Using device 0 (rank 0, local rank 0, local size 4) : Tesla V100-PCIE-16GB
Using device 2 (rank 2, local rank 2, local size 4) : Tesla V100-PCIE-16GB
Using device 1 (rank 1, local rank 1, local size 4) : Tesla V100-PCIE-16GB
Using device 3 (rank 3, local rank 3, local size 4) : Tesla V100-PCIE-16GB
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on    1 cores,    4 groups
  
 *******************************************************************************
  You are running the GPU port of VASP! When publishing results obtained with
  this version, please cite:
   - M. Hacene et al., http://dx.doi.org/10.1002/jcc.23096
   - M. Hutchinson and M. Widom, http://dx.doi.org/10.1016/j.cpc.2012.02.017
  
  in addition to the usual required citations (see manual).
  
  GPU developers: A. Anciaux-Sedrakian, C. Angerer, and M. Hutchinson.
 *******************************************************************************
  
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     Please note that VASP has recently been ported to GPU by means of       |
|     OpenACC. You are running the CUDA-C GPU-port of VASP, which is          |
|     deprecated and no longer actively developed, maintained, or             |
|     supported. In the near future, the CUDA-C GPU-port of VASP will be      |
|     dropped completely. We encourage you to switch to the OpenACC           |
|     GPU-port of VASP as soon as possible.                                   |
|                                                                             |
 -----------------------------------------------------------------------------

 vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 POSCAR found type information on POSCAR SiO C N B H 
 POSCAR found :  6 types and      94 ions
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 NWRITE =            1
 LDA part: xc-table for Pade appr. of Perdew
  
 WARNING: The GPU port of VASP has been extensively
 tested for: ALGO=Normal, Fast, and VeryFast.
 Other algorithms may produce incorrect results or
 yield suboptimal performance. Handle with care!
  
 POSCAR, INCAR and KPOINTS ok, starting setup
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUDA streams...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
creating 32 CUFFT plans with grid size 50 x 50 x 50...
 FFT: planning ...
 WAVECAR not read
 entering main loop
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1     0.197006086557E+04    0.19701E+04   -0.16349E+05  3840   0.117E+03 
DAV:   2    -0.501754971567E+03   -0.24718E+04   -0.23934E+04  4688   0.293E+02 
DAV:   3    -0.701823398955E+03   -0.20007E+03   -0.19865E+03  4520   0.893E+01 
DAV:   4    -0.706000194773E+03   -0.41768E+01   -0.41594E+01  4584   0.135E+01 
DAV:   5    -0.706117812597E+03   -0.11762E+00   -0.11745E+00  4600   0.210E+00    0.643E+01
DAV:   6    -0.626257556487E+03    0.79860E+02   -0.32269E+02  4344   0.326E+01    0.308E+01
DAV:   7    -0.624495453188E+03    0.17621E+01   -0.14434E+01  4768   0.778E+00    0.135E+01
DAV:   8    -0.624013148141E+03    0.48231E+00   -0.21669E+00  4528   0.372E+00    0.548E+00
DAV:   9    -0.623975289478E+03    0.37859E-01   -0.42922E-01  4600   0.166E+00    0.111E+00
DAV:  10    -0.623989852885E+03   -0.14563E-01   -0.62204E-02  4456   0.648E-01    0.657E-01
DAV:  11    -0.623996347854E+03   -0.64950E-02   -0.17614E-02  4432   0.363E-01    0.328E-01
DAV:  12    -0.623999288736E+03   -0.29409E-02   -0.46276E-03  4360   0.192E-01    0.138E-01
DAV:  13    -0.624000121869E+03   -0.83313E-03   -0.15643E-03  4672   0.125E-01    0.473E-02
DAV:  14    -0.624000237372E+03   -0.11550E-03   -0.43115E-04  4512   0.534E-02    0.319E-02
DAV:  15    -0.624000258117E+03   -0.20745E-04   -0.66256E-05  4248   0.242E-02    0.141E-02
DAV:  16    -0.624000264018E+03   -0.59005E-05   -0.23008E-05  3008   0.153E-02 
   1 F= -.62400026E+03 E0= -.62398266E+03  d E =-.624000E+03
 curvature:   0.00 expect dE= 0.000E+00 dE for cont linesearch  0.000E+00
 trial: gam= 0.00000 g(F)=  0.264E+02 g(S)=  0.000E+00 ort = 0.000E+00 (trialstep = 0.100E+01)
 search vector abs. value=  0.264E+02
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.607917720998E+03    0.16083E+02   -0.20039E+03  4000   0.864E+01    0.226E+01
DAV:   2    -0.622803543502E+03   -0.14886E+02   -0.16567E+02  4368   0.201E+01    0.115E+01
DAV:   3    -0.620504398085E+03    0.22991E+01   -0.77787E+00  4672   0.825E+00    0.706E+00
DAV:   4    -0.620151195147E+03    0.35320E+00   -0.63482E+00  4352   0.567E+00    0.391E+00
DAV:   5    -0.620087953133E+03    0.63242E-01   -0.95340E-01  4720   0.220E+00    0.247E+00
DAV:   6    -0.620011530223E+03    0.76423E-01   -0.23980E-01  4432   0.164E+00    0.795E-01
DAV:   7    -0.620011572961E+03   -0.42738E-04   -0.15593E-01  4496   0.863E-01    0.429E-01
DAV:   8    -0.620009354100E+03    0.22189E-02   -0.23811E-02  4496   0.362E-01    0.244E-01
DAV:   9    -0.620007101645E+03    0.22525E-02   -0.66200E-03  4560   0.255E-01    0.115E-01
DAV:  10    -0.620007118190E+03   -0.16544E-04   -0.32024E-03  4672   0.183E-01    0.109E-01
DAV:  11    -0.620006949140E+03    0.16905E-03   -0.12889E-03  4472   0.808E-02    0.875E-02
DAV:  12    -0.620006928348E+03    0.20792E-04   -0.19983E-04  4464   0.338E-02    0.532E-02
DAV:  13    -0.620006890771E+03    0.37577E-04   -0.18011E-04  4544   0.390E-02    0.265E-02
DAV:  14    -0.620006886366E+03    0.44044E-05   -0.76046E-05  4432   0.245E-02 
   2 F= -.62000689E+03 E0= -.61999582E+03  d E =0.399338E+01
 trial-energy change:    3.993378  1 .order   -6.582865  -26.376880   13.211150
 step:   0.6663(harm=  0.6663)  dis= 0.51785  next Energy=  -632.787513 (dE=-0.879E+01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.622931450741E+03   -0.29246E+01   -0.30168E+02  3840   0.291E+01    0.598E+00
DAV:   2    -0.624109040522E+03   -0.11776E+01   -0.16624E+01  4528   0.607E+00    0.425E+00
DAV:   3    -0.623921971032E+03    0.18707E+00   -0.65760E-01  4504   0.185E+00    0.276E+00
DAV:   4    -0.623865612230E+03    0.56359E-01   -0.39293E-01  4288   0.121E+00    0.129E+00
DAV:   5    -0.623854078233E+03    0.11534E-01   -0.39686E-02  4888   0.731E-01    0.601E-01
DAV:   6    -0.623852798867E+03    0.12794E-02   -0.21788E-02  4464   0.366E-01    0.229E-01
DAV:   7    -0.623852549805E+03    0.24906E-03   -0.46181E-03  4424   0.162E-01    0.126E-01
DAV:   8    -0.623852506282E+03    0.43523E-04   -0.78778E-04  4520   0.634E-02    0.520E-02
DAV:   9    -0.623852498382E+03    0.78994E-05   -0.93854E-05  4528   0.361E-02 
   3 F= -.62385250E+03 E0= -.62384202E+03  d E =0.147766E+00
 curvature:  -0.33 expect dE=-0.369E+01 dE for cont linesearch -0.119E+01
 ZBRENT: interpolating
 opt :   0.4871  next Energy=  -624.722315 (dE=-0.722E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.625195440888E+03   -0.13429E+01   -0.91519E+01  3840   0.178E+01    0.316E+00
DAV:   2    -0.625424263327E+03   -0.22882E+00   -0.35236E+00  4488   0.325E+00    0.183E+00
DAV:   3    -0.625392142488E+03    0.32121E-01   -0.12898E-01  4528   0.858E-01    0.123E+00
DAV:   4    -0.625374328836E+03    0.17814E-01   -0.12918E-01  4368   0.814E-01    0.471E-01
DAV:   5    -0.625370835188E+03    0.34936E-02   -0.18838E-02  5136   0.434E-01    0.257E-01
DAV:   6    -0.625370785793E+03    0.49395E-04   -0.99314E-03  4400   0.257E-01    0.159E-01
DAV:   7    -0.625370666939E+03    0.11885E-03   -0.80738E-04  4528   0.863E-02    0.813E-02
DAV:   8    -0.625370619012E+03    0.47927E-04   -0.42763E-04  4560   0.607E-02    0.373E-02
DAV:   9    -0.625370604103E+03    0.14909E-04   -0.83214E-05  4704   0.335E-02    0.188E-02
DAV:  10    -0.625370604693E+03   -0.58988E-06   -0.64151E-05  4432   0.203E-02 
   4 F= -.62537060E+03 E0= -.62536048E+03  d E =-.137034E+01
 curvature:  -0.24 expect dE=-0.149E+01 dE for cont linesearch -0.464E+00
 ZBRENT: bisectioning
 opt :   0.2435  next Energy=  -626.664120 (dE=-0.266E+01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.625933621364E+03   -0.56302E+00   -0.17534E+02  3840   0.263E+01    0.577E+00
DAV:   2    -0.626519146940E+03   -0.58553E+00   -0.79220E+00  4504   0.510E+00    0.277E+00
DAV:   3    -0.626444102634E+03    0.75044E-01   -0.24491E-01  4600   0.125E+00    0.196E+00
DAV:   4    -0.626403100716E+03    0.41002E-01   -0.24965E-01  4416   0.117E+00    0.762E-01
DAV:   5    -0.626394703947E+03    0.83968E-02   -0.28530E-02  5256   0.612E-01    0.393E-01
DAV:   6    -0.626393797603E+03    0.90634E-03   -0.21135E-02  5264   0.435E-01    0.164E-01
DAV:   7    -0.626393790783E+03    0.68205E-05   -0.45761E-03  4696   0.176E-01    0.137E-01
DAV:   8    -0.626393616331E+03    0.17445E-03   -0.10959E-03  4488   0.858E-02    0.621E-02
DAV:   9    -0.626393554528E+03    0.61804E-04   -0.16746E-04  4640   0.505E-02    0.271E-02
DAV:  10    -0.626393529300E+03    0.25227E-04   -0.14734E-04  4960   0.393E-02    0.156E-02
DAV:  11    -0.626393509738E+03    0.19562E-04   -0.49752E-05  4240   0.224E-02    0.135E-02
DAV:  12    -0.626393493799E+03    0.15939E-04   -0.18575E-05  3040   0.143E-02    0.123E-02
DAV:  13    -0.626393508141E+03   -0.14342E-04   -0.13174E-05  2960   0.109E-02    0.146E-02
DAV:  14    -0.626393519185E+03   -0.11044E-04   -0.97930E-06  2984   0.108E-02    0.146E-02
DAV:  15    -0.626393600345E+03   -0.81160E-04   -0.45879E-04  4912   0.809E-02    0.145E-02
DAV:  16    -0.626393637575E+03   -0.37230E-04   -0.20802E-04  4488   0.286E-02    0.259E-02
DAV:  17    -0.626393621191E+03    0.16384E-04   -0.31120E-05  3240   0.135E-02    0.328E-02
DAV:  18    -0.626393476723E+03    0.14447E-03   -0.68220E-04  4752   0.956E-02    0.346E-02
DAV:  19    -0.626393367849E+03    0.10887E-03   -0.61951E-04  4552   0.733E-02    0.406E-02
DAV:  20    -0.626393302097E+03    0.65752E-04   -0.23983E-04  4568   0.436E-02    0.345E-02
DAV:  21    -0.626393393107E+03   -0.91010E-04   -0.17502E-04  4456   0.390E-02    0.248E-02
DAV:  22    -0.626393476947E+03   -0.83840E-04   -0.26083E-04  4552   0.509E-02    0.201E-02
