Using device 2 (rank 2, local rank 2, local size 4) : Tesla V100-PCIE-16GB
Using device 3 (rank 3, local rank 3, local size 4) : Tesla V100-SXM2-16GB
Using device 0 (rank 0, local rank 0, local size 4) : Tesla V100-SXM2-16GB
Using device 1 (rank 1, local rank 1, local size 4) : Tesla V100-PCIE-16GB
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on    1 cores,    4 groups
  
 *******************************************************************************
  You are running the GPU port of VASP! When publishing results obtained with
  this version, please cite:
   - M. Hacene et al., http://dx.doi.org/10.1002/jcc.23096
   - M. Hutchinson and M. Widom, http://dx.doi.org/10.1016/j.cpc.2012.02.017
  
  in addition to the usual required citations (see manual).
  
  GPU developers: A. Anciaux-Sedrakian, C. Angerer, and M. Hutchinson.
 *******************************************************************************
  
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     Please note that VASP has recently been ported to GPU by means of       |
|     OpenACC. You are running the CUDA-C GPU-port of VASP, which is          |
|     deprecated and no longer actively developed, maintained, or             |
|     supported. In the near future, the CUDA-C GPU-port of VASP will be      |
|     dropped completely. We encourage you to switch to the OpenACC           |
|     GPU-port of VASP as soon as possible.                                   |
|                                                                             |
 -----------------------------------------------------------------------------

 vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 POSCAR found type information on POSCAR B H 
 POSCAR found :  2 types and      10 ions
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 LDA part: xc-table for Pade appr. of Perdew
  
 WARNING: The GPU port of VASP has been extensively
 tested for: ALGO=Normal, Fast, and VeryFast.
 Other algorithms may produce incorrect results or
 yield suboptimal performance. Handle with care!
  
 POSCAR, INCAR and KPOINTS ok, starting setup
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUFFT plans with grid size 20 x 28 x 30...
creating 32 CUFFT plans with grid size 20 x 28 x 30...
creating 32 CUFFT plans with grid size 20 x 28 x 30...
creating 32 CUFFT plans with grid size 20 x 28 x 30...
 FFT: planning ...
 WAVECAR not read
 entering main loop
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1     0.281664351242E+02    0.28166E+02   -0.38948E+03   320   0.439E+02 
DAV:   2    -0.386242952673E+02   -0.66791E+02   -0.63813E+02   448   0.120E+02 
DAV:   3    -0.435091881288E+02   -0.48849E+01   -0.48752E+01   400   0.358E+01 
DAV:   4    -0.435538120027E+02   -0.44624E-01   -0.44611E-01   464   0.379E+00 
DAV:   5    -0.435542949638E+02   -0.48296E-03   -0.48296E-03   408   0.349E-01    0.112E+01
DAV:   6    -0.380206069667E+02    0.55337E+01   -0.61785E+00   344   0.132E+01    0.574E+00
DAV:   7    -0.367344395933E+02    0.12862E+01   -0.32447E+00   464   0.862E+00    0.230E+00
DAV:   8    -0.366055935943E+02    0.12885E+00   -0.37557E-01   344   0.296E+00    0.682E-01
DAV:   9    -0.365961742062E+02    0.94194E-02   -0.31714E-02   448   0.848E-01    0.375E-01
DAV:  10    -0.365992208938E+02   -0.30467E-02   -0.26770E-02   344   0.703E-01    0.194E-01
DAV:  11    -0.366035656961E+02   -0.43448E-02   -0.43792E-03   328   0.338E-01    0.593E-02
DAV:  12    -0.366050266258E+02   -0.14609E-02   -0.28678E-04   368   0.116E-01    0.254E-02
