000416  1 .order   -0.000390   -0.000463   -0.000316
 step:   1.1591(harm=  1.1591)  dis= 0.02145  next Energy=  -116.060496 (dE=-0.729E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116060206113E+03   -0.25343E-04   -0.51774E-01   640   0.372E+00    0.187E-01
DAV:   2    -0.116060796191E+03   -0.59008E-03   -0.80243E-03   720   0.429E-01    0.112E-01
DAV:   3    -0.116060728700E+03    0.67491E-04   -0.26194E-04   856   0.100E-01    0.602E-02
DAV:   4    -0.116060732819E+03   -0.41182E-05   -0.21881E-04   752   0.844E-02    0.164E-02
DAV:   5    -0.116060728144E+03    0.46749E-05   -0.40423E-05   800   0.387E-02 
 173 F= -.11606073E+03 E0= -.11604194E+03  d E =-.961204E-03
 curvature: -11.97 expect dE=-0.162E-01 dE for cont linesearch -0.616E-04
 ZBRENT: increasing intervall
 opt :   2.7401  next Energy=  -116.060528 (dE=-0.761E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116058345712E+03    0.23871E-02   -0.20660E+00   640   0.744E+00    0.372E-01
DAV:   2    -0.116060714610E+03   -0.23689E-02   -0.31993E-02   728   0.856E-01    0.224E-01
DAV:   3    -0.116060436336E+03    0.27827E-03   -0.10582E-03   856   0.202E-01    0.121E-01
DAV:   4    -0.116060446215E+03   -0.98788E-05   -0.88870E-04   776   0.170E-01    0.333E-02
DAV:   5    -0.116060425483E+03    0.20732E-04   -0.16780E-04   808   0.787E-02    0.170E-02
DAV:   6    -0.116060429470E+03   -0.39875E-05   -0.45290E-05   784   0.326E-02 
 174 F= -.11606043E+03 E0= -.11604164E+03  d E =-.662531E-03
 curvature:  38.83 expect dE= 0.247E+00 dE for cont linesearch  0.895E-03
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   1.6664  next Energy=  -116.060821 (dE=-0.105E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116059912220E+03    0.51326E-03   -0.95269E-01   640   0.505E+00    0.248E-01
DAV:   2    -0.116060964879E+03   -0.10527E-02   -0.14263E-02   736   0.572E-01    0.150E-01
DAV:   3    -0.116060841682E+03    0.12320E-03   -0.45326E-04   808   0.134E-01    0.784E-02
DAV:   4    -0.116060849009E+03   -0.73272E-05   -0.36745E-04   720   0.109E-01    0.201E-02
DAV:   5    -0.116060842237E+03    0.67725E-05   -0.67282E-05   800   0.496E-02 
 175 F= -.11606084E+03 E0= -.11604205E+03  d E =-.107530E-02
 curvature:  -4.02 expect dE=-0.924E-02 dE for cont linesearch -0.617E-06
 trial: gam= 1.70479 g(F)=  0.230E-02 g(S)=  0.000E+00 ort = 0.631E-04 (trialstep = 0.209E+00)
 search vector abs. value=  0.780E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116061174242E+03   -0.32523E-03   -0.10576E-01   640   0.168E+00    0.829E-02
DAV:   2    -0.116061285694E+03   -0.11145E-03   -0.16350E-03   736   0.196E-01    0.502E-02
DAV:   3    -0.116061271911E+03    0.13783E-04   -0.65598E-05   864   0.451E-02    0.259E-02
DAV:   4    -0.116061270938E+03    0.97328E-06   -0.32121E-05   688   0.317E-02 
 176 F= -.11606127E+03 E0= -.11604248E+03  d E =-.428701E-03
 trial-energy change:   -0.000429  1 .order   -0.000414   -0.000503   -0.000326
 step:   0.5933(harm=  0.5933)  dis= 0.01915  next Energy=  -116.061556 (dE=-0.713E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116061355299E+03   -0.83388E-04   -0.35736E-01   640   0.308E+00    0.153E-01
DAV:   2    -0.116061761789E+03   -0.40649E-03   -0.57075E-03   760   0.366E-01    0.925E-02
DAV:   3    -0.116061717707E+03    0.44082E-04   -0.20870E-04   848   0.829E-02    0.491E-02
DAV:   4    -0.116061714722E+03    0.29843E-05   -0.11832E-04   728   0.605E-02    0.128E-02
DAV:   5    -0.116061711499E+03    0.32237E-05   -0.21165E-05   640   0.307E-02 
 177 F= -.11606171E+03 E0= -.11604292E+03  d E =-.869262E-03
 curvature:  -9.62 expect dE=-0.149E-01 dE for cont linesearch -0.368E-04
 ZBRENT: increasing intervall
 opt :   1.3615  next Energy=  -116.061355 (dE=-0.513E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116059863269E+03    0.18515E-02   -0.14267E+00   640   0.616E+00    0.304E-01
DAV:   2    -0.116061495794E+03   -0.16325E-02   -0.22689E-02   760   0.729E-01    0.185E-01
DAV:   3    -0.116061316753E+03    0.17904E-03   -0.84676E-04   864   0.166E-01    0.976E-02
DAV:   4    -0.116061303060E+03    0.13693E-04   -0.46610E-04   752   0.120E-01    0.252E-02
DAV:   5    -0.116061292850E+03    0.10209E-04   -0.95179E-05   872   0.607E-02    0.117E-02
DAV:   6    -0.116061294560E+03   -0.17093E-05   -0.24212E-05   768   0.234E-02 
 178 F= -.11606129E+03 E0= -.11604250E+03  d E =-.452323E-03
 curvature:  93.07 expect dE= 0.798E+00 dE for cont linesearch  0.327E-02
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   0.7839  next Energy=  -116.061764 (dE=-0.921E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116060963419E+03    0.32943E-03   -0.80625E-01   640   0.463E+00    0.227E-01
DAV:   2    -0.116061866408E+03   -0.90299E-03   -0.12537E-02   768   0.542E-01    0.138E-01
DAV:   3    -0.116061773634E+03    0.92774E-04   -0.45500E-04   840   0.122E-01    0.715E-02
DAV:   4    -0.116061777810E+03   -0.41759E-05   -0.24563E-04   720   0.864E-02    0.175E-02
DAV:   5    -0.116061774904E+03    0.29057E-05   -0.46053E-05   792   0.419E-02 
 179 F= -.11606177E+03 E0= -.11604298E+03  d E =-.932668E-03
 curvature:  -1.48 expect dE=-0.357E-02 dE for cont linesearch -0.748E-08
 trial: gam= 1.06601 g(F)=  0.241E-02 g(S)=  0.000E+00 ort = 0.199E-04 (trialstep = 0.278E+00)
 search vector abs. value=  0.910E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116062124817E+03   -0.34701E-03   -0.22669E-01   640   0.246E+00    0.118E-01
DAV:   2    -0.116062392399E+03   -0.26758E-03   -0.36507E-03   752   0.293E-01    0.711E-02
DAV:   3    -0.116062368797E+03    0.23602E-04   -0.12002E-04   776   0.623E-02    0.374E-02
DAV:   4    -0.116062366859E+03    0.19381E-05   -0.75153E-05   744   0.497E-02 
 180 F= -.11606237E+03 E0= -.11604358E+03  d E =-.591954E-03
 trial-energy change:   -0.000592  1 .order   -0.000543   -0.000675   -0.000411
 step:   0.4356(harm=  0.7099)  dis= 0.01526  next Energy=  -116.062493 (dE=-0.718E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116062530925E+03   -0.16213E-03   -0.74056E-02   640   0.141E+00    0.695E-02
DAV:   2    -0.116062624240E+03   -0.93316E-04   -0.12596E-03   760   0.172E-01    0.407E-02
DAV:   3    -0.116062617647E+03    0.65934E-05   -0.37243E-05   784   0.361E-02 
 181 F= -.11606262E+03 E0= -.11604383E+03  d E =-.842742E-03
 curvature:  -7.94 expect dE=-0.104E-01 dE for cont linesearch -0.169E-03
 ZBRENT: increasing intervall
 opt :   0.7518  next Energy=  -116.063031 (dE=-0.126E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116062615014E+03    0.92259E-05   -0.29173E-01   640   0.280E+00    0.136E-01
DAV:   2    -0.116062953683E+03   -0.33867E-03   -0.46336E-03   760   0.330E-01    0.805E-02
DAV:   3    -0.116062929028E+03    0.24655E-04   -0.15771E-04   856   0.705E-02    0.421E-02
DAV:   4    -0.116062926878E+03    0.21500E-05   -0.87469E-05   760   0.544E-02 
 182 F= -.11606293E+03 E0= -.11604414E+03  d E =-.115197E-02
 curvature: -19.34 expect dE=-0.365E-01 dE for cont linesearch -0.125E-04
 trial: gam= 0.58103 g(F)=  0.188E-02 g(S)=  0.000E+00 ort = 0.243E-03 (trialstep = 0.372E+00)
 search vector abs. value=  0.329E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116063398894E+03   -0.46987E-03   -0.15873E-01   640   0.208E+00    0.102E-01
DAV:   2    -0.116063606741E+03   -0.20785E-03   -0.28638E-03   760   0.258E-01    0.600E-02
DAV:   3    -0.116063588733E+03    0.18009E-04   -0.89224E-05   864   0.569E-02    0.334E-02
DAV:   4    -0.116063590160E+03   -0.14272E-05   -0.67191E-05   736   0.491E-02 
 183 F= -.11606359E+03 E0= -.11604480E+03  d E =-.663282E-03
 trial-energy change:   -0.000663  1 .order   -0.000593   -0.000754   -0.000432
 step:   0.5441(harm=  0.8715)  dis= 0.01137  next Energy=  -116.063697 (dE=-0.770E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116063744999E+03   -0.15627E-03   -0.33954E-02   640   0.960E-01    0.486E-02
DAV:   2    -0.116063791728E+03   -0.46729E-04   -0.63950E-04   768   0.122E-01    0.281E-02
DAV:   3    -0.116063788285E+03    0.34424E-05   -0.17239E-05   640   0.266E-02 
 184 F= -.11606379E+03 E0= -.11604500E+03  d E =-.861407E-03
 curvature:  -4.03 expect dE=-0.271E-02 dE for cont linesearch -0.118E-03
 ZBRENT: increasing intervall
 opt :   0.8874  next Energy=  -116.064065 (dE=-0.114E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116063828700E+03   -0.36972E-04   -0.13303E-01   640   0.190E+00    0.932E-02
DAV:   2    -0.116063993988E+03   -0.16529E-03   -0.22948E-03   760   0.230E-01    0.548E-02
DAV:   3    -0.116063980057E+03    0.13930E-04   -0.73638E-05   880   0.508E-02    0.297E-02
DAV:   4    -0.116063980936E+03   -0.87868E-06   -0.47347E-05   744   0.415E-02 
 185 F= -.11606398E+03 E0= -.11604519E+03  d E =-.105406E-02
 curvature:  -9.42 expect dE=-0.142E-01 dE for cont linesearch -0.837E-08
 trial: gam= 0.99681 g(F)=  0.151E-02 g(S)=  0.000E+00 ort = 0.541E-05 (trialstep = 0.457E+00)
 search vector abs. value=  0.342E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116064187236E+03   -0.20718E-03   -0.24842E-01   640   0.261E+00    0.128E-01
DAV:   2    -0.116064513591E+03   -0.32636E-03   -0.43662E-03   760   0.318E-01    0.750E-02
DAV:   3    -0.116064483743E+03    0.29849E-04   -0.11592E-04   808   0.650E-02    0.424E-02
DAV:   4    -0.116064482105E+03    0.16375E-05   -0.10607E-04   728   0.575E-02    0.113E-02
DAV:   5    -0.116064480107E+03    0.19985E-05   -0.18746E-05   648   0.269E-02 
 186 F= -.11606448E+03 E0= -.11604569E+03  d E =-.499170E-03
 trial-energy change:   -0.000499  1 .order   -0.000458   -0.000692   -0.000225
 step:   0.5882(harm=  0.6771)  dis= 0.01258  next Energy=  -116.064513 (dE=-0.532E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116064506121E+03   -0.24016E-04   -0.20454E-02   656   0.750E-01    0.366E-02
DAV:   2    -0.116064534669E+03   -0.28547E-04   -0.36531E-04   784   0.919E-02    0.215E-02
DAV:   3    -0.116064532087E+03    0.25812E-05   -0.85074E-06   592   0.189E-02 
 187 F= -.11606453E+03 E0= -.11604574E+03  d E =-.551151E-03
 curvature:  -6.41 expect dE=-0.594E-02 dE for cont linesearch -0.124E-04
 ZBRENT: increasing intervall
 opt :   0.8503  next Energy=  -116.064538 (dE=-0.558E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116064421575E+03    0.11309E-03   -0.80631E-02   640   0.149E+00    0.733E-02
DAV:   2    -0.116064520467E+03   -0.98892E-04   -0.13682E-03   792   0.178E-01    0.421E-02
DAV:   3    -0.116064510717E+03    0.97508E-05   -0.32659E-05   728   0.348E-02 
 188 F= -.11606451E+03 E0= -.11604572E+03  d E =-.529781E-03
 curvature:  -3.28 expect dE=-0.639E-02 dE for cont linesearch -0.131E-04
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   0.6959  next Energy=  -116.064546 (dE=-0.565E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116064506050E+03    0.14417E-04   -0.29170E-02   640   0.894E-01    0.425E-02