DAV:  23    -0.626393555556E+03   -0.78609E-04   -0.44867E-04  4448   0.683E-02    0.236E-02
DAV:  24    -0.626393719711E+03   -0.16415E-03   -0.79197E-04  4624   0.909E-02    0.381E-02
DAV:  25    -0.626393704009E+03    0.15702E-04   -0.24683E-04  4312   0.321E-02    0.245E-02
DAV:  26    -0.626393655918E+03    0.48092E-04   -0.34203E-05  3104   0.191E-02    0.192E-02
DAV:  27    -0.626393615839E+03    0.40079E-04   -0.58202E-05  3496   0.225E-02    0.152E-02
DAV:  28    -0.626393595923E+03    0.19916E-04   -0.41401E-05  4056   0.190E-02    0.135E-02
DAV:  29    -0.626393589421E+03    0.65017E-05   -0.10757E-05  2472   0.944E-03 
   5 F= -.62639359E+03 E0= -.62638319E+03  d E =-.239333E+01
 curvature:  -0.68 expect dE=-0.186E+01 dE for cont linesearch -0.107E-02
 trial: gam= 0.11133 g(F)=  0.273E+01 g(S)=  0.000E+00 ort =-0.204E+00 (trialstep = 0.849E+00)
 search vector abs. value=  0.301E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.626101662064E+03    0.29193E+00   -0.21708E+02  3840   0.334E+01    0.554E+00
DAV:   2    -0.626623857430E+03   -0.52220E+00   -0.77485E+00  4536   0.556E+00    0.300E+00
DAV:   3    -0.626478471280E+03    0.14539E+00   -0.32333E-01  4592   0.162E+00    0.176E+00
DAV:   4    -0.626436031677E+03    0.42440E-01   -0.30376E-01  4440   0.148E+00    0.672E-01
DAV:   5    -0.626432122221E+03    0.39095E-02   -0.58293E-02  5032   0.696E-01    0.498E-01
DAV:   6    -0.626431605745E+03    0.51648E-03   -0.18549E-02  4432   0.345E-01    0.253E-01
DAV:   7    -0.626431092415E+03    0.51333E-03   -0.16873E-03  4816   0.136E-01    0.166E-01
DAV:   8    -0.626430878103E+03    0.21431E-03   -0.14951E-03  4528   0.117E-01    0.761E-02
DAV:   9    -0.626430799044E+03    0.79059E-04   -0.32410E-04  5192   0.610E-02    0.394E-02
DAV:  10    -0.626430787742E+03    0.11302E-04   -0.21618E-04  4592   0.390E-02    0.199E-02
DAV:  11    -0.626430783309E+03    0.44331E-05   -0.20251E-05  3488   0.184E-02 
   6 F= -.62643078E+03 E0= -.62641243E+03  d E =-.371939E-01
 trial-energy change:   -0.037194  1 .order   -0.153016   -2.300231    1.994198
 step:   0.4203(harm=  0.4546)  dis= 0.05782  next Energy=  -626.949040 (dE=-0.555E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.626861177557E+03   -0.43039E+00   -0.55243E+01  3840   0.166E+01    0.282E+00
DAV:   2    -0.626983367626E+03   -0.12219E+00   -0.19077E+00  4528   0.282E+00    0.148E+00
DAV:   3    -0.626950406429E+03    0.32961E-01   -0.76280E-02  4600   0.814E-01    0.922E-01
DAV:   4    -0.626940081077E+03    0.10325E-01   -0.76602E-02  4440   0.715E-01    0.366E-01
DAV:   5    -0.626938803924E+03    0.12772E-02   -0.13205E-02  5168   0.352E-01    0.242E-01
DAV:   6    -0.626938863004E+03   -0.59079E-04   -0.53987E-03  4424   0.194E-01    0.126E-01
DAV:   7    -0.626938721612E+03    0.14139E-03   -0.65231E-04  4864   0.785E-02    0.837E-02
DAV:   8    -0.626938679574E+03    0.42037E-04   -0.43094E-04  4504   0.534E-02    0.368E-02
DAV:   9    -0.626938661959E+03    0.17615E-04   -0.42135E-05  4208   0.263E-02    0.170E-02
DAV:  10    -0.626938659852E+03    0.21068E-05   -0.49538E-05  4400   0.199E-02 
   7 F= -.62693866E+03 E0= -.62692041E+03  d E =-.545070E+00
 curvature:  -0.25 expect dE=-0.223E+00 dE for cont linesearch -0.477E-05
 trial: gam= 0.25718 g(F)=  0.887E+00 g(S)=  0.000E+00 ort = 0.757E-02 (trialstep = 0.763E+00)
 search vector abs. value=  0.109E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627141456635E+03   -0.20279E+00   -0.92545E+01  3840   0.219E+01    0.316E+00
DAV:   2    -0.627324804481E+03   -0.18335E+00   -0.22788E+00  4496   0.307E+00    0.123E+00
DAV:   3    -0.627297797466E+03    0.27007E-01   -0.54792E-02  4608   0.647E-01    0.703E-01
DAV:   4    -0.627289806229E+03    0.79912E-02   -0.45030E-02  4464   0.562E-01    0.215E-01
DAV:   5    -0.627290074578E+03   -0.26835E-03   -0.94851E-03  4544   0.262E-01    0.172E-01
DAV:   6    -0.627290140404E+03   -0.65826E-04   -0.21179E-03  4488   0.114E-01    0.906E-02
DAV:   7    -0.627290076820E+03    0.63583E-04   -0.23026E-04  4504   0.458E-02    0.624E-02
DAV:   8    -0.627290059803E+03    0.17017E-04   -0.16205E-04  4608   0.383E-02    0.250E-02
DAV:   9    -0.627290052324E+03    0.74789E-05   -0.38380E-05  4040   0.219E-02 
   8 F= -.62729005E+03 E0= -.62727199E+03  d E =-.351392E+00
 trial-energy change:   -0.351392  1 .order   -0.344677   -0.678584   -0.010771
 step:   0.7746(harm=  0.7753)  dis= 0.04578  next Energy=  -627.290134 (dE=-0.351E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627290096789E+03   -0.36986E-04   -0.21497E-02  3976   0.337E-01    0.479E-02
DAV:   2    -0.627290138569E+03   -0.41779E-04   -0.54222E-04  4496   0.479E-02    0.200E-02
DAV:   3    -0.627290130510E+03    0.80585E-05   -0.11579E-05  3024   0.110E-02 
   9 F= -.62729013E+03 E0= -.62727208E+03  d E =-.351471E+00
 curvature:  -0.47 expect dE=-0.371E+00 dE for cont linesearch -0.143E-06
 trial: gam= 0.89732 g(F)=  0.783E+00 g(S)=  0.000E+00 ort = 0.574E-03 (trialstep = 0.502E+00)
 search vector abs. value=  0.166E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627488820393E+03   -0.19868E+00   -0.53280E+01  3840   0.167E+01    0.182E+00
DAV:   2    -0.627585997989E+03   -0.97178E-01   -0.11831E+00  4488   0.221E+00    0.916E-01
DAV:   3    -0.627574294990E+03    0.11703E-01   -0.26222E-02  4608   0.471E-01    0.565E-01
DAV:   4    -0.627569959334E+03    0.43357E-02   -0.25568E-02  4472   0.463E-01    0.179E-01
DAV:   5    -0.627570064120E+03   -0.10479E-03   -0.57141E-03  4488   0.199E-01    0.136E-01
DAV:   6    -0.627570056521E+03    0.75988E-05   -0.20901E-03  4488   0.117E-01    0.667E-02
DAV:   7    -0.627570027317E+03    0.29204E-04   -0.20246E-04  4664   0.439E-02    0.432E-02
DAV:   8    -0.627570017443E+03    0.98742E-05   -0.10554E-04  4576   0.293E-02    0.177E-02
DAV:   9    -0.627570014104E+03    0.33391E-05   -0.14023E-05  3048   0.142E-02 
  10 F= -.62757001E+03 E0= -.62755165E+03  d E =-.279884E+00
 trial-energy change:   -0.279884  1 .order   -0.279517   -0.393404   -0.165629
 step:   0.8675(harm=  0.8675)  dis= 0.06903  next Energy=  -627.629867 (dE=-0.340E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627586154574E+03   -0.16137E-01   -0.28245E+01  3840   0.122E+01    0.133E+00
DAV:   2    -0.627637246743E+03   -0.51092E-01   -0.62650E-01  4480   0.161E+00    0.662E-01
DAV:   3    -0.627630926439E+03    0.63203E-02   -0.13680E-02  4608   0.340E-01    0.407E-01
DAV:   4    -0.627628605857E+03    0.23206E-02   -0.13909E-02  4480   0.340E-01    0.128E-01
DAV:   5    -0.627628669972E+03   -0.64115E-04   -0.31479E-03  4480   0.146E-01    0.101E-01
DAV:   6    -0.627628660520E+03    0.94517E-05   -0.11382E-03  4496   0.867E-02    0.489E-02
DAV:   7    -0.627628645543E+03    0.14978E-04   -0.10844E-04  4504   0.318E-02    0.317E-02
DAV:   8    -0.627628639690E+03    0.58529E-05   -0.55333E-05  4472   0.215E-02 
  11 F= -.62762864E+03 E0= -.62761026E+03  d E =-.338509E+00
 curvature:  -0.92 expect dE=-0.821E+00 dE for cont linesearch -0.379E-04
 trial: gam= 1.15332 g(F)=  0.892E+00 g(S)=  0.000E+00 ort =-0.827E-02 (trialstep = 0.310E+00)
 search vector abs. value=  0.308E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627791266986E+03   -0.16262E+00   -0.33277E+01  3840   0.132E+01    0.150E+00
DAV:   2    -0.627852854463E+03   -0.61587E-01   -0.75484E-01  4472   0.178E+00    0.719E-01
DAV:   3    -0.627846099666E+03    0.67548E-02   -0.16733E-02  4600   0.354E-01    0.450E-01
DAV:   4    -0.627843955731E+03    0.21439E-02   -0.13778E-02  4448   0.327E-01    0.143E-01
DAV:   5    -0.627844069044E+03   -0.11331E-03   -0.29279E-03  4440   0.138E-01    0.956E-02
DAV:   6    -0.627844109207E+03   -0.40163E-04   -0.10069E-03  4472   0.802E-02    0.462E-02
DAV:   7    -0.627844089916E+03    0.19291E-04   -0.11911E-04  4408   0.304E-02    0.301E-02
DAV:   8    -0.627844090321E+03   -0.40511E-06   -0.52519E-05  4368   0.175E-02 
  12 F= -.62784409E+03 E0= -.62782571E+03  d E =-.215451E+00
 trial-energy change:   -0.215451  1 .order   -0.215773   -0.273539   -0.158008
 step:   0.7342(harm=  0.7342)  dis= 0.09381  next Energy=  -627.952465 (dE=-0.324E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.627853920794E+03   -0.98309E-02   -0.62290E+01  3840   0.181E+01    0.208E+00
DAV:   2    -0.627970079187E+03   -0.11616E+00   -0.14231E+00  4440   0.246E+00    0.983E-01
DAV:   3    -0.627957368806E+03    0.12710E-01   -0.31942E-02  4600   0.491E-01    0.619E-01
DAV:   4    -0.627953280722E+03    0.40881E-02   -0.25545E-02  4448   0.448E-01    0.198E-01
DAV:   5    -0.627953499860E+03   -0.21914E-03   -0.54426E-03  4424   0.188E-01    0.133E-01
DAV:   6    -0.627953570798E+03   -0.70938E-04   -0.18334E-03  4496   0.108E-01    0.640E-02
DAV:   7    -0.627953537912E+03    0.32887E-04   -0.21418E-04  4368   0.405E-02    0.417E-02
DAV:   8    -0.627953538215E+03   -0.30372E-06   -0.90989E-05  4544   0.232E-02 
  13 F= -.62795354E+03 E0= -.62793516E+03  d E =-.324899E+00
 curvature:  -1.28 expect dE=-0.129E+01 dE for cont linesearch -0.323E-04
 trial: gam= 1.04382 g(F)=  0.100E+01 g(S)=  0.000E+00 ort = 0.881E-02 (trialstep = 0.278E+00)
 search vector abs. value=  0.438E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628136785002E+03   -0.18325E+00   -0.33033E+01  3840   0.132E+01    0.136E+00
DAV:   2    -0.628197949674E+03   -0.61165E-01   -0.73627E-01  4368   0.176E+00    0.734E-01
DAV:   3    -0.628191804731E+03    0.61449E-02   -0.15037E-02  4576   0.329E-01    0.462E-01
DAV:   4    -0.628189744036E+03    0.20607E-02   -0.14203E-02  4408   0.335E-01    0.143E-01
DAV:   5    -0.628189808057E+03   -0.64022E-04   -0.31764E-03  4592   0.147E-01    0.104E-01
DAV:   6    -0.628189811918E+03   -0.38605E-05   -0.11286E-03  4480   0.867E-02    0.486E-02
DAV:   7    -0.628189798424E+03    0.13494E-04   -0.11495E-04  4560   0.302E-02    0.277E-02
DAV:   8    -0.628189795945E+03    0.24784E-05   -0.39857E-05  4312   0.174E-02 