DAV:  13    -0.366053277587E+02   -0.30113E-03   -0.10276E-04   328   0.667E-02    0.838E-03
DAV:  14    -0.366053508049E+02   -0.23046E-04   -0.22015E-05   352   0.280E-02    0.497E-03
DAV:  15    -0.366053481108E+02    0.26940E-05   -0.60246E-06   328   0.983E-03 
   1 F= -.36605348E+02 E0= -.36612290E+02  d E =-.366053E+02
 curvature:   0.00 expect dE= 0.000E+00 dE for cont linesearch  0.000E+00
 trial: gam= 0.00000 g(F)=  0.233E+01 g(S)=  0.000E+00 ort = 0.000E+00 (trialstep = 0.100E+01)
 search vector abs. value=  0.233E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.375157086713E+02   -0.91036E+00   -0.70453E+01   320   0.518E+01    0.298E+00
DAV:   2    -0.372733778888E+02    0.24233E+00   -0.11491E+00   424   0.642E+00    0.163E+00
DAV:   3    -0.372164485094E+02    0.56929E-01   -0.36440E-01   448   0.310E+00    0.470E-01
DAV:   4    -0.372169288099E+02   -0.48030E-03   -0.35827E-02   384   0.101E+00    0.282E-01
DAV:   5    -0.372178376148E+02   -0.90880E-03   -0.35061E-03   360   0.364E-01    0.406E-02
DAV:   6    -0.372181191617E+02   -0.28155E-03   -0.50810E-04   416   0.126E-01    0.287E-02
DAV:   7    -0.372183590410E+02   -0.23988E-03   -0.13457E-04   336   0.654E-02    0.873E-03
DAV:   8    -0.372183864443E+02   -0.27403E-04   -0.21948E-05   464   0.276E-02    0.462E-03
DAV:   9    -0.372183999591E+02   -0.13515E-04   -0.41958E-06   312   0.117E-02    0.137E-03
DAV:  10    -0.372183999478E+02    0.11335E-07   -0.38604E-07   376   0.335E-03 
   2 F= -.37218400E+02 E0= -.37222731E+02  d E =-.613052E+00
 trial-energy change:   -0.613052  1 .order   -0.676839   -2.326058    0.972380
 step:   0.6799(harm=  0.7052)  dis= 0.09482  next Energy=   -37.376097 (dE=-0.771E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.374048722032E+02   -0.18647E+00   -0.70563E+00   320   0.160E+01    0.941E-01
DAV:   2    -0.373847655071E+02    0.20107E-01   -0.13796E-01   416   0.221E+00    0.518E-01
DAV:   3    -0.373790534249E+02    0.57121E-02   -0.48723E-02   408   0.112E+00    0.159E-01
DAV:   4    -0.373784333145E+02    0.62011E-03   -0.46795E-03   328   0.358E-01    0.926E-02
DAV:   5    -0.373784673125E+02   -0.33998E-04   -0.34878E-04   416   0.110E-01    0.117E-02
DAV:   6    -0.373784614157E+02    0.58968E-05   -0.35632E-05   368   0.351E-02 
   3 F= -.37378461E+02 E0= -.37382765E+02  d E =-.773113E+00
 curvature:  -0.35 expect dE=-0.587E+00 dE for cont linesearch -0.159E-04
 trial: gam= 0.72523 g(F)=  0.168E+01 g(S)=  0.000E+00 ort =-0.103E-01 (trialstep = 0.755E+00)
 search vector abs. value=  0.289E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.379068523533E+02   -0.52839E+00   -0.31396E+01   320   0.343E+01    0.226E+00
DAV:   2    -0.378180056770E+02    0.88847E-01   -0.64736E-01   408   0.453E+00    0.113E+00
DAV:   3    -0.378005597390E+02    0.17446E-01   -0.12187E-01   416   0.169E+00    0.362E-01
DAV:   4    -0.378004016016E+02    0.15814E-03   -0.63321E-03   352   0.434E-01    0.214E-01
DAV:   5    -0.378005639739E+02   -0.16237E-03   -0.12415E-03   384   0.182E-01    0.283E-02
DAV:   6    -0.378005682653E+02   -0.42914E-05   -0.41664E-05   448   0.348E-02 
   4 F= -.37800568E+02 E0= -.37808188E+02  d E =-.422107E+00
 trial-energy change:   -0.422107  1 .order   -0.492335   -1.259593    0.274923
 step:   0.5830(harm=  0.6194)  dis= 0.11215  next Energy=   -37.832653 (dE=-0.454E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.378356300452E+02   -0.35066E-01   -0.16030E+00   336   0.774E+00    0.425E-01