DAV:   2    -0.116064550384E+03   -0.44334E-04   -0.53444E-04   752   0.112E-01    0.266E-02
DAV:   3    -0.116064546123E+03    0.42610E-05   -0.14257E-05   592   0.246E-02 
 189 F= -.11606455E+03 E0= -.11604575E+03  d E =-.565187E-03
 curvature:  -3.47 expect dE=-0.455E-02 dE for cont linesearch -0.190E-06
 trial: gam= 0.88705 g(F)=  0.131E-02 g(S)=  0.000E+00 ort =-0.433E-04 (trialstep = 0.505E+00)
 search vector abs. value=  0.282E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116064690806E+03   -0.14042E-03   -0.25431E-01   640   0.265E+00    0.121E-01
DAV:   2    -0.116065037515E+03   -0.34671E-03   -0.43265E-03   752   0.317E-01    0.742E-02
DAV:   3    -0.116065011646E+03    0.25869E-04   -0.13969E-04   848   0.691E-02    0.396E-02
DAV:   4    -0.116065008946E+03    0.27001E-05   -0.61317E-05   744   0.465E-02 
 190 F= -.11606501E+03 E0= -.11604622E+03  d E =-.462823E-03
 trial-energy change:   -0.000463  1 .order   -0.000427   -0.000643   -0.000211
 step:   0.7515(harm=  0.7515)  dis= 0.01465  next Energy=  -116.065025 (dE=-0.479E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116065025834E+03   -0.14188E-04   -0.60639E-02   640   0.129E+00    0.617E-02
DAV:   2    -0.116065107582E+03   -0.81748E-04   -0.10427E-03   768   0.155E-01    0.365E-02
DAV:   3    -0.116065102455E+03    0.51273E-05   -0.34508E-05   728   0.352E-02 
 191 F= -.11606510E+03 E0= -.11604631E+03  d E =-.556331E-03
 curvature:  -8.31 expect dE=-0.887E-02 dE for cont linesearch -0.130E-04
 trial: gam= 0.51618 g(F)=  0.107E-02 g(S)=  0.000E+00 ort = 0.210E-03 (trialstep = 0.554E+00)
 search vector abs. value=  0.879E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116065437919E+03   -0.33034E-03   -0.97047E-02   640   0.164E+00    0.785E-02
DAV:   2    -0.116065552391E+03   -0.11447E-03   -0.16090E-03   864   0.194E-01    0.503E-02
DAV:   3    -0.116065536907E+03    0.15484E-04   -0.71716E-05   760   0.492E-02    0.247E-02
DAV:   4    -0.116065537360E+03   -0.45301E-06   -0.24496E-05   568   0.278E-02 
 192 F= -.11606554E+03 E0= -.11604675E+03  d E =-.434905E-03
 trial-energy change:   -0.000435  1 .order   -0.000428   -0.000652   -0.000204
 step:   0.8066(harm=  0.8066)  dis= 0.00849  next Energy=  -116.065577 (dE=-0.474E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116065567338E+03   -0.30431E-04   -0.20303E-02   640   0.749E-01    0.357E-02
DAV:   2    -0.116065594594E+03   -0.27256E-04   -0.36721E-04   880   0.932E-02    0.230E-02
DAV:   3    -0.116065591174E+03    0.34200E-05   -0.13433E-05   656   0.230E-02 
 193 F= -.11606559E+03 E0= -.11604680E+03  d E =-.488719E-03
 curvature:  -3.01 expect dE=-0.317E-02 dE for cont linesearch -0.439E-06
 trial: gam= 1.13486 g(F)=  0.105E-02 g(S)=  0.000E+00 ort = 0.358E-04 (trialstep = 0.427E+00)
 search vector abs. value=  0.124E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116065832414E+03   -0.23782E-03   -0.87945E-02   640   0.158E+00    0.754E-02
DAV:   2    -0.116065951199E+03   -0.11878E-03   -0.16106E-03   800   0.194E-01    0.449E-02
DAV:   3    -0.116065941880E+03    0.93183E-05   -0.49230E-05   808   0.424E-02 
 194 F= -.11606594E+03 E0= -.11604715E+03  d E =-.350706E-03
 trial-energy change:   -0.000351  1 .order   -0.000348   -0.000466   -0.000229
 step:   0.8392(harm=  0.8392)  dis= 0.01043  next Energy=  -116.066050 (dE=-0.459E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116065962379E+03   -0.11181E-04   -0.81302E-02   640   0.152E+00    0.740E-02
DAV:   2    -0.116066064707E+03   -0.10233E-03   -0.14415E-03   800   0.183E-01    0.433E-02
DAV:   3    -0.116066057385E+03    0.73220E-05   -0.45879E-05   800   0.405E-02 
 195 F= -.11606606E+03 E0= -.11604726E+03  d E =-.466211E-03
 curvature:  -4.78 expect dE=-0.555E-02 dE for cont linesearch -0.590E-07
 trial: gam= 1.04330 g(F)=  0.116E-02 g(S)=  0.000E+00 ort = 0.124E-04 (trialstep = 0.430E+00)
 search vector abs. value=  0.147E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116066333700E+03   -0.26899E-03   -0.11084E-01   640   0.177E+00    0.815E-02
DAV:   2    -0.116066487605E+03   -0.15390E-03   -0.19742E-03   776   0.214E-01    0.482E-02
DAV:   3    -0.116066477778E+03    0.98270E-05   -0.66368E-05   888   0.479E-02 
 196 F= -.11606648E+03 E0= -.11604769E+03  d E =-.420393E-03
 trial-energy change:   -0.000420  1 .order   -0.000409   -0.000505   -0.000312
 step:   1.1244(harm=  1.1244)  dis= 0.01513  next Energy=  -116.066718 (dE=-0.660E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116066372174E+03    0.11543E-03   -0.28932E-01   640   0.286E+00    0.131E-01
DAV:   2    -0.116066780826E+03   -0.40865E-03   -0.51743E-03   768   0.346E-01    0.777E-02
DAV:   3    -0.116066753869E+03    0.26957E-04   -0.15266E-04   880   0.733E-02    0.421E-02
DAV:   4    -0.116066752226E+03    0.16425E-05   -0.87388E-05   760   0.584E-02 
 197 F= -.11606675E+03 E0= -.11604796E+03  d E =-.694841E-03
 curvature:  -7.06 expect dE=-0.110E-01 dE for cont linesearch -0.591E-05
 trial: gam= 1.30326 g(F)=  0.156E-02 g(S)=  0.000E+00 ort =-0.111E-03 (trialstep = 0.319E+00)
 search vector abs. value=  0.263E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116067009885E+03   -0.25602E-03   -0.10746E-01   640   0.172E+00    0.788E-02
DAV:   2    -0.116067160485E+03   -0.15060E-03   -0.19011E-03   784   0.210E-01    0.460E-02
DAV:   3    -0.116067153137E+03    0.73473E-05   -0.49843E-05   784   0.419E-02 
 198 F= -.11606715E+03 E0= -.11604836E+03  d E =-.400911E-03
 trial-energy change:   -0.000401  1 .order   -0.000366   -0.000451   -0.000282
 step:   0.8533(harm=  0.8533)  dis= 0.01536  next Energy=  -116.067355 (dE=-0.603E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116066967046E+03    0.19344E-03   -0.29765E-01   640   0.287E+00    0.129E-01
DAV:   2    -0.116067365876E+03   -0.39883E-03   -0.50504E-03   792   0.341E-01    0.763E-02
DAV:   3    -0.116067343238E+03    0.22638E-04   -0.13410E-04   840   0.679E-02    0.392E-02
DAV:   4    -0.116067345720E+03   -0.24816E-05   -0.69560E-05   736   0.485E-02 
 199 F= -.11606735E+03 E0= -.11604855E+03  d E =-.593494E-03
 curvature:  -7.94 expect dE=-0.182E-01 dE for cont linesearch -0.528E-04
 ZBRENT: interpolating
 opt :   0.6818  next Energy=  -116.067382 (dE=-0.629E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116067314987E+03    0.28252E-04   -0.30493E-02   664   0.920E-01    0.389E-02
DAV:   2    -0.116067357063E+03   -0.42076E-04   -0.51371E-04   784   0.110E-01    0.245E-02
DAV:   3    -0.116067354519E+03    0.25432E-05   -0.13128E-05   592   0.222E-02 
 200 F= -.11606735E+03 E0= -.11604856E+03  d E =-.602293E-03
 curvature:  -5.39 expect dE=-0.774E-02 dE for cont linesearch -0.442E-05
 trial: gam= 0.83232 g(F)=  0.144E-02 g(S)=  0.000E+00 ort = 0.147E-03 (trialstep = 0.391E+00)
 search vector abs. value=  0.199E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116067633154E+03   -0.27609E-03   -0.13039E-01   640   0.192E+00    0.911E-02
DAV:   2    -0.116067845691E+03   -0.21254E-03   -0.25179E-03   760   0.242E-01    0.502E-02
DAV:   3    -0.116067830466E+03    0.15225E-04   -0.63863E-05   840   0.485E-02    0.285E-02
DAV:   4    -0.116067830016E+03    0.45002E-06   -0.50748E-05   736   0.399E-02 
 201 F= -.11606783E+03 E0= -.11604904E+03  d E =-.475496E-03
 trial-energy change:   -0.000475  1 .order   -0.000446   -0.000610   -0.000281
 step:   0.7267(harm=  0.7267)  dis= 0.01121  next Energy=  -116.067921 (dE=-0.566E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116067875595E+03   -0.45129E-04   -0.95765E-02   640   0.164E+00    0.815E-02
DAV:   2    -0.116068032147E+03   -0.15655E-03   -0.18702E-03   768   0.209E-01    0.442E-02
DAV:   3    -0.116068021189E+03    0.10958E-04   -0.50054E-05   800   0.441E-02    0.249E-02
DAV:   4    -0.116068021664E+03   -0.47495E-06   -0.40024E-05   760   0.352E-02 
 202 F= -.11606802E+03 E0= -.11604923E+03  d E =-.667144E-03
 curvature:  -4.64 expect dE=-0.380E-02 dE for cont linesearch -0.563E-05
 trial: gam= 0.56110 g(F)=  0.820E-03 g(S)=  0.000E+00 ort = 0.155E-03 (trialstep = 0.458E+00)
 search vector abs. value=  0.726E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116068278918E+03   -0.25773E-03   -0.65270E-02   656   0.136E+00    0.597E-02
DAV:   2    -0.116068377548E+03   -0.98630E-04   -0.11627E-03   768   0.165E-01    0.354E-02
DAV:   3    -0.116068372102E+03    0.54460E-05   -0.31687E-05   712   0.325E-02 
 203 F= -.11606837E+03 E0= -.11604958E+03  d E =-.350438E-03
 trial-energy change:   -0.000350  1 .order   -0.000335   -0.000416   -0.000254
 step:   1.1789(harm=  1.1789)  dis= 0.01073  next Energy=  -116.068557 (dE=-0.535E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116068331619E+03    0.45929E-04   -0.15880E-01   640   0.213E+00    0.920E-02
DAV:   2    -0.116068566726E+03   -0.23511E-03   -0.27539E-03   760   0.254E-01    0.547E-02
DAV:   3    -0.116068553758E+03    0.12968E-04   -0.77417E-05   832   0.492E-02    0.288E-02
DAV:   4    -0.116068552234E+03    0.15237E-05   -0.31038E-05   688   0.337E-02 
 204 F= -.11606855E+03 E0= -.11604976E+03  d E =-.530570E-03
 curvature:  -4.72 expect dE=-0.645E-02 dE for cont linesearch -0.901E-05
 trial: gam= 2.03103 g(F)=  0.137E-02 g(S)=  0.000E+00 ort =-0.118E-03 (trialstep = 0.142E+00)
 search vector abs. value=  0.308E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116068672787E+03   -0.11903E-03   -0.25828E-02   672   0.853E-01    0.379E-02
DAV:   2    -0.116068711677E+03   -0.38890E-04   -0.45094E-04   760   0.101E-01    0.219E-02
DAV:   3    -0.116068710321E+03    0.13564E-05   -0.97078E-06   576   0.187E-02 
 205 F= -.11606871E+03 E0= -.11604992E+03  d E =-.158087E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000158  1 .order   -0.000149   -0.000160   -0.000137
 step:   0.5675(harm=  0.9978)  dis= 0.01074  next Energy=  -116.069115 (dE=-0.563E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116068643272E+03    0.68405E-04   -0.22942E-01   640   0.254E+00    0.109E-01
DAV:   2    -0.116068978780E+03   -0.33551E-03   -0.38911E-03   736   0.297E-01    0.648E-02
DAV:   3    -0.116068962885E+03    0.15894E-04   -0.93929E-05   864   0.551E-02    0.347E-02
DAV:   4    -0.116068962319E+03    0.56621E-06   -0.54991E-05   760   0.427E-02 
 206 F= -.11606896E+03 E0= -.11605017E+03  d E =-.410085E-03
 curvature: -10.19 expect dE=-0.113E-01 dE for cont linesearch -0.683E-07
 trial: gam= 0.28907 g(F)=  0.111E-02 g(S)=  0.000E+00 ort =-0.144E-04 (trialstep = 0.227E+00)
 search vector abs. value=  0.368E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069161897E+03   -0.19901E-03   -0.83740E-03   672   0.496E-01    0.275E-02