  14 F= -.62818980E+03 E0= -.62817145E+03  d E =-.236258E+00
 trial-energy change:   -0.236258  1 .order   -0.235628   -0.281614   -0.189642
 step:   0.7909(harm=  0.8509)  dis= 0.14637  next Energy=  -628.368805 (dE=-0.415E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628178748520E+03    0.11050E-01   -0.11298E+02  3840   0.243E+01    0.279E+00
DAV:   2    -0.628393955043E+03   -0.21521E+00   -0.26075E+00  4448   0.331E+00    0.139E+00
DAV:   3    -0.628371788688E+03    0.22166E-01   -0.56590E-02  4592   0.619E-01    0.904E-01
DAV:   4    -0.628364059055E+03    0.77296E-02   -0.44173E-02  4416   0.586E-01    0.277E-01
DAV:   5    -0.628364360348E+03   -0.30129E-03   -0.99089E-03  4616   0.261E-01    0.184E-01
DAV:   6    -0.628364411943E+03   -0.51595E-04   -0.33361E-03  4496   0.150E-01    0.894E-02
DAV:   7    -0.628364371490E+03    0.40453E-04   -0.37012E-04  4928   0.571E-02    0.496E-02
DAV:   8    -0.628364365374E+03    0.61167E-05   -0.11002E-04  4496   0.290E-02    0.207E-02
DAV:   9    -0.628364359497E+03    0.58765E-05   -0.24018E-05  3432   0.198E-02 
  15 F= -.62836436E+03 E0= -.62834605E+03  d E =-.410821E+00
 curvature:  -1.82 expect dE=-0.147E+01 dE for cont linesearch -0.396E-03
 trial: gam= 0.65418 g(F)=  0.808E+00 g(S)=  0.000E+00 ort =-0.309E-01 (trialstep = 0.380E+00)
 search vector abs. value=  0.264E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628521218201E+03   -0.15685E+00   -0.40499E+01  3840   0.146E+01    0.165E+00
DAV:   2    -0.628592938580E+03   -0.71720E-01   -0.90574E-01  4496   0.197E+00    0.779E-01
DAV:   3    -0.628583436312E+03    0.95023E-02   -0.20600E-02  4600   0.384E-01    0.465E-01
DAV:   4    -0.628580000476E+03    0.34358E-02   -0.16064E-02  4504   0.387E-01    0.129E-01
DAV:   5    -0.628580221019E+03   -0.22054E-03   -0.47120E-03  4544   0.171E-01    0.121E-01
DAV:   6    -0.628580164180E+03    0.56838E-04   -0.83812E-04  4504   0.717E-02    0.691E-02
DAV:   7    -0.628580121364E+03    0.42816E-04   -0.74520E-05  4536   0.292E-02    0.383E-02
DAV:   8    -0.628580099519E+03    0.21845E-04   -0.52913E-05  4504   0.301E-02    0.119E-02
DAV:   9    -0.628580097787E+03    0.17319E-05   -0.29852E-05  3544   0.182E-02 
  16 F= -.62858010E+03 E0= -.62856181E+03  d E =-.215738E+00
 trial-energy change:   -0.215738  1 .order   -0.215540   -0.299756   -0.131324
 step:   0.6771(harm=  0.6771)  dis= 0.11523  next Energy=  -628.631094 (dE=-0.267E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628594577330E+03   -0.14478E-01   -0.24737E+01  3840   0.114E+01    0.128E+00
DAV:   2    -0.628637425010E+03   -0.42848E-01   -0.54921E-01  4536   0.153E+00    0.608E-01
DAV:   3    -0.628631481718E+03    0.59433E-02   -0.12748E-02  4600   0.301E-01    0.359E-01
DAV:   4    -0.628629389826E+03    0.20919E-02   -0.98242E-03  4528   0.302E-01    0.993E-02
DAV:   5    -0.628629530361E+03   -0.14053E-03   -0.29002E-03  4520   0.133E-01    0.943E-02
DAV:   6    -0.628629494900E+03    0.35461E-04   -0.49285E-04  4504   0.549E-02    0.541E-02
DAV:   7    -0.628629467388E+03    0.27512E-04   -0.45235E-05  4408   0.229E-02    0.300E-02
DAV:   8    -0.628629453775E+03    0.13613E-04   -0.32563E-05  3864   0.241E-02    0.903E-03
DAV:   9    -0.628629452827E+03    0.94803E-06   -0.18354E-05  2984   0.144E-02 
  17 F= -.62862945E+03 E0= -.62861119E+03  d E =-.265093E+00
 curvature:  -1.14 expect dE=-0.688E+00 dE for cont linesearch -0.665E-04
 trial: gam= 0.57307 g(F)=  0.605E+00 g(S)=  0.000E+00 ort =-0.124E-01 (trialstep = 0.440E+00)
 search vector abs. value=  0.146E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628766852618E+03   -0.13740E+00   -0.30340E+01  3840   0.129E+01    0.159E+00
DAV:   2    -0.628823921037E+03   -0.57068E-01   -0.73359E-01  4480   0.181E+00    0.716E-01
DAV:   3    -0.628815797413E+03    0.81236E-02   -0.18347E-02  4608   0.364E-01    0.428E-01
DAV:   4    -0.628812744100E+03    0.30533E-02   -0.15943E-02  4528   0.346E-01    0.135E-01
DAV:   5    -0.628812726732E+03    0.17368E-04   -0.33720E-03  4512   0.162E-01    0.107E-01
DAV:   6    -0.628812701583E+03    0.25148E-04   -0.12242E-03  4488   0.952E-02    0.542E-02
DAV:   7    -0.628812676558E+03    0.25025E-04   -0.12644E-04  4536   0.344E-02    0.351E-02
DAV:   8    -0.628812661604E+03    0.14954E-04   -0.62224E-05  4528   0.257E-02    0.130E-02
DAV:   9    -0.628812658914E+03    0.26899E-05   -0.13614E-05  2976   0.143E-02 
  18 F= -.62881266E+03 E0= -.62879438E+03  d E =-.183206E+00
 trial-energy change:   -0.183206  1 .order   -0.183122   -0.263142   -0.103102
 step:   0.7231(harm=  0.7231)  dis= 0.08156  next Energy=  -628.845785 (dE=-0.216E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628826094357E+03   -0.13433E-01   -0.12629E+01  3840   0.832E+00    0.102E+00
DAV:   2    -0.628849823390E+03   -0.23729E-01   -0.30588E-01  4480   0.117E+00    0.465E-01
DAV:   3    -0.628846368221E+03    0.34552E-02   -0.76035E-03  4608   0.235E-01    0.277E-01
DAV:   4    -0.628845071644E+03    0.12966E-02   -0.68611E-03  4520   0.227E-01    0.877E-02
DAV:   5    -0.628845064160E+03    0.74846E-05   -0.14536E-03  4528   0.106E-01    0.706E-02
DAV:   6    -0.628845051890E+03    0.12270E-04   -0.53050E-04  4496   0.628E-02    0.354E-02
DAV:   7    -0.628845040903E+03    0.10987E-04   -0.55865E-05  4472   0.227E-02    0.233E-02
DAV:   8    -0.628845033886E+03    0.70171E-05   -0.24684E-05  3448   0.171E-02 
  19 F= -.62884503E+03 E0= -.62882675E+03  d E =-.215581E+00
 curvature:  -0.88 expect dE=-0.410E+00 dE for cont linesearch -0.260E-04
 trial: gam= 0.76422 g(F)=  0.465E+00 g(S)=  0.000E+00 ort =-0.656E-02 (trialstep = 0.496E+00)
 search vector abs. value=  0.131E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.628962210634E+03   -0.11717E+00   -0.28936E+01  3840   0.126E+01    0.127E+00
DAV:   2    -0.629011946742E+03   -0.49736E-01   -0.62340E-01  4496   0.167E+00    0.657E-01
DAV:   3    -0.629006937826E+03    0.50089E-02   -0.15262E-02  4608   0.315E-01    0.406E-01
DAV:   4    -0.629005021496E+03    0.19163E-02   -0.11756E-02  4504   0.315E-01    0.123E-01
DAV:   5    -0.629005118874E+03   -0.97378E-04   -0.27928E-03  4528   0.135E-01    0.100E-01
DAV:   6    -0.629005084011E+03    0.34863E-04   -0.94659E-04  4520   0.801E-02    0.501E-02
DAV:   7    -0.629005069597E+03    0.14414E-04   -0.98399E-05  4424   0.273E-02    0.258E-02
DAV:   8    -0.629005067267E+03    0.23293E-05   -0.30316E-05  3712   0.169E-02 
  20 F= -.62900507E+03 E0= -.62898676E+03  d E =-.160033E+00
 trial-energy change:   -0.160033  1 .order   -0.159917   -0.228209   -0.091626
 step:   0.8295(harm=  0.8295)  dis= 0.07670  next Energy=  -629.035685 (dE=-0.191E+00)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629015564485E+03   -0.10495E-01   -0.13048E+01  3840   0.847E+00    0.847E-01
DAV:   2    -0.629037893802E+03   -0.22329E-01   -0.27997E-01  4504   0.112E+00    0.439E-01
DAV:   3    -0.629035638425E+03    0.22554E-02   -0.68458E-03  4608   0.211E-01    0.271E-01
DAV:   4    -0.629034767373E+03    0.87105E-03   -0.52239E-03  4488   0.211E-01    0.813E-02
DAV:   5    -0.629034816530E+03   -0.49157E-04   -0.12747E-03  4528   0.913E-02    0.667E-02
DAV:   6    -0.629034800939E+03    0.15590E-04   -0.41396E-04  4536   0.529E-02    0.340E-02
DAV:   7    -0.629034793716E+03    0.72231E-05   -0.41775E-05  3824   0.181E-02 
  21 F= -.62903479E+03 E0= -.62901648E+03  d E =-.189760E+00
 curvature:  -1.18 expect dE=-0.444E+00 dE for cont linesearch -0.415E-04
 trial: gam= 0.81147 g(F)=  0.377E+00 g(S)=  0.000E+00 ort =-0.678E-02 (trialstep = 0.563E+00)
 search vector abs. value=  0.123E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629072423386E+03   -0.37622E-01   -0.35345E+01  3840   0.140E+01    0.151E+00
DAV:   2    -0.629140492292E+03   -0.68069E-01   -0.84095E-01  4504   0.195E+00    0.779E-01
DAV:   3    -0.629133546272E+03    0.69460E-02   -0.20457E-02  4624   0.374E-01    0.484E-01
DAV:   4    -0.629131156251E+03    0.23900E-02   -0.20631E-02  4464   0.392E-01    0.167E-01
DAV:   5    -0.629131050222E+03    0.10603E-03   -0.37945E-03  4592   0.169E-01    0.126E-01
DAV:   6    -0.629131013235E+03    0.36988E-04   -0.19597E-03  4520   0.116E-01    0.538E-02
DAV:   7    -0.629130999563E+03    0.13671E-04   -0.21732E-04  4464   0.375E-02    0.337E-02
DAV:   8    -0.629130996925E+03    0.26387E-05   -0.67376E-05  4520   0.212E-02 
  22 F= -.62913100E+03 E0= -.62911268E+03  d E =-.962032E-01
 trial-energy change:   -0.096203  1 .order   -0.097569   -0.209058    0.013919
 step:   0.5267(harm=  0.5279)  dis= 0.04797  next Energy=  -629.131447 (dE=-0.967E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629131235955E+03   -0.23639E-03   -0.14797E-01  3968   0.903E-01    0.966E-02
DAV:   2    -0.629131513428E+03   -0.27747E-03   -0.33954E-03  4504   0.124E-01    0.508E-02
DAV:   3    -0.629131484244E+03    0.29184E-04   -0.79586E-05  4624   0.234E-02    0.314E-02
DAV:   4    -0.629131474436E+03    0.98080E-05   -0.80098E-05  4448   0.242E-02 
  23 F= -.62913147E+03 E0= -.62911316E+03  d E =-.966807E-01
 curvature:  -0.87 expect dE=-0.156E+00 dE for cont linesearch -0.188E-05
 trial: gam= 0.45369 g(F)=  0.179E+00 g(S)=  0.000E+00 ort = 0.163E-02 (trialstep = 0.556E+00)
 search vector abs. value=  0.433E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629172851874E+03   -0.41368E-01   -0.15649E+01  3840   0.924E+00    0.105E+00
DAV:   2    -0.629202398827E+03   -0.29547E-01   -0.35718E-01  4480   0.126E+00    0.465E-01
DAV:   3    -0.629199183585E+03    0.32152E-02   -0.83847E-03  4544   0.247E-01    0.278E-01
DAV:   4    -0.629198019460E+03    0.11641E-02   -0.63403E-03  4480   0.227E-01    0.869E-02
DAV:   5    -0.629198066835E+03   -0.47375E-04   -0.14878E-03  4568   0.992E-02    0.727E-02
DAV:   6    -0.629198058594E+03    0.82405E-05   -0.44744E-04  4472   0.531E-02    0.364E-02
DAV:   7    -0.629198047479E+03    0.11115E-04   -0.42081E-05  4008   0.203E-02    0.221E-02
