vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2024.08.31  23:18:04
 running on    3 total cores
 distrk:  each k-point on    3 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    3 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 2
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.32
   NPAR = 3

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     You use a magnetic or noncollinear calculation, but did not specify     |
|     the initial magnetic moment with the MAGMOM tag. Note that a            |
|     default of 1 will be used for all atoms. This ferromagnetic setup       |
|     may break the symmetry of the crystal, in particular it may rule        |
|     out finding an antiferromagnetic solution. Thence, we recommend         |
|     setting the initial magnetic moment manually or verifying carefully     |
|     that this magnetic setup is desired.                                    |
|                                                                             |
 -----------------------------------------------------------------------------

 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.913  0.536  0.065-  19 2.31  14 2.41   3 2.42
   2  0.845  0.309  0.386-  20 2.30  13 2.32   4 2.34  24 2.49
   3  0.117  0.459  0.161-   8 2.34  17 2.37   7 2.39   1 2.42
   4  0.131  0.312  0.313-   2 2.34   7 2.35   8 2.37  18 2.45
   5  0.803  0.333  0.013-  14 2.37   7 2.37  10 2.38  23 2.38
   6  0.934  0.458  0.507-   8 2.35   9 2.37  24 2.40  13 2.41
   7  0.084  0.342  0.105-  21 2.35   4 2.35   5 2.37   3 2.39
   8  0.157  0.429  0.368-   3 2.34   6 2.35  22 2.35   4 2.37
   9  0.943  0.575  0.560-  27 2.32   6 2.37  11 2.41
  10  0.763  0.255  0.847-  28 2.37   5 2.38  12 2.39  31 2.47
  11  0.150  0.547  0.721-  25 2.28  16 2.35   9 2.41
  12  0.001  0.227  0.714-  26 2.37  10 2.39  15 2.52
  13  0.905  0.344  0.586-  31 2.29   2 2.32  15 2.38   6 2.41
  14  0.848  0.443  0.929-  16 2.35   5 2.37   1 2.41  32 2.42
  15  0.163  0.338  0.708-  29 2.34  16 2.37  13 2.38  26 2.48  12 2.52
  16  0.109  0.441  0.815-  30 2.29  14 2.35  11 2.35  15 2.37
  17  0.419  0.455  0.114-  30 2.30  19 2.30   3 2.37  23 2.46
  18  0.328  0.238  0.430-  20 2.33  29 2.41   4 2.45
  19  0.696  0.483  0.177-  17 2.30   1 2.31  24 2.36
  20  0.562  0.289  0.327-   2 2.30  18 2.33  23 2.36
  21  0.324  0.315  0.980-  26 2.34   7 2.35  23 2.37  30 2.38
  22  0.431  0.436  0.464-  25 2.31  29 2.35   8 2.35  24 2.38
  23  0.540  0.339  0.130-  20 2.36  21 2.37   5 2.38  17 2.46
  24  0.708  0.424  0.366-  19 2.36  22 2.38   6 2.40   2 2.49
  25  0.393  0.520  0.610-  33 1.71  11 2.28  22 2.31  27 2.56
  26  0.269  0.237  0.821-  21 2.34  12 2.37  28 2.41  15 2.48
  27  0.694  0.561  0.680-  34 1.68  33 1.75   9 2.32  25 2.56  32 2.57
  28  0.539  0.217  0.713-  10 2.37  26 2.41  31 2.52
  29  0.394  0.331  0.567-  15 2.34  22 2.35  31 2.40  18 2.41
  30  0.374  0.427  0.910-  16 2.29  17 2.30  32 2.33  21 2.38
  31  0.649  0.337  0.695-  13 2.29  32 2.37  29 2.40  10 2.47  28 2.52
  32  0.612  0.447  0.780-  30 2.33  31 2.37  14 2.42  27 2.57
  33  0.524  0.589  0.583-  25 1.71  27 1.75
  34  0.677  0.608  0.809-  36 0.95  27 1.68
  35  0.447  0.613  0.722-
  36  0.746  0.600  0.881-  34 0.95
 
  LATTYP: Found a simple orthorhombic cell.
 ALAT       =     7.6631000000
 B/A-ratio  =     1.4142135689
 C/A-ratio  =     2.5659458966
  