DAV:   2    -0.116069179226E+03   -0.17329E-04   -0.22594E-04   856   0.753E-02    0.182E-02
DAV:   3    -0.116069176566E+03    0.26602E-05   -0.82943E-06   568   0.196E-02 
 207 F= -.11606918E+03 E0= -.11605038E+03  d E =-.214247E-03
 trial-energy change:   -0.000214  1 .order   -0.000210   -0.000251   -0.000169
 step:   0.6972(harm=  0.6972)  dis= 0.00411  next Energy=  -116.069347 (dE=-0.385E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069257430E+03   -0.78204E-04   -0.34828E-02   656   0.101E+00    0.537E-02
DAV:   2    -0.116069319487E+03   -0.62057E-04   -0.83793E-04   864   0.146E-01    0.352E-02
DAV:   3    -0.116069309124E+03    0.10363E-04   -0.31420E-05   784   0.354E-02    0.209E-02
DAV:   4    -0.116069308827E+03    0.29677E-06   -0.43070E-05   728   0.363E-02 
 208 F= -.11606931E+03 E0= -.11605052E+03  d E =-.346508E-03
 curvature:  -1.16 expect dE=-0.928E-03 dE for cont linesearch -0.153E-04
 ZBRENT: interpolating
 opt :   0.5898  next Energy=  -116.069321 (dE=-0.358E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069313621E+03   -0.44972E-05   -0.17959E-03   720   0.229E-01    0.111E-02
DAV:   2    -0.116069315654E+03   -0.20326E-05   -0.31847E-05   712   0.293E-02 
 209 F= -.11606932E+03 E0= -.11605052E+03  d E =-.353334E-03
 curvature:  -0.90 expect dE=-0.457E-03 dE for cont linesearch -0.220E-06
 trial: gam= 0.51842 g(F)=  0.510E-03 g(S)=  0.000E+00 ort = 0.301E-04 (trialstep = 0.300E+00)
 search vector abs. value=  0.153E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069436785E+03   -0.12316E-03   -0.73629E-03   672   0.466E-01    0.211E-02
DAV:   2    -0.116069449023E+03   -0.12238E-04   -0.15652E-04   824   0.618E-02    0.120E-02
DAV:   3    -0.116069447725E+03    0.12975E-05   -0.50052E-06   552   0.141E-02 
 210 F= -.11606945E+03 E0= -.11605066E+03  d E =-.132072E-03
 trial-energy change:   -0.000132  1 .order   -0.000133   -0.000158   -0.000109
 step:   0.9667(harm=  0.9667)  dis= 0.00337  next Energy=  -116.069570 (dE=-0.254E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069516964E+03   -0.67941E-04   -0.36080E-02   656   0.103E+00    0.491E-02
DAV:   2    -0.116069569654E+03   -0.52690E-04   -0.71746E-04   840   0.132E-01    0.286E-02
DAV:   3    -0.116069563322E+03    0.63317E-05   -0.27746E-05   768   0.314E-02 
 211 F= -.11606956E+03 E0= -.11605077E+03  d E =-.247669E-03
 curvature:  -1.41 expect dE=-0.698E-03 dE for cont linesearch -0.281E-07
 trial: gam= 0.98850 g(F)=  0.497E-03 g(S)=  0.000E+00 ort =-0.553E-05 (trialstep = 0.334E+00)
 search vector abs. value=  0.198E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069672503E+03   -0.10285E-03   -0.11527E-02   688   0.586E-01    0.271E-02
DAV:   2    -0.116069690625E+03   -0.18122E-04   -0.24000E-04   848   0.758E-02    0.171E-02
DAV:   3    -0.116069688840E+03    0.17854E-05   -0.83187E-06   568   0.180E-02 
 212 F= -.11606969E+03 E0= -.11605090E+03  d E =-.125517E-03
 trial-energy change:   -0.000126  1 .order   -0.000124   -0.000164   -0.000085
 step:   0.6903(harm=  0.6903)  dis= 0.00267  next Energy=  -116.069733 (dE=-0.169E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069712281E+03   -0.21656E-04   -0.13036E-02   656   0.622E-01    0.276E-02
DAV:   2    -0.116069733612E+03   -0.21331E-04   -0.26892E-04   856   0.796E-02    0.172E-02
DAV:   3    -0.116069731782E+03    0.18293E-05   -0.66068E-06   560   0.162E-02 
 213 F= -.11606973E+03 E0= -.11605094E+03  d E =-.168460E-03
 curvature:  -1.39 expect dE=-0.491E-03 dE for cont linesearch -0.409E-07
 trial: gam= 0.69438 g(F)=  0.353E-03 g(S)=  0.000E+00 ort =-0.763E-05 (trialstep = 0.406E+00)
 search vector abs. value=  0.130E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069829152E+03   -0.95540E-04   -0.11195E-02   656   0.577E-01    0.275E-02
DAV:   2    -0.116069850001E+03   -0.20850E-04   -0.25468E-04   832   0.781E-02    0.162E-02
DAV:   3    -0.116069847677E+03    0.23242E-05   -0.87970E-06   576   0.198E-02 
 214 F= -.11606985E+03 E0= -.11605106E+03  d E =-.115895E-03
 trial-energy change:   -0.000116  1 .order   -0.000115   -0.000141   -0.000089
 step:   1.0954(harm=  1.0954)  dis= 0.00338  next Energy=  -116.069922 (dE=-0.190E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116069863899E+03   -0.13897E-04   -0.32394E-02   656   0.981E-01    0.467E-02
DAV:   2    -0.116069924508E+03   -0.60609E-04   -0.73641E-04   832   0.133E-01    0.272E-02
DAV:   3    -0.116069918100E+03    0.64078E-05   -0.20266E-05   648   0.293E-02 
 215 F= -.11606992E+03 E0= -.11605113E+03  d E =-.186317E-03
 curvature:  -2.04 expect dE=-0.631E-03 dE for cont linesearch -0.167E-07
 trial: gam= 0.82498 g(F)=  0.309E-03 g(S)=  0.000E+00 ort =-0.326E-05 (trialstep = 0.544E+00)
 search vector abs. value=  0.119E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070001177E+03   -0.76669E-04   -0.19884E-02   656   0.760E-01    0.340E-02
DAV:   2    -0.116070034363E+03   -0.33186E-04   -0.40718E-04   848   0.987E-02    0.203E-02
DAV:   3    -0.116070031774E+03    0.25884E-05   -0.88221E-06   576   0.180E-02 
 216 F= -.11607003E+03 E0= -.11605124E+03  d E =-.113675E-03
 trial-energy change:   -0.000114  1 .order   -0.000115   -0.000167   -0.000064
 step:   0.8823(harm=  0.8823)  dis= 0.00262  next Energy=  -116.070053 (dE=-0.135E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070038973E+03   -0.46098E-05   -0.75926E-03   672   0.469E-01    0.208E-02
DAV:   2    -0.116070051176E+03   -0.12204E-04   -0.14573E-04   880   0.586E-02    0.123E-02
DAV:   3    -0.116070050292E+03    0.88398E-06   -0.27813E-06   568   0.104E-02 
 217 F= -.11607005E+03 E0= -.11605126E+03  d E =-.132193E-03
 curvature:  -1.71 expect dE=-0.906E-03 dE for cont linesearch -0.629E-09
 trial: gam= 1.67146 g(F)=  0.530E-03 g(S)=  0.000E+00 ort =-0.661E-06 (trialstep = 0.189E+00)
 search vector abs. value=  0.384E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070134231E+03   -0.83055E-04   -0.66909E-03   672   0.438E-01    0.189E-02
DAV:   2    -0.116070144592E+03   -0.10361E-04   -0.12315E-04   768   0.526E-02    0.112E-02
DAV:   3    -0.116070144121E+03    0.47124E-06   -0.32784E-06   496   0.118E-02 
 218 F= -.11607014E+03 E0= -.11605135E+03  d E =-.938284E-04
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000094  1 .order   -0.000093   -0.000100   -0.000086
 step:   0.7550(harm=  1.3720)  dis= 0.00406  next Energy=  -116.070413 (dE=-0.363E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070253091E+03   -0.10850E-03   -0.60734E-02   640   0.132E+00    0.560E-02
DAV:   2    -0.116070349270E+03   -0.96179E-04   -0.11491E-03   760   0.161E-01    0.334E-02
DAV:   3    -0.116070343807E+03    0.54625E-05   -0.31447E-05   760   0.332E-02 
 219 F= -.11607034E+03 E0= -.11605155E+03  d E =-.293515E-03
 curvature:  -3.63 expect dE=-0.117E-02 dE for cont linesearch -0.528E-04
 ZBRENT: increasing intervall
 opt :   1.8874  next Energy=  -116.070363 (dE=-0.312E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070014415E+03    0.33486E-03   -0.24225E-01   640   0.264E+00    0.113E-01
DAV:   2    -0.116070393842E+03   -0.37943E-03   -0.45405E-03   760   0.320E-01    0.670E-02
DAV:   3    -0.116070372074E+03    0.21768E-04   -0.13342E-04   872   0.668E-02    0.370E-02
DAV:   4    -0.116070370405E+03    0.16693E-05   -0.59984E-05   744   0.464E-02 
 220 F= -.11607037E+03 E0= -.11605158E+03  d E =-.320113E-03
 curvature:  -1.30 expect dE=-0.177E-02 dE for cont linesearch -0.269E-04
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   1.2713  next Energy=  -116.070405 (dE=-0.355E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070313245E+03    0.58830E-04   -0.71753E-02   640   0.144E+00    0.578E-02
DAV:   2    -0.116070427213E+03   -0.11397E-03   -0.13595E-03   768   0.176E-01    0.362E-02
DAV:   3    -0.116070419866E+03    0.73469E-05   -0.41729E-05   784   0.364E-02 
 221 F= -.11607042E+03 E0= -.11605163E+03  d E =-.369574E-03
 curvature:  -2.95 expect dE=-0.174E-02 dE for cont linesearch -0.320E-05
 trial: gam= 0.98397 g(F)=  0.590E-03 g(S)=  0.000E+00 ort = 0.646E-04 (trialstep = 0.351E+00)
 search vector abs. value=  0.444E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070530695E+03   -0.10348E-03   -0.30918E-02   656   0.944E-01    0.382E-02
DAV:   2    -0.116070593160E+03   -0.62465E-04   -0.70544E-04   840   0.126E-01    0.231E-02
DAV:   3    -0.116070589193E+03    0.39676E-05   -0.10695E-05   608   0.220E-02 
 222 F= -.11607059E+03 E0= -.11605180E+03  d E =-.169327E-03
 trial-energy change:   -0.000169  1 .order   -0.000175   -0.000229   -0.000122
 step:   0.7468(harm=  0.7468)  dis= 0.00430  next Energy=  -116.070664 (dE=-0.244E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070595087E+03   -0.19272E-05   -0.38065E-02   672   0.105E+00    0.465E-02
DAV:   2    -0.116070659747E+03   -0.64659E-04   -0.77666E-04   848   0.133E-01    0.263E-02
DAV:   3    -0.116070655892E+03    0.38550E-05   -0.12100E-05   624   0.221E-02 
 223 F= -.11607066E+03 E0= -.11605186E+03  d E =-.236026E-03
 curvature:  -2.54 expect dE=-0.132E-02 dE for cont linesearch -0.250E-06
 trial: gam= 0.94445 g(F)=  0.522E-03 g(S)=  0.000E+00 ort = 0.209E-04 (trialstep = 0.422E+00)
 search vector abs. value=  0.452E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070782689E+03   -0.12294E-03   -0.40459E-02   640   0.107E+00    0.469E-02
DAV:   2    -0.116070843261E+03   -0.60571E-04   -0.73888E-04   760   0.130E-01    0.268E-02
DAV:   3    -0.116070840520E+03    0.27406E-05   -0.19707E-05   648   0.249E-02 
 224 F= -.11607084E+03 E0= -.11605205E+03  d E =-.184628E-03
 trial-energy change:   -0.000185  1 .order   -0.000185   -0.000229   -0.000142
 step:   1.1073(harm=  1.1073)  dis= 0.00652  next Energy=  -116.070956 (dE=-0.300E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070806633E+03    0.36627E-04   -0.10711E-01   640   0.175E+00    0.760E-02
DAV:   2    -0.116070969870E+03   -0.16324E-03   -0.19751E-03   752   0.213E-01    0.441E-02
DAV:   3    -0.116070961539E+03    0.83309E-05   -0.52984E-05   824   0.389E-02 
 225 F= -.11607096E+03 E0= -.11605217E+03  d E =-.305648E-03
 curvature:  -4.62 expect dE=-0.376E-02 dE for cont linesearch -0.241E-06
 trial: gam= 1.51069 g(F)=  0.814E-03 g(S)=  0.000E+00 ort =-0.154E-04 (trialstep = 0.228E+00)
 search vector abs. value=  0.111E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116071090243E+03   -0.12037E-03   -0.25677E-02   672   0.858E-01    0.404E-02
DAV:   2    -0.116071129597E+03   -0.39354E-04   -0.46762E-04   800   0.103E-01    0.232E-02
DAV:   3    -0.116071127723E+03    0.18739E-05   -0.12298E-05   552   0.215E-02 
 226 F= -.11607113E+03 E0= -.11605234E+03  d E =-.166184E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000166  1 .order   -0.000161   -0.000180   -0.000141