DAV:   8    -0.629198043866E+03    0.36125E-05   -0.27713E-05  3872   0.168E-02 
  24 F= -.62919804E+03 E0= -.62917972E+03  d E =-.665694E-01
 trial-energy change:   -0.066569  1 .order   -0.066833   -0.099931   -0.033734
 step:   0.8498(harm=  0.8390)  dis= 0.04200  next Energy=  -629.206926 (dE=-0.755E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629199599019E+03   -0.15515E-02   -0.43812E+00  3840   0.489E+00    0.553E-01
DAV:   2    -0.629207838272E+03   -0.82393E-02   -0.99888E-02  4480   0.668E-01    0.245E-01
DAV:   3    -0.629206941031E+03    0.89724E-03   -0.23481E-03  4544   0.131E-01    0.148E-01
DAV:   4    -0.629206612174E+03    0.32886E-03   -0.17946E-03  4480   0.122E-01    0.466E-02
DAV:   5    -0.629206625514E+03   -0.13340E-04   -0.42928E-04  4560   0.533E-02    0.393E-02
DAV:   6    -0.629206622207E+03    0.33065E-05   -0.13154E-04  4376   0.289E-02    0.196E-02
DAV:   7    -0.629206618773E+03    0.34348E-05   -0.11270E-05  2736   0.111E-02 
  25 F= -.62920662E+03 E0= -.62918829E+03  d E =-.751443E-01
 curvature:  -1.01 expect dE=-0.214E+00 dE for cont linesearch -0.138E-04
 trial: gam= 1.20121 g(F)=  0.212E+00 g(S)=  0.000E+00 ort =-0.244E-02 (trialstep = 0.320E+00)
 search vector abs. value=  0.831E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629245821525E+03   -0.39199E-01   -0.97119E+00  3840   0.725E+00    0.711E-01
DAV:   2    -0.629263541028E+03   -0.17720E-01   -0.21040E-01  4480   0.961E-01    0.343E-01
DAV:   3    -0.629261948500E+03    0.15925E-02   -0.41612E-03  4608   0.165E-01    0.212E-01
DAV:   4    -0.629261280413E+03    0.66809E-03   -0.36263E-03  4480   0.171E-01    0.615E-02
DAV:   5    -0.629261317717E+03   -0.37304E-04   -0.87264E-04  4496   0.729E-02    0.536E-02
DAV:   6    -0.629261307482E+03    0.10236E-04   -0.24495E-04  4432   0.398E-02    0.263E-02
DAV:   7    -0.629261302453E+03    0.50283E-05   -0.24513E-05  3168   0.141E-02 
  26 F= -.62926130E+03 E0= -.62924296E+03  d E =-.546837E-01
 trial-energy change:   -0.054684  1 .order   -0.054516   -0.067059   -0.041972
 step:   0.8064(harm=  0.8556)  dis= 0.05182  next Energy=  -629.293777 (dE=-0.872E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629260178727E+03    0.11288E-02   -0.22410E+01  3840   0.110E+01    0.108E+00
DAV:   2    -0.629301405112E+03   -0.41226E-01   -0.48951E-01  4480   0.146E+00    0.523E-01
DAV:   3    -0.629297690932E+03    0.37142E-02   -0.97416E-03  4608   0.254E-01    0.324E-01
DAV:   4    -0.629296140969E+03    0.15500E-02   -0.85597E-03  4480   0.261E-01    0.957E-02
DAV:   5    -0.629296219008E+03   -0.78039E-04   -0.20376E-03  4504   0.112E-01    0.826E-02
DAV:   6    -0.629296195374E+03    0.23635E-04   -0.58977E-04  4440   0.617E-02    0.402E-02
DAV:   7    -0.629296183739E+03    0.11635E-04   -0.60822E-05  4464   0.220E-02    0.208E-02
DAV:   8    -0.629296182011E+03    0.17279E-05   -0.18755E-05  3176   0.143E-02 
  27 F= -.62929618E+03 E0= -.62927783E+03  d E =-.895632E-01
 curvature:  -1.68 expect dE=-0.247E+00 dE for cont linesearch -0.275E-03
 trial: gam= 0.61823 g(F)=  0.147E+00 g(S)=  0.000E+00 ort = 0.117E-01 (trialstep = 0.417E+00)
 search vector abs. value=  0.479E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629327359018E+03   -0.31175E-01   -0.94825E+00  3840   0.716E+00    0.756E-01
DAV:   2    -0.629345447425E+03   -0.18088E-01   -0.21880E-01  4496   0.982E-01    0.368E-01
DAV:   3    -0.629343483446E+03    0.19640E-02   -0.44446E-03  4592   0.186E-01    0.226E-01
DAV:   4    -0.629342715782E+03    0.76766E-03   -0.47036E-03  4496   0.198E-01    0.725E-02
DAV:   5    -0.629342727483E+03   -0.11702E-04   -0.10835E-03  4536   0.865E-02    0.608E-02
DAV:   6    -0.629342715617E+03    0.11866E-04   -0.37439E-04  4496   0.492E-02    0.286E-02
DAV:   7    -0.629342708987E+03    0.66300E-05   -0.30898E-05  3448   0.169E-02 
  28 F= -.62934271E+03 E0= -.62932435E+03  d E =-.465270E-01
 trial-energy change:   -0.046527  1 .order   -0.046425   -0.064249   -0.028600
 step:   0.7522(harm=  0.7522)  dis= 0.03796  next Energy=  -629.354080 (dE=-0.579E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629344655267E+03   -0.19397E-02   -0.61075E+00  3840   0.575E+00    0.608E-01
DAV:   2    -0.629356281414E+03   -0.11626E-01   -0.14089E-01  4504   0.789E-01    0.294E-01
DAV:   3    -0.629355013521E+03    0.12679E-02   -0.28822E-03  4584   0.149E-01    0.180E-01
DAV:   4    -0.629354512628E+03    0.50089E-03   -0.29762E-03  4496   0.158E-01    0.575E-02
DAV:   5    -0.629354521476E+03   -0.88486E-05   -0.70536E-04  4536   0.698E-02    0.489E-02
DAV:   6    -0.629354512903E+03    0.85730E-05   -0.23502E-04  4488   0.390E-02    0.234E-02
DAV:   7    -0.629354508031E+03    0.48728E-05   -0.18436E-05  3024   0.137E-02 
  29 F= -.62935451E+03 E0= -.62933615E+03  d E =-.583260E-01
 curvature:  -1.17 expect dE=-0.137E+00 dE for cont linesearch -0.267E-05
 trial: gam= 0.87096 g(F)=  0.117E+00 g(S)=  0.000E+00 ort = 0.105E-02 (trialstep = 0.481E+00)
 search vector abs. value=  0.482E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629373978101E+03   -0.19465E-01   -0.13120E+01  3840   0.841E+00    0.789E-01
DAV:   2    -0.629398888822E+03   -0.24911E-01   -0.28814E-01  4472   0.111E+00    0.405E-01
DAV:   3    -0.629396981388E+03    0.19074E-02   -0.53446E-03  4592   0.191E-01    0.255E-01
DAV:   4    -0.629396241743E+03    0.73964E-03   -0.51620E-03  4480   0.201E-01    0.795E-02
DAV:   5    -0.629396255702E+03   -0.13959E-04   -0.10534E-03  4488   0.859E-02    0.649E-02
DAV:   6    -0.629396251766E+03    0.39359E-05   -0.48369E-04  4488   0.580E-02    0.309E-02
DAV:   7    -0.629396244955E+03    0.68110E-05   -0.56760E-05  4160   0.206E-02 
  30 F= -.62939624E+03 E0= -.62937788E+03  d E =-.417369E-01
 trial-energy change:   -0.041737  1 .order   -0.041561   -0.056701   -0.026422
 step:   0.8761(harm=  0.9011)  dis= 0.03950  next Energy=  -629.407183 (dE=-0.527E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629392632931E+03    0.36188E-02   -0.88348E+00  3840   0.690E+00    0.649E-01
DAV:   2    -0.629409443408E+03   -0.16810E-01   -0.19441E-01  4456   0.915E-01    0.332E-01
DAV:   3    -0.629408166183E+03    0.12772E-02   -0.36138E-03  4592   0.157E-01    0.209E-01
DAV:   4    -0.629407671225E+03    0.49496E-03   -0.34299E-03  4480   0.164E-01    0.650E-02
DAV:   5    -0.629407681411E+03   -0.10186E-04   -0.70714E-04  4496   0.706E-02    0.531E-02
DAV:   6    -0.629407678656E+03    0.27559E-05   -0.32352E-04  4496   0.476E-02    0.255E-02
DAV:   7    -0.629407673750E+03    0.49057E-05   -0.36438E-05  3496   0.169E-02 
  31 F= -.62940767E+03 E0= -.62938931E+03  d E =-.531657E-01
 curvature:  -1.84 expect dE=-0.210E+00 dE for cont linesearch -0.296E-04
 trial: gam= 0.93028 g(F)=  0.115E+00 g(S)=  0.000E+00 ort = 0.279E-02 (trialstep = 0.503E+00)
 search vector abs. value=  0.537E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629416603179E+03   -0.89245E-02   -0.18255E+01  3840   0.996E+00    0.102E+00
DAV:   2    -0.629451878637E+03   -0.35275E-01   -0.40375E-01  4448   0.132E+00    0.454E-01
DAV:   3    -0.629449031705E+03    0.28469E-02   -0.68731E-03  4616   0.221E-01    0.280E-01
DAV:   4    -0.629447836762E+03    0.11949E-02   -0.59064E-03  4496   0.229E-01    0.725E-02
DAV:   5    -0.629447944986E+03   -0.10822E-03   -0.16171E-03  4432   0.970E-02    0.664E-02
DAV:   6    -0.629447935932E+03    0.90541E-05   -0.30674E-04  4504   0.438E-02    0.359E-02
DAV:   7    -0.629447929655E+03    0.62769E-05   -0.24772E-05  3000   0.155E-02 
  32 F= -.62944793E+03 E0= -.62942956E+03  d E =-.402559E-01
 trial-energy change:   -0.040256  1 .order   -0.039987   -0.058898   -0.021076
 step:   0.7661(harm=  0.7832)  dis= 0.03453  next Energy=  -629.453481 (dE=-0.458E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629445544317E+03    0.23916E-02   -0.50014E+00  3840   0.521E+00    0.532E-01
DAV:   2    -0.629455136052E+03   -0.95917E-02   -0.11001E-01  4448   0.689E-01    0.236E-01
DAV:   3    -0.629454358660E+03    0.77739E-03   -0.18892E-03  4624   0.115E-01    0.146E-01
DAV:   4    -0.629454028995E+03    0.32966E-03   -0.15706E-03  4496   0.119E-01    0.373E-02
DAV:   5    -0.629454059939E+03   -0.30944E-04   -0.44406E-04  4448   0.507E-02    0.347E-02
DAV:   6    -0.629454057009E+03    0.29304E-05   -0.82022E-05  4440   0.228E-02 
  33 F= -.62945406E+03 E0= -.62943569E+03  d E =-.463833E-01
 curvature:  -1.79 expect dE=-0.175E+00 dE for cont linesearch -0.393E-04
 trial: gam= 0.85066 g(F)=  0.981E-01 g(S)=  0.000E+00 ort = 0.343E-02 (trialstep = 0.556E+00)
 search vector abs. value=  0.492E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629452861993E+03    0.11979E-02   -0.21426E+01  3840   0.108E+01    0.111E+00
DAV:   2    -0.629494225344E+03   -0.41363E-01   -0.48009E-01  4440   0.145E+00    0.498E-01
DAV:   3    -0.629490798975E+03    0.34264E-02   -0.87698E-03  4616   0.248E-01    0.308E-01
DAV:   4    -0.629489423960E+03    0.13750E-02   -0.70724E-03  4496   0.241E-01    0.837E-02
DAV:   5    -0.629489530997E+03   -0.10704E-03   -0.17195E-03  4392   0.102E-01    0.709E-02
DAV:   6    -0.629489537417E+03   -0.64200E-05   -0.46170E-04  4528   0.554E-02    0.367E-02
DAV:   7    -0.629489529315E+03    0.81019E-05   -0.48849E-05  4016   0.207E-02 
  34 F= -.62948953E+03 E0= -.62947116E+03  d E =-.354723E-01
 trial-energy change:   -0.035472  1 .order   -0.035198   -0.056114   -0.014282
 step:   0.7359(harm=  0.7453)  dis= 0.03115  next Energy=  -629.491856 (dE=-0.378E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629488058569E+03    0.14788E-02   -0.22572E+00  3840   0.351E+00    0.365E-01
DAV:   2    -0.629492400961E+03   -0.43424E-02   -0.50410E-02  4440   0.470E-01    0.160E-01
DAV:   3    -0.629492044575E+03    0.35639E-03   -0.93125E-04  4616   0.807E-02    0.986E-02
DAV:   4    -0.629491903280E+03    0.14130E-03   -0.71583E-04  4496   0.772E-02    0.267E-02
DAV:   5    -0.629491915274E+03   -0.11994E-04   -0.17771E-04  4392   0.325E-02    0.229E-02
