vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.05.17  23:18:13
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.77 0.32
   NPAR = 4

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  3       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  4       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.171  0.565  0.722-   8 1.50   3 1.66   6 1.88   7 1.88
   2  0.382  0.582  0.679-  22 1.49   3 1.67   4 1.88   5 1.90
   3  0.276  0.616  0.718-   1 1.66   2 1.67
   4  0.402  0.644  0.504-  11 1.09  10 1.10   9 1.10   2 1.88
   5  0.479  0.649  0.782-  21 1.09  13 1.09  12 1.10   2 1.90
   6  0.165  0.378  0.741-  16 1.10  15 1.10  14 1.10   1 1.88
   7  0.108  0.620  0.569-  18 1.10  17 1.10  19 1.10   1 1.88
   8  0.128  0.628  0.842-   1 1.50
   9  0.471  0.625  0.470-   4 1.10
  10  0.389  0.751  0.496-   4 1.10
  11  0.356  0.592  0.437-   4 1.09
  12  0.495  0.756  0.777-   5 1.10
  13  0.484  0.617  0.886-   5 1.09
  14  0.095  0.345  0.749-   6 1.10
  15  0.200  0.344  0.830-   6 1.10
  16  0.194  0.328  0.654-   6 1.10
  17  0.135  0.575  0.478-   7 1.10
  18  0.109  0.729  0.557-   7 1.10
  19  0.037  0.589  0.576-   7 1.10
  20  0.323  0.901  0.907-
  21  0.531  0.596  0.727-   5 1.09
  22  0.392  0.434  0.689-   2 1.49
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =    10.0000000000
 C/A-ratio  =     1.5000000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,  10.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  10.0000000000)
 A3 = (  15.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    1500.0000

  direct lattice vectors                    reciprocal lattice vectors
    15.000000000  0.000000000  0.000000000     0.066666667  0.000000000  0.000000000
     0.000000000 10.000000000  0.000000000     0.000000000  0.100000000  0.000000000
     0.000000000  0.000000000 10.000000000     0.000000000  0.000000000  0.100000000

  length of vectors
    15.000000000 10.000000000 10.000000000     0.066666667  0.100000000  0.100000000

  position of ions in fractional coordinates (direct lattice)
     0.170829150  0.564690740  0.722168440
     0.382090380  0.582470630  0.678987230
     0.276344610  0.615803160  0.717781300
     0.402010040  0.643589470  0.504104260
     0.478986310  0.648864810  0.782120760
     0.164871920  0.377877080  0.740568330
     0.107723240  0.619649970  0.569012620
     0.127913590  0.628219110  0.842268250
     0.470574120  0.624992200  0.470451120
     0.389258820  0.751287480  0.495887400
     0.355912840  0.592249860  0.436708070
     0.495153360  0.755853630  0.777007670
     0.484383740  0.616545630  0.886257190
     0.095118130  0.344582290  0.748871890
     0.200304850  0.343678150  0.830433880
     0.194365060  0.327534090  0.653581870
     0.135028900  0.574838680  0.477528920
     0.108561220  0.728744760  0.556889860
     0.037340390  0.588782260  0.576025490
     0.323014830  0.900767580  0.906856910
     0.531270440  0.596144270  0.727329990
     0.391514140  0.434092700  0.688631950

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    1    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.066666667  0.000000000  0.000000000     1.000000000  0.000000000  0.000000000
     0.000000000  0.050000000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.050000000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.066666667  0.050000000  0.050000000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      4 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.000000  0.050000  0.000000      1.000000
  0.000000  0.000000  0.050000      1.000000
  0.000000  0.050000  0.050000      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      4   k-points in BZ     NKDIM =      4   number of bands    NBANDS=     36
   number of dos      NEDOS =    301   number of ions     NIONS =     22
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 200000
   max r-space proj   IRMAX =   1519   max aug-charges    IRDMAX=   4657
   dimension x,y,z NGX =    80 NGY =   50 NGZ =   50
   dimension x,y,z NGXF=   160 NGYF=  100 NGZF=  100
   support grid    NGXF=   160 NGYF=  100 NGZF=  100
   ions per type =               2   1   4  15
   NGX,Y,Z   is equivalent  to a cutoff of   8.87,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  17.73, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  24.46 16.31 16.31*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.514E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00 12.01  1.00
  Ionic Valenz
   ZVAL   =   4.00  6.00  4.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.77  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =      45.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.69E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      68.18       460.11
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.508685  0.961274  3.520644  0.258760
  Thomas-Fermi vector in A             =   1.520821
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           13
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     1500.00
      direct lattice vectors                 reciprocal lattice vectors
    15.000000000  0.000000000  0.000000000     0.066666667  0.000000000  0.000000000
     0.000000000 10.000000000  0.000000000     0.000000000  0.100000000  0.000000000
     0.000000000  0.000000000 10.000000000     0.000000000  0.000000000  0.100000000

  length of vectors
    15.000000000 10.000000000 10.000000000     0.066666667  0.100000000  0.100000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.250
   0.00000000  0.05000000  0.00000000       0.250
   0.00000000  0.00000000  0.05000000       0.250
   0.00000000  0.05000000  0.05000000       0.250
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.250
   0.00000000  0.50000000  0.00000000       0.250
   0.00000000  0.00000000  0.50000000       0.250
   0.00000000  0.50000000  0.50000000       0.250
 
 position of ions in fractional coordinates (direct lattice) 
   0.17082915  0.56469074  0.72216844
   0.38209038  0.58247063  0.67898723
   0.27634461  0.61580316  0.71778130
   0.40201004  0.64358947  0.50410426
   0.47898631  0.64886481  0.78212076
   0.16487192  0.37787708  0.74056833
   0.10772324  0.61964997  0.56901262
   0.12791359  0.62821911  0.84226825
   0.47057412  0.62499220  0.47045112
   0.38925882  0.75128748  0.49588740
   0.35591284  0.59224986  0.43670807
   0.49515336  0.75585363  0.77700767
   0.48438374  0.61654563  0.88625719
   0.09511813  0.34458229  0.74887189
   0.20030485  0.34367815  0.83043388
   0.19436506  0.32753409  0.65358187
   0.13502890  0.57483868  0.47752892
   0.10856122  0.72874476  0.55688986
   0.03734039  0.58878226  0.57602549
   0.32301483  0.90076758  0.90685691
   0.53127044  0.59614427  0.72732999
   0.39151414  0.43409270  0.68863195
 