 step:   0.9123(harm=  1.0414)  dis= 0.00852  next Energy=  -116.071374 (dE=-0.412E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116070974659E+03    0.15494E-03   -0.23522E-01   640   0.260E+00    0.116E-01
DAV:   2    -0.116071367632E+03   -0.39297E-03   -0.45348E-03   792   0.320E-01    0.669E-02
DAV:   3    -0.116071349336E+03    0.18295E-04   -0.93216E-05   840   0.545E-02    0.370E-02
DAV:   4    -0.116071346252E+03    0.30845E-05   -0.57337E-05   728   0.452E-02 
 227 F= -.11607135E+03 E0= -.11605256E+03  d E =-.384712E-03
 curvature:  -7.11 expect dE=-0.741E-02 dE for cont linesearch -0.724E-05
 trial: gam= 1.27727 g(F)=  0.104E-02 g(S)=  0.000E+00 ort =-0.106E-03 (trialstep = 0.215E+00)
 search vector abs. value=  0.189E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116071489605E+03   -0.14027E-03   -0.34997E-02   664   0.991E-01    0.470E-02
DAV:   2    -0.116071543452E+03   -0.53847E-04   -0.65127E-04   768   0.123E-01    0.265E-02
DAV:   3    -0.116071541434E+03    0.20181E-05   -0.13152E-05   632   0.223E-02 
 228 F= -.11607154E+03 E0= -.11605275E+03  d E =-.195182E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000195  1 .order   -0.000182   -0.000194   -0.000170
 step:   0.8582(harm=  1.7216)  dis= 0.01063  next Energy=  -116.072126 (dE=-0.780E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116071381283E+03    0.16217E-03   -0.31015E-01   640   0.295E+00    0.134E-01
DAV:   2    -0.116071838353E+03   -0.45707E-03   -0.55535E-03   784   0.358E-01    0.783E-02
DAV:   3    -0.116071814601E+03    0.23752E-04   -0.11801E-04   832   0.647E-02    0.433E-02
DAV:   4    -0.116071814604E+03   -0.26321E-08   -0.10037E-04   712   0.570E-02    0.102E-02
DAV:   5    -0.116071813724E+03    0.87986E-06   -0.15558E-05   640   0.238E-02 
 229 F= -.11607181E+03 E0= -.11605302E+03  d E =-.467472E-03
 curvature: -12.03 expect dE=-0.127E-01 dE for cont linesearch -0.722E-07
 trial: gam= 0.91149 g(F)=  0.106E-02 g(S)=  0.000E+00 ort = 0.106E-04 (trialstep = 0.343E+00)
 search vector abs. value=  0.167E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072001045E+03   -0.18644E-03   -0.81264E-02   640   0.151E+00    0.707E-02
DAV:   2    -0.116072125521E+03   -0.12448E-03   -0.14702E-03   760   0.186E-01    0.402E-02
DAV:   3    -0.116072118233E+03    0.72875E-05   -0.39597E-05   776   0.391E-02 
 230 F= -.11607212E+03 E0= -.11605333E+03  d E =-.304509E-03
 trial-energy change:   -0.000305  1 .order   -0.000294   -0.000366   -0.000221
 step:   0.8638(harm=  0.8638)  dis= 0.01018  next Energy=  -116.072275 (dE=-0.461E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072042230E+03    0.83291E-04   -0.18461E-01   640   0.227E+00    0.109E-01
DAV:   2    -0.116072308083E+03   -0.26585E-03   -0.31922E-03   760   0.274E-01    0.612E-02
DAV:   3    -0.116072292870E+03    0.15212E-04   -0.86461E-05   864   0.560E-02    0.321E-02
DAV:   4    -0.116072295117E+03   -0.22467E-05   -0.47405E-05   760   0.397E-02 
 231 F= -.11607230E+03 E0= -.11605351E+03  d E =-.481393E-03
 curvature:  -6.78 expect dE=-0.673E-02 dE for cont linesearch -0.787E-05
 trial: gam= 1.10310 g(F)=  0.993E-03 g(S)=  0.000E+00 ort =-0.139E-03 (trialstep = 0.356E+00)
 search vector abs. value=  0.211E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072427174E+03   -0.13430E-03   -0.92691E-02   640   0.160E+00    0.785E-02
DAV:   2    -0.116072565553E+03   -0.13838E-03   -0.16198E-03   760   0.191E-01    0.444E-02
DAV:   3    -0.116072560040E+03    0.55138E-05   -0.38651E-05   664   0.369E-02 
 232 F= -.11607256E+03 E0= -.11605377E+03  d E =-.264923E-03
 trial-energy change:   -0.000265  1 .order   -0.000239   -0.000299   -0.000179
 step:   0.8847(harm=  0.8847)  dis= 0.01193  next Energy=  -116.072667 (dE=-0.371E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072383671E+03    0.18188E-03   -0.20175E-01   640   0.236E+00    0.113E-01
DAV:   2    -0.116072671621E+03   -0.28795E-03   -0.33771E-03   768   0.275E-01    0.642E-02
DAV:   3    -0.116072660127E+03    0.11494E-04   -0.82392E-05   856   0.507E-02    0.330E-02
DAV:   4    -0.116072660828E+03   -0.70108E-06   -0.40899E-05   760   0.371E-02 
 233 F= -.11607266E+03 E0= -.11605387E+03  d E =-.365711E-03
 curvature: -11.09 expect dE=-0.142E-01 dE for cont linesearch -0.385E-04
 ZBRENT: interpolating
 opt :   0.6995  next Energy=  -116.072686 (dE=-0.391E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072633483E+03    0.26644E-04   -0.24636E-02   640   0.826E-01    0.376E-02
DAV:   2    -0.116072669079E+03   -0.35595E-04   -0.41028E-04   768   0.967E-02    0.226E-02
DAV:   3    -0.116072667432E+03    0.16461E-05   -0.10126E-05   624   0.187E-02 
 234 F= -.11607267E+03 E0= -.11605388E+03  d E =-.372315E-03
 curvature:  -7.21 expect dE=-0.567E-02 dE for cont linesearch -0.319E-05
 trial: gam= 0.63551 g(F)=  0.786E-03 g(S)=  0.000E+00 ort = 0.965E-04 (trialstep = 0.424E+00)
 search vector abs. value=  0.941E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072854409E+03   -0.18533E-03   -0.61710E-02   640   0.131E+00    0.607E-02
DAV:   2    -0.116072945744E+03   -0.91334E-04   -0.11147E-03   768   0.161E-01    0.372E-02
DAV:   3    -0.116072937904E+03    0.78392E-05   -0.38077E-05   808   0.353E-02 
 235 F= -.11607294E+03 E0= -.11605415E+03  d E =-.270472E-03
 trial-energy change:   -0.000270  1 .order   -0.000266   -0.000360   -0.000173
 step:   0.8193(harm=  0.8193)  dis= 0.00745  next Energy=  -116.073015 (dE=-0.347E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116072963795E+03   -0.18052E-04   -0.52304E-02   640   0.120E+00    0.584E-02
DAV:   2    -0.116073034342E+03   -0.70546E-04   -0.89459E-04   792   0.145E-01    0.349E-02
DAV:   3    -0.116073027931E+03    0.64109E-05   -0.29186E-05   696   0.327E-02 
 236 F= -.11607303E+03 E0= -.11605424E+03  d E =-.360498E-03
 curvature:  -4.55 expect dE=-0.261E-02 dE for cont linesearch -0.910E-06
 trial: gam= 0.80669 g(F)=  0.573E-03 g(S)=  0.000E+00 ort = 0.434E-04 (trialstep = 0.503E+00)
 search vector abs. value=  0.677E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073153936E+03   -0.11959E-03   -0.70398E-02   640   0.141E+00    0.690E-02
DAV:   2    -0.116073251935E+03   -0.97999E-04   -0.11783E-03   792   0.166E-01    0.384E-02
DAV:   3    -0.116073245340E+03    0.65952E-05   -0.36570E-05   792   0.369E-02 
 237 F= -.11607325E+03 E0= -.11605446E+03  d E =-.217409E-03
 trial-energy change:   -0.000217  1 .order   -0.000210   -0.000306   -0.000114
 step:   0.8022(harm=  0.8022)  dis= 0.00632  next Energy=  -116.073272 (dE=-0.244E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073255950E+03   -0.40151E-05   -0.24538E-02   656   0.830E-01    0.426E-02
DAV:   2    -0.116073288293E+03   -0.32343E-04   -0.39549E-04   792   0.958E-02    0.234E-02
DAV:   3    -0.116073286580E+03    0.17128E-05   -0.10696E-05   632   0.206E-02 
 238 F= -.11607329E+03 E0= -.11605450E+03  d E =-.258649E-03
 curvature:  -4.47 expect dE=-0.229E-02 dE for cont linesearch -0.622E-06
 trial: gam= 0.88781 g(F)=  0.512E-03 g(S)=  0.000E+00 ort = 0.307E-04 (trialstep = 0.563E+00)
 search vector abs. value=  0.590E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073379024E+03   -0.90731E-04   -0.60063E-02   640   0.129E+00    0.694E-02
DAV:   2    -0.116073470393E+03   -0.91369E-04   -0.11417E-03   792   0.163E-01    0.398E-02
DAV:   3    -0.116073461330E+03    0.90629E-05   -0.33250E-05   696   0.372E-02 
 239 F= -.11607346E+03 E0= -.11605467E+03  d E =-.174750E-03
 trial-energy change:   -0.000175  1 .order   -0.000175   -0.000304   -0.000047
 step:   0.6672(harm=  0.6672)  dis= 0.00503  next Energy=  -116.073466 (dE=-0.180E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073462660E+03    0.77330E-05   -0.19102E-03   736   0.231E-01    0.152E-02
DAV:   2    -0.116073463116E+03   -0.45694E-06   -0.30125E-05   728   0.311E-02 
 240 F= -.11607346E+03 E0= -.11605467E+03  d E =-.176537E-03
 curvature:  -3.65 expect dE=-0.164E-02 dE for cont linesearch -0.446E-06
 trial: gam= 0.92048 g(F)=  0.450E-03 g(S)=  0.000E+00 ort =-0.268E-04 (trialstep = 0.584E+00)
 search vector abs. value=  0.540E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073586635E+03   -0.12398E-03   -0.58062E-02   640   0.126E+00    0.643E-02
DAV:   2    -0.116073663996E+03   -0.77361E-04   -0.96104E-04   760   0.148E-01    0.380E-02
DAV:   3    -0.116073659342E+03    0.46546E-05   -0.31515E-05   688   0.315E-02 
 241 F= -.11607366E+03 E0= -.11605487E+03  d E =-.196225E-03
 trial-energy change:   -0.000196  1 .order   -0.000191   -0.000248   -0.000133
 step:   1.2603(harm=  1.2603)  dis= 0.00940  next Energy=  -116.073731 (dE=-0.268E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073650987E+03    0.13009E-04   -0.77088E-02   640   0.145E+00    0.734E-02
DAV:   2    -0.116073750541E+03   -0.99554E-04   -0.12324E-03   760   0.167E-01    0.422E-02
DAV:   3    -0.116073746047E+03    0.44945E-05   -0.45710E-05   760   0.366E-02 
 242 F= -.11607375E+03 E0= -.11605496E+03  d E =-.282930E-03
 curvature:  -8.01 expect dE=-0.682E-02 dE for cont linesearch -0.138E-06
 trial: gam= 1.66693 g(F)=  0.852E-03 g(S)=  0.000E+00 ort =-0.966E-05 (trialstep = 0.245E+00)
 search vector abs. value=  0.158E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073881503E+03   -0.13096E-03   -0.31864E-02   640   0.926E-01    0.472E-02
DAV:   2    -0.116073919025E+03   -0.37521E-04   -0.47751E-04   744   0.107E-01    0.278E-02
DAV:   3    -0.116073916981E+03    0.20437E-05   -0.17415E-05   624   0.247E-02 
 243 F= -.11607392E+03 E0= -.11605513E+03  d E =-.170934E-03
 trial-energy change:   -0.000171  1 .order   -0.000166   -0.000205   -0.000128
 step:   0.6494(harm=  0.6494)  dis= 0.00840  next Energy=  -116.074017 (dE=-0.271E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116073909444E+03    0.95809E-05   -0.86895E-02   640   0.153E+00    0.748E-02
DAV:   2    -0.116074018559E+03   -0.10912E-03   -0.13435E-03   744   0.178E-01    0.443E-02
DAV:   3    -0.116074012379E+03    0.61803E-05   -0.41373E-05   752   0.361E-02 
 244 F= -.11607401E+03 E0= -.11605522E+03  d E =-.266332E-03
 curvature:  -6.15 expect dE=-0.422E-02 dE for cont linesearch -0.249E-05
 trial: gam= 0.93270 g(F)=  0.685E-03 g(S)=  0.000E+00 ort =-0.800E-04 (trialstep = 0.326E+00)
 search vector abs. value=  0.143E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116074157401E+03   -0.13884E-03   -0.38947E-02   640   0.101E+00    0.527E-02
DAV:   2    -0.116074196374E+03   -0.38973E-04   -0.52836E-04   768   0.109E-01    0.320E-02
DAV:   3    -0.116074193818E+03    0.25557E-05   -0.19504E-05   616   0.275E-02 
 245 F= -.11607419E+03 E0= -.11605541E+03  d E =-.181439E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000181  1 .order   -0.000178   -0.000199   -0.000156