  Lattice vectors:
  
 A1 = (  -7.6631000000,   0.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  10.8372600000)
 A3 = (   0.0000000000,  19.6631000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple orthorhombic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of  8 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple orthorhombic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of  8 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple orthorhombic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of  8 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    1632.9616

  direct lattice vectors                    reciprocal lattice vectors
     7.663100000  0.000000000  0.000000000     0.130495491  0.000000000  0.000000000
     0.000000000 19.663100000  0.000000000     0.000000000  0.050856681  0.000000000
     0.000000000  0.000000000 10.837260000     0.000000000  0.000000000  0.092274246

  length of vectors
     7.663100000 19.663100000 10.837260000     0.130495491  0.050856681  0.092274246

  position of ions in fractional coordinates (direct lattice)
     0.913450270  0.536059900  0.064827520
     0.844539580  0.309413070  0.385931150
     0.117114270  0.458643390  0.160946210
     0.131292930  0.312165930  0.312661670
     0.803286110  0.332761990  0.012950420
     0.934059830  0.457890630  0.506953890
     0.083585720  0.341717250  0.104940290
     0.156725510  0.428582640  0.367764180
     0.943192210  0.574532580  0.560121440
     0.762523710  0.255107430  0.847055440
     0.149988150  0.547412000  0.720720560
     0.000757010  0.226936440  0.713513160
     0.905498430  0.344042660  0.586013840
     0.847626710  0.442528530  0.928830970
     0.162915160  0.338099690  0.707671160
     0.108514290  0.440850040  0.815417410
     0.418828910  0.454608460  0.113571990
     0.328364590  0.238398440  0.429933010
     0.696430880  0.482677720  0.177347590
     0.561559730  0.288765810  0.326893890
     0.324245580  0.314597160  0.980049810
     0.431245240  0.435611010  0.463877470
     0.540404280  0.339308220  0.130036240
     0.707864330  0.423559730  0.366343590
     0.392531750  0.519971530  0.609802380
     0.268577840  0.236669510  0.821083780
     0.693756160  0.561373990  0.679770640
     0.538957170  0.217190340  0.712519500
     0.394063080  0.331311400  0.566719570
     0.374069690  0.427327440  0.909606320
     0.649266910  0.337342520  0.694881660
     0.611964170  0.447331010  0.780422530
     0.524290310  0.588617240  0.582901060
     0.676854240  0.608254320  0.809219190
     0.446753910  0.613464320  0.721542450
     0.745964860  0.600421650  0.880528410

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34
                35          35
                36          36

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    1    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.065247746  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.050856681  0.000000000     0.000000000  1.000000000  0.000000000
     0.000000000  0.000000000  0.046137123     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.065247746  0.050856681  0.046137123

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      4 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.000000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.065248  0.000000  0.000000      1.000000
  0.000000  0.000000  0.046137      1.000000
  0.065248  0.000000  0.046137      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      4   k-points in BZ     NKDIM =      4   number of bands    NBANDS=    108
   number of dos      NEDOS =    301   number of ions     NIONS =     36
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 207360
   max r-space proj   IRMAX =   1449   max aug-charges    IRDMAX=   4445
   dimension x,y,z NGX =    40 NGY =   96 NGZ =   54
   dimension x,y,z NGXF=    80 NGYF=  192 NGZF=  108
   support grid    NGXF=    80 NGYF=  192 NGZF=  108
   ions per type =              32   2   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.68,  8.12,  8.28 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  17.36, 16.23, 16.57 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      2    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  12.50 32.07 17.67*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  605.4 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.134E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  6.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =     142.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.23E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      45.36       306.10
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.725291  1.370601  7.157304  0.526047
  Thomas-Fermi vector in A             =   1.815976
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           37
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     1632.96
      direct lattice vectors                 reciprocal lattice vectors
     7.663100000  0.000000000  0.000000000     0.130495491  0.000000000  0.000000000
     0.000000000 19.663100000  0.000000000     0.000000000  0.050856681  0.000000000
     0.000000000  0.000000000 10.837260000     0.000000000  0.000000000  0.092274246

  length of vectors
     7.663100000 19.663100000 10.837260000     0.130495491  0.050856681  0.092274246