DAV:   2    -0.378331876225E+02    0.24424E-02   -0.28302E-02   416   0.983E-01    0.238E-01
DAV:   3    -0.378323533927E+02    0.83423E-03   -0.83451E-03   440   0.441E-01    0.743E-02
DAV:   4    -0.378321683542E+02    0.18504E-03   -0.70585E-04   376   0.142E-01    0.472E-02
DAV:   5    -0.378321654490E+02    0.29052E-05   -0.12558E-04   336   0.567E-02    0.727E-03
DAV:   6    -0.378321656281E+02   -0.17911E-06   -0.44932E-06   384   0.125E-02 
   5 F= -.37832166E+02 E0= -.37836800E+02  d E =-.453704E+00
 curvature:  -0.50 expect dE=-0.131E+00 dE for cont linesearch -0.636E-04
 trial: gam= 0.15435 g(F)=  0.263E+00 g(S)=  0.000E+00 ort = 0.192E-01 (trialstep = 0.720E+00)
 search vector abs. value=  0.338E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.379898665897E+02   -0.15770E+00   -0.29376E+00   320   0.106E+01    0.363E-01
DAV:   2    -0.379941260841E+02   -0.42595E-02   -0.49665E-02   472   0.127E+00    0.228E-01
DAV:   3    -0.379940764663E+02    0.49618E-04   -0.16933E-03   392   0.240E-01    0.698E-02
DAV:   4    -0.379941197930E+02   -0.43327E-04   -0.32883E-04   432   0.107E-01    0.211E-02
DAV:   5    -0.379941187519E+02    0.10412E-05   -0.31768E-05   328   0.311E-02 
   6 F= -.37994119E+02 E0= -.38001679E+02  d E =-.161953E+00
 trial-energy change:   -0.161953  1 .order   -0.161468   -0.191698   -0.131238
 step:   2.0920(harm=  2.2838)  dis= 0.11439  next Energy=   -38.122437 (dE=-0.290E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.381513676146E+02   -0.15725E+00   -0.10894E+01   320   0.204E+01    0.766E-01
DAV:   2    -0.381666649377E+02   -0.15297E-01   -0.20425E-01   472   0.257E+00    0.467E-01
DAV:   3    -0.381662276323E+02    0.43731E-03   -0.64872E-03   400   0.422E-01    0.150E-01
DAV:   4    -0.381663311773E+02   -0.10355E-03   -0.74309E-04   464   0.145E-01    0.412E-02
DAV:   5    -0.381663028493E+02    0.28328E-04   -0.12895E-04   384   0.592E-02    0.114E-02
DAV:   6    -0.381662900305E+02    0.12819E-04   -0.20012E-05   408   0.242E-02    0.575E-03
DAV:   7    -0.381662849007E+02    0.51298E-05   -0.47017E-06   272   0.124E-02 
   7 F= -.38166285E+02 E0= -.38172047E+02  d E =-.334119E+00
 curvature:  -1.43 expect dE=-0.220E+00 dE for cont linesearch -0.177E-01
 ZBRENT: increasing intervall
 opt :   4.8356  next Energy=   -38.021786 (dE=-0.190E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.379049688577E+02    0.26132E+00   -0.43745E+01   320   0.413E+01    0.147E+00
DAV:   2    -0.379921845891E+02   -0.87216E-01   -0.94990E-01   456   0.561E+00    0.959E-01
DAV:   3    -0.379940228598E+02   -0.18383E-02   -0.20708E-02   400   0.792E-01    0.350E-01
DAV:   4    -0.379955110941E+02   -0.14882E-02   -0.31176E-03   440   0.308E-01    0.736E-02
DAV:   5    -0.379956301273E+02   -0.11903E-03   -0.54281E-04   344   0.121E-01    0.192E-02
DAV:   6    -0.379956878054E+02   -0.57678E-04   -0.60384E-05   400   0.419E-02    0.127E-02
DAV:   7    -0.379956829979E+02    0.48076E-05   -0.20242E-05   384   0.255E-02 
   8 F= -.37995683E+02 E0= -.37998159E+02  d E =-.163517E+00
 curvature:  11.64 expect dE= 0.122E+02 dE for cont linesearch  0.110E+01
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   2.8213  next Energy=   -38.189901 (dE=-0.358E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.381462861574E+02   -0.15060E+00   -0.23675E+01   320   0.305E+01    0.113E+00
DAV:   2    -0.381838347830E+02   -0.37549E-01   -0.45100E-01   456   0.382E+00    0.703E-01
DAV:   3    -0.381848117474E+02   -0.97696E-03   -0.85979E-03   416   0.525E-01    0.281E-01