 step:   1.3050(harm=  1.5138)  dis= 0.01638  next Energy=  -116.074475 (dE=-0.462E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116074074501E+03    0.12187E-03   -0.35460E-01   640   0.304E+00    0.155E-01
DAV:   2    -0.116074459092E+03   -0.38459E-03   -0.50245E-03   752   0.339E-01    0.946E-02
DAV:   3    -0.116074427559E+03    0.31533E-04   -0.18132E-04   808   0.802E-02    0.431E-02
DAV:   4    -0.116074431489E+03   -0.39305E-05   -0.83521E-05   744   0.494E-02 
 246 F= -.11607443E+03 E0= -.11605564E+03  d E =-.419111E-03
 curvature: -17.18 expect dE=-0.186E-01 dE for cont linesearch -0.163E-04
 trial: gam= 1.35287 g(F)=  0.108E-02 g(S)=  0.000E+00 ort =-0.116E-03 (trialstep = 0.277E+00)
 search vector abs. value=  0.269E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116074607195E+03   -0.17964E-03   -0.46615E-02   640   0.108E+00    0.587E-02
DAV:   2    -0.116074656251E+03   -0.49056E-04   -0.62985E-04   784   0.118E-01    0.368E-02
DAV:   3    -0.116074652464E+03    0.37872E-05   -0.24418E-05   608   0.319E-02 
 247 F= -.11607465E+03 E0= -.11605586E+03  d E =-.220974E-03
 trial-energy change:   -0.000221  1 .order   -0.000206   -0.000256   -0.000156
 step:   0.7105(harm=  0.7105)  dis= 0.01239  next Energy=  -116.074760 (dE=-0.329E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116074641077E+03    0.15174E-04   -0.11236E-01   640   0.167E+00    0.892E-02
DAV:   2    -0.116074753991E+03   -0.11291E-03   -0.14408E-03   784   0.179E-01    0.559E-02
DAV:   3    -0.116074743838E+03    0.10152E-04   -0.54643E-05   752   0.443E-02    0.203E-02
DAV:   4    -0.116074744139E+03   -0.30037E-06   -0.13487E-05   576   0.214E-02 
 248 F= -.11607474E+03 E0= -.11605596E+03  d E =-.312649E-03
 curvature: -10.34 expect dE=-0.144E-01 dE for cont linesearch -0.119E-04
 trial: gam= 1.45223 g(F)=  0.140E-02 g(S)=  0.000E+00 ort =-0.176E-03 (trialstep = 0.170E+00)
 search vector abs. value=  0.577E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116074895005E+03   -0.15117E-03   -0.37881E-02   640   0.962E-01    0.512E-02
DAV:   2    -0.116074930400E+03   -0.35394E-04   -0.44980E-04   752   0.100E-01    0.316E-02
DAV:   3    -0.116074928523E+03    0.18768E-05   -0.17552E-05   600   0.257E-02 
 249 F= -.11607493E+03 E0= -.11605614E+03  d E =-.184384E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000184  1 .order   -0.000181   -0.000194   -0.000168
 step:   0.6793(harm=  1.2680)  dis= 0.01752  next Energy=  -116.075467 (dE=-0.722E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075007886E+03   -0.77487E-04   -0.33908E-01   640   0.288E+00    0.152E-01
DAV:   2    -0.116075311498E+03   -0.30361E-03   -0.39185E-03   720   0.295E-01    0.941E-02
DAV:   3    -0.116075285384E+03    0.26114E-04   -0.16629E-04   824   0.720E-02    0.320E-02
DAV:   4    -0.116075287828E+03   -0.24444E-05   -0.35918E-05   760   0.308E-02 
 250 F= -.11607529E+03 E0= -.11605650E+03  d E =-.543690E-03
 curvature: -22.88 expect dE=-0.263E-01 dE for cont linesearch -0.361E-04
 ZBRENT: extrapolating
 opt :   0.9036  next Energy=  -116.075322 (dE=-0.578E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075300683E+03   -0.15299E-04   -0.66330E-02   640   0.127E+00    0.682E-02
DAV:   2    -0.116075363576E+03   -0.62893E-04   -0.79627E-04   736   0.133E-01    0.421E-02
DAV:   3    -0.116075359617E+03    0.39595E-05   -0.31899E-05   672   0.341E-02 
 251 F= -.11607536E+03 E0= -.11605657E+03  d E =-.615478E-03
 curvature: -21.46 expect dE=-0.306E-01 dE for cont linesearch -0.139E-04
 trial: gam= 0.51938 g(F)=  0.143E-02 g(S)=  0.000E+00 ort = 0.193E-03 (trialstep = 0.317E+00)
 search vector abs. value=  0.172E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075619217E+03   -0.25564E-03   -0.53175E-02   640   0.119E+00    0.584E-02
DAV:   2    -0.116075692884E+03   -0.73667E-04   -0.88830E-04   856   0.148E-01    0.382E-02
DAV:   3    -0.116075685968E+03    0.69163E-05   -0.36117E-05   680   0.388E-02 
 252 F= -.11607569E+03 E0= -.11605690E+03  d E =-.326351E-03
 trial-energy change:   -0.000326  1 .order   -0.000319   -0.000483   -0.000154
 step:   0.4650(harm=  0.4650)  dis= 0.00646  next Energy=  -116.075715 (dE=-0.355E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075712864E+03   -0.19979E-04   -0.11541E-02   704   0.555E-01    0.294E-02
DAV:   2    -0.116075728516E+03   -0.15653E-04   -0.18535E-04   872   0.672E-02    0.191E-02
DAV:   3    -0.116075727620E+03    0.89622E-06   -0.60524E-06   560   0.174E-02 
 253 F= -.11607573E+03 E0= -.11605694E+03  d E =-.368003E-03
 curvature:  -2.62 expect dE=-0.142E-02 dE for cont linesearch -0.808E-07
 trial: gam= 0.48177 g(F)=  0.543E-03 g(S)=  0.000E+00 ort = 0.230E-04 (trialstep = 0.346E+00)
 search vector abs. value=  0.456E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075862311E+03   -0.13379E-03   -0.15264E-02   640   0.650E-01    0.350E-02
DAV:   2    -0.116075883949E+03   -0.21639E-04   -0.26574E-04   840   0.790E-02    0.214E-02
DAV:   3    -0.116075881446E+03    0.25034E-05   -0.83280E-06   576   0.202E-02 
 254 F= -.11607588E+03 E0= -.11605709E+03  d E =-.153826E-03
 trial-energy change:   -0.000154  1 .order   -0.000153   -0.000192   -0.000114
 step:   0.8567(harm=  0.8567)  dis= 0.00615  next Energy=  -116.075965 (dE=-0.237E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116075918020E+03   -0.34071E-04   -0.33100E-02   640   0.956E-01    0.520E-02
DAV:   2    -0.116075963184E+03   -0.45164E-04   -0.57006E-04   848   0.115E-01    0.314E-02
DAV:   3    -0.116075957129E+03    0.60549E-05   -0.17503E-05   592   0.289E-02 
 255 F= -.11607596E+03 E0= -.11605717E+03  d E =-.229509E-03
 curvature:  -3.52 expect dE=-0.216E-02 dE for cont linesearch -0.141E-06
 trial: gam= 1.10564 g(F)=  0.614E-03 g(S)=  0.000E+00 ort =-0.135E-04 (trialstep = 0.332E+00)
 search vector abs. value=  0.615E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076102208E+03   -0.13902E-03   -0.18379E-02   640   0.704E-01    0.355E-02
DAV:   2    -0.116076121607E+03   -0.19399E-04   -0.26373E-04   856   0.783E-02    0.225E-02
DAV:   3    -0.116076119855E+03    0.17517E-05   -0.11316E-05   576   0.230E-02 
 256 F= -.11607612E+03 E0= -.11605733E+03  d E =-.162726E-03
 trial-energy change:   -0.000163  1 .order   -0.000163   -0.000199   -0.000126
 step:   0.9105(harm=  0.9105)  dis= 0.00767  next Energy=  -116.076230 (dE=-0.273E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076173056E+03   -0.51449E-04   -0.56243E-02   640   0.123E+00    0.615E-02
DAV:   2    -0.116076235813E+03   -0.62757E-04   -0.83400E-04   848   0.139E-01    0.390E-02
DAV:   3    -0.116076229079E+03    0.67338E-05   -0.25153E-05   640   0.350E-02 
 257 F= -.11607623E+03 E0= -.11605744E+03  d E =-.271949E-03
 curvature:  -4.68 expect dE=-0.337E-02 dE for cont linesearch -0.793E-07
 trial: gam= 1.06554 g(F)=  0.721E-03 g(S)=  0.000E+00 ort = 0.102E-04 (trialstep = 0.356E+00)
 search vector abs. value=  0.773E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076389645E+03   -0.15383E-03   -0.28843E-02   640   0.881E-01    0.504E-02
DAV:   2    -0.116076423511E+03   -0.33866E-04   -0.46907E-04   824   0.108E-01    0.275E-02
DAV:   3    -0.116076420404E+03    0.31069E-05   -0.17124E-05   592   0.251E-02 
 258 F= -.11607642E+03 E0= -.11605763E+03  d E =-.191326E-03
 trial-energy change:   -0.000191  1 .order   -0.000191   -0.000261   -0.000121
 step:   0.6667(harm=  0.6667)  dis= 0.00628  next Energy=  -116.076473 (dE=-0.244E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076448063E+03   -0.24552E-04   -0.21790E-02   640   0.764E-01    0.443E-02
DAV:   2    -0.116076473973E+03   -0.25910E-04   -0.33532E-04   800   0.900E-02    0.242E-02
DAV:   3    -0.116076472154E+03    0.18198E-05   -0.10439E-05   568   0.198E-02 
 259 F= -.11607647E+03 E0= -.11605768E+03  d E =-.243075E-03
 curvature:  -3.52 expect dE=-0.204E-02 dE for cont linesearch -0.360E-07
 trial: gam= 0.83472 g(F)=  0.579E-03 g(S)=  0.000E+00 ort =-0.889E-05 (trialstep = 0.418E+00)
 search vector abs. value=  0.595E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076611598E+03   -0.13762E-03   -0.30184E-02   640   0.906E-01    0.478E-02
DAV:   2    -0.116076653281E+03   -0.41683E-04   -0.52952E-04   840   0.111E-01    0.279E-02
DAV:   3    -0.116076650118E+03    0.31631E-05   -0.19316E-05   560   0.264E-02 
 260 F= -.11607665E+03 E0= -.11605786E+03  d E =-.177964E-03
 trial-energy change:   -0.000178  1 .order   -0.000176   -0.000239   -0.000112
 step:   0.7885(harm=  0.7885)  dis= 0.00654  next Energy=  -116.076697 (dE=-0.225E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076673542E+03   -0.20261E-04   -0.23485E-02   640   0.798E-01    0.433E-02
DAV:   2    -0.116076704703E+03   -0.31161E-04   -0.40321E-04   864   0.966E-02    0.251E-02
DAV:   3    -0.116076702381E+03    0.23220E-05   -0.12897E-05   568   0.217E-02 
 261 F= -.11607670E+03 E0= -.11605791E+03  d E =-.230228E-03
 curvature:  -4.11 expect dE=-0.228E-02 dE for cont linesearch -0.121E-08
 trial: gam= 0.88596 g(F)=  0.554E-03 g(S)=  0.000E+00 ort =-0.132E-05 (trialstep = 0.492E+00)
 search vector abs. value=  0.522E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076847717E+03   -0.14301E-03   -0.42379E-02   640   0.109E+00    0.579E-02
DAV:   2    -0.116076905532E+03   -0.57815E-04   -0.76393E-04   768   0.135E-01    0.324E-02
DAV:   3    -0.116076900646E+03    0.48861E-05   -0.21070E-05   656   0.306E-02 
 262 F= -.11607690E+03 E0= -.11605811E+03  d E =-.198265E-03
 trial-energy change:   -0.000198  1 .order   -0.000200   -0.000272   -0.000127
 step:   0.9214(harm=  0.9214)  dis= 0.00716  next Energy=  -116.076957 (dE=-0.255E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116076910642E+03   -0.51102E-05   -0.31677E-02   640   0.943E-01    0.507E-02
DAV:   2    -0.116076949540E+03   -0.38897E-04   -0.54266E-04   784   0.114E-01    0.275E-02
DAV:   3    -0.116076946631E+03    0.29091E-05   -0.15748E-05   656   0.260E-02 
 263 F= -.11607695E+03 E0= -.11605816E+03  d E =-.244249E-03
 curvature:  -4.35 expect dE=-0.367E-02 dE for cont linesearch -0.284E-06
 trial: gam= 1.55847 g(F)=  0.843E-03 g(S)=  0.000E+00 ort =-0.185E-04 (trialstep = 0.224E+00)
 search vector abs. value=  0.135E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077078309E+03   -0.12877E-03   -0.20785E-02   640   0.756E-01    0.387E-02
DAV:   2    -0.116077102662E+03   -0.24353E-04   -0.33300E-04   744   0.884E-02    0.231E-02
DAV:   3    -0.116077100443E+03    0.22191E-05   -0.12893E-05   648   0.231E-02 
 264 F= -.11607710E+03 E0= -.11605831E+03  d E =-.153812E-03
 trial-energy change:   -0.000154  1 .order   -0.000155   -0.000183   -0.000127