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.250
   0.06524775  0.00000000  0.00000000       0.250
   0.00000000  0.00000000  0.04613712       0.250
   0.06524775  0.00000000  0.04613712       0.250
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.250
   0.50000000  0.00000000  0.00000000       0.250
   0.00000000  0.00000000  0.50000000       0.250
   0.50000000  0.00000000  0.50000000       0.250
 
 position of ions in fractional coordinates (direct lattice) 
   0.91345027  0.53605990  0.06482752
   0.84453958  0.30941307  0.38593115
   0.11711427  0.45864339  0.16094621
   0.13129293  0.31216593  0.31266167
   0.80328611  0.33276199  0.01295042
   0.93405983  0.45789063  0.50695389
   0.08358572  0.34171725  0.10494029
   0.15672551  0.42858264  0.36776418
   0.94319221  0.57453258  0.56012144
   0.76252371  0.25510743  0.84705544
   0.14998815  0.54741200  0.72072056
   0.00075701  0.22693644  0.71351316
   0.90549843  0.34404266  0.58601384
   0.84762671  0.44252853  0.92883097
   0.16291516  0.33809969  0.70767116
   0.10851429  0.44085004  0.81541741
   0.41882891  0.45460846  0.11357199
   0.32836459  0.23839844  0.42993301
   0.69643088  0.48267772  0.17734759
   0.56155973  0.28876581  0.32689389
   0.32424558  0.31459716  0.98004981
   0.43124524  0.43561101  0.46387747
   0.54040428  0.33930822  0.13003624
   0.70786433  0.42355973  0.36634359
   0.39253175  0.51997153  0.60980238
   0.26857784  0.23666951  0.82108378
   0.69375616  0.56137399  0.67977064
   0.53895717  0.21719034  0.71251950
   0.39406308  0.33131140  0.56671957
   0.37406969  0.42732744  0.90960632
   0.64926691  0.33734252  0.69488166
   0.61196417  0.44733101  0.78042253
   0.52429031  0.58861724  0.58290106
   0.67685424  0.60825432  0.80921919
   0.44675391  0.61346432  0.72154245
   0.74596486  0.60042165  0.88052841
 
 position of ions in cartesian coordinates  (Angst):
   6.99986076 10.54059942  0.70255269
   6.47179126  6.08402014  4.18243621
   0.89745836  9.01835084  1.74421592
   1.00611085  6.13814990  3.38839581
   6.15566179  6.54313229  0.14034707
   7.15779388  9.00354925  5.49399111
   0.64052573  6.71922046  1.13726521
   1.20100326  8.42726331  3.98555604
   7.22777622 11.29709157  6.07018168
   5.84329544  5.01620291  9.17976004
   1.14937419 10.76381690  7.81063610
   0.00580104  4.46227391  7.73252763
   6.93892502  6.76494523  6.35078435
   6.49544824  8.70148274 10.06598272
   1.24843516  6.64808801  7.66921636
   0.83155586  8.66847842  8.83689048
   3.20952782  8.93901161  1.23080918
   2.51629069  4.68765237  4.65929581
   5.33681948  9.49094028  1.92196194
   4.30328837  5.67803100  3.54263408
   2.48472630  6.18595542 10.62105460
   3.30467540  8.56546285  5.02716075
   4.14117204  6.67185146  1.40923654
   5.42443515  8.32849733  3.97016073
   3.00801005 10.22425219  6.60858694
   2.05813885  4.65365624  8.89829841
   5.31632283 11.03835290  7.36685117
   4.13008269  4.27063537  7.72175908
   3.01974479  6.51460919  6.14168733
   2.86653344  8.40258219  9.85764019
   4.97539726  6.63319971  7.53061322
   4.68954263  8.79591438  8.45764187
   4.01768907 11.57403965  6.31705034
   5.18680173 11.96016552  8.76971876
   3.42351989 12.06261027  7.81954313
   5.71640332 11.80615095  9.54251532
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   29735
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   29568
 k-point  3 :   0.0000 0.0000 0.5000  plane waves:   29692
 k-point  4 :   0.5000 0.0000 0.5000  plane waves:   29632

 maximum and minimum number of plane-waves per node :     29735    29568

 maximum number of plane-waves:     29735
 maximum index in each direction: 
   IXMAX=   12   IYMAX=   32   IZMAX=   17
   IXMIN=  -12   IYMIN=  -32   IZMIN=  -18