DAV:   6    -0.629491915906E+03   -0.63186E-06   -0.47666E-05  4024   0.179E-02 
  35 F= -.62949192E+03 E0= -.62947355E+03  d E =-.378589E-01
 curvature:  -1.81 expect dE=-0.153E+00 dE for cont linesearch -0.171E-07
 trial: gam= 0.89643 g(F)=  0.844E-01 g(S)=  0.000E+00 ort = 0.681E-04 (trialstep = 0.592E+00)
 search vector abs. value=  0.480E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629488095428E+03    0.38198E-02   -0.22222E+01  3840   0.110E+01    0.948E-01
DAV:   2    -0.629530497462E+03   -0.42402E-01   -0.48279E-01  4440   0.145E+00    0.507E-01
DAV:   3    -0.629527488088E+03    0.30094E-02   -0.80918E-03  4648   0.232E-01    0.323E-01
DAV:   4    -0.629526072967E+03    0.14151E-02   -0.84526E-03  4472   0.269E-01    0.961E-02
DAV:   5    -0.629526135142E+03   -0.62175E-04   -0.20439E-03  4400   0.114E-01    0.841E-02
DAV:   6    -0.629526106720E+03    0.28422E-04   -0.63869E-04  4432   0.657E-02    0.391E-02
DAV:   7    -0.629526100154E+03    0.65663E-05   -0.65237E-05  4288   0.206E-02 
  36 F= -.62952610E+03 E0= -.62950772E+03  d E =-.341842E-01
 trial-energy change:   -0.034184  1 .order   -0.034088   -0.049957   -0.018219
 step:   0.9219(harm=  0.9312)  dis= 0.02831  next Energy=  -629.531202 (dE=-0.393E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629519355974E+03    0.67507E-02   -0.69248E+00  3840   0.616E+00    0.527E-01
DAV:   2    -0.629532586264E+03   -0.13230E-01   -0.15044E-01  4432   0.810E-01    0.282E-01
DAV:   3    -0.629531649642E+03    0.93662E-03   -0.25094E-03  4648   0.129E-01    0.179E-01
DAV:   4    -0.629531208659E+03    0.44098E-03   -0.26589E-03  4472   0.151E-01    0.540E-02
DAV:   5    -0.629531226995E+03   -0.18336E-04   -0.64265E-04  4408   0.640E-02    0.475E-02
DAV:   6    -0.629531217458E+03    0.95363E-05   -0.20225E-04  4376   0.370E-02    0.219E-02
DAV:   7    -0.629531215301E+03    0.21576E-05   -0.19778E-05  2704   0.116E-02 
  37 F= -.62953122E+03 E0= -.62951283E+03  d E =-.392994E-01
 curvature:  -2.65 expect dE=-0.233E+00 dE for cont linesearch -0.879E-07
 trial: gam= 1.01156 g(F)=  0.881E-01 g(S)=  0.000E+00 ort =-0.126E-03 (trialstep = 0.545E+00)
 search vector abs. value=  0.579E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629522607402E+03    0.86101E-02   -0.23050E+01  3840   0.112E+01    0.101E+00
DAV:   2    -0.629567754991E+03   -0.45148E-01   -0.51253E-01  4456   0.149E+00    0.513E-01
DAV:   3    -0.629564568379E+03    0.31866E-02   -0.85645E-03  4624   0.244E-01    0.323E-01
DAV:   4    -0.629563092273E+03    0.14761E-02   -0.90136E-03  4552   0.282E-01    0.998E-02
DAV:   5    -0.629563145861E+03   -0.53589E-04   -0.21872E-03  4432   0.118E-01    0.887E-02
DAV:   6    -0.629563109676E+03    0.36186E-04   -0.67459E-04  4424   0.672E-02    0.413E-02
DAV:   7    -0.629563100703E+03    0.89728E-05   -0.71922E-05  4400   0.212E-02 
  38 F= -.62956310E+03 E0= -.62954471E+03  d E =-.318854E-01
 trial-energy change:   -0.031885  1 .order   -0.031685   -0.047958   -0.015412
 step:   0.7904(harm=  0.8035)  dis= 0.02514  next Energy=  -629.566583 (dE=-0.354E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629558428400E+03    0.46813E-02   -0.46601E+00  3840   0.505E+00    0.456E-01
DAV:   2    -0.629567573886E+03   -0.91455E-02   -0.10368E-01  4456   0.672E-01    0.229E-01
DAV:   3    -0.629566930932E+03    0.64295E-03   -0.17159E-03  4616   0.110E-01    0.144E-01
DAV:   4    -0.629566634308E+03    0.29662E-03   -0.18330E-03  4560   0.127E-01    0.449E-02
DAV:   5    -0.629566644421E+03   -0.10113E-04   -0.44820E-04  4432   0.538E-02    0.402E-02
DAV:   6    -0.629566636520E+03    0.79010E-05   -0.13801E-04  4368   0.304E-02    0.188E-02
DAV:   7    -0.629566634496E+03    0.20242E-05   -0.13537E-05  2624   0.969E-03 
  39 F= -.62956663E+03 E0= -.62954824E+03  d E =-.354192E-01
 curvature:  -2.64 expect dE=-0.210E+00 dE for cont linesearch -0.332E-06
 trial: gam= 0.90367 g(F)=  0.795E-01 g(S)=  0.000E+00 ort = 0.270E-03 (trialstep = 0.594E+00)
 search vector abs. value=  0.553E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629553147785E+03    0.13489E-01   -0.26128E+01  3840   0.120E+01    0.105E+00
DAV:   2    -0.629604254576E+03   -0.51107E-01   -0.57504E-01  4448   0.158E+00    0.536E-01
DAV:   3    -0.629600695089E+03    0.35595E-02   -0.90395E-03  4616   0.250E-01    0.338E-01
DAV:   4    -0.629599049333E+03    0.16458E-02   -0.97505E-03  4544   0.293E-01    0.101E-01
DAV:   5    -0.629599120248E+03   -0.70914E-04   -0.23859E-03  4408   0.123E-01    0.893E-02
DAV:   6    -0.629599086936E+03    0.33311E-04   -0.72665E-04  4456   0.699E-02    0.405E-02
DAV:   7    -0.629599077325E+03    0.96118E-05   -0.75958E-05  4504   0.234E-02 
  40 F= -.62959908E+03 E0= -.62958067E+03  d E =-.324428E-01
 trial-energy change:   -0.032443  1 .order   -0.032353   -0.047398   -0.017308
 step:   0.9268(harm=  0.9361)  dis= 0.03306  next Energy=  -629.603936 (dE=-0.373E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629589581283E+03    0.95057E-02   -0.81863E+00  3840   0.670E+00    0.583E-01
DAV:   2    -0.629605561576E+03   -0.15980E-01   -0.17980E-01  4448   0.882E-01    0.298E-01
DAV:   3    -0.629604453750E+03    0.11078E-02   -0.28155E-03  4616   0.140E-01    0.188E-01
DAV:   4    -0.629603941076E+03    0.51267E-03   -0.30259E-03  4544   0.164E-01    0.560E-02
DAV:   5    -0.629603964009E+03   -0.22933E-04   -0.75346E-04  4424   0.691E-02    0.502E-02
DAV:   6    -0.629603952688E+03    0.11321E-04   -0.22649E-04  4448   0.391E-02    0.230E-02
DAV:   7    -0.629603949165E+03    0.35236E-05   -0.22153E-05  2904   0.133E-02 
  41 F= -.62960395E+03 E0= -.62958553E+03  d E =-.373147E-01
 curvature:  -3.24 expect dE=-0.269E+00 dE for cont linesearch -0.181E-06
 trial: gam= 1.05143 g(F)=  0.829E-01 g(S)=  0.000E+00 ort =-0.175E-03 (trialstep = 0.527E+00)
 search vector abs. value=  0.694E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629592167776E+03    0.11785E-01   -0.24226E+01  3840   0.115E+01    0.990E-01
DAV:   2    -0.629638622071E+03   -0.46454E-01   -0.52401E-01  4456   0.151E+00    0.522E-01
DAV:   3    -0.629635435320E+03    0.31868E-02   -0.85745E-03  4608   0.239E-01    0.331E-01
DAV:   4    -0.629633949171E+03    0.14861E-02   -0.88457E-03  4496   0.277E-01    0.972E-02
DAV:   5    -0.629634022238E+03   -0.73067E-04   -0.22351E-03  4424   0.118E-01    0.852E-02
DAV:   6    -0.629633993050E+03    0.29189E-04   -0.62700E-04  4440   0.642E-02    0.397E-02
DAV:   7    -0.629633984632E+03    0.84180E-05   -0.62613E-05  4248   0.204E-02 
  42 F= -.62963398E+03 E0= -.62961557E+03  d E =-.300355E-01
 trial-energy change:   -0.030035  1 .order   -0.029910   -0.043538   -0.016281
 step:   0.8281(harm=  0.8413)  dis= 0.03910  next Energy=  -629.638668 (dE=-0.347E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629625131873E+03    0.88612E-02   -0.79429E+00  3840   0.661E+00    0.565E-01
DAV:   2    -0.629640341950E+03   -0.15210E-01   -0.17150E-01  4464   0.864E-01    0.298E-01
DAV:   3    -0.629639307240E+03    0.10347E-02   -0.27990E-03  4608   0.137E-01    0.188E-01
DAV:   4    -0.629638825487E+03    0.48175E-03   -0.29063E-03  4536   0.159E-01    0.559E-02
DAV:   5    -0.629638848070E+03   -0.22583E-04   -0.73310E-04  4440   0.678E-02    0.492E-02
DAV:   6    -0.629638838034E+03    0.10037E-04   -0.21140E-04  4440   0.374E-02    0.229E-02
DAV:   7    -0.629638834958E+03    0.30755E-05   -0.19839E-05  2736   0.119E-02 
  43 F= -.62963883E+03 E0= -.62962041E+03  d E =-.348858E-01
 curvature:  -3.52 expect dE=-0.252E+00 dE for cont linesearch -0.227E-05
 trial: gam= 0.85226 g(F)=  0.715E-01 g(S)=  0.000E+00 ort = 0.668E-03 (trialstep = 0.587E+00)
 search vector abs. value=  0.577E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629623949641E+03    0.14888E-01   -0.24484E+01  3840   0.116E+01    0.105E+00
DAV:   2    -0.629670676867E+03   -0.46727E-01   -0.53173E-01  4456   0.153E+00    0.529E-01
DAV:   3    -0.629667413853E+03    0.32630E-02   -0.90003E-03  4616   0.242E-01    0.334E-01
DAV:   4    -0.629665940750E+03    0.14731E-02   -0.85885E-03  4480   0.271E-01    0.942E-02
DAV:   5    -0.629666023690E+03   -0.82940E-04   -0.21346E-03  4392   0.115E-01    0.816E-02
DAV:   6    -0.629666004614E+03    0.19077E-04   -0.62717E-04  4432   0.641E-02    0.385E-02
DAV:   7    -0.629665995140E+03    0.94737E-05   -0.62339E-05  4120   0.214E-02 
  44 F= -.62966600E+03 E0= -.62964757E+03  d E =-.271602E-01
 trial-energy change:   -0.027160  1 .order   -0.027072   -0.042313   -0.011830
 step:   0.8094(harm=  0.8147)  dis= 0.03818  next Energy=  -629.668241 (dE=-0.294E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629662214806E+03    0.37898E-02   -0.35191E+00  3840   0.441E+00    0.400E-01
DAV:   2    -0.629668927283E+03   -0.67125E-02   -0.76303E-02  4456   0.578E-01    0.199E-01
DAV:   3    -0.629668463875E+03    0.46341E-03   -0.12915E-03  4616   0.918E-02    0.125E-01
DAV:   4    -0.629668257042E+03    0.20683E-03   -0.12085E-03  4488   0.102E-01    0.352E-02
DAV:   5    -0.629668269591E+03   -0.12549E-04   -0.30322E-04  4400   0.432E-02    0.309E-02
DAV:   6    -0.629668266858E+03    0.27328E-05   -0.90460E-05  4320   0.245E-02 
  45 F= -.62966827E+03 E0= -.62964984E+03  d E =-.294319E-01
 curvature:  -3.26 expect dE=-0.218E+00 dE for cont linesearch -0.859E-06
 trial: gam= 0.96368 g(F)=  0.670E-01 g(S)=  0.000E+00 ort =-0.390E-03 (trialstep = 0.605E+00)
 search vector abs. value=  0.602E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629647906857E+03    0.20363E-01   -0.26505E+01  3840   0.121E+01    0.109E+00
DAV:   2    -0.629698705385E+03   -0.50799E-01   -0.57398E-01  4472   0.159E+00    0.549E-01
DAV:   3    -0.629695316889E+03    0.33885E-02   -0.94393E-03  4656   0.250E-01    0.349E-01
DAV:   4    -0.629693751432E+03    0.15655E-02   -0.99557E-03  4488   0.296E-01    0.103E-01
DAV:   5    -0.629693825935E+03   -0.74504E-04   -0.24905E-03  4432   0.125E-01    0.920E-02