 step:   0.7396(harm=  0.7396)  dis= 0.00926  next Energy=  -116.077248 (dE=-0.301E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077120104E+03   -0.17442E-04   -0.11098E-01   640   0.175E+00    0.879E-02
DAV:   2    -0.116077259731E+03   -0.13963E-03   -0.18372E-03   752   0.207E-01    0.529E-02
DAV:   3    -0.116077247200E+03    0.12531E-04   -0.68278E-05   872   0.517E-02    0.279E-02
DAV:   4    -0.116077248999E+03   -0.17991E-05   -0.40592E-05   768   0.365E-02 
 265 F= -.11607725E+03 E0= -.11605846E+03  d E =-.302368E-03
 curvature:  -6.11 expect dE=-0.448E-02 dE for cont linesearch -0.302E-05
 trial: gam= 0.75029 g(F)=  0.733E-03 g(S)=  0.000E+00 ort =-0.815E-04 (trialstep = 0.327E+00)
 search vector abs. value=  0.819E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077387070E+03   -0.13987E-03   -0.24755E-02   640   0.816E-01    0.461E-02
DAV:   2    -0.116077423677E+03   -0.36607E-04   -0.48377E-04   832   0.107E-01    0.262E-02
DAV:   3    -0.116077420693E+03    0.29845E-05   -0.16811E-05   576   0.250E-02 
 266 F= -.11607742E+03 E0= -.11605863E+03  d E =-.171694E-03
 trial-energy change:   -0.000172  1 .order   -0.000166   -0.000220   -0.000113
 step:   0.6722(harm=  0.6722)  dis= 0.00655  next Energy=  -116.077475 (dE=-0.226E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077438099E+03   -0.14422E-04   -0.26990E-02   640   0.852E-01    0.483E-02
DAV:   2    -0.116077474611E+03   -0.36512E-04   -0.48811E-04   848   0.108E-01    0.273E-02
DAV:   3    -0.116077471359E+03    0.32523E-05   -0.17007E-05   576   0.248E-02 
 267 F= -.11607747E+03 E0= -.11605868E+03  d E =-.222360E-03
 curvature:  -4.10 expect dE=-0.287E-02 dE for cont linesearch -0.852E-06
 trial: gam= 1.00389 g(F)=  0.701E-03 g(S)=  0.000E+00 ort =-0.413E-04 (trialstep = 0.366E+00)
 search vector abs. value=  0.887E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077623622E+03   -0.14901E-03   -0.36653E-02   640   0.993E-01    0.517E-02
DAV:   2    -0.116077669871E+03   -0.46249E-04   -0.60767E-04   768   0.117E-01    0.293E-02
DAV:   3    -0.116077668320E+03    0.15506E-05   -0.30080E-05   728   0.276E-02 
 268 F= -.11607767E+03 E0= -.11605888E+03  d E =-.196961E-03
 trial-energy change:   -0.000197  1 .order   -0.000189   -0.000241   -0.000137
 step:   0.8497(harm=  0.8497)  dis= 0.00861  next Energy=  -116.077752 (dE=-0.280E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077706321E+03   -0.36450E-04   -0.64211E-02   640   0.131E+00    0.700E-02
DAV:   2    -0.116077784898E+03   -0.78576E-04   -0.10474E-03   744   0.153E-01    0.396E-02
DAV:   3    -0.116077781647E+03    0.32501E-05   -0.54824E-05   784   0.373E-02 
 269 F= -.11607778E+03 E0= -.11605899E+03  d E =-.310289E-03
 curvature:  -5.71 expect dE=-0.449E-02 dE for cont linesearch -0.224E-06
 trial: gam= 1.00745 g(F)=  0.786E-03 g(S)=  0.000E+00 ort = 0.187E-04 (trialstep = 0.418E+00)
 search vector abs. value=  0.983E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077977465E+03   -0.19257E-03   -0.62197E-02   640   0.132E+00    0.731E-02
DAV:   2    -0.116078064372E+03   -0.86907E-04   -0.11586E-03   840   0.164E-01    0.392E-02
DAV:   3    -0.116078056542E+03    0.78301E-05   -0.30340E-05   648   0.351E-02 
 270 F= -.11607806E+03 E0= -.11605927E+03  d E =-.274894E-03
 trial-energy change:   -0.000275  1 .order   -0.000268   -0.000336   -0.000200
 step:   1.0295(harm=  1.0295)  dis= 0.01085  next Energy=  -116.078196 (dE=-0.414E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116077997035E+03    0.67337E-04   -0.13278E-01   640   0.193E+00    0.104E-01
DAV:   2    -0.116078184339E+03   -0.18730E-03   -0.24887E-03   832   0.239E-01    0.544E-02
DAV:   3    -0.116078168162E+03    0.16176E-04   -0.61945E-05   816   0.491E-02    0.306E-02
DAV:   4    -0.116078166869E+03    0.12934E-05   -0.59510E-05   680   0.487E-02 
 271 F= -.11607817E+03 E0= -.11605938E+03  d E =-.385221E-03
 curvature:  -6.29 expect dE=-0.910E-02 dE for cont linesearch -0.298E-04
 ZBRENT: interpolating
 opt :   0.8391  next Energy=  -116.078187 (dE=-0.406E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078153302E+03    0.14861E-04   -0.12766E-02   640   0.600E-01    0.298E-02
DAV:   2    -0.116078171647E+03   -0.18346E-04   -0.22782E-04   800   0.730E-02    0.169E-02
DAV:   3    -0.116078170474E+03    0.11738E-05   -0.67845E-06   568   0.161E-02 
 272 F= -.11607817E+03 E0= -.11605938E+03  d E =-.388826E-03
 curvature:  -4.33 expect dE=-0.365E-02 dE for cont linesearch -0.223E-05
 trial: gam= 1.18680 g(F)=  0.842E-03 g(S)=  0.000E+00 ort = 0.711E-04 (trialstep = 0.332E+00)
 search vector abs. value=  0.149E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078347733E+03   -0.17609E-03   -0.51080E-02   640   0.118E+00    0.604E-02
DAV:   2    -0.116078419709E+03   -0.71976E-04   -0.95831E-04   776   0.148E-01    0.370E-02
DAV:   3    -0.116078411848E+03    0.78606E-05   -0.30825E-05   704   0.366E-02 
 273 F= -.11607841E+03 E0= -.11605962E+03  d E =-.241375E-03
 trial-energy change:   -0.000241  1 .order   -0.000242   -0.000308   -0.000176
 step:   0.7776(harm=  0.7776)  dis= 0.00998  next Energy=  -116.078531 (dE=-0.360E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078423371E+03   -0.36621E-05   -0.90150E-02   640   0.157E+00    0.842E-02
DAV:   2    -0.116078530047E+03   -0.10668E-03   -0.16155E-03   792   0.194E-01    0.486E-02
DAV:   3    -0.116078520545E+03    0.95016E-05   -0.55789E-05   800   0.462E-02 
 274 F= -.11607852E+03 E0= -.11605973E+03  d E =-.350072E-03
 curvature:  -6.23 expect dE=-0.378E-02 dE for cont linesearch -0.220E-06
 trial: gam= 0.84644 g(F)=  0.607E-03 g(S)=  0.000E+00 ort =-0.229E-04 (trialstep = 0.421E+00)
 search vector abs. value=  0.112E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078646293E+03   -0.11625E-03   -0.57664E-02   640   0.125E+00    0.648E-02
DAV:   2    -0.116078709835E+03   -0.63542E-04   -0.92334E-04   848   0.147E-01    0.381E-02
DAV:   3    -0.116078706894E+03    0.29406E-05   -0.40035E-05   784   0.347E-02 
 275 F= -.11607871E+03 E0= -.11605992E+03  d E =-.186349E-03
 trial-energy change:   -0.000186  1 .order   -0.000182   -0.000247   -0.000117
 step:   0.8011(harm=  0.8011)  dis= 0.00893  next Energy=  -116.078756 (dE=-0.235E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078715236E+03   -0.54010E-05   -0.47206E-02   640   0.113E+00    0.590E-02
DAV:   2    -0.116078770881E+03   -0.55645E-04   -0.75587E-04   848   0.131E-01    0.353E-02
DAV:   3    -0.116078767230E+03    0.36512E-05   -0.22389E-05   664   0.286E-02 
 276 F= -.11607877E+03 E0= -.11605998E+03  d E =-.246684E-03
 curvature:  -7.65 expect dE=-0.750E-02 dE for cont linesearch -0.329E-06
 trial: gam= 1.41337 g(F)=  0.981E-03 g(S)=  0.000E+00 ort = 0.220E-04 (trialstep = 0.238E+00)
 search vector abs. value=  0.234E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078935110E+03   -0.16423E-03   -0.38848E-02   640   0.103E+00    0.537E-02
DAV:   2    -0.116078985305E+03   -0.50194E-04   -0.63037E-04   776   0.120E-01    0.307E-02
DAV:   3    -0.116078983518E+03    0.17869E-05   -0.20881E-05   568   0.261E-02 
 277 F= -.11607898E+03 E0= -.11606019E+03  d E =-.216288E-03
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000216  1 .order   -0.000212   -0.000241   -0.000182
 step:   0.9512(harm=  0.9820)  dis= 0.01524  next Energy=  -116.079264 (dE=-0.497E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116078843144E+03    0.14216E-03   -0.35173E-01   640   0.311E+00    0.159E-01
DAV:   2    -0.116079301858E+03   -0.45871E-03   -0.57132E-03   720   0.361E-01    0.915E-02
DAV:   3    -0.116079270474E+03    0.31384E-04   -0.17730E-04   776   0.727E-02    0.439E-02
DAV:   4    -0.116079268937E+03    0.15365E-05   -0.62137E-05   752   0.470E-02 
 278 F= -.11607927E+03 E0= -.11606048E+03  d E =-.501707E-03
 curvature: -11.35 expect dE=-0.112E-01 dE for cont linesearch -0.422E-05
 trial: gam= 1.14834 g(F)=  0.984E-03 g(S)=  0.000E+00 ort =-0.933E-04 (trialstep = 0.282E+00)
 search vector abs. value=  0.317E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116079424308E+03   -0.15383E-03   -0.67720E-02   640   0.135E+00    0.701E-02
DAV:   2    -0.116079503237E+03   -0.78929E-04   -0.10372E-03   736   0.153E-01    0.416E-02
DAV:   3    -0.116079500057E+03    0.31802E-05   -0.29783E-05   680   0.310E-02 
 279 F= -.11607950E+03 E0= -.11606071E+03  d E =-.231120E-03
 trial-energy change:   -0.000231  1 .order   -0.000214   -0.000247   -0.000181
 step:   1.0515(harm=  1.0515)  dis= 0.01959  next Energy=  -116.079730 (dE=-0.461E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116079099473E+03    0.40376E-03   -0.50160E-01   640   0.367E+00    0.187E-01
DAV:   2    -0.116079667910E+03   -0.56844E-03   -0.74882E-03   736   0.413E-01    0.112E-01
DAV:   3    -0.116079637593E+03    0.30317E-04   -0.23502E-04   840   0.835E-02    0.535E-02
DAV:   4    -0.116079641367E+03   -0.37742E-05   -0.91982E-05   736   0.522E-02 
 280 F= -.11607964E+03 E0= -.11606085E+03  d E =-.372430E-03
 curvature: -19.00 expect dE=-0.505E-01 dE for cont linesearch -0.130E-03
 ZBRENT: interpolating
 opt :   0.7282  next Energy=  -116.079716 (dE=-0.448E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116079580881E+03    0.56712E-04   -0.88115E-02   640   0.154E+00    0.762E-02
DAV:   2    -0.116079679735E+03   -0.98855E-04   -0.12691E-03   728   0.170E-01    0.470E-02
DAV:   3    -0.116079675096E+03    0.46395E-05   -0.38171E-05   632   0.343E-02 
 281 F= -.11607968E+03 E0= -.11606088E+03  d E =-.406159E-03
 curvature: -11.02 expect dE=-0.138E-01 dE for cont linesearch -0.567E-05
 trial: gam= 1.17091 g(F)=  0.125E-02 g(S)=  0.000E+00 ort = 0.128E-03 (trialstep = 0.261E+00)
 search vector abs. value=  0.450E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116079884435E+03   -0.20470E-03   -0.89247E-02   640   0.156E+00    0.771E-02
DAV:   2    -0.116079996336E+03   -0.11190E-03   -0.14258E-03   744   0.181E-01    0.475E-02
DAV:   3    -0.116079985975E+03    0.10361E-04   -0.48625E-05   744   0.446E-02    0.246E-02
DAV:   4    -0.116079987661E+03   -0.16858E-05   -0.32848E-05   624   0.325E-02 
 282 F= -.11607999E+03 E0= -.11606120E+03  d E =-.312565E-03
 trial-energy change:   -0.000313  1 .order   -0.000294   -0.000366   -0.000221
 step:   0.6600(harm=  0.6600)  dis= 0.01456  next Energy=  -116.080138 (dE=-0.463E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080021507E+03   -0.35532E-04   -0.20696E-01   640   0.237E+00    0.120E-01
DAV:   2    -0.116080281268E+03   -0.25976E-03   -0.33471E-03   744   0.276E-01    0.727E-02
DAV:   3    -0.116080258488E+03    0.22781E-04   -0.11148E-04   856   0.674E-02    0.383E-02
DAV:   4    -0.116080261357E+03   -0.28689E-05   -0.79683E-05   736   0.506E-02 
 283 F= -.11608026E+03 E0= -.11606147E+03  d E =-.586261E-03