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    50 to avoid them
 WARNING: aliasing errors must be expected set NGY to   140 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    72 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   258500. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       3293. kBytes
   fftplans  :      19938. kBytes
   grid      :      66726. kBytes
   one-center:        221. kBytes
   wavefun   :     138322. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 25   NGY = 65   NGZ = 35
  (NGX  = 80   NGY  =192   NGZ  =108)
  gives a total of  56875 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron     142.0000000 magnetization      36.0000000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1364
 Maximum index for augmentation-charges         1478 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.151
 Maximum number of real-space cells 4x 2x 3
 Maximum number of reciprocal cells 2x 4x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  1728
 total energy-change (2. order) : 0.6663722E+03  (-0.4129856E+04)
 number of electron     142.0000000 magnetization      36.0000000
 augmentation part      142.0000000 magnetization      36.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13126.17074864
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -235.57803010
  PAW double counting   =      3513.49417245    -2953.91778466
  entropy T*S    EENTRO =        -0.00495227
  eigenvalues    EBANDS =      -205.28908835
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       666.37216159 eV

  energy without entropy =      666.37711387  energy(sigma->0) =      666.37381235


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  2322
 total energy-change (2. order) :-0.7499411E+03  (-0.7123396E+03)
 number of electron     142.0000000 magnetization      36.0000000
 augmentation part      142.0000000 magnetization      36.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13126.17074864
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -235.57803010
  PAW double counting   =      3513.49417245    -2953.91778466
  entropy T*S    EENTRO =        -0.00547358
  eigenvalues    EBANDS =      -955.22964881
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -83.56892017 eV

  energy without entropy =      -83.56344659  energy(sigma->0) =      -83.56709564


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  2286
 total energy-change (2. order) :-0.8957859E+02  (-0.8735295E+02)
 number of electron     142.0000000 magnetization      36.0000000
 augmentation part      142.0000000 magnetization      36.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13126.17074864
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -235.57803010
  PAW double counting   =      3513.49417245    -2953.91778466
  entropy T*S    EENTRO =         0.01383573
  eigenvalues    EBANDS =     -1044.82755229
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -173.14751434 eV

  energy without entropy =     -173.16135008  energy(sigma->0) =     -173.15212625


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  2259
 total energy-change (2. order) :-0.3382086E+01  (-0.3355867E+01)
 number of electron     142.0000000 magnetization      36.0000000
 augmentation part      142.0000000 magnetization      36.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13126.17074864
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -235.57803010
  PAW double counting   =      3513.49417245    -2953.91778466
  entropy T*S    EENTRO =         0.01686245
  eigenvalues    EBANDS =     -1048.21266522
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -176.52960055 eV

  energy without entropy =     -176.54646301  energy(sigma->0) =     -176.53522137


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :  2502
 total energy-change (2. order) :-0.1551672E+00  (-0.1550710E+00)
 number of electron     142.0000031 magnetization      31.1458703
 augmentation part       -6.1084658 magnetization      27.9266763

 Broyden mixing:
  rms(total) = 0.27719E+01    rms(broyden)= 0.27714E+01
  rms(prec ) = 0.28861E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13126.17074864
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -235.57803010
  PAW double counting   =      3513.49417245    -2953.91778466
  entropy T*S    EENTRO =         0.01678268
  eigenvalues    EBANDS =     -1048.36775263
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -176.68476773 eV

  energy without entropy =     -176.70155041  energy(sigma->0) =     -176.69036196


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  1935
 total energy-change (2. order) : 0.2936098E+02  (-0.7247014E+01)
 number of electron     142.0000025 magnetization      26.2012234
 augmentation part       -6.3291183 magnetization      23.0745955

 Broyden mixing:
  rms(total) = 0.16905E+01    rms(broyden)= 0.16902E+01
  rms(prec ) = 0.17594E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9773
  0.9773