DAV:   4    -0.381854090247E+02   -0.59728E-03   -0.15222E-03   448   0.220E-01    0.485E-02
DAV:   5    -0.381853470210E+02    0.62004E-04   -0.33107E-04   368   0.908E-02    0.155E-02
DAV:   6    -0.381853474310E+02   -0.40996E-06   -0.38468E-05   368   0.338E-02 
   9 F= -.38185347E+02 E0= -.38188464E+02  d E =-.353182E+00
 curvature:  -0.25 expect dE=-0.686E-01 dE for cont linesearch -0.442E-04
 trial: gam= 1.15692 g(F)=  0.275E+00 g(S)=  0.000E+00 ort =-0.774E-02 (trialstep = 0.543E+00)
 search vector abs. value=  0.709E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.383209517448E+02   -0.13560E+00   -0.33359E+00   336   0.121E+01    0.526E-01
DAV:   2    -0.383206232690E+02    0.32848E-03   -0.43113E-02   464   0.123E+00    0.306E-01
DAV:   3    -0.383199008374E+02    0.72243E-03   -0.51372E-03   384   0.408E-01    0.715E-02
DAV:   4    -0.383199305514E+02   -0.29714E-04   -0.88950E-04   440   0.170E-01    0.352E-02
DAV:   5    -0.383199388193E+02   -0.82679E-05   -0.58411E-05   424   0.407E-02 
  10 F= -.38319939E+02 E0= -.38323224E+02  d E =-.134591E+00
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.134591  1 .order   -0.134515   -0.144535   -0.124496
 step:   2.1728(harm=  3.9179)  dis= 0.17854  next Energy=   -38.706573 (dE=-0.521E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.385870085676E+02   -0.26708E+00   -0.30156E+01   360   0.361E+01    0.164E+00
DAV:   2    -0.385939099215E+02   -0.69014E-02   -0.46467E-01   432   0.404E+00    0.972E-01
DAV:   3    -0.385846385370E+02    0.92714E-02   -0.36871E-02   456   0.121E+00    0.214E-01
DAV:   4    -0.385851138203E+02   -0.47528E-03   -0.68007E-03   392   0.480E-01    0.103E-01
DAV:   5    -0.385851240536E+02   -0.10233E-04   -0.48631E-04   400   0.132E-01    0.275E-02
DAV:   6    -0.385851220777E+02    0.19758E-05   -0.10277E-04   392   0.594E-02    0.114E-02
DAV:   7    -0.385851080336E+02    0.14044E-04   -0.21127E-05   352   0.266E-02    0.484E-03
DAV:   8    -0.385851047133E+02    0.33203E-05   -0.35816E-06   432   0.109E-02 
  11 F= -.38585105E+02 E0= -.38589296E+02  d E =-.399757E+00
 curvature:  -3.83 expect dE=-0.184E+01 dE for cont linesearch -0.340E-01
 ZBRENT: increasing intervall
 opt :   5.4321  next Energy=   -38.355980 (dE=-0.171E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.375492341460E+02    0.10359E+01   -0.12231E+02   368   0.711E+01    0.344E+00
DAV:   2    -0.376844131710E+02   -0.13518E+00   -0.31912E+00   440   0.978E+00    0.218E+00
DAV:   3    -0.376206040807E+02    0.63809E-01   -0.12386E-01   432   0.200E+00    0.653E-01
DAV:   4    -0.376205082621E+02    0.95819E-04   -0.22514E-02   416   0.867E-01    0.165E-01
DAV:   5    -0.376207001043E+02   -0.19184E-03   -0.10553E-03   376   0.200E-01    0.443E-02
DAV:   6    -0.376207397937E+02   -0.39689E-04   -0.15841E-04   376   0.716E-02    0.176E-02
DAV:   7    -0.376207041074E+02    0.35686E-04   -0.62421E-05   384   0.455E-02    0.105E-02
DAV:   8    -0.376206974443E+02    0.66631E-05   -0.10589E-05   408   0.211E-02 
  12 F= -.37620697E+02 E0= -.37625912E+02  d E =0.564650E+00
 curvature:  25.75 expect dE= 0.128E+03 dE for cont linesearch  0.266E+02
 ZBRENT: bracketing found
 ZBRENT: interpolating
 opt :   2.4498  next Energy=   -38.596105 (dE=-0.411E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.385499013729E+02   -0.92920E+00   -0.10434E+02   328   0.665E+01    0.303E+00
DAV:   2    -0.386701104985E+02   -0.12021E+00   -0.24747E+00   464   0.902E+00    0.205E+00