 curvature: -10.59 expect dE=-0.619E-02 dE for cont linesearch -0.732E-05
 ZBRENT: extrapolating
 opt :   0.7648  next Energy=  -116.080271 (dE=-0.595E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080272842E+03   -0.14354E-04   -0.14572E-02   640   0.629E-01    0.343E-02
DAV:   2    -0.116080293585E+03   -0.20743E-04   -0.27193E-04   776   0.789E-02    0.203E-02
DAV:   3    -0.116080291878E+03    0.17074E-05   -0.81790E-06   576   0.202E-02 
 284 F= -.11608029E+03 E0= -.11606150E+03  d E =-.616782E-03
 curvature: -13.37 expect dE=-0.101E-01 dE for cont linesearch -0.191E-04
 ZBRENT: increasing intervall
 opt :   0.9744  next Energy=  -116.080361 (dE=-0.686E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080248652E+03    0.44933E-04   -0.56370E-02   640   0.124E+00    0.626E-02
DAV:   2    -0.116080313343E+03   -0.64691E-04   -0.87257E-04   728   0.141E-01    0.370E-02
DAV:   3    -0.116080308973E+03    0.43700E-05   -0.26243E-05   752   0.319E-02 
 285 F= -.11608031E+03 E0= -.11606152E+03  d E =-.633877E-03
 curvature: -48.48 expect dE=-0.629E-01 dE for cont linesearch -0.485E-05
 trial: gam= 1.25998 g(F)=  0.130E-02 g(S)=  0.000E+00 ort =-0.671E-04 (trialstep = 0.250E+00)
 search vector abs. value=  0.725E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080393161E+03   -0.79817E-04   -0.13982E-01   640   0.197E+00    0.986E-02
DAV:   2    -0.116080570749E+03   -0.17759E-03   -0.22703E-03   728   0.228E-01    0.563E-02
DAV:   3    -0.116080561957E+03    0.87919E-05   -0.59401E-05   720   0.462E-02 
 286 F= -.11608056E+03 E0= -.11606177E+03  d E =-.252984E-03
 trial-energy change:   -0.000253  1 .order   -0.000251   -0.000304   -0.000198
 step:   0.7166(harm=  0.7166)  dis= 0.02004  next Energy=  -116.080744 (dE=-0.435E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080187909E+03    0.38284E-03   -0.48492E-01   640   0.366E+00    0.183E-01
DAV:   2    -0.116080805680E+03   -0.61777E-03   -0.78692E-03   736   0.424E-01    0.105E-01
DAV:   3    -0.116080770849E+03    0.34830E-04   -0.20665E-04   824   0.870E-02    0.556E-02
DAV:   4    -0.116080775553E+03   -0.47036E-05   -0.15136E-04   744   0.723E-02    0.128E-02
DAV:   5    -0.116080774078E+03    0.14750E-05   -0.27607E-05   808   0.312E-02 
 287 F= -.11608077E+03 E0= -.11606198E+03  d E =-.465105E-03
 curvature: -21.44 expect dE=-0.408E-01 dE for cont linesearch -0.108E-05
 trial: gam= 1.16304 g(F)=  0.190E-02 g(S)=  0.000E+00 ort = 0.603E-04 (trialstep = 0.249E+00)
 search vector abs. value=  0.100E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080983901E+03   -0.20835E-03   -0.18200E-01   640   0.223E+00    0.112E-01
DAV:   2    -0.116081214522E+03   -0.23062E-03   -0.29349E-03   720   0.258E-01    0.646E-02
DAV:   3    -0.116081204929E+03    0.95926E-05   -0.83747E-05   832   0.506E-02 
 288 F= -.11608120E+03 E0= -.11606241E+03  d E =-.430851E-03
 trial-energy change:   -0.000431  1 .order   -0.000417   -0.000491   -0.000344
 step:   0.8289(harm=  0.8289)  dis= 0.02710  next Energy=  -116.081592 (dE=-0.818E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116080594618E+03    0.61990E-03   -0.98303E-01   640   0.520E+00    0.263E-01
DAV:   2    -0.116081791727E+03   -0.11971E-02   -0.15474E-02   696   0.592E-01    0.151E-01
DAV:   3    -0.116081734783E+03    0.56945E-04   -0.46517E-04   840   0.117E-01    0.745E-02
DAV:   4    -0.116081739234E+03   -0.44514E-05   -0.18663E-04   720   0.805E-02    0.136E-02
DAV:   5    -0.116081739673E+03   -0.43911E-06   -0.35040E-05   816   0.328E-02 
 289 F= -.11608174E+03 E0= -.11606295E+03  d E =-.965595E-03
 curvature: -21.04 expect dE=-0.339E-01 dE for cont linesearch -0.272E-04
 ZBRENT: extrapolating
 opt :   1.0335  next Energy=  -116.081776 (dE=-0.100E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116081628056E+03    0.11118E-03   -0.12307E-01   640   0.184E+00    0.928E-02
DAV:   2    -0.116081787127E+03   -0.15907E-03   -0.19935E-03   760   0.212E-01    0.530E-02
DAV:   3    -0.116081781488E+03    0.56386E-05   -0.54600E-05   792   0.418E-02 
 290 F= -.11608178E+03 E0= -.11606299E+03  d E =-.100741E-02
 curvature: -28.47 expect dE=-0.714E-01 dE for cont linesearch -0.174E-05
 trial: gam= 1.46296 g(F)=  0.251E-02 g(S)=  0.000E+00 ort =-0.782E-04 (trialstep = 0.188E+00)
 search vector abs. value=  0.217E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116081947716E+03   -0.16059E-03   -0.21473E-01   640   0.242E+00    0.122E-01
DAV:   2    -0.116082197166E+03   -0.24945E-03   -0.32567E-03   728   0.273E-01    0.716E-02
DAV:   3    -0.116082188021E+03    0.91450E-05   -0.10647E-04   848   0.556E-02    0.336E-02
DAV:   4    -0.116082192035E+03   -0.40139E-05   -0.36644E-05   656   0.356E-02 
 291 F= -.11608219E+03 E0= -.11606340E+03  d E =-.410547E-03
 trial-energy change:   -0.000411  1 .order   -0.000366   -0.000449   -0.000284
 step:   0.2819(harm=  0.5101)  dis= 0.01351  next Energy=  -116.082269 (dE=-0.487E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082282468E+03   -0.94447E-04   -0.55094E-02   640   0.122E+00    0.624E-02
DAV:   2    -0.116082351533E+03   -0.69065E-04   -0.88258E-04   776   0.142E-01    0.364E-02
DAV:   3    -0.116082349656E+03    0.18769E-05   -0.24699E-05   640   0.283E-02 
 292 F= -.11608235E+03 E0= -.11606356E+03  d E =-.568168E-03
 curvature: -11.53 expect dE=-0.146E-01 dE for cont linesearch -0.116E-03
 ZBRENT: increasing intervall
 opt :   0.4705  next Energy=  -116.082622 (dE=-0.841E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082325084E+03    0.26449E-04   -0.21748E-01   640   0.243E+00    0.122E-01
DAV:   2    -0.116082580378E+03   -0.25529E-03   -0.33279E-03   768   0.276E-01    0.720E-02
DAV:   3    -0.116082569893E+03    0.10486E-04   -0.10617E-04   856   0.556E-02    0.342E-02
DAV:   4    -0.116082572143E+03   -0.22506E-05   -0.38814E-05   704   0.363E-02 
 293 F= -.11608257E+03 E0= -.11606378E+03  d E =-.790655E-03
 curvature: -27.01 expect dE=-0.333E-01 dE for cont linesearch -0.341E-04
 ZBRENT: increasing intervall
 opt :   0.8476  next Energy=  -116.082409 (dE=-0.628E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116081617114E+03    0.95278E-03   -0.87726E-01   640   0.488E+00    0.245E-01
DAV:   2    -0.116082693709E+03   -0.10766E-02   -0.13836E-02   736   0.562E-01    0.145E-01
DAV:   3    -0.116082632228E+03    0.61481E-04   -0.41044E-04   848   0.112E-01    0.708E-02
DAV:   4    -0.116082639591E+03   -0.73631E-05   -0.18898E-04   752   0.775E-02    0.143E-02
DAV:   5    -0.116082638549E+03    0.10424E-05   -0.32213E-05   784   0.332E-02 
 294 F= -.11608264E+03 E0= -.11606384E+03  d E =-.857061E-03
 curvature: 129.08 expect dE= 0.393E+00 dE for cont linesearch  0.130E-03
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   0.6696  next Energy=  -116.082680 (dE=-0.899E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082451344E+03    0.18825E-03   -0.19500E-01   640   0.230E+00    0.115E-01
DAV:   2    -0.116082684103E+03   -0.23276E-03   -0.29715E-03   744   0.261E-01    0.688E-02
DAV:   3    -0.116082673815E+03    0.10287E-04   -0.91802E-05   760   0.523E-02    0.318E-02
DAV:   4    -0.116082678243E+03   -0.44272E-05   -0.35319E-05   688   0.339E-02 
 295 F= -.11608268E+03 E0= -.11606388E+03  d E =-.896755E-03
 curvature: -41.25 expect dE=-0.745E-01 dE for cont linesearch -0.421E-04
 ZBRENT: interpolating
 opt :   0.7589  next Energy=  -116.082659 (dE=-0.878E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082627012E+03    0.46804E-04   -0.48741E-02   640   0.115E+00    0.562E-02
DAV:   2    -0.116082684063E+03   -0.57051E-04   -0.73289E-04   768   0.129E-01    0.342E-02
DAV:   3    -0.116082680313E+03    0.37497E-05   -0.22125E-05   624   0.264E-02 
 296 F= -.11608268E+03 E0= -.11606389E+03  d E =-.898825E-03
 curvature: -20.32 expect dE=-0.485E-01 dE for cont linesearch -0.208E-05
 trial: gam= 0.97955 g(F)=  0.239E-02 g(S)=  0.000E+00 ort =-0.149E-03 (trialstep = 0.302E+00)
 search vector abs. value=  0.210E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082653553E+03    0.30510E-04   -0.53493E-01   640   0.381E+00    0.193E-01
DAV:   2    -0.116083275200E+03   -0.62165E-03   -0.80467E-03   680   0.426E-01    0.115E-01
DAV:   3    -0.116083230155E+03    0.45045E-04   -0.23842E-04   848   0.968E-02    0.575E-02
DAV:   4    -0.116083237149E+03   -0.69945E-05   -0.16431E-04   776   0.730E-02    0.143E-02
DAV:   5    -0.116083233648E+03    0.35014E-05   -0.28057E-05   792   0.320E-02 
 297 F= -.11608323E+03 E0= -.11606444E+03  d E =-.553335E-03
 trial-energy change:   -0.000553  1 .order   -0.000544   -0.000676   -0.000412
 step:   0.7727(harm=  0.7727)  dis= 0.03631  next Energy=  -116.083545 (dE=-0.865E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116082124177E+03    0.11130E-02   -0.13065E+00   640   0.595E+00    0.301E-01
DAV:   2    -0.116083692912E+03   -0.15687E-02   -0.20066E-02   696   0.674E-01    0.180E-01
DAV:   3    -0.116083568586E+03    0.12433E-03   -0.60298E-04   848   0.156E-01    0.917E-02
DAV:   4    -0.116083585944E+03   -0.17358E-04   -0.42866E-04   784   0.118E-01    0.237E-02
DAV:   5    -0.116083576062E+03    0.98816E-05   -0.82334E-05   800   0.559E-02 
 298 F= -.11608358E+03 E0= -.11606478E+03  d E =-.895749E-03
 curvature: -36.23 expect dE=-0.743E-01 dE for cont linesearch -0.802E-07
 trial: gam= 0.71474 g(F)=  0.205E-02 g(S)=  0.000E+00 ort = 0.216E-04 (trialstep = 0.396E+00)
 search vector abs. value=  0.109E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116083603676E+03   -0.17732E-04   -0.45274E-01   640   0.348E+00    0.182E-01
DAV:   2    -0.116084130792E+03   -0.52712E-03   -0.69137E-03   760   0.396E-01    0.110E-01
DAV:   3    -0.116084089626E+03    0.41166E-04   -0.22872E-04   824   0.980E-02    0.540E-02
DAV:   4    -0.116084098281E+03   -0.86549E-05   -0.11857E-04   752   0.621E-02    0.126E-02
DAV:   5    -0.116084097668E+03    0.61324E-06   -0.23878E-05   744   0.311E-02 
 299 F= -.11608410E+03 E0= -.11606530E+03  d E =-.521605E-03
 trial-energy change:   -0.000522  1 .order   -0.000504   -0.000818   -0.000191
 step:   0.5166(harm=  0.5166)  dis= 0.01732  next Energy=  -116.084109 (dE=-0.533E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084083077E+03    0.15204E-04   -0.41918E-02   640   0.106E+00    0.552E-02
DAV:   2    -0.116084133458E+03   -0.50381E-04   -0.63667E-04   800   0.120E-01    0.334E-02
DAV:   3    -0.116084131263E+03    0.21950E-05   -0.20028E-05   640   0.304E-02 
 300 F= -.11608413E+03 E0= -.11606534E+03  d E =-.555200E-03
 curvature: -13.68 expect dE=-0.126E-01 dE for cont linesearch -0.178E-07
 trial: gam= 0.47569 g(F)=  0.924E-03 g(S)=  0.000E+00 ort =-0.119E-04 (trialstep = 0.420E+00)