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13229.73108335
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -213.00985117
  PAW double counting   =      6657.06198306    -6099.55771993
  entropy T*S    EENTRO =        -0.02573923
  eigenvalues    EBANDS =      -935.89997478
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -147.32379224 eV

  energy without entropy =     -147.29805301  energy(sigma->0) =     -147.31521250


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  2088
 total energy-change (2. order) : 0.8331540E+00  (-0.1864522E+01)
 number of electron     142.0000026 magnetization      22.3127637
 augmentation part       -6.4348547 magnetization      18.6675621

 Broyden mixing:
  rms(total) = 0.11460E+01    rms(broyden)= 0.11458E+01
  rms(prec ) = 0.11851E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9777
  1.2323  0.7232

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13291.67769787
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -209.87034551
  PAW double counting   =     10035.17444417    -9478.74388569
  entropy T*S    EENTRO =         0.00035077
  eigenvalues    EBANDS =      -875.21209725
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -146.49063822 eV

  energy without entropy =     -146.49098899  energy(sigma->0) =     -146.49075514


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  2016
 total energy-change (2. order) :-0.2798198E+01  (-0.9404716E+00)
 number of electron     142.0000029 magnetization      17.3941492
 augmentation part       -6.3407677 magnetization      14.1718354

 Broyden mixing:
  rms(total) = 0.79619E+00    rms(broyden)= 0.79613E+00
  rms(prec ) = 0.81109E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1997
  1.9698  0.9972  0.6322

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13320.48037538
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -211.32446933
  PAW double counting   =     11972.55482288   -11416.43807099
  entropy T*S    EENTRO =        -0.00860443
  eigenvalues    EBANDS =      -847.43073194
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -149.28883603 eV

  energy without entropy =     -149.28023160  energy(sigma->0) =     -149.28596789


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  2448
 total energy-change (2. order) :-0.1874444E+03  (-0.1770141E+03)
 number of electron     141.9999983 magnetization      17.3930729
 augmentation part       -6.3658458 magnetization      15.9460009

 Broyden mixing:
  rms(total) = 0.59018E+01    rms(broyden)= 0.56800E+01
  rms(prec ) = 0.59119E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9122
  2.0067  1.0037  0.6210  0.0174

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13353.94300761
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -211.80617347
  PAW double counting   =     13715.50401708   -13159.68192599
  entropy T*S    EENTRO =         0.00060840
  eigenvalues    EBANDS =     -1000.64531893
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -336.73320735 eV

  energy without entropy =     -336.73381576  energy(sigma->0) =     -336.73341015


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :  2259
 total energy-change (2. order) : 0.1928386E+03  (-0.2376021E+03)
 number of electron     142.0000023 magnetization      15.3862753
 augmentation part       -6.3317804 magnetization      13.3747766

 Broyden mixing:
  rms(total) = 0.15139E+01    rms(broyden)= 0.80185E+00
  rms(prec ) = 0.84798E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8508
  2.2969  1.0097  0.5245  0.4224  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13354.33046470
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -204.51407858
  PAW double counting   =     13716.24382899   -13160.37792596
  entropy T*S    EENTRO =         0.01658176
  eigenvalues    EBANDS =      -814.77111857
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -143.89458390 eV

  energy without entropy =     -143.91116565  energy(sigma->0) =     -143.90011115


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  2187
 total energy-change (2. order) :-0.9123560E+01  (-0.5450824E+00)
 number of electron     142.0000029 magnetization      11.9514640
 augmentation part       -6.2517813 magnetization       9.3272680

 Broyden mixing:
  rms(total) = 0.58564E+00    rms(broyden)= 0.52679E+00
  rms(prec ) = 0.53798E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9160
  2.6161  0.9598  0.9598  0.5967  0.3634  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13364.14079128
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -211.05986403
  PAW double counting   =     14244.29577461   -13688.58263427
  entropy T*S    EENTRO =        -0.00521165
  eigenvalues    EBANDS =      -807.36401023
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -153.01814368 eV

  energy without entropy =     -153.01293203  energy(sigma->0) =     -153.01640646


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  2007
 total energy-change (2. order) :-0.8603663E+01  (-0.2790491E+00)
 number of electron     142.0000028 magnetization       7.2710456
 augmentation part       -6.2409066 magnetization       5.0460868