DAV:   3    -0.386027400295E+02    0.67370E-01   -0.21839E-01   376   0.242E+00    0.489E-01
DAV:   4    -0.386032373674E+02   -0.49734E-03   -0.20071E-02   440   0.821E-01    0.231E-01
DAV:   5    -0.386018914666E+02    0.13459E-02   -0.50078E-03   376   0.379E-01    0.523E-02
DAV:   6    -0.386018736061E+02    0.17861E-04   -0.56446E-04   432   0.132E-01    0.267E-02
DAV:   7    -0.386018347716E+02    0.38834E-04   -0.46879E-05   384   0.385E-02    0.784E-03
DAV:   8    -0.386018219317E+02    0.12840E-04   -0.79080E-06   424   0.156E-02    0.489E-03
DAV:   9    -0.386018183406E+02    0.35911E-05   -0.31881E-06   344   0.991E-03 
  13 F= -.38601818E+02 E0= -.38606122E+02  d E =-.416471E+00
 curvature:  -0.01 expect dE=-0.603E-02 dE for cont linesearch -0.245E-04
 trial: gam= 2.08711 g(F)=  0.566E+00 g(S)=  0.000E+00 ort = 0.404E-01 (trialstep = 0.171E+00)
 search vector abs. value=  0.382E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.386977467790E+02   -0.95925E-01   -0.17613E+00   360   0.863E+00    0.389E-01
DAV:   2    -0.386992070038E+02   -0.14602E-02   -0.27086E-02   440   0.968E-01    0.243E-01
DAV:   3    -0.386987819948E+02    0.42501E-03   -0.13102E-03   392   0.192E-01    0.384E-02
DAV:   4    -0.386987811701E+02    0.82468E-06   -0.86163E-05   424   0.524E-02 
  14 F= -.38698781E+02 E0= -.38703183E+02  d E =-.969628E-01
 trial-energy change:   -0.096963  1 .order   -0.096431   -0.111489   -0.081373
 step:   0.5218(harm=  0.6348)  dis= 0.09928  next Energy=   -38.786439 (dE=-0.185E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.387860942868E+02   -0.87312E-01   -0.74242E+00   368   0.177E+01    0.794E-01
DAV:   2    -0.387920744344E+02   -0.59801E-02   -0.12211E-01   448   0.204E+00    0.499E-01
DAV:   3    -0.387900942685E+02    0.19802E-02   -0.69674E-03   416   0.436E-01    0.906E-02
DAV:   4    -0.387900416153E+02    0.52653E-04   -0.58720E-04   416   0.137E-01    0.418E-02
DAV:   5    -0.387900214038E+02    0.20212E-04   -0.13501E-04   392   0.629E-02    0.103E-02
DAV:   6    -0.387900178585E+02    0.35453E-05   -0.17531E-05   416   0.238E-02 
  15 F= -.38790018E+02 E0= -.38795452E+02  d E =-.188200E+00
 curvature:  -1.76 expect dE=-0.624E+00 dE for cont linesearch -0.174E-03
 trial: gam= 0.17498 g(F)=  0.355E+00 g(S)=  0.000E+00 ort = 0.195E-01 (trialstep = 0.242E+00)
 search vector abs. value=  0.479E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.388618145048E+02   -0.71793E-01   -0.67352E-01   336   0.505E+00    0.256E-01
DAV:   2    -0.388620422335E+02   -0.22773E-03   -0.16197E-02   408   0.721E-01    0.159E-01
DAV:   3    -0.388615708476E+02    0.47139E-03   -0.19144E-03   384   0.239E-01    0.251E-02
DAV:   4    -0.388615842578E+02   -0.13410E-04   -0.20843E-04   432   0.823E-02    0.176E-02
DAV:   5    -0.388615841605E+02    0.97255E-07   -0.10506E-05   344   0.187E-02 
  16 F= -.38861584E+02 E0= -.38866251E+02  d E =-.715663E-01
 trial-energy change:   -0.071566  1 .order   -0.071553   -0.086646   -0.056459
 step:   0.6933(harm=  0.6933)  dis= 0.04876  next Energy=   -38.914369 (dE=-0.124E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.389144023815E+02   -0.52818E-01   -0.23756E+00   344   0.948E+00    0.492E-01
DAV:   2    -0.389149076430E+02   -0.50526E-03   -0.55616E-02   408   0.134E+00    0.305E-01
DAV:   3    -0.389131626885E+02    0.17450E-02   -0.70788E-03   376   0.453E-01    0.460E-02
DAV:   4    -0.389131970797E+02   -0.34391E-04   -0.72717E-04   424   0.152E-01    0.329E-02