 search vector abs. value=  0.257E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084314245E+03   -0.18079E-03   -0.11620E-01   640   0.175E+00    0.940E-02
DAV:   2    -0.116084432857E+03   -0.11861E-03   -0.16877E-03   776   0.198E-01    0.558E-02
DAV:   3    -0.116084424766E+03    0.80915E-05   -0.73209E-05   808   0.464E-02 
 301 F= -.11608442E+03 E0= -.11606563E+03  d E =-.293503E-03
 trial-energy change:   -0.000294  1 .order   -0.000278   -0.000386   -0.000171
 step:   0.7556(harm=  0.7556)  dis= 0.01199  next Energy=  -116.084478 (dE=-0.347E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084445464E+03   -0.12607E-04   -0.73715E-02   640   0.140E+00    0.777E-02
DAV:   2    -0.116084519531E+03   -0.74067E-04   -0.10450E-03   784   0.155E-01    0.459E-02
DAV:   3    -0.116084515015E+03    0.45164E-05   -0.44052E-05   720   0.367E-02 
 302 F= -.11608452E+03 E0= -.11606572E+03  d E =-.383752E-03
 curvature: -10.56 expect dE=-0.652E-02 dE for cont linesearch -0.467E-06
 trial: gam= 0.59010 g(F)=  0.617E-03 g(S)=  0.000E+00 ort = 0.337E-04 (trialstep = 0.487E+00)
 search vector abs. value=  0.959E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084631712E+03   -0.11218E-03   -0.60425E-02   656   0.128E+00    0.699E-02
DAV:   2    -0.116084706200E+03   -0.74488E-04   -0.95250E-04   808   0.150E-01    0.416E-02
DAV:   3    -0.116084699820E+03    0.63804E-05   -0.38610E-05   680   0.342E-02 
 303 F= -.11608470E+03 E0= -.11606590E+03  d E =-.184805E-03
 trial-energy change:   -0.000185  1 .order   -0.000172   -0.000310   -0.000033
 step:   0.5453(harm=  0.5453)  dis= 0.00505  next Energy=  -116.084689 (dE=-0.174E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084702729E+03    0.34715E-05   -0.80750E-04   720   0.149E-01    0.106E-02
DAV:   2    -0.116084703904E+03   -0.11755E-05   -0.11004E-05   640   0.169E-02 
 304 F= -.11608470E+03 E0= -.11606591E+03  d E =-.188890E-03
 curvature:  -4.11 expect dE=-0.111E-02 dE for cont linesearch -0.642E-08
 trial: gam= 0.51692 g(F)=  0.271E-03 g(S)=  0.000E+00 ort = 0.387E-05 (trialstep = 0.499E+00)
 search vector abs. value=  0.284E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084780341E+03   -0.77612E-04   -0.19959E-02   640   0.743E-01    0.406E-02
DAV:   2    -0.116084807397E+03   -0.27056E-04   -0.34163E-04   792   0.899E-02    0.244E-02
DAV:   3    -0.116084804796E+03    0.26010E-05   -0.11248E-05   552   0.221E-02 
 305 F= -.11608480E+03 E0= -.11606601E+03  d E =-.100892E-03
 trial-energy change:   -0.000101  1 .order   -0.000098   -0.000136   -0.000060
 step:   0.8880(harm=  0.8880)  dis= 0.00416  next Energy=  -116.084825 (dE=-0.121E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084813466E+03   -0.60694E-05   -0.11950E-02   672   0.576E-01    0.316E-02
DAV:   2    -0.116084829112E+03   -0.15646E-04   -0.19764E-04   808   0.680E-02    0.185E-02
DAV:   3    -0.116084827971E+03    0.11408E-05   -0.60676E-06   592   0.163E-02 
 306 F= -.11608483E+03 E0= -.11606603E+03  d E =-.124067E-03
 curvature:  -4.61 expect dE=-0.154E-02 dE for cont linesearch -0.375E-07
 trial: gam= 1.22809 g(F)=  0.333E-03 g(S)=  0.000E+00 ort =-0.480E-05 (trialstep = 0.356E+00)
 search vector abs. value=  0.460E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084895408E+03   -0.66296E-04   -0.18683E-02   640   0.723E-01    0.371E-02
DAV:   2    -0.116084920839E+03   -0.25431E-04   -0.31812E-04   808   0.862E-02    0.220E-02
DAV:   3    -0.116084918634E+03    0.22046E-05   -0.81456E-06   592   0.184E-02 
 307 F= -.11608492E+03 E0= -.11606612E+03  d E =-.906628E-04
 trial-energy change:   -0.000091  1 .order   -0.000091   -0.000116   -0.000065
 step:   0.8002(harm=  0.8002)  dis= 0.00452  next Energy=  -116.084959 (dE=-0.131E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116084921119E+03   -0.27979E-06   -0.29046E-02   640   0.902E-01    0.464E-02
DAV:   2    -0.116084959481E+03   -0.38362E-04   -0.49016E-04   840   0.107E-01    0.272E-02
DAV:   3    -0.116084955988E+03    0.34928E-05   -0.11704E-05   592   0.223E-02 
 308 F= -.11608496E+03 E0= -.11606616E+03  d E =-.128017E-03
 curvature:  -5.63 expect dE=-0.182E-02 dE for cont linesearch -0.453E-07
 trial: gam= 0.92586 g(F)=  0.324E-03 g(S)=  0.000E+00 ort =-0.609E-05 (trialstep = 0.445E+00)
 search vector abs. value=  0.426E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085033797E+03   -0.74316E-04   -0.28043E-02   640   0.889E-01    0.446E-02
DAV:   2    -0.116085070257E+03   -0.36460E-04   -0.48313E-04   824   0.106E-01    0.264E-02
DAV:   3    -0.116085068379E+03    0.18782E-05   -0.14429E-05   544   0.226E-02 
 309 F= -.11608507E+03 E0= -.11606627E+03  d E =-.112391E-03
 trial-energy change:   -0.000112  1 .order   -0.000111   -0.000142   -0.000080
 step:   1.0284(harm=  1.0284)  dis= 0.00526  next Energy=  -116.085120 (dE=-0.164E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085058952E+03    0.11305E-04   -0.48420E-02   640   0.117E+00    0.585E-02
DAV:   2    -0.116085122548E+03   -0.63596E-04   -0.82579E-04   824   0.138E-01    0.348E-02
DAV:   3    -0.116085119003E+03    0.35448E-05   -0.24597E-05   632   0.289E-02 
 310 F= -.11608512E+03 E0= -.11606632E+03  d E =-.163015E-03
 curvature:  -6.87 expect dE=-0.410E-02 dE for cont linesearch -0.202E-06
 trial: gam= 1.80803 g(F)=  0.597E-03 g(S)=  0.000E+00 ort =-0.112E-04 (trialstep = 0.165E+00)
 search vector abs. value=  0.145E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085192060E+03   -0.69512E-04   -0.12928E-02   640   0.605E-01    0.314E-02
DAV:   2    -0.116085208039E+03   -0.15978E-04   -0.21492E-04   784   0.706E-02    0.181E-02
DAV:   3    -0.116085207888E+03    0.15105E-06   -0.89185E-06   576   0.167E-02 
 311 F= -.11608521E+03 E0= -.11606641E+03  d E =-.888843E-04
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000089  1 .order   -0.000086   -0.000095   -0.000077
 step:   0.6604(harm=  0.8612)  dis= 0.00601  next Energy=  -116.085368 (dE=-0.249E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085203981E+03    0.40571E-05   -0.11829E-01   640   0.183E+00    0.903E-02
DAV:   2    -0.116085365582E+03   -0.16160E-03   -0.20599E-03   752   0.218E-01    0.531E-02
DAV:   3    -0.116085357707E+03    0.78746E-05   -0.71719E-05   848   0.480E-02 
 312 F= -.11608536E+03 E0= -.11606656E+03  d E =-.238704E-03
 curvature:  -9.90 expect dE=-0.373E-02 dE for cont linesearch -0.507E-05
 ZBRENT: extrapolating
 opt :   0.7726  next Energy=  -116.085363 (dE=-0.244E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085362352E+03    0.32303E-05   -0.58141E-03   736   0.407E-01    0.238E-02
DAV:   2    -0.116085367564E+03   -0.52124E-05   -0.89427E-05   824   0.469E-02 
 313 F= -.11608537E+03 E0= -.11606657E+03  d E =-.248561E-03
 curvature:  -9.42 expect dE=-0.438E-02 dE for cont linesearch -0.179E-06
 trial: gam= 0.65589 g(F)=  0.464E-03 g(S)=  0.000E+00 ort = 0.166E-04 (trialstep = 0.287E+00)
 search vector abs. value=  0.671E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085452866E+03   -0.90514E-04   -0.21866E-02   640   0.791E-01    0.418E-02
DAV:   2    -0.116085485422E+03   -0.32556E-04   -0.40528E-04   816   0.966E-02    0.249E-02
DAV:   3    -0.116085482733E+03    0.26892E-05   -0.10590E-05   608   0.218E-02 
 314 F= -.11608548E+03 E0= -.11606669E+03  d E =-.115168E-03
 trial-energy change:   -0.000115  1 .order   -0.000112   -0.000136   -0.000088
 step:   0.8016(harm=  0.8016)  dis= 0.00466  next Energy=  -116.085558 (dE=-0.191E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085452400E+03    0.33021E-04   -0.70252E-02   640   0.142E+00    0.686E-02
DAV:   2    -0.116085555652E+03   -0.10325E-03   -0.12957E-03   824   0.173E-01    0.396E-02
DAV:   3    -0.116085548753E+03    0.68991E-05   -0.31795E-05   696   0.341E-02 
 315 F= -.11608555E+03 E0= -.11606675E+03  d E =-.181189E-03
 curvature:  -5.66 expect dE=-0.302E-02 dE for cont linesearch -0.161E-05
 trial: gam= 1.33687 g(F)=  0.534E-03 g(S)=  0.000E+00 ort =-0.437E-04 (trialstep = 0.211E+00)
 search vector abs. value=  0.124E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085610040E+03   -0.54387E-04   -0.22118E-02   648   0.795E-01    0.385E-02
DAV:   2    -0.116085638265E+03   -0.28225E-04   -0.37063E-04   760   0.919E-02    0.224E-02
DAV:   3    -0.116085636935E+03    0.13305E-05   -0.11455E-05   648   0.207E-02 
 316 F= -.11608564E+03 E0= -.11606684E+03  d E =-.881814E-04
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.000088  1 .order   -0.000089   -0.000100   -0.000077
 step:   0.8427(harm=  0.9188)  dis= 0.00642  next Energy=  -116.085767 (dE=-0.218E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085482785E+03    0.15548E-03   -0.20264E-01   640   0.240E+00    0.112E-01
DAV:   2    -0.116085773667E+03   -0.29088E-03   -0.35405E-03   728   0.283E-01    0.670E-02
DAV:   3    -0.116085754276E+03    0.19391E-04   -0.98336E-05   864   0.604E-02    0.362E-02
DAV:   4    -0.116085755694E+03   -0.14179E-05   -0.69530E-05   744   0.497E-02 
 317 F= -.11608576E+03 E0= -.11606696E+03  d E =-.206940E-03
 curvature: -11.86 expect dE=-0.834E-02 dE for cont linesearch -0.191E-04
 ZBRENT: interpolating
 opt :   0.6668  next Energy=  -116.085768 (dE=-0.219E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085726175E+03    0.28101E-04   -0.15470E-02   640   0.665E-01    0.288E-02
DAV:   2    -0.116085747348E+03   -0.21174E-04   -0.25210E-04   704   0.757E-02    0.184E-02
DAV:   3    -0.116085745824E+03    0.15240E-05   -0.72784E-06   552   0.164E-02 
 318 F= -.11608575E+03 E0= -.11606695E+03  d E =-.197071E-03
 curvature:  -7.73 expect dE=-0.406E-02 dE for cont linesearch -0.835E-05
 ZBRENT: interpolating
 opt :   0.7461  next Energy=  -116.085750 (dE=-0.202E-03)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085748400E+03   -0.10518E-05   -0.33081E-03   712   0.307E-01    0.136E-02
DAV:   2    -0.116085753879E+03   -0.54786E-05   -0.64313E-05   768   0.386E-02 
 319 F= -.11608575E+03 E0= -.11606696E+03  d E =-.205125E-03
 curvature:  -4.25 expect dE=-0.241E-02 dE for cont linesearch -0.127E-06
 trial: gam= 0.61543 g(F)=  0.567E-03 g(S)=  0.000E+00 ort = 0.192E-04 (trialstep = 0.318E+00)
 search vector abs. value=  0.529E-02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.116085838569E+03   -0.90169E-04   -0.26062E-02   672   0.869E-01    0.452E-02
DAV:   2    -0.116085889066E+03   -0.50497E-04   -0.59600E-04   832   0.116E-01    0.259E-02
DAV:   3    -0.116085885600E+03    0.34665E-05   -0.10219E-05   560   0.196E-02 
 320 F= -.11608589E+03 E0= -.11606709E+03  d E =-.131721E-03
 trial-energy change:   -0.000132  1 .order   -0.000128   -0.000184   -0.000072
 step:   0.5227(harm=  0.5227)  dis= 0.00238  next Energy=  -116.085905 (dE=-0.151E-03)
 reached required accuracy - stopping structural energy minimisation