 Broyden mixing:
  rms(total) = 0.41389E+00    rms(broyden)= 0.41060E+00
  rms(prec ) = 0.42514E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0358
  3.0416  1.5400  0.9855  0.6481  0.6481  0.3873  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13381.44394305
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -215.99451652
  PAW double counting   =     14549.15800003   -13993.35560669
  entropy T*S    EENTRO =         0.01430528
  eigenvalues    EBANDS =      -793.83863878
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -161.62180657 eV

  energy without entropy =     -161.63611184  energy(sigma->0) =     -161.62657499


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  1998
 total energy-change (2. order) :-0.8910118E+01  (-0.6345879E+00)
 number of electron     142.0000027 magnetization       4.3896701
 augmentation part       -6.2627120 magnetization       2.6626848

 Broyden mixing:
  rms(total) = 0.26133E+00    rms(broyden)= 0.26107E+00
  rms(prec ) = 0.27774E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2502
  4.4029  2.2297  0.8583  0.8583  0.6354  0.6354  0.3817  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13389.28250495
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -221.45538485
  PAW double counting   =     14280.52235150   -13724.41448444
  entropy T*S    EENTRO =         0.01545638
  eigenvalues    EBANDS =      -789.75595113
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -170.53192431 eV

  energy without entropy =     -170.54738070  energy(sigma->0) =     -170.53707644


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  2007
 total energy-change (2. order) :-0.5417840E+01  (-0.4096736E+00)
 number of electron     142.0000025 magnetization       3.8336761
 augmentation part       -6.2864918 magnetization       3.2746980

 Broyden mixing:
  rms(total) = 0.26900E+00    rms(broyden)= 0.26881E+00
  rms(prec ) = 0.28461E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1392
  4.4265  2.2659  0.7975  0.7425  0.7425  0.6197  0.3888  0.2689  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13385.79866495
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -224.90405440
  PAW double counting   =     13931.01841083   -13374.81858869
  entropy T*S    EENTRO =        -0.01634467
  eigenvalues    EBANDS =      -795.26911605
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -175.94976476 eV

  energy without entropy =     -175.93342009  energy(sigma->0) =     -175.94431654


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :  2349
 total energy-change (2. order) :-0.8102552E+00  (-0.5761655E-01)
 number of electron     142.0000025 magnetization       2.4741573
 augmentation part       -6.2776790 magnetization       2.3305663

 Broyden mixing:
  rms(total) = 0.25659E+00    rms(broyden)= 0.25654E+00
  rms(prec ) = 0.27062E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2192
  4.7231  2.3815  0.8210  0.8210  0.9201  0.9201  0.6120  0.6120  0.3812  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13381.88341503
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -225.56124137
  PAW double counting   =     13798.05116034   -13241.76130445
  entropy T*S    EENTRO =         0.01078435
  eigenvalues    EBANDS =      -799.45459701
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -176.76002000 eV

  energy without entropy =     -176.77080435  energy(sigma->0) =     -176.76361478


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  1944
 total energy-change (2. order) :-0.1268545E+01  (-0.1031652E+00)
 number of electron     142.0000025 magnetization       1.0172304
 augmentation part       -6.2680608 magnetization       1.0623909

 Broyden mixing:
  rms(total) = 0.16676E+00    rms(broyden)= 0.16675E+00
  rms(prec ) = 0.17777E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3872
  6.2318  2.4899  1.1095  1.1095  1.0329  1.0329  0.3801  0.7004  0.5858  0.5858
  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13373.46761450
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -226.54598367
  PAW double counting   =     13524.64588033   -12968.27787353
  entropy T*S    EENTRO =         0.03798997
  eigenvalues    EBANDS =      -808.25955708
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -178.02856531 eV

  energy without entropy =     -178.06655528  energy(sigma->0) =     -178.04122864


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  2097
 total energy-change (2. order) :-0.1033273E+01  (-0.8781682E-01)
 number of electron     142.0000025 magnetization       0.9127456
 augmentation part       -6.2521727 magnetization       0.9444659

 Broyden mixing:
  rms