DAV:   5    -0.389131950280E+02    0.20517E-05   -0.42746E-05   360   0.378E-02 
  17 F= -.38913195E+02 E0= -.38917671E+02  d E =-.123177E+00
 curvature:  -0.46 expect dE=-0.698E-01 dE for cont linesearch -0.582E-04
 trial: gam= 0.43805 g(F)=  0.151E+00 g(S)=  0.000E+00 ort =-0.776E-02 (trialstep = 0.332E+00)
 search vector abs. value=  0.236E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.389570512054E+02   -0.43854E-01   -0.51580E-01   320   0.478E+00    0.188E-01
DAV:   2    -0.389564205639E+02    0.63064E-03   -0.63796E-03   448   0.492E-01    0.113E-01
DAV:   3    -0.389562273079E+02    0.19326E-03   -0.12717E-03   376   0.197E-01    0.352E-02
DAV:   4    -0.389562274301E+02   -0.12221E-06   -0.12685E-04   424   0.703E-02    0.201E-02
DAV:   5    -0.389562270706E+02    0.35947E-06   -0.14598E-05   408   0.225E-02 
  18 F= -.38956227E+02 E0= -.38960868E+02  d E =-.430320E-01
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.043032  1 .order   -0.043081   -0.048885   -0.037278
 step:   1.3276(harm=  1.3978)  dis= 0.06088  next Energy=   -39.016136 (dE=-0.103E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.390230007106E+02   -0.66773E-01   -0.45979E+00   320   0.143E+01    0.546E-01
DAV:   2    -0.390185568817E+02    0.44438E-02   -0.56450E-02   448   0.148E+00    0.336E-01
DAV:   3    -0.390168758305E+02    0.16811E-02   -0.11126E-02   368   0.591E-01    0.102E-01
DAV:   4    -0.390168688896E+02    0.69409E-05   -0.12119E-03   424   0.218E-01    0.613E-02
DAV:   5    -0.390168772152E+02   -0.83256E-05   -0.13124E-04   392   0.668E-02    0.968E-03
DAV:   6    -0.390168719360E+02    0.52792E-05   -0.13766E-05   424   0.226E-02 
  19 F= -.39016872E+02 E0= -.39021574E+02  d E =-.103677E+00
 curvature:  -1.11 expect dE=-0.117E+00 dE for cont linesearch -0.487E-03
 trial: gam= 0.57217 g(F)=  0.105E+00 g(S)=  0.000E+00 ort = 0.102E-01 (trialstep = 0.531E+00)
 search vector abs. value=  0.193E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.390516501349E+02   -0.34773E-01   -0.10605E+00   336   0.666E+00    0.358E-01
DAV:   2    -0.390520268919E+02   -0.37676E-03   -0.24274E-02   456   0.860E-01    0.225E-01
DAV:   3    -0.390512132902E+02    0.81360E-03   -0.22297E-03   400   0.250E-01    0.351E-02
DAV:   4    -0.390512249344E+02   -0.11644E-04   -0.20027E-04   432   0.733E-02    0.170E-02
DAV:   5    -0.390512237801E+02    0.11542E-05   -0.17887E-05   352   0.235E-02 
  20 F= -.39051224E+02 E0= -.39055954E+02  d E =-.343518E-01
 trial-energy change:   -0.034352  1 .order   -0.034530   -0.058612   -0.010448
 step:   0.6494(harm=  0.6462)  dis= 0.01988  next Energy=   -39.052387 (dE=-0.355E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.390524088669E+02   -0.11839E-02   -0.52573E-02   336   0.148E+00    0.790E-02
DAV:   2    -0.390524332805E+02   -0.24414E-04   -0.12242E-03   464   0.194E-01    0.496E-02
DAV:   3    -0.390523945797E+02    0.38701E-04   -0.10597E-04   384   0.546E-02    0.836E-03
DAV:   4    -0.390523952658E+02   -0.68608E-06   -0.98197E-06   344   0.161E-02 
  21 F= -.39052395E+02 E0= -.39057128E+02  d E =-.355233E-01
 curvature:  -0.57 expect dE=-0.189E-01 dE for cont linesearch -0.258E-08
 trial: gam= 0.37725 g(F)=  0.334E-01 g(S)=  0.000E+00 ort = 0.297E-04 (trialstep = 0.555E+00)
 search vector abs. value=  0.609E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.390685328388E+02   -0.16138E-01   -0.30167E-01   320   0.375E+00    0.152E-01
DAV:   2    -0.390687544846E+02   -0.22165E-03   -0.77780E-03   464   0.512E-01    0.966E-02