 position of ions in cartesian coordinates  (Angst):
   2.56243725  5.64690740  7.22168440
   5.73135570  5.82470630  6.78987230
   4.14516915  6.15803160  7.17781300
   6.03015060  6.43589470  5.04104260
   7.18479465  6.48864810  7.82120760
   2.47307880  3.77877080  7.40568330
   1.61584860  6.19649970  5.69012620
   1.91870385  6.28219110  8.42268250
   7.05861180  6.24992200  4.70451120
   5.83888230  7.51287480  4.95887400
   5.33869260  5.92249860  4.36708070
   7.42730040  7.55853630  7.77007670
   7.26575610  6.16545630  8.86257190
   1.42677195  3.44582290  7.48871890
   3.00457275  3.43678150  8.30433880
   2.91547590  3.27534090  6.53581870
   2.02543350  5.74838680  4.77528920
   1.62841830  7.28744760  5.56889860
   0.56010585  5.88782260  5.76025490
   4.84522245  9.00767580  9.06856910
   7.96905660  5.96144270  7.27329990
   5.87271210  4.34092700  6.88631950
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   27261
 k-point  2 :   0.0000 0.5000 0.0000  plane waves:   27252
 k-point  3 :   0.0000 0.0000 0.5000  plane waves:   27252
 k-point  4 :   0.0000 0.5000 0.5000  plane waves:   27168

 maximum and minimum number of plane-waves per node :     27261    27168

 maximum number of plane-waves:     27261
 maximum index in each direction: 
   IXMAX=   24   IYMAX=   16   IZMAX=   16
   IXMIN=  -24   IYMIN=  -16   IZMIN=  -16

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    98 to avoid them
 WARNING: aliasing errors must be expected set NGY to    70 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    70 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    99526. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1847. kBytes
   fftplans  :      14520. kBytes
   grid      :      37312. kBytes
   one-center:         67. kBytes
   wavefun   :      15780. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 49   NGY = 33   NGZ = 33
  (NGX  =160   NGY  =100   NGZ  =100)
  gives a total of  53361 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      45.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1421
 Maximum index for augmentation-charges         1090 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.155
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 2x 2



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   320
 total energy-change (2. order) : 0.2846561E+03  (-0.1141378E+04)
 number of electron      45.0000000 magnetization 
 augmentation part       45.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2340.36763302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =        95.07168714
  PAW double counting   =       988.89567318     -957.91857019
  entropy T*S    EENTRO =        -0.00636535
  eigenvalues    EBANDS =      -275.95992337
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       284.65607362 eV

  energy without entropy =      284.66243897  energy(sigma->0) =      284.65819541


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   440
 total energy-change (2. order) :-0.3133872E+03  (-0.3024209E+03)
 number of electron      45.0000000 magnetization 
 augmentation part       45.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2340.36763302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =        95.07168714
  PAW double counting   =       988.89567318     -957.91857019
  entropy T*S    EENTRO =         0.00392416
  eigenvalues    EBANDS =      -589.35736515
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -28.73107865 eV

  energy without entropy =      -28.73500281  energy(sigma->0) =      -28.73238670


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   408
 total energy-change (2. order) :-0.8807401E+02  (-0.8765795E+02)
 number of electron      45.0000000 magnetization 
 augmentation part       45.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2340.36763302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =        95.07168714
  PAW double counting   =       988.89567318     -957.91857019
  entropy T*S    EENTRO =        -0.05564569
  eigenvalues    EBANDS =      -677.37180348
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -116.80508683 eV

  energy without entropy =     -116.74944114  energy(sigma->0) =     -116.78653827


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   384
 total energy-change (2. order) :-0.5921017E+01  (-0.5903270E+01)
 number of electron      45.0000000 magnetization 
 augmentation part       45.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2340.36763302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =        95.07168714
  PAW double counting   =       988.89567318     -957.91857019
  entropy T*S    EENTRO =        -0.05641799
  eigenvalues    EBANDS =      -683.29204865
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -122.72610430 eV

  energy without entropy =     -122.66968631  energy(sigma->0) =     -122.70729830


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   440
 total energy-change (2. order) :-0.1783791E+00  (-0.1783066E+00)
 number of electron      44.9999939 magnetization 
 augmentation part        1.2975649 magnetization 

 Broyden mixing:
  rms(total) = 0.20537E+01    rms(broyden)= 0.20530E+01
  rms(prec ) = 0.24085E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2340.36763302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =        95.07168714
  PAW double counting   =       988.89567318     -957.91857019
  entropy T*S    EENTRO =        -0.05641889
  eigenvalues    EBANDS =      -683.47042685
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -122.90448339 eV

  energy without entropy =     -122.84806451  energy(sigma->0) =     -122.88567710


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   364
 total energy-change (2. order) : 0.1288836E+02  (-0.3412469E+01)
 number of electron      44.9999943 magnetization 
 augmentation part        1.0075540 magnetization 

 Broyden mixing:
  rms(total) = 0.10119E+01    rms(broyden)= 0.10117E+01
  rms(prec ) = 0.11154E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2413
  1.2413

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2437.37730237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       100.91293084
  PAW double counting   =      1945.41898588    -1915.44185017
  entropy T*S    EENTRO =        -0.05641887
  eigenvalues    EBANDS =      -578.41367356
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -110.01612303 eV

  energy without entropy =     -109.95970415  energy(sigma->0) =     -109.99731673


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   408
 total energy-change (2. order) : 0.1499340E+01  (-0.5253342E+00)
 number of electron      44.9999944 magnetization 
 augmentation part        0.9386288 magnetization 

 Broyden mixing:
  rms(total) = 0.50364E+00    rms(broyden)= 0.50352E+00
  rms(prec ) = 0.55732E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3731
  1.3731  1.3731

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2482.10069705
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       103.86273540
  PAW double counting   =      3084.06070600    -3054.26820802
  entropy T*S    EENTRO =        -0.05641887
  eigenvalues    EBANDS =      -534.95610586
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -108.51678316 eV

  energy without entropy =     -108.46036429  energy(sigma->0) =     -108.49797687


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   392
 total energy-change (2. order) : 0.5128301E+00  (-0.4547527E-01)
 number of electron      44.9999944 magnetization 
 augmentation part        0.9551064 magnetization 

 Broyden mixing:
  rms(total) = 0.17579E+00    rms(broyden)= 0.17578E+00
  rms(prec ) = 0.21632E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5215
  2.3016  1.1315  1.1315