DAV:   6    -0.629693783583E+03    0.42353E-04   -0.65990E-04  4424   0.656E-02    0.432E-02
DAV:   7    -0.629693772631E+03    0.10952E-04   -0.74493E-05  4384   0.222E-02    0.212E-02
DAV:   8    -0.629693772217E+03    0.41397E-06   -0.18847E-05  3128   0.135E-02 
  46 F= -.62969377E+03 E0= -.62967534E+03  d E =-.255054E-01
 trial-energy change:   -0.025505  1 .order   -0.025407   -0.040290   -0.010523
 step:   0.8135(harm=  0.8191)  dis= 0.03784  next Energy=  -629.695588 (dE=-0.273E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629690186314E+03    0.35863E-02   -0.31416E+00  3840   0.417E+00    0.373E-01
DAV:   2    -0.629696158379E+03   -0.59721E-02   -0.67462E-02  4464   0.547E-01    0.188E-01
DAV:   3    -0.629695755670E+03    0.40271E-03   -0.11093E-03  4664   0.857E-02    0.119E-01
DAV:   4    -0.629695568298E+03    0.18737E-03   -0.11694E-03  4536   0.102E-01    0.351E-02
DAV:   5    -0.629695577396E+03   -0.90985E-05   -0.29518E-04  4440   0.429E-02    0.316E-02
DAV:   6    -0.629695572188E+03    0.52082E-05   -0.78542E-05  4224   0.227E-02 
  47 F= -.62969557E+03 E0= -.62967713E+03  d E =-.273053E-01
 curvature:  -3.70 expect dE=-0.259E+00 dE for cont linesearch -0.805E-06
 trial: gam= 1.03247 g(F)=  0.699E-01 g(S)=  0.000E+00 ort =-0.362E-03 (trialstep = 0.548E+00)
 search vector abs. value=  0.711E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629677214179E+03    0.18363E-01   -0.24536E+01  3840   0.117E+01    0.107E+00
DAV:   2    -0.629725088204E+03   -0.47874E-01   -0.53859E-01  4464   0.154E+00    0.536E-01
DAV:   3    -0.629722050340E+03    0.30379E-02   -0.90208E-03  4624   0.242E-01    0.341E-01
DAV:   4    -0.629720666260E+03    0.13841E-02   -0.91105E-03  4472   0.279E-01    0.102E-01
DAV:   5    -0.629720724911E+03   -0.58651E-04   -0.21565E-03  4408   0.118E-01    0.882E-02
DAV:   6    -0.629720691909E+03    0.33002E-04   -0.66914E-04  4424   0.664E-02    0.401E-02
DAV:   7    -0.629720681603E+03    0.10306E-04   -0.77909E-05  4376   0.230E-02    0.198E-02
DAV:   8    -0.629720682714E+03   -0.11109E-05   -0.18902E-05  3088   0.118E-02 
  48 F= -.62972068E+03 E0= -.62970224E+03  d E =-.251105E-01
 trial-energy change:   -0.025111  1 .order   -0.024984   -0.038098   -0.011869
 step:   0.7856(harm=  0.7955)  dis= 0.04038  next Energy=  -629.723271 (dE=-0.277E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629715104472E+03    0.55771E-02   -0.46297E+00  3840   0.507E+00    0.464E-01
DAV:   2    -0.629724072642E+03   -0.89682E-02   -0.10088E-01  4464   0.669E-01    0.232E-01
DAV:   3    -0.629723498090E+03    0.57455E-03   -0.16830E-03  4624   0.105E-01    0.147E-01
DAV:   4    -0.629723236115E+03    0.26197E-03   -0.17041E-03  4488   0.121E-01    0.439E-02
DAV:   5    -0.629723247862E+03   -0.11747E-04   -0.40646E-04  4400   0.511E-02    0.382E-02
DAV:   6    -0.629723241490E+03    0.63724E-05   -0.12590E-04  4416   0.289E-02    0.174E-02
DAV:   7    -0.629723239571E+03    0.19187E-05   -0.13722E-05  2552   0.100E-02 
  49 F= -.62972324E+03 E0= -.62970479E+03  d E =-.276674E-01
 curvature:  -4.06 expect dE=-0.264E+00 dE for cont linesearch -0.253E-08
 trial: gam= 0.92123 g(F)=  0.651E-01 g(S)=  0.000E+00 ort = 0.211E-04 (trialstep = 0.595E+00)
 search vector abs. value=  0.668E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629704668119E+03    0.18573E-01   -0.25936E+01  3840   0.120E+01    0.106E+00
DAV:   2    -0.629754773656E+03   -0.50106E-01   -0.56312E-01  4472   0.158E+00    0.556E-01
DAV:   3    -0.629751596495E+03    0.31772E-02   -0.92980E-03  4608   0.251E-01    0.356E-01
DAV:   4    -0.629750181570E+03    0.14149E-02   -0.10021E-02  4480   0.298E-01    0.106E-01
DAV:   5    -0.629750244921E+03   -0.63350E-04   -0.24118E-03  4368   0.123E-01    0.953E-02
DAV:   6    -0.629750199928E+03    0.44993E-04   -0.72439E-04  4456   0.690E-02    0.443E-02
DAV:   7    -0.629750188471E+03    0.11456E-04   -0.82431E-05  4336   0.231E-02    0.221E-02
DAV:   8    -0.629750188985E+03   -0.51381E-06   -0.20866E-05  3008   0.124E-02 
  50 F= -.62975019E+03 E0= -.62973174E+03  d E =-.269494E-01
 trial-energy change:   -0.026949  1 .order   -0.026948   -0.038780   -0.015116
 step:   0.9755(harm=  0.9755)  dis= 0.05049  next Energy=  -629.755016 (dE=-0.318E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629736390010E+03    0.13798E-01   -0.10581E+01  3840   0.766E+00    0.672E-01
DAV:   2    -0.629756714193E+03   -0.20324E-01   -0.22837E-01  4472   0.100E+00    0.354E-01
DAV:   3    -0.629755430771E+03    0.12834E-02   -0.37644E-03  4608   0.160E-01    0.226E-01
DAV:   4    -0.629754858723E+03    0.57205E-03   -0.40322E-03  4480   0.189E-01    0.673E-02
DAV:   5    -0.629754885778E+03   -0.27055E-04   -0.98092E-04  4368   0.783E-02    0.606E-02
DAV:   6    -0.629754867040E+03    0.18737E-04   -0.29218E-04  4488   0.438E-02    0.283E-02
DAV:   7    -0.629754862166E+03    0.48744E-05   -0.31622E-05  2984   0.147E-02 
  51 F= -.62975486E+03 E0= -.62973641E+03  d E =-.316226E-01
 curvature:  -5.00 expect dE=-0.361E+00 dE for cont linesearch -0.603E-05
 trial: gam= 1.11239 g(F)=  0.722E-01 g(S)=  0.000E+00 ort =-0.897E-03 (trialstep = 0.500E+00)
 search vector abs. value=  0.897E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629739401527E+03    0.15466E-01   -0.24412E+01  3840   0.116E+01    0.102E+00
DAV:   2    -0.629786373616E+03   -0.46972E-01   -0.52620E-01  4432   0.153E+00    0.541E-01
DAV:   3    -0.629783414099E+03    0.29595E-02   -0.87223E-03  4616   0.243E-01    0.346E-01
DAV:   4    -0.629782112039E+03    0.13021E-02   -0.93028E-03  4472   0.289E-01    0.105E-01
DAV:   5    -0.629782171087E+03   -0.59048E-04   -0.22708E-03  4360   0.119E-01    0.915E-02
DAV:   6    -0.629782128785E+03    0.42302E-04   -0.71051E-04  4496   0.684E-02    0.406E-02
DAV:   7    -0.629782120338E+03    0.84472E-05   -0.79541E-05  4272   0.220E-02 
  52 F= -.62978212E+03 E0= -.62976366E+03  d E =-.272582E-01
 trial-energy change:   -0.027258  1 .order   -0.027138   -0.035626   -0.018649
 step:   1.0059(harm=  1.0493)  dis= 0.05916  next Energy=  -629.791679 (dE=-0.368E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629747689032E+03    0.34440E-01   -0.24983E+01  3840   0.118E+01    0.103E+00
DAV:   2    -0.629795832500E+03   -0.48143E-01   -0.53923E-01  4408   0.154E+00    0.547E-01
DAV:   3    -0.629792824047E+03    0.30085E-02   -0.90083E-03  4616   0.246E-01    0.349E-01
DAV:   4    -0.629791497318E+03    0.13267E-02   -0.94662E-03  4472   0.292E-01    0.106E-01
DAV:   5    -0.629791557330E+03   -0.60012E-04   -0.23109E-03  4360   0.121E-01    0.924E-02
DAV:   6    -0.629791515086E+03    0.42244E-04   -0.73360E-04  4496   0.695E-02    0.409E-02
DAV:   7    -0.629791506467E+03    0.86192E-05   -0.80717E-05  4280   0.223E-02 
  53 F= -.62979151E+03 E0= -.62977304E+03  d E =-.366443E-01
 curvature:  -6.56 expect dE=-0.598E+00 dE for cont linesearch -0.727E-05
 trial: gam= 1.23071 g(F)=  0.911E-01 g(S)=  0.000E+00 ort = 0.997E-03 (trialstep = 0.371E+00)
 search vector abs. value=  0.145E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629778596392E+03    0.12919E-01   -0.22100E+01  3840   0.111E+01    0.982E-01
DAV:   2    -0.629821186951E+03   -0.42591E-01   -0.47942E-01  4456   0.146E+00    0.515E-01
DAV:   3    -0.629818574810E+03    0.26121E-02   -0.82665E-03  4600   0.231E-01    0.330E-01
DAV:   4    -0.629817396962E+03    0.11778E-02   -0.83342E-03  4448   0.266E-01    0.102E-01
DAV:   5    -0.629817431535E+03   -0.34573E-04   -0.18520E-03  4440   0.110E-01    0.841E-02
DAV:   6    -0.629817399162E+03    0.32372E-04   -0.74464E-04  4480   0.717E-02    0.355E-02
DAV:   7    -0.629817391329E+03    0.78334E-05   -0.81411E-05  4232   0.231E-02 
  54 F= -.62981739E+03 E0= -.62979892E+03  d E =-.258849E-01
 trial-energy change:   -0.025885  1 .order   -0.026026   -0.034281   -0.017770
 step:   0.8220(harm=  0.7710)  dis= 0.06029  next Energy=  -629.827922 (dE=-0.364E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629768902805E+03    0.48496E-01   -0.32541E+01  3840   0.134E+01    0.120E+00
DAV:   2    -0.629831827339E+03   -0.62925E-01   -0.70872E-01  4448   0.177E+00    0.627E-01
DAV:   3    -0.629827955476E+03    0.38719E-02   -0.12275E-02  4600   0.282E-01    0.402E-01
DAV:   4    -0.629826202922E+03    0.17526E-02   -0.12257E-02  4448   0.322E-01    0.124E-01
DAV:   5    -0.629826253477E+03   -0.50555E-04   -0.27154E-03  4456   0.134E-01    0.102E-01
DAV:   6    -0.629826208251E+03    0.45226E-04   -0.10885E-03  4488   0.867E-02    0.430E-02
DAV:   7    -0.629826196712E+03    0.11539E-04   -0.11889E-04  4320   0.281E-02    0.224E-02
DAV:   8    -0.629826198453E+03   -0.17415E-05   -0.25519E-05  3032   0.126E-02 
  55 F= -.62982620E+03 E0= -.62980772E+03  d E =-.346920E-01
 curvature:  -5.97 expect dE=-0.563E+00 dE for cont linesearch -0.247E-03
 trial: gam= 1.11684 g(F)=  0.944E-01 g(S)=  0.000E+00 ort =-0.776E-02 (trialstep = 0.355E+00)
 search vector abs. value=  0.189E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629804115665E+03    0.22081E-01   -0.25663E+01  3840   0.119E+01    0.104E+00
DAV:   2    -0.629853533333E+03   -0.49418E-01   -0.55374E-01  4472   0.157E+00    0.549E-01
DAV:   3    -0.629850636081E+03    0.28973E-02   -0.90964E-03  4600   0.243E-01    0.351E-01
DAV:   4    -0.629849343216E+03    0.12929E-02   -0.95045E-03  4488   0.291E-01    0.106E-01
DAV:   5    -0.629849396632E+03   -0.53416E-04   -0.22692E-03  4400   0.120E-01    0.925E-02
DAV:   6    -0.629849346937E+03    0.49695E-04   -0.72999E-04  4472   0.697E-02    0.408E-02
DAV:   7    -0.629849337563E+03    0.93733E-05   -0.82640E-05  4296   0.226E-02 
  56 F= -.62984934E+03 E0= -.62983086E+03  d E =-.231391E-01
 trial-energy change:   -0.023139  1 .order   -0.023230   -0.030437   -0.016022
 step:   0.7851(harm=  0.7493)  dis= 0.06405  next Energy=  -629.858888 (dE=-0.327E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629790693089E+03    0.58654E-01   -0.37715E+01  3840   0.145E+01    0.126E+00