DAV:   3    -0.390686154523E+02    0.13903E-03   -0.74348E-04   352   0.162E-01    0.256E-02
DAV:   4    -0.390686180552E+02   -0.26029E-05   -0.96693E-05   456   0.585E-02 
  22 F= -.39068618E+02 E0= -.39073337E+02  d E =-.162228E-01
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.016223  1 .order   -0.016208   -0.018519   -0.013897
 step:   2.2189(harm=  2.2228)  dis= 0.04609  next Energy=   -39.089498 (dE=-0.371E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.390899065959E+02   -0.21291E-01   -0.27067E+00   320   0.112E+01    0.453E-01
DAV:   2    -0.390918962126E+02   -0.19896E-02   -0.69540E-02   456   0.152E+00    0.292E-01
DAV:   3    -0.390906338164E+02    0.12624E-02   -0.66817E-03   344   0.476E-01    0.767E-02
DAV:   4    -0.390906575982E+02   -0.23782E-04   -0.85176E-04   448   0.173E-01    0.488E-02
DAV:   5    -0.390906639985E+02   -0.64003E-05   -0.11181E-04   392   0.528E-02    0.118E-02
DAV:   6    -0.390906640269E+02   -0.28400E-07   -0.82491E-06   384   0.168E-02 
  23 F= -.39090664E+02 E0= -.39095339E+02  d E =-.382688E-01
 curvature:  -2.03 expect dE=-0.114E+00 dE for cont linesearch -0.101E-03
 trial: gam= 1.55355 g(F)=  0.560E-01 g(S)=  0.000E+00 ort = 0.174E-02 (trialstep = 0.259E+00)
 search vector abs. value=  0.208E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391036036365E+02   -0.12940E-01   -0.29794E-01   320   0.361E+00    0.167E-01
DAV:   2    -0.391034541090E+02    0.14953E-03   -0.63800E-03   456   0.489E-01    0.110E-01
DAV:   3    -0.391032208836E+02    0.23323E-03   -0.10076E-03   376   0.197E-01    0.232E-02
DAV:   4    -0.391032281959E+02   -0.73123E-05   -0.18623E-04   400   0.821E-02    0.155E-02
DAV:   5    -0.391032288305E+02   -0.63457E-06   -0.95645E-06   360   0.173E-02 
  24 F= -.39103229E+02 E0= -.39107821E+02  d E =-.125648E-01
 trial-energy change:   -0.012565  1 .order   -0.012572   -0.015226   -0.009919
 step:   0.7442(harm=  0.7442)  dis= 0.03026  next Energy=   -39.112505 (dE=-0.218E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391136678782E+02   -0.10440E-01   -0.10434E+00   320   0.675E+00    0.310E-01
DAV:   2    -0.391132390426E+02    0.42884E-03   -0.22387E-02   456   0.912E-01    0.205E-01
DAV:   3    -0.391124349307E+02    0.80411E-03   -0.35668E-03   360   0.366E-01    0.430E-02
DAV:   4    -0.391124553606E+02   -0.20430E-04   -0.64639E-04   384   0.152E-01    0.288E-02
DAV:   5    -0.391124576026E+02   -0.22420E-05   -0.34094E-05   432   0.322E-02 
  25 F= -.39112458E+02 E0= -.39116781E+02  d E =-.217936E-01
 curvature:  -1.32 expect dE=-0.455E-01 dE for cont linesearch -0.620E-07
 trial: gam= 0.63468 g(F)=  0.344E-01 g(S)=  0.000E+00 ort = 0.989E-04 (trialstep = 0.356E+00)
 search vector abs. value=  0.119E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391238546321E+02   -0.11399E-01   -0.30796E-01   328   0.355E+00    0.190E-01
DAV:   2    -0.391236174452E+02    0.23719E-03   -0.65501E-03   424   0.466E-01    0.118E-01
DAV:   3    -0.391233672766E+02    0.25017E-03   -0.12288E-03   400   0.191E-01    0.262E-02
DAV:   4    -0.391233594473E+02    0.78293E-05   -0.15568E-04   408   0.712E-02    0.168E-02
DAV:   5    -0.391233597524E+02   -0.30512E-06   -0.17730E-05   424   0.217E-02 
  26 F= -.39123360E+02 E0= -.39127765E+02  d E =-.109021E-01
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.010902  1 .order   -0.010928   -0.012293   -0.009563
 step:   1.4255(harm=  1.6049)  dis= 0.04757  next Energy=   -39.140138 (dE=-0.277E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391427085607E+02   -0.19349E-01   -0.27911E+00   328   0.107E+01    0.570E-01