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2501.77388078
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       105.27486873
  PAW double counting   =      3572.29083297    -3542.48281547
  entropy T*S    EENTRO =        -0.05641884
  eigenvalues    EBANDS =      -516.19774490
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -108.00395306 eV

  energy without entropy =     -107.94753421  energy(sigma->0) =     -107.98514678


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   400
 total energy-change (2. order) : 0.1679769E+00  (-0.2037095E-01)
 number of electron      44.9999944 magnetization 
 augmentation part        0.9469575 magnetization 

 Broyden mixing:
  rms(total) = 0.46364E-01    rms(broyden)= 0.46329E-01
  rms(prec ) = 0.77820E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3893
  2.2075  1.0074  1.0074  1.3348

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2521.50255811
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.49453991
  PAW double counting   =      3882.56264868    -3852.78223857
  entropy T*S    EENTRO =        -0.05641051
  eigenvalues    EBANDS =      -497.49316281
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83597618 eV

  energy without entropy =     -107.77956567  energy(sigma->0) =     -107.81717267


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   384
 total energy-change (2. order) : 0.1034457E-01  (-0.1051517E-02)
 number of electron      44.9999944 magnetization 
 augmentation part        0.9465821 magnetization 

 Broyden mixing:
  rms(total) = 0.30720E-01    rms(broyden)= 0.30718E-01
  rms(prec ) = 0.58214E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6842
  2.5690  2.5690  1.1158  1.1158  1.0515

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2525.12839618
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.57257355
  PAW double counting   =      3859.53887249    -3829.73614395
  entropy T*S    EENTRO =        -0.05637706
  eigenvalues    EBANDS =      -493.95736568
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.82563160 eV

  energy without entropy =     -107.76925454  energy(sigma->0) =     -107.80683925


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   336
 total energy-change (2. order) : 0.1144803E-01  (-0.3311317E-02)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9477736 magnetization 

 Broyden mixing:
  rms(total) = 0.22247E-01    rms(broyden)= 0.22239E-01
  rms(prec ) = 0.32217E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5926
  2.7377  2.6723  1.0820  1.0820  0.9907  0.9907

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2535.20617754
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.85604761
  PAW double counting   =      3825.97143189    -3796.12953317
  entropy T*S    EENTRO =        -0.05440017
  eigenvalues    EBANDS =      -484.19275744
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.81418357 eV

  energy without entropy =     -107.75978341  energy(sigma->0) =     -107.79605018


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   372
 total energy-change (2. order) :-0.1885493E-02  (-0.4610162E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9453407 magnetization 

 Broyden mixing:
  rms(total) = 0.12080E-01    rms(broyden)= 0.12074E-01
  rms(prec ) = 0.21570E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5834
  3.1099  2.4890  1.2371  1.2371  0.9382  1.0364  1.0364

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2536.75685108
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.89147339
  PAW double counting   =      3822.45865876    -3792.62198645
  entropy T*S    EENTRO =        -0.05237719
  eigenvalues    EBANDS =      -482.67619172
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.81606906 eV

  energy without entropy =     -107.76369187  energy(sigma->0) =     -107.79861000


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   292
 total energy-change (2. order) :-0.4750190E-02  (-0.4609149E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9460464 magnetization 

 Broyden mixing:
  rms(total) = 0.97147E-02    rms(broyden)= 0.97047E-02
  rms(prec ) = 0.15963E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6061
  3.5154  2.4450  1.3887  1.2517  1.2517  0.9195  1.0382  1.0382

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2538.82234818
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.92091796
  PAW double counting   =      3820.85280821    -3791.01458572
  entropy T*S    EENTRO =        -0.04775668
  eigenvalues    EBANDS =      -480.65106008
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.82081925 eV

  energy without entropy =     -107.77306257  energy(sigma->0) =     -107.80490036


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   328
 total energy-change (2. order) :-0.1986767E-02  (-0.2408217E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9467672 magnetization 

 Broyden mixing:
  rms(total) = 0.13590E-01    rms(broyden)= 0.13568E-01
  rms(prec ) = 0.20648E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5008
  3.5421  2.4625  1.4613  1.2606  1.2606  0.9148  1.0512  1.0512  0.5030

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.49492169
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.94353409
  PAW double counting   =      3819.12024275    -3789.28370931
  entropy T*S    EENTRO =        -0.03813510
  eigenvalues    EBANDS =      -479.01102200
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.82280602 eV

  energy without entropy =     -107.78467092  energy(sigma->0) =     -107.81009432


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   400
 total energy-change (2. order) :-0.1840207E-03  (-0.4791834E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9462910 magnetization 

 Broyden mixing:
  rms(total) = 0.94585E-02    rms(broyden)= 0.94551E-02
  rms(prec ) = 0.15001E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6852
  4.6682  2.4524  2.4524  1.0644  1.0644  1.0828  1.0828  1.1048  0.9013  0.9787

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.23897313
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.93855082
  PAW double counting   =      3818.00143904    -3788.16431570
  entropy T*S    EENTRO =        -0.04341107
  eigenvalues    EBANDS =      -479.25748523
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.82299004 eV

  energy without entropy =     -107.77957898  energy(sigma->0) =     -107.80851969


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   300
 total energy-change (2. order) :-0.4244848E-02  (-0.1203450E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9459161 magnetization 

 Broyden mixing:
  rms(total) = 0.69612E-02    rms(broyden)= 0.69463E-02
  rms(prec ) = 0.99491E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7206
  5.0686  1.1597  2.7405  2.3964  1.1613  1.1613  1.2313  1.0760  1.0760  1.0187
  0.8369

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.65536170
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.93260113
  PAW double counting   =      3818.70397797    -3788.86714354
  entropy T*S    EENTRO =        -0.04887836
  eigenvalues    EBANDS =      -478.83363563
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.82723489 eV

  energy without entropy =     -107.77835653  energy(sigma->0) =     -107.81094210


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   344
 total energy-change (2. order) :-0.3532146E-02  (-0.9594623E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455690 magnetization 

 Broyden mixing:
  rms(total) = 0.58267E-02    rms(broyden)= 0.58120E-02
  rms(prec ) = 0.78783E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7724
  5.2591  1.2430  2.9557  2.3938  1.6234  1.6234  1.0043  1.0043  1.1934  1.0352
  1.0352  0.8981

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.48821265
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.92081491
  PAW double counting   =      3818.99451416    -3789.15730390
  entropy T*S    EENTRO =        -0.05317651
  eigenvalues    EBANDS =      -478.98860827
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83076704 eV

  energy without entropy =     -107.77759053  energy(sigma->0) =     -107.81304153


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   332
 total energy-change (2. order) :-0.3678755E-02  (-0.1828046E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9458593 magnetization 