DAV:   2    -0.629863735934E+03   -0.73043E-01   -0.81813E-01  4464   0.190E+00    0.667E-01
DAV:   3    -0.629859464644E+03    0.42713E-02   -0.13512E-02  4600   0.296E-01    0.426E-01
DAV:   4    -0.629857565427E+03    0.18992E-02   -0.14012E-02  4480   0.353E-01    0.129E-01
DAV:   5    -0.629857642002E+03   -0.76574E-04   -0.33470E-03  4400   0.145E-01    0.112E-01
DAV:   6    -0.629857569921E+03    0.72081E-04   -0.10725E-03  4528   0.844E-02    0.494E-02
DAV:   7    -0.629857556491E+03    0.13430E-04   -0.11956E-04  4376   0.272E-02    0.232E-02
DAV:   8    -0.629857558569E+03   -0.20778E-05   -0.26202E-05  3208   0.130E-02 
  57 F= -.62985756E+03 E0= -.62983908E+03  d E =-.313601E-01
 curvature:  -8.18 expect dE=-0.693E+00 dE for cont linesearch -0.146E-03
 trial: gam= 0.74125 g(F)=  0.848E-01 g(S)=  0.000E+00 ort =-0.580E-02 (trialstep = 0.441E+00)
 search vector abs. value=  0.111E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629843955969E+03    0.13601E-01   -0.22456E+01  3840   0.112E+01    0.997E-01
DAV:   2    -0.629886953368E+03   -0.42997E-01   -0.48481E-01  4448   0.147E+00    0.523E-01
DAV:   3    -0.629884237986E+03    0.27154E-02   -0.80005E-03  4600   0.231E-01    0.331E-01
DAV:   4    -0.629883090547E+03    0.11474E-02   -0.81986E-03  4472   0.271E-01    0.968E-02
DAV:   5    -0.629883146569E+03   -0.56021E-04   -0.20426E-03  4400   0.114E-01    0.848E-02
DAV:   6    -0.629883114123E+03    0.32445E-04   -0.59484E-04  4480   0.620E-02    0.389E-02
DAV:   7    -0.629883105906E+03    0.82174E-05   -0.59062E-05  4192   0.201E-02 
  58 F= -.62988311E+03 E0= -.62986462E+03  d E =-.255473E-01
 trial-energy change:   -0.025547  1 .order   -0.025680   -0.035478   -0.015882
 step:   0.8277(harm=  0.7983)  dis= 0.05136  next Energy=  -629.889982 (dE=-0.324E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629859099455E+03    0.24015E-01   -0.17287E+01  3840   0.979E+00    0.877E-01
DAV:   2    -0.629892233383E+03   -0.33134E-01   -0.37376E-01  4448   0.129E+00    0.459E-01
DAV:   3    -0.629890141400E+03    0.20920E-02   -0.61865E-03  4600   0.203E-01    0.290E-01
DAV:   4    -0.629889260180E+03    0.88122E-03   -0.62676E-03  4472   0.237E-01    0.848E-02
DAV:   5    -0.629889304361E+03   -0.44181E-04   -0.15681E-03  4400   0.999E-02    0.743E-02
DAV:   6    -0.629889279634E+03    0.24728E-04   -0.45730E-04  4488   0.544E-02    0.342E-02
DAV:   7    -0.629889273227E+03    0.64070E-05   -0.43540E-05  3376   0.176E-02 
  59 F= -.62988927E+03 E0= -.62987078E+03  d E =-.317147E-01
 curvature:  -5.49 expect dE=-0.453E+00 dE for cont linesearch -0.936E-04
 trial: gam= 0.95967 g(F)=  0.826E-01 g(S)=  0.000E+00 ort =-0.436E-02 (trialstep = 0.518E+00)
 search vector abs. value=  0.110E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629865575753E+03    0.23704E-01   -0.29686E+01  3840   0.128E+01    0.115E+00
DAV:   2    -0.629922125047E+03   -0.56549E-01   -0.64541E-01  4448   0.170E+00    0.610E-01
DAV:   3    -0.629918474481E+03    0.36506E-02   -0.11283E-02  4592   0.277E-01    0.388E-01
DAV:   4    -0.629916939635E+03    0.15348E-02   -0.11233E-02  4536   0.311E-01    0.119E-01
DAV:   5    -0.629916975293E+03   -0.35658E-04   -0.25072E-03  4448   0.131E-01    0.966E-02
DAV:   6    -0.629916947514E+03    0.27778E-04   -0.10599E-03  4496   0.850E-02    0.425E-02
DAV:   7    -0.629916934393E+03    0.13121E-04   -0.10499E-04  4432   0.285E-02    0.239E-02
DAV:   8    -0.629916933226E+03    0.11680E-05   -0.30491E-05  3520   0.148E-02 
  60 F= -.62991693E+03 E0= -.62989843E+03  d E =-.276600E-01
 trial-energy change:   -0.027660  1 .order   -0.027630   -0.040618   -0.014643
 step:   0.8104(harm=  0.8104)  dis= 0.04560  next Energy=  -629.921031 (dE=-0.318E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629904597514E+03    0.12337E-01   -0.94324E+00  3840   0.723E+00    0.645E-01
DAV:   2    -0.629922407828E+03   -0.17810E-01   -0.20364E-01  4448   0.953E-01    0.342E-01
DAV:   3    -0.629921260792E+03    0.11470E-02   -0.35843E-03  4592   0.156E-01    0.217E-01
DAV:   4    -0.629920777510E+03    0.48328E-03   -0.34996E-03  4536   0.174E-01    0.665E-02
DAV:   5    -0.629920790445E+03   -0.12934E-04   -0.78948E-04  4448   0.734E-02    0.543E-02
DAV:   6    -0.629920780965E+03    0.94797E-05   -0.33696E-04  4488   0.481E-02    0.240E-02
DAV:   7    -0.629920776373E+03    0.45925E-05   -0.31282E-05  2872   0.162E-02 
  61 F= -.62992078E+03 E0= -.62990226E+03  d E =-.315031E-01
 curvature:  -5.69 expect dE=-0.407E+00 dE for cont linesearch -0.172E-04
 trial: gam= 0.83471 g(F)=  0.715E-01 g(S)=  0.000E+00 ort =-0.182E-02 (trialstep = 0.577E+00)
 search vector abs. value=  0.835E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629900235570E+03    0.20545E-01   -0.27278E+01  3840   0.123E+01    0.109E+00
DAV:   2    -0.629952416915E+03   -0.52181E-01   -0.59546E-01  4480   0.163E+00    0.586E-01
DAV:   3    -0.629949007496E+03    0.34094E-02   -0.10261E-02  4600   0.264E-01    0.372E-01
DAV:   4    -0.629947548342E+03    0.14592E-02   -0.10461E-02  4488   0.304E-01    0.114E-01
DAV:   5    -0.629947598206E+03   -0.49864E-04   -0.24817E-03  4456   0.128E-01    0.950E-02
DAV:   6    -0.629947560851E+03    0.37355E-04   -0.88322E-04  4488   0.768E-02    0.423E-02
DAV:   7    -0.629947554514E+03    0.63373E-05   -0.82645E-05  4248   0.234E-02 
  62 F= -.62994755E+03 E0= -.62992903E+03  d E =-.267781E-01
 trial-energy change:   -0.026778  1 .order   -0.026626   -0.040371   -0.012881
 step:   0.8346(harm=  0.8470)  dis= 0.03923  next Energy=  -629.950448 (dE=-0.297E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629941029385E+03    0.65315E-02   -0.54571E+00  3856   0.550E+00    0.486E-01
DAV:   2    -0.629951456150E+03   -0.10427E-01   -0.11883E-01  4480   0.729E-01    0.261E-01
DAV:   3    -0.629950784017E+03    0.67213E-03   -0.20413E-03  4600   0.118E-01    0.165E-01
DAV:   4    -0.629950499187E+03    0.28483E-03   -0.20333E-03  4488   0.134E-01    0.501E-02
DAV:   5    -0.629950510975E+03   -0.11789E-04   -0.49110E-04  4456   0.569E-02    0.419E-02
DAV:   6    -0.629950503995E+03    0.69807E-05   -0.17355E-04  4456   0.341E-02    0.188E-02
DAV:   7    -0.629950502603E+03    0.13915E-05   -0.15102E-05  2576   0.105E-02 
  63 F= -.62995050E+03 E0= -.62993197E+03  d E =-.297262E-01
 curvature:  -5.04 expect dE=-0.406E+00 dE for cont linesearch -0.523E-08
 trial: gam= 1.11510 g(F)=  0.806E-01 g(S)=  0.000E+00 ort =-0.294E-04 (trialstep = 0.469E+00)
 search vector abs. value=  0.112E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629937851544E+03    0.12652E-01   -0.24341E+01  3840   0.116E+01    0.102E+00
DAV:   2    -0.629983341258E+03   -0.45490E-01   -0.52435E-01  4472   0.153E+00    0.552E-01
DAV:   3    -0.629980262320E+03    0.30789E-02   -0.92515E-03  4568   0.247E-01    0.352E-01
DAV:   4    -0.629978906545E+03    0.13558E-02   -0.87761E-03  4528   0.272E-01    0.107E-01
DAV:   5    -0.629978961706E+03   -0.55160E-04   -0.20037E-03  4456   0.115E-01    0.844E-02
DAV:   6    -0.629978941955E+03    0.19751E-04   -0.84107E-04  4488   0.760E-02    0.386E-02
DAV:   7    -0.629978932516E+03    0.94388E-05   -0.85672E-05  4376   0.258E-02 
  64 F= -.62997893E+03 E0= -.62996039E+03  d E =-.284299E-01
 trial-energy change:   -0.028430  1 .order   -0.028363   -0.037785   -0.018942
 step:   0.9214(harm=  0.9403)  dis= 0.04817  next Energy=  -629.988132 (dE=-0.376E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629949755241E+03    0.29187E-01   -0.22673E+01  3840   0.112E+01    0.982E-01
DAV:   2    -0.629992215735E+03   -0.42460E-01   -0.48899E-01  4480   0.148E+00    0.532E-01
DAV:   3    -0.629989359831E+03    0.28559E-02   -0.86355E-03  4568   0.238E-01    0.339E-01
DAV:   4    -0.629988102222E+03    0.12576E-02   -0.81087E-03  4528   0.262E-01    0.103E-01
DAV:   5    -0.629988153989E+03   -0.51767E-04   -0.18555E-03  4464   0.111E-01    0.812E-02
DAV:   6    -0.629988135772E+03    0.18217E-04   -0.77847E-04  4488   0.732E-02    0.373E-02
DAV:   7    -0.629988126914E+03    0.88582E-05   -0.79468E-05  4344   0.249E-02 
  65 F= -.62998813E+03 E0= -.62996957E+03  d E =-.376243E-01
 curvature:  -6.52 expect dE=-0.585E+00 dE for cont linesearch -0.179E-06
 trial: gam= 1.10523 g(F)=  0.898E-01 g(S)=  0.000E+00 ort = 0.175E-03 (trialstep = 0.430E+00)
 search vector abs. value=  0.146E+01
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.629971915969E+03    0.16220E-01   -0.25219E+01  3840   0.118E+01    0.107E+00
DAV:   2    -0.630019648248E+03   -0.47732E-01   -0.55104E-01  4496   0.157E+00    0.571E-01
DAV:   3    -0.630016455857E+03    0.31924E-02   -0.10048E-02  4568   0.265E-01    0.360E-01
DAV:   4    -0.630015162368E+03    0.12935E-02   -0.94458E-03  4560   0.286E-01    0.115E-01
DAV:   5    -0.630015195047E+03   -0.32679E-04   -0.21259E-03  4504   0.121E-01    0.912E-02
DAV:   6    -0.630015168593E+03    0.26454E-04   -0.91267E-04  4480   0.782E-02    0.406E-02
DAV:   7    -0.630015160494E+03    0.80991E-05   -0.86042E-05  4488   0.260E-02 
  66 F= -.63001516E+03 E0= -.62999659E+03  d E =-.270336E-01
 trial-energy change:   -0.027034  1 .order   -0.027073   -0.038665   -0.015481
 step:   0.7164(harm=  0.7164)  dis= 0.04801  next Energy=  -630.020368 (dE=-0.322E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630000830381E+03    0.14338E-01   -0.11256E+01  3840   0.790E+00    0.717E-01
DAV:   2    -0.630022086320E+03   -0.21256E-01   -0.24504E-01  4504   0.105E+00    0.379E-01
DAV:   3    -0.630020677996E+03    0.14083E-02   -0.44666E-03  4568   0.177E-01    0.239E-01
DAV:   4    -0.630020105610E+03    0.57239E-03   -0.41384E-03  4560   0.190E-01    0.758E-02
DAV:   5    -0.630020122009E+03   -0.16398E-04   -0.94377E-04  4512   0.807E-02    0.605E-02
DAV:   6    -0.630020109896E+03    0.12113E-04   -0.39779E-04  4480   0.517E-02    0.272E-02
DAV:   7    -0.630020106011E+03    0.38851E-05   -0.35158E-05  3200   0.171E-02 
  67 F= -.63002011E+03 E0= -.63000153E+03  d E =-.319791E-01