DAV:   2    -0.391411065825E+02    0.16020E-02   -0.61087E-02   392   0.141E+00    0.361E-01
DAV:   3    -0.391388450541E+02    0.22615E-02   -0.10611E-02   400   0.549E-01    0.757E-02
DAV:   4    -0.391387671342E+02    0.77920E-04   -0.13057E-03   392   0.203E-01    0.476E-02
DAV:   5    -0.391387675895E+02   -0.45532E-06   -0.14296E-04   448   0.603E-02    0.999E-03
DAV:   6    -0.391387653777E+02    0.22118E-05   -0.12276E-05   352   0.195E-02 
  27 F= -.39138765E+02 E0= -.39143361E+02  d E =-.263078E-01
 curvature:  -2.70 expect dE=-0.369E-01 dE for cont linesearch -0.513E-04
 trial: gam= 0.11707 g(F)=  0.137E-01 g(S)=  0.000E+00 ort = 0.150E-02 (trialstep = 0.570E+00)
 search vector abs. value=  0.156E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391432425364E+02   -0.44749E-02   -0.14499E-01   368   0.231E+00    0.116E-01
DAV:   2    -0.391432684292E+02   -0.25893E-04   -0.24589E-03   416   0.303E-01    0.749E-02
DAV:   3    -0.391431769454E+02    0.91484E-04   -0.30778E-04   368   0.105E-01    0.940E-03
DAV:   4    -0.391431802731E+02   -0.33278E-05   -0.42478E-05   400   0.395E-02 
  28 F= -.39143180E+02 E0= -.39147858E+02  d E =-.441490E-02
 trial-energy change:   -0.004415  1 .order   -0.004397   -0.007886   -0.000907
 step:   0.6443(harm=  0.6443)  dis= 0.00622  next Energy=   -39.143221 (dE=-0.446E-02)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391432424266E+02   -0.65481E-04   -0.25006E-03   368   0.304E-01    0.152E-02
DAV:   2    -0.391432435141E+02   -0.10876E-05   -0.47709E-05   400   0.423E-02 
  29 F= -.39143244E+02 E0= -.39147927E+02  d E =-.447814E-02
 curvature:  -0.36 expect dE=-0.277E-02 dE for cont linesearch -0.353E-06
 trial: gam= 0.56456 g(F)=  0.760E-02 g(S)=  0.000E+00 ort = 0.123E-03 (trialstep = 0.585E+00)
 search vector abs. value=  0.127E-01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391472363246E+02   -0.39939E-02   -0.66875E-02   320   0.169E+00    0.679E-02
DAV:   2    -0.391473481844E+02   -0.11186E-03   -0.14995E-03   464   0.218E-01    0.472E-02
DAV:   3    -0.391473350891E+02    0.13095E-04   -0.78804E-05   360   0.488E-02    0.127E-02
DAV:   4    -0.391473351169E+02   -0.27794E-07   -0.87485E-06   320   0.176E-02 
  30 F= -.39147335E+02 E0= -.39152005E+02  d E =-.409160E-02
 ZBRENT: can't locate minimum, use default step
 trial-energy change:   -0.004092  1 .order   -0.004081   -0.004488   -0.003675
 step:   2.3401(harm=  3.2314)  dis= 0.02893  next Energy=   -39.155638 (dE=-0.124E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391538152377E+02   -0.64801E-02   -0.59850E-01   320   0.506E+00    0.200E-01
DAV:   2    -0.391548291180E+02   -0.10139E-02   -0.13395E-02   472   0.651E-01    0.140E-01
DAV:   3    -0.391547142685E+02    0.11485E-03   -0.68292E-04   352   0.144E-01    0.380E-02
DAV:   4    -0.391547170980E+02   -0.28295E-05   -0.82360E-05   464   0.523E-02 
  31 F= -.39154717E+02 E0= -.39159333E+02  d E =-.114736E-01
 curvature:  -2.38 expect dE=-0.208E-01 dE for cont linesearch -0.748E-03
 ZBRENT: extrapolating
 opt :   3.1609  next Energy=   -39.155539 (dE=-0.123E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.391553682139E+02   -0.65395E-03   -0.13049E-01   320   0.237E+00    0.929E-02
DAV:   2    -0.391555993262E+02   -0.23111E-03   -0.29660E-03   472   0.306E-01    0.650E-02
DAV:   3    -0.391555765639E+02    0.22762E-04   -0.13873E-04   360   0.656E-02    0.190E-02