 Broyden mixing:
  rms(total) = 0.83828E-02    rms(broyden)= 0.83776E-02
  rms(prec ) = 0.11039E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6911
  5.0454  3.0983  1.2698  2.3624  1.7507  1.7507  1.0050  1.0050  1.0880  1.0880
  1.0760  0.8898  0.5553

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.10488505
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90879586
  PAW double counting   =      3819.38219947    -3789.54389912
  entropy T*S    EENTRO =        -0.05571764
  eigenvalues    EBANDS =      -479.36214455
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83444579 eV

  energy without entropy =     -107.77872815  energy(sigma->0) =     -107.81587325


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   384
 total energy-change (2. order) :-0.6362374E-03  (-0.2283389E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9460201 magnetization 

 Broyden mixing:
  rms(total) = 0.10064E-01    rms(broyden)= 0.10063E-01
  rms(prec ) = 0.13213E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6338
  5.1510  3.2491  1.2255  2.3340  1.6875  1.6875  0.9904  0.9904  1.1887  1.0502
  1.0502  0.8830  0.7956  0.5895

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2539.97289196
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90696351
  PAW double counting   =      3819.37092522    -3789.53250463
  entropy T*S    EENTRO =        -0.05600726
  eigenvalues    EBANDS =      -479.49277215
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83508203 eV

  energy without entropy =     -107.77907477  energy(sigma->0) =     -107.81641294


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   316
 total energy-change (2. order) : 0.4281616E-03  (-0.5001899E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9459148 magnetization 

 Broyden mixing:
  rms(total) = 0.77057E-02    rms(broyden)= 0.77052E-02
  rms(prec ) = 0.98834E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8332
  6.3519  2.5401  3.3424  1.4117  2.3725  2.3725  1.4070  1.1618  1.1618  1.0173
  1.0173  1.0141  0.8050  0.7613  0.7613

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.27436740
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90942059
  PAW double counting   =      3820.28122657    -3790.44285469
  entropy T*S    EENTRO =        -0.05526572
  eigenvalues    EBANDS =      -479.19401845
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83465387 eV

  energy without entropy =     -107.77938815  energy(sigma->0) =     -107.81623196


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   332
 total energy-change (2. order) : 0.3200218E-03  (-0.3457561E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9462721 magnetization 

 Broyden mixing:
  rms(total) = 0.84059E-02    rms(broyden)= 0.83847E-02
  rms(prec ) = 0.10633E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8548
  6.4974  3.3347  3.5001  1.3853  2.3335  2.3335  1.2726  1.2726  1.1952  1.0142
  1.0142  0.9912  0.9912  0.9404  0.8001  0.8001

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.05267175
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91711778
  PAW double counting   =      3820.69757343    -3790.85953055
  entropy T*S    EENTRO =        -0.04749445
  eigenvalues    EBANDS =      -478.43053354
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83433384 eV

  energy without entropy =     -107.78683940  energy(sigma->0) =     -107.81850236


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   380
 total energy-change (2. order) : 0.7395576E-03  (-0.1415927E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9473155 magnetization 

 Broyden mixing:
  rms(total) = 0.15959E-01    rms(broyden)= 0.15937E-01
  rms(prec ) = 0.21692E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7397
  6.4878  3.0087  3.4978  1.3940  2.3351  2.3351  1.2603  1.2603  1.0216  1.0216
  1.2189  0.9377  0.9931  0.9931  0.7856  0.7856  0.2381

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.38762475
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.92051222
  PAW double counting   =      3820.78502863    -3790.94736991
  entropy T*S    EENTRO =        -0.03738157
  eigenvalues    EBANDS =      -478.10796414
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83359429 eV

  energy without entropy =     -107.79621272  energy(sigma->0) =     -107.82113377


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   400
 total energy-change (2. order) : 0.5911343E-03  (-0.1916428E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9478831 magnetization 

 Broyden mixing:
  rms(total) = 0.19862E-01    rms(broyden)= 0.19857E-01
  rms(prec ) = 0.27254E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6896
  6.5052  3.2457  3.5424  1.3854  2.3402  2.3402  1.2598  1.2598  1.2210  1.0158
  1.0158  0.9890  0.9890  0.9476  0.7939  0.7939  0.3838  0.3838

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.48861100
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.92182278
  PAW double counting   =      3821.03940176    -3791.20172614
  entropy T*S    EENTRO =        -0.03348049
  eigenvalues    EBANDS =      -478.01161529
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83300315 eV

  energy without entropy =     -107.79952266  energy(sigma->0) =     -107.82184299


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   304
 total energy-change (2. order) : 0.1213066E-03  (-0.4139353E-06)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9479317 magnetization 

 Broyden mixing:
  rms(total) = 0.20278E-01    rms(broyden)= 0.20278E-01
  rms(prec ) = 0.27848E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6460
  6.4822  2.9264  3.5657  2.3272  2.3272  1.4030  1.2864  1.2864  1.1824  1.0177
  1.0177  1.0193  1.0193  0.9218  0.7623  0.7623  0.6599  0.6599  0.6465

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.49995445
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.92205029
  PAW double counting   =      3821.12285230    -3791.28518638
  entropy T*S    EENTRO =        -0.03308081
  eigenvalues    EBANDS =      -478.00076805
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83288185 eV

  energy without entropy =     -107.79980104  energy(sigma->0) =     -107.82185491


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :   324
 total energy-change (2. order) :-0.7064866E-03  (-0.1508459E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9476617 magnetization 

 Broyden mixing:
  rms(total) = 0.17813E-01    rms(broyden)= 0.17813E-01
  rms(prec ) = 0.24596E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7340
  6.6427  4.2352  2.2358  1.5438  2.6123  1.0441  2.1932  1.7989  1.7989  1.5085
  1.0061  1.0061  1.1188  1.1188  1.0499  0.9658  0.8396  0.8396  0.5613  0.5613

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.40619391
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91990514
  PAW double counting   =      3819.89864283    -3790.06083668
  entropy T*S    EENTRO =        -0.03512963
  eigenvalues    EBANDS =      -478.09118132
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83358833 eV

  energy without entropy =     -107.79845870  energy(sigma->0) =     -107.82187846


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :   336
 total energy-change (2. order) :-0.1813729E-02  (-0.1482433E-03)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9461042 magnetization 