 curvature:  -5.80 expect dE=-0.361E+00 dE for cont linesearch -0.187E-04
 trial: gam= 0.63271 g(F)=  0.623E-01 g(S)=  0.000E+00 ort =-0.217E-02 (trialstep = 0.487E+00)
 search vector abs. value=  0.643E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630017637886E+03    0.24720E-02   -0.13490E+01  3840   0.865E+00    0.843E-01
DAV:   2    -0.630043839003E+03   -0.26201E-01   -0.30138E-01  4512   0.116E+00    0.423E-01
DAV:   3    -0.630042085773E+03    0.17532E-02   -0.55713E-03  4560   0.197E-01    0.264E-01
DAV:   4    -0.630041426726E+03    0.65905E-03   -0.47107E-03  4496   0.202E-01    0.815E-02
DAV:   5    -0.630041463937E+03   -0.37211E-04   -0.10824E-03  4448   0.860E-02    0.634E-02
DAV:   6    -0.630041460888E+03    0.30495E-05   -0.41990E-04  4480   0.526E-02    0.297E-02
DAV:   7    -0.630041455936E+03    0.49520E-05   -0.39930E-05  3432   0.185E-02 
  68 F= -.63004146E+03 E0= -.63002287E+03  d E =-.213499E-01
 trial-energy change:   -0.021350  1 .order   -0.021138   -0.029681   -0.012595
 step:   0.8066(harm=  0.8460)  dis= 0.03882  next Energy=  -630.045649 (dE=-0.255E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630035780487E+03    0.56804E-02   -0.58165E+00  3856   0.568E+00    0.555E-01
DAV:   2    -0.630047074082E+03   -0.11294E-01   -0.12979E-01  4504   0.763E-01    0.277E-01
DAV:   3    -0.630046326022E+03    0.74806E-03   -0.24183E-03  4560   0.129E-01    0.172E-01
DAV:   4    -0.630046044168E+03    0.28185E-03   -0.20060E-03  4488   0.132E-01    0.532E-02
DAV:   5    -0.630046061395E+03   -0.17226E-04   -0.46637E-04  4448   0.563E-02    0.417E-02
DAV:   6    -0.630046059698E+03    0.16965E-05   -0.17935E-04  4480   0.344E-02    0.195E-02
DAV:   7    -0.630046057473E+03    0.22246E-05   -0.16256E-05  2600   0.121E-02 
  69 F= -.63004606E+03 E0= -.63002746E+03  d E =-.259515E-01
 curvature:  -4.41 expect dE=-0.254E+00 dE for cont linesearch -0.318E-04
 trial: gam= 0.82460 g(F)=  0.576E-01 g(S)=  0.000E+00 ort = 0.215E-02 (trialstep = 0.551E+00)
 search vector abs. value=  0.498E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630046646583E+03   -0.58688E-03   -0.12358E+01  3840   0.829E+00    0.817E-01
DAV:   2    -0.630070291249E+03   -0.23645E-01   -0.27887E-01  4520   0.113E+00    0.421E-01
DAV:   3    -0.630068505359E+03    0.17859E-02   -0.58397E-03  4576   0.206E-01    0.263E-01
DAV:   4    -0.630067829109E+03    0.67625E-03   -0.50322E-03  4528   0.204E-01    0.875E-02
DAV:   5    -0.630067830385E+03   -0.12754E-05   -0.10422E-03  4544   0.901E-02    0.663E-02
DAV:   6    -0.630067823560E+03    0.68244E-05   -0.51490E-04  4496   0.604E-02    0.312E-02
DAV:   7    -0.630067816610E+03    0.69505E-05   -0.53765E-05  3976   0.208E-02 
  70 F= -.63006782E+03 E0= -.63004921E+03  d E =-.217591E-01
 trial-energy change:   -0.021759  1 .order   -0.021698   -0.032716   -0.010681
 step:   0.8115(harm=  0.8179)  dis= 0.03763  next Energy=  -630.070350 (dE=-0.243E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630065607636E+03    0.22159E-02   -0.27706E+00  3856   0.392E+00    0.388E-01
DAV:   2    -0.630070919200E+03   -0.53116E-02   -0.62569E-02  4512   0.534E-01    0.198E-01
DAV:   3    -0.630070524277E+03    0.39492E-03   -0.13168E-03  4568   0.979E-02    0.124E-01
DAV:   4    -0.630070372021E+03    0.15226E-03   -0.11092E-03  4536   0.961E-02    0.412E-02
DAV:   5    -0.630070372393E+03   -0.37147E-06   -0.23533E-04  4576   0.430E-02    0.315E-02
DAV:   6    -0.630070370229E+03    0.21639E-05   -0.11535E-04  4496   0.288E-02    0.150E-02
DAV:   7    -0.630070368427E+03    0.18017E-05   -0.10938E-05  2568   0.991E-03 
  71 F= -.63007037E+03 E0= -.63005176E+03  d E =-.243110E-01
 curvature:  -3.43 expect dE=-0.193E+00 dE for cont linesearch -0.784E-07
 trial: gam= 1.00371 g(F)=  0.562E-01 g(S)=  0.000E+00 ort = 0.107E-03 (trialstep = 0.538E+00)
 search vector abs. value=  0.558E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630070058543E+03    0.31169E-03   -0.12499E+01  3840   0.833E+00    0.796E-01
DAV:   2    -0.630094118021E+03   -0.24059E-01   -0.27911E-01  4488   0.112E+00    0.417E-01
DAV:   3    -0.630092607608E+03    0.15104E-02   -0.57796E-03  4552   0.199E-01    0.261E-01
DAV:   4    -0.630092048426E+03    0.55918E-03   -0.45989E-03  4488   0.198E-01    0.863E-02
DAV:   5    -0.630092063666E+03   -0.15241E-04   -0.96510E-04  4496   0.847E-02    0.644E-02
DAV:   6    -0.630092057844E+03    0.58227E-05   -0.45559E-04  4488   0.548E-02    0.294E-02
DAV:   7    -0.630092052459E+03    0.53843E-05   -0.42877E-05  3704   0.192E-02 
  72 F= -.63009205E+03 E0= -.63007343E+03  d E =-.216840E-01
 trial-energy change:   -0.021684  1 .order   -0.021663   -0.030283   -0.013044
 step:   0.9453(harm=  0.9453)  dis= 0.05040  next Energy=  -630.096966 (dE=-0.266E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630084573501E+03    0.74843E-02   -0.71661E+00  3840   0.631E+00    0.603E-01
DAV:   2    -0.630098410004E+03   -0.13837E-01   -0.16023E-01  4480   0.851E-01    0.314E-01
DAV:   3    -0.630097555913E+03    0.85409E-03   -0.33237E-03  4544   0.151E-01    0.197E-01
DAV:   4    -0.630097235366E+03    0.32055E-03   -0.26045E-03  4496   0.150E-01    0.649E-02
DAV:   5    -0.630097245928E+03   -0.10562E-04   -0.55755E-04  4480   0.641E-02    0.488E-02
DAV:   6    -0.630097241828E+03    0.41006E-05   -0.25696E-04  4488   0.411E-02    0.224E-02
DAV:   7    -0.630097238612E+03    0.32152E-05   -0.22429E-05  2752   0.144E-02 
  73 F= -.63009724E+03 E0= -.63007862E+03  d E =-.268702E-01
 curvature:  -4.69 expect dE=-0.281E+00 dE for cont linesearch -0.197E-05
 trial: gam= 1.01087 g(F)=  0.599E-01 g(S)=  0.000E+00 ort = 0.485E-03 (trialstep = 0.548E+00)
 search vector abs. value=  0.631E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630091945490E+03    0.52963E-02   -0.15583E+01  3840   0.930E+00    0.912E-01
DAV:   2    -0.630121785980E+03   -0.29840E-01   -0.34730E-01  4472   0.125E+00    0.460E-01
DAV:   3    -0.630119751182E+03    0.20348E-02   -0.73210E-03  4568   0.219E-01    0.286E-01
DAV:   4    -0.630118940750E+03    0.81043E-03   -0.53600E-03  4472   0.215E-01    0.888E-02
DAV:   5    -0.630118994533E+03   -0.53783E-04   -0.12689E-03  4496   0.922E-02    0.685E-02
DAV:   6    -0.630118984185E+03    0.10348E-04   -0.45575E-04  4440   0.544E-02    0.335E-02
DAV:   7    -0.630118977314E+03    0.68711E-05   -0.41682E-05  3624   0.195E-02 
  74 F= -.63011898E+03 E0= -.63010035E+03  d E =-.217387E-01
 trial-energy change:   -0.021739  1 .order   -0.021580   -0.033060   -0.010099
 step:   0.7755(harm=  0.7889)  dis= 0.04478  next Energy=  -630.121087 (dE=-0.238E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630116586780E+03    0.23974E-02   -0.26947E+00  3856   0.387E+00    0.380E-01
DAV:   2    -0.630121734351E+03   -0.51476E-02   -0.59939E-02  4472   0.521E-01    0.190E-01
DAV:   3    -0.630121386215E+03    0.34814E-03   -0.12765E-03  4568   0.913E-02    0.118E-01
DAV:   4    -0.630121246081E+03    0.14013E-03   -0.90931E-04  4480   0.889E-02    0.366E-02
DAV:   5    -0.630121256015E+03   -0.99340E-05   -0.22068E-04  4512   0.385E-02    0.285E-02
DAV:   6    -0.630121253873E+03    0.21419E-05   -0.77700E-05  4280   0.225E-02 
  75 F= -.63012125E+03 E0= -.63010262E+03  d E =-.240153E-01
 curvature:  -4.11 expect dE=-0.208E+00 dE for cont linesearch -0.603E-05
 trial: gam= 0.86869 g(F)=  0.507E-01 g(S)=  0.000E+00 ort = 0.962E-03 (trialstep = 0.593E+00)
 search vector abs. value=  0.529E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630117080618E+03    0.41754E-02   -0.14461E+01  3840   0.897E+00    0.869E-01
DAV:   2    -0.630144467396E+03   -0.27387E-01   -0.31966E-01  4464   0.121E+00    0.447E-01
DAV:   3    -0.630142770971E+03    0.16964E-02   -0.76327E-03  4568   0.222E-01    0.277E-01
DAV:   4    -0.630142063049E+03    0.70792E-03   -0.43151E-03  4480   0.190E-01    0.911E-02
DAV:   5    -0.630142097532E+03   -0.34483E-04   -0.10091E-03  4568   0.873E-02    0.604E-02
DAV:   6    -0.630142091548E+03    0.59847E-05   -0.43112E-04  4440   0.538E-02    0.308E-02
DAV:   7    -0.630142083973E+03    0.75750E-05   -0.37771E-05  3512   0.194E-02 
  76 F= -.63014208E+03 E0= -.63012344E+03  d E =-.208301E-01
 trial-energy change:   -0.020830  1 .order   -0.020797   -0.030561   -0.011032
 step:   0.9286(harm=  0.9286)  dis= 0.05165  next Energy=  -630.145166 (dE=-0.239E-01)
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630137295492E+03    0.47961E-02   -0.46233E+00  3840   0.507E+00    0.492E-01
DAV:   2    -0.630146024602E+03   -0.87291E-02   -0.10216E-01  4464   0.684E-01    0.251E-01
DAV:   3    -0.630145487492E+03    0.53711E-03   -0.24889E-03  4576   0.126E-01    0.156E-01
DAV:   4    -0.630145254927E+03    0.23257E-03   -0.13524E-03  4488   0.107E-01    0.518E-02
DAV:   5    -0.630145265420E+03   -0.10494E-04   -0.32225E-04  4552   0.497E-02    0.342E-02
DAV:   6    -0.630145262910E+03    0.25100E-05   -0.14112E-04  4432   0.309E-02    0.176E-02
DAV:   7    -0.630145260321E+03    0.25896E-05   -0.11673E-05  2568   0.111E-02 
  77 F= -.63014526E+03 E0= -.63012661E+03  d E =-.240064E-01
 curvature:  -4.77 expect dE=-0.283E+00 dE for cont linesearch -0.220E-05
 trial: gam= 1.18145 g(F)=  0.594E-01 g(S)=  0.000E+00 ort = 0.494E-03 (trialstep = 0.437E+00)
 search vector abs. value=  0.799E+00
 ######################################################################
 bond charge predicted
       N       E                     dE             d eps       ncg     rms          rms(c)
DAV:   1    -0.630145183473E+03    0.79437E-04   -0.11589E+01  3840   0.801E+00    0.783E-01
DAV:   2    -0.630166601640E+03   -0.21418E-01   -0.25455E-01  4472   0.108E+00    0.404E-01
DAV:   3    -0.630165296787E+03    0.13049E-02   -0.65687E-03  4592   0.206E-01    0.253E-01
DAV:   4    -0.630164786022E+03    0.51077E-03   -0.36514E-03  4488   0.174E-01    0.867E-02
DAV:   5    -0.630164821233E+03   -0.35211E-04   -0.79419E-04  4544   0.764E-02    0.564E-02