 Broyden mixing:
  rms(total) = 0.77269E-02    rms(broyden)= 0.76822E-02
  rms(prec ) = 0.10572E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7378
  7.0922  4.7473  1.6399  1.6399  2.7365  2.5370  1.2085  2.1377  1.4321  1.4321
  1.0044  1.0044  1.1322  1.1322  0.9443  0.9443  0.9468  0.9468  0.6491  0.6491
  0.5381

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2541.10909421
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91564127
  PAW double counting   =      3817.45104041    -3787.61372068
  entropy T*S    EENTRO =        -0.04569888
  eigenvalues    EBANDS =      -478.37477520
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83540206 eV

  energy without entropy =     -107.78970318  energy(sigma->0) =     -107.82016910


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :   352
 total energy-change (2. order) :-0.6134476E-03  (-0.8731911E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455034 magnetization 

 Broyden mixing:
  rms(total) = 0.51300E-02    rms(broyden)= 0.50956E-02
  rms(prec ) = 0.66202E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6623
  7.0834  4.7307  1.6225  1.6225  2.7415  2.5572  1.2193  2.1354  1.3982  1.3982
  1.0085  1.0085  1.1293  1.1293  0.9519  0.9519  0.9523  0.9523  0.6517  0.6517
  0.5223  0.1510

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.82329930
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91138724
  PAW double counting   =      3816.42484990    -3786.58756799
  entropy T*S    EENTRO =        -0.05158894
  eigenvalues    EBANDS =      -478.65100166
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83601551 eV

  energy without entropy =     -107.78442657  energy(sigma->0) =     -107.81881920


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :   384
 total energy-change (2. order) :-0.9136476E-04  (-0.6305306E-05)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455535 magnetization 

 Broyden mixing:
  rms(total) = 0.48150E-02    rms(broyden)= 0.48123E-02
  rms(prec ) = 0.63122E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6026
  7.0826  4.7278  1.6162  1.6162  2.7396  2.5133  1.2245  2.1717  1.3707  1.3707
  1.0052  1.0052  1.1266  1.1266  0.9598  0.9598  0.9599  0.9599  0.6483  0.6483
  0.5253  0.2508  0.2508

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.77477187
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91070823
  PAW double counting   =      3816.36937953    -3786.53206700
  entropy T*S    EENTRO =        -0.05227776
  eigenvalues    EBANDS =      -478.69828324
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83610687 eV

  energy without entropy =     -107.78382912  energy(sigma->0) =     -107.81868096


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :   304
 total energy-change (2. order) :-0.1880452E-04  (-0.2957214E-06)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455342 magnetization 

 Broyden mixing:
  rms(total) = 0.46772E-02    rms(broyden)= 0.46770E-02
  rms(prec ) = 0.61706E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6604
  7.3076  5.0017  3.0282  1.5550  1.5550  2.4705  1.2488  2.0336  1.4297  1.4297
  1.4405  1.2031  1.2031  1.0245  1.0245  0.8930  0.8930  0.9966  0.8730  0.8730
  0.7287  0.5885  0.5885  0.4600

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.76706027
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91080186
  PAW double counting   =      3816.43824911    -3786.60098289
  entropy T*S    EENTRO =        -0.05244532
  eigenvalues    EBANDS =      -478.70589341
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83612568 eV

  energy without entropy =     -107.78368036  energy(sigma->0) =     -107.81864391


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :   252
 total energy-change (2. order) :-0.1764486E-03  (-0.7673410E-05)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9454728 magnetization 

 Broyden mixing:
  rms(total) = 0.44188E-02    rms(broyden)= 0.44179E-02
  rms(prec ) = 0.59604E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7039
  7.5164  5.1511  3.0495  1.5262  1.5262  2.0951  2.0951  2.4013  1.2537  1.9859
  1.9859  1.1406  1.1406  1.0225  1.0225  1.0644  0.8813  0.8813  0.9311  0.9014
  0.7734  0.7734  0.4949  0.4949  0.4891

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.69054517
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.91004380
  PAW double counting   =      3816.66932219    -3786.83214848
  entropy T*S    EENTRO =        -0.05350918
  eigenvalues    EBANDS =      -478.78067053
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83630213 eV

  energy without entropy =     -107.78279295  energy(sigma->0) =     -107.81846573


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :   340
 total energy-change (2. order) :-0.2699001E-03  (-0.2786516E-04)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9454947 magnetization 

 Broyden mixing:
  rms(total) = 0.47902E-02    rms(broyden)= 0.47887E-02
  rms(prec ) = 0.66802E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6421
  7.5146  5.1587  3.0271  2.1074  2.1074  1.5252  1.5252  1.2538  2.3972  1.9919
  1.9919  1.1369  1.1369  1.0252  1.0252  1.0455  0.9334  0.9028  0.8575  0.8575
  0.7775  0.7775  0.4954  0.4954  0.4812  0.1450

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.56962763
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90941128
  PAW double counting   =      3817.23679255    -3787.39980661
  entropy T*S    EENTRO =        -0.05478401
  eigenvalues    EBANDS =      -478.89976283
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83657203 eV

  energy without entropy =     -107.78178801  energy(sigma->0) =     -107.81831069


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :   400
 total energy-change (2. order) :-0.1300802E-04  (-0.3533335E-05)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455293 magnetization 

 Broyden mixing:
  rms(total) = 0.48112E-02    rms(broyden)= 0.48111E-02
  rms(prec ) = 0.67159E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5852
  7.5015  5.1903  2.9778  2.1042  2.1042  1.5240  1.5240  2.3396  2.0087  2.0087
  1.2540  1.1341  1.1341  1.0228  1.0228  1.0334  0.9337  0.8899  0.8514  0.8514
  0.7938  0.7938  0.4931  0.4931  0.4870  0.1647  0.1647

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.56523524
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90932801
  PAW double counting   =      3817.24099491    -3787.40398618
  entropy T*S    EENTRO =        -0.05480645
  eigenvalues    EBANDS =      -478.90408532
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83658504 eV

  energy without entropy =     -107.78177858  energy(sigma->0) =     -107.81831622


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :   272
 total energy-change (2. order) :-0.3617753E-05  (-0.4062553E-07)
 number of electron      44.9999945 magnetization 
 augmentation part        0.9455293 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         4.76039610
  Ewald energy   TEWEN  =      1356.09773519
  -Hartree energ DENC   =     -2540.56348780
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       106.90932139
  PAW double counting   =      3817.26013493    -3787.42312122
  entropy T*S    EENTRO =        -0.05481792
  eigenvalues    EBANDS =      -478.90582327
  atomic energy  EATOM  =      1414.08307395
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -107.83658865 eV

  energy without entropy =     -107.78177073  energy(sigma->0) =     -107.81831601


--------------------------------------------------------------------------------------------------------




 average (electrostatic) potential at core
  the test charge radii are     0.9892  0.7215  0.6991  0.5201
  (the norm of the test charge is              1.0000)
       1 -92.7172       2 -92.7923       3 -79.5926       4 -57.3834       5 -57.4851
       6 -57.3898       7 -57.4147       8 -39.5137       9 -41.2269      10 -41.2065
      11 -41.2076      12 -41.1926      13 -41.1967      14 -41.2038      15 -41.1457
      16 -41.1841      17 -41.2061      18 -41.1653      19 -41.2219      20 -41.3604
      21 -41.4406      22 -39.6222
 
 
 
 E-fermi :  -5.4991     XC(G=0):  -1.8439     alpha+bet : -0.9131


 k-point     1 :       0.0000    0.0000    0.0000
  band No.  band energies     occupation 
      1     -23.5574      2.00000
      2     -16.8703      2.00000
      3     -16.6896      2.00000
      4     -16.1271      2.00000
      5     -16.1028      2.00000
      6     -12.8589      2.00000
      7     -10.6082      2.00000
      8      -9.7926      2.00000
      9      -9.5579      2.00000
     10      -9.3882      2.00000
     11      -9.2176      2.00000
     12      -9.0620      2.00000
     13      -8.9285      2.00000
     14      -8.8914      2.00000
     15      -8.7886      2.00000
     16      -8.3964      2.00000
     17      -8.1133      2.00000
     18      -7.9891      2.00000
     19      -6.8682      2.00000
     20      -6.7945      2.00000
     21      -6.1111      2.00013
     22      -5.9896      2.00286
     23      -5.4991      1.00039
     24      -0.2672     -0.00000
     25       0.2087      0.00000
     26       0.5359      0.00000
     27       0.6443      0.00000
     28       0.7486      0.00000
     29       0.8847      0.00000
     30       1.1043      0.00000
     31       1.3089      0.00000
     32       1.3848      0.00000
     33       1.4880      0.00000
     34       1.5957      0.00000
     35       1.6430      0.00000
     36       1.7493      0.00000

 k-point     2 :       0.0000    0.5000    0.0000
  band No.  band energies     occupation 
      1     -23.5574      2.00000
      2     -16.8703      2.00000
      3     -16.6896      2.00000
      4     -16.1272      2.00000
      5     -16.1028      2.00000
      6     -12.8589      2.00000
      7     -10.6081      2.00000
      8      -9.7928      2.00000
      9      -9.5579      2.00000
     10      -9.3883      2.00000
     11      -9.2176      2.00000
     12      -9.0619      2.00000
     13      -8.9286      2.00000
     14      -8.8912      2.00000
     15      -8.7885      2.00000
     16      -8.3963      2.00000
     17      -8.1131      2.00000
     18      -7.9893      2.00000
     19      -6.8676      2.00000
     20      -6.7944      2.00000
     21      -6.1124      2.00013
     22      -5.9898      2.00284
     23      -5.4982      0.99283
     24      -0.0784      0.00000
     25       0.1489      0.00000
     26       0.4442      0.00000
     27       0.6774      0.00000
     28       0.7125      0.00000
     29       0.7500      0.00000
     30       0.9489      0.00000
     31       1.1187      0.00000
     32       1.3446      0.00000
     33       1.4539      0.00000
     34       1.5335      0.00000
     35       1.7049      0.00000
     36       1.7424      0.00000

 k-point     3 :       0.0000    0.0000    0.5000
  band No.  band energies     occupation 
      1     -23.5574      2.00000
      2     -16.8703      2.00000
      3     -16.6896      2.00000
      4     -16.1272      2.00000
      5     -16.1028      2.00000
      6     -12.8589      2.00000
      7     -10.6081      2.00000
      8      -9.7928      2.00000
      9      -9.5579      2.00000
     10      -9.3877      2.00000
     11      -9.2174      2.00000
     12      -9.0621      2.00000
     13      -8.9289      2.00000
     14      -8.8911      2.00000
     15      -8.7884      2.00000
     16      -8.3967      2.00000
     17      -8.1131      2.00000
     18      -7.9892      2.00000
     19      -6.8683      2.00000
     20      -6.7945      2.00000
     21      -6.1109      2.00013
     22      -5.9898      2.00284
     23      -5.4993      1.00169
     24      -0.0926      0.00000
     25       0.1592      0.00000
     26       0.4460      0.00000
     27       0.6027      0.00000
     28       0.6560      0.00000
     29       0.8038      0.00000
     30       0.9763      0.00000
     31       1.1940      0.00000
     32       1.3855      0.00000
     33       1.4512      0.00000
     34       1.5805      0.00000
     35       1.6449      0.00000
     36       1.7265      0.00000

 k-point     4 :       0.0000    0.5000    0.5000
  band No.  band energies     occupation 
      1     -23.5573      2.00000
      2     -16.8702      2.00000
      3     -16.6895      2.00000
      4     -16.1272      2.00000
      5     -16.1028      2.00000
      6     -12.8589      2.00000
      7     -10.6080      2.00000
      8      -9.7929      2.00000
      9      -9.5578      2.00000
     10      -9.3877      2.00000
     11      -9.2172      2.00000
     12      -9.0618      2.00000
     13      -8.9287      2.00000
     14      -8.8908      2.00000
     15      -8.7883      2.00000
     16      -8.3965      2.00000
     17      -8.1126      2.00000
     18      -7.9889      2.00000
     19      -6.8676      2.00000
     20      -6.7944      2.00000
     21      -6.1121      2.00013
     22      -5.9898      2.00284
     23      -5.4983      0.99319
     24       0.1171      0.00000
     25       0.2218      0.00000
     26       0.3646      0.00000
     27       0.6848      0.00000
     28       0.6902      0.00000
     29       0.7620      0.00000
     30       0.8258      0.00000
     31       0.9072      0.00000
     32       1.1112      0.00000
     33       1.2283      0.00000
     34       1.3452      0.00000
     35       1.4118      0.00000
     36       1.5932      0.00000


--------------------------------------------------------------------------------------------------------


 soft charge-density along one line, spin component           1
         0         1         2         3         4         5         6         7         8         9
 total charge-density along one line
 
 pseudopotential strength for first ion, spin component:           1
 19.523  27.245   0.005  -0.001   0.012   0.009  -0.002   0.023
 27.245  38.026   0.007  -0.002   0.017   0.013  -0.003   0.032
  0.005   0.007   4.340   0.000   0.002   8.095   0.001   0.003
 -0.001  -0.002   0.000   4.339  -0.001   0.001   8.095  -0.001
  0.012   0.017   0.002  -0.001   4.344   0.003  -0.001   8.103
  0.009   0.013   8.095   0.001   0.003  15.110   0.001   0.005
 -0.002  -0.003   0.001   8.095  -0.001   0.001  15.109  -0.002
  0.023   0.032   0.003  -0.001   8.103   0.005  -0.002  15.124
 total augmentation occupancy for first ion, spin component:           1
  8.505  -3.893   0.280  -0.189   1.303  -0.115   0.088  -0.558
 -3.893   1.907  -0.235   0.139  -1.006   0.085  -0.063   0.392
  0.280  -0.235   4.041  -0.091   0.312  -1.070   0.039  -0.179
 -0.189   0.139  -0.091   3.809   0.093   0.039  -0.962  -0.030
  1.303  -1.006   0.312   0.093   4.831  -0.180  -0.030  -1.526
 -0.115   0.085  -1.070   0.039  -0.180   0.297  -0.016   0.080
  0.088  -0.063   0.039  -0.962  -0.030  -0.016   0.251   0.012
 -0.558   0.392  -0.179  -0.030  -1.526   0.080   0.012   0.498


------------------------ aborting loop because EDIFF is reached ----------------------------------------



  FORCE on cell =-STRESS in cart. coord.  units (eV):
  Direction    XX          YY          ZZ          XY          YZ          ZX
  --------------------------------------------------------------------------------------
  Alpha Z     4.76040     4.76040     4.76040
  Ewald     479.65532   379.87143   496.57000   191.38211  -106.86007    48.48886
  Hartree   725.02029   858.49164   957.89613   151.19578   -86.34463    51.07411
  E(xc)    -161.10083  -161.69657  -161.72354     0.06741     0.04144    -0.06690
  Local   -1605.03928 -1662.05438 -1883.23968  -342.04850   198.45525  -107.55005
  n-local    -9.69363    -9.85872    -9.82760     0.34722    -0.90554     0.68793
  augment    -4.12596    -3.33549    -3.26709    -0.08222    -0.00257     0.05718
  Kinetic   566.52652   592.16761   597.21842    -1.73218    -4.16790     6.56821
  Fock        0.00000     0.00000     0.00000     0.00000     0.00000     0.00000
  -------------------------------------------------------------------------------------
  Total       -3.9971753     -1.6540818     -1.6129750     -0.8703864      0.2159768     -0.7406604
  in kB       -4.2694558     -1.7667549     -1.7228479     -0.9296756      0.2306888     -0.7911129
  external PRESSURE =      -2.5863529 kB  Pullay stress =       0.0000000 kB


 VOLUME and BASIS-vectors are now :
 -----------------------------------------------------------------------------
  energy-cutoff  :      400.00
  volume of cell :     1500.00
      direct lattice vectors                 reciprocal lattice vectors
    15.000000000  0.000000000  0.000000000     0.066666667  0.000000000  0.000000000
     0.000000000 10.000000000  0.000000000     0.000000000  0.100000000  0.000000000
     0.000000000  0.000000000 10.000000000     0.000000000  0.000000000  0.100000000

  length of vectors
    15.000000000 10.000000000 10.000000000     0.066666667  0.100000000  0.100000000


 FORCES acting on ions
    electron-ion (+dipol)            ewald-force                    non-local-force                 convergence-correction
 -----------------------------------------------------------------------------------------------
   0.115E+03 -.777E+01 -.539E+02   -.118E+03 0.609E+01 0.542E+02   0.380E+01 0.170E+01 -.209E+00   -.102E-01 -.278E-02 0.172E-01
   -.938E+02 0.459E+02 -.484E+01   0.973E+02 -.480E+02 0.223E+01   -.344E+01 0.238E+01 0.271E+01   0.177E-01 0.351E-02 0.185E-01
   0.531E+01 -.818E+02 -.694E+02   -.550E+01 0.970E+02 0.754E+02   0.413E+00 -.152E+02 -.592E+01   0.127E-01 0.542E-01 0.415E-01
   -.590E+02 -.202E+02 0.898E+02   0.586E+02 0.193E+02 -.869E+02   0.275E+00 0.800E+00 -.276E+01   0.119E-01 0.184E-01 -.290E-01
   -.891E+02 -.244E+02 -.568E+02   0.853E+02 0.246E+02 0.564E+02   0.319E+01 -.232E+00 0.251E+00   0.881E-02 0.258E-01 0.246E-01
   0.518E+02 0.892E+02 -.272E+02   -.515E+02 -.862E+02 0.271E+02   -.304E+00 -.290E+01 0.140E+00   -.208E-02 -.305E-01 0.797E-02
   0.947E+02 -.303E+02 0.573E+02   -.929E+02 0.296E+02 -.547E+02   -.171E+01 0.665E+00 -.246E+01   -.198E-01 0.132E-01 -.232E-01
   0.316E+02 -.192E+02 -.395E+02   -.327E+02 0.205E+02 0.418E+02   0.129E+01 -.127E+01 -.240E+01   -.113E-02 0.638E-02 0.833E-02
   -.634E+02 0.705E+01 0.331E+02   0.685E+02 -.800E+01 -.349E+02   -.506E+01 0.887E+00 0.170E+01   0.842E-02 0.817E-03 -.514E-02
   -.194E+01 -.632E+02 0.220E+02   0.963E+00 0.686E+02 -.224E+02   0.949E+00 -.533E+01 0.455E+00   0.303E-03 0.121E-01 -.266E-02
   0.220E+02 0.238E+02 0.537E+02   -.255E+02 -.264E+02 -.574E+02   0.346E+01 0.255E+01 0.339E+01   -.231E-02 -.150E-02 -.983E-02
   -.311E+02 -.596E+02 -.698E+01   0.321E+02 0.649E+02 0.667E+01   -.125E+01 -.529E+01 0.209E+00   -.256E-02 0.123E-01 0.577E-02
   -.222E+02 0.136E+02 -.614E+02   0.224E+02 -.153E+02 0.668E+02   -.449E+00 0.160E+01 -.526E+01   -.507E-03 0.371E-02 0.871E-02
   0.635E+02 0.316E+02 -.939E+01   -.686E+02 -.332E+02 0.980E+01   0.507E+01 0.168E+01 -.416E+00   -.206E-02 -.558E-02 0.163E-02
   -.166E+02 0.344E+02 -.528E+02   0.192E+02 -.361E+02 0.572E+02   -.261E+01 0.172E+01 -.442E+01   0.171E-02 -.738E-02 0.418E-02
   -.121E+02 0.459E+02 0.421E+02   0.143E+02 -.485E+02 -.464E+02   -.218E+01 0.252E+01 0.426E+01   0.688E-03 -.760E-02 -.657E-05
   -.383E+00 0.186E+02 0.610E+02   0.243E+01 -.208E+02 -.656E+02   -.198E+01 0.218E+01 0.453E+01   -.483E-03 -.130E-02 -.861E-02
   0.191E+02 -.624E+02 0.165E+02   -.191E+02 0.679E+02 -.172E+02   -.428E-01 -.540E+01 0.627E+00   -.173E-02 0.941E-02 -.254E-02
   0.711E+02 0.998E+01 0.635E+01   -.762E+02 -.115E+02 -.600E+01   0.513E+01 0.146E+01 -.281E+00   -.814E-02 -.521E-03 -.173E-02
   -.958E+00 -.143E+02 -.114E+02   0.943E+00 0.142E+02 0.114E+02   0.142E-01 0.179E-01 0.589E-02   0.106E-02 0.387E-02 0.254E-02
   -.635E+02 0.248E+02 0.171E+02   0.680E+02 -.276E+02 -.199E+02   -.397E+01 0.260E+01 0.267E+01   0.665E-02 -.430E-03 0.521E-03
   -.202E+02 0.481E+02 -.205E+01   0.205E+02 -.512E+02 0.218E+01   -.281E+00 0.301E+01 -.220E+00   0.314E-02 -.851E-02 0.232E-02
 -----------------------------------------------------------------------------------------------
   -.317E+00 0.974E+01 0.335E+01   0.462E-13 0.782E-13 0.124E-13   0.311E+00 -.984E+01 -.339E+01   0.220E-01 0.976E-01 0.612E-01
 
 
 POSITION                                       TOTAL-FORCE (eV/Angst)
 -----------------------------------------------------------------------------------
      2.56244      5.64691      7.22168        -0.000888      0.021519      0.092535
      5.73136      5.82471      6.78987        -0.006006      0.309305      0.118324
      4.14517      6.15803      7.17781         0.235435      0.096114      0.124292
      6.03015      6.43589      5.04104        -0.068364     -0.126527      0.155358
      7.18479      6.48865      7.82121        -0.583116     -0.020025     -0.065248
      2.47308      3.77877      7.40568         0.003491      0.102382     -0.001366
      1.61585      6.19650      5.69013         0.068057     -0.027294      0.098227
      1.91870      6.28219      8.42268         0.108395     -0.006183     -0.071896
      7.05861      6.24992      4.70451         0.038047     -0.061468     -0.022389
      5.83888      7.51287      4.95887        -0.031194      0.116146      0.038646
      5.33869      5.92250      4.36708        -0.073127     -0.063580     -0.262898
      7.42730      7.55854      7.77008        -0.244160      0.063287     -0.093119
      7.26576      6.16546      8.86257        -0.196999     -0.088311      0.159140
      1.42677      3.44582      7.48872        -0.013180      0.036080     -0.004564
      3.00457      3.43678      8.30434         0.035337     -0.012834      0.028176
      2.91548      3.27534      6.53582         0.044668     -0.068895     -0.060334
      2.02543      5.74839      4.77529         0.062615     -0.032041     -0.082520
      1.62842      7.28745      5.56890         0.042980      0.077425      0.006918
      0.56011      5.88782      5.76025         0.027664     -0.023322      0.064852
      4.84522      9.00768      9.06857        -0.000742     -0.023250     -0.021675
      7.96906      5.96144      7.27330         0.525665     -0.144063     -0.113539
      5.87271      4.34093      6.88632         0.025421     -0.124466     -0.086920
 -----------------------------------------------------------------------------------
    total drift:                                0.015725      0.000191      0.020209


--------------------------------------------------------------------------------------------------------



  FREE ENERGIE OF THE ION-ELECTRON SYSTEM (eV)
  ---------------------------------------------------
  free  energy   TOTEN  =      -107.8365886531 eV

  energy  without entropy=     -107.7817707306  energy(sigma->0) =     -107.81831601
 


--------------------------------------------------------------------------------------------------------




--------------------------------------------------------------------------------------------------------



volume of typ            1:     0.8 %

volume of typ            2:     0.1 %

volume of typ            3:     0.5 %

volume of typ            4:     0.1 %
 
total charge     
 
# of ion       s       p       d       tot
------------------------------------------
    1        0.681   0.963   0.235   1.879
    2        0.680   0.957   0.235   1.871
    3        1.233   2.961   0.005   4.198
    4        0.672   1.508   0.017   2.197
    5        0.673   1.498   0.018   2.188
    6        0.671   1.502   0.017   2.191
    7        0.672   1.501   0.017   2.190
    8        0.151   0.001   0.000   0.152
    9        0.162   0.002   0.000   0.164
   10        0.162   0.002   0.000   0.164
   11        0.163   0.002   0.000   0.166
   12        0.162   0.002   0.000   0.164
   13        0.163   0.002   0.000   0.165
   14        0.161   0.002   0.000   0.164
   15        0.162   0.002   0.000   0.164
   16        0.162   0.002   0.000   0.164
   17        0.162   0.002   0.000   0.165
   18        0.162   0.002   0.000   0.164
   19        0.161   0.002   0.000   0.163
   20        0.096   0.000   0.000   0.096
   21        0.164   0.002   0.000   0.166
   22        0.153   0.001   0.000   0.153
--------------------------------------------------
tot           7.63   10.92    0.55   19.09
 

 total amount of memory used by VASP MPI-rank0    99526. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1847. kBytes
   fftplans  :      14520. kBytes
   grid      :      37312. kBytes
   one-center:         67. kBytes
   wavefun   :      15780. kBytes
 
  
  
 General timing and accounting informations for this job:
 ========================================================
  
                  Total CPU time used (sec):       73.174
                            User time (sec):       66.529
                          System time (sec):        6.645
                         Elapsed time (sec):       75.371
  
                   Maximum memory used (kb):      738700.
                   Average memory used (kb):          N/A
  
                          Minor page faults:       166014
                          Major page faults:            0
                 Voluntary context switches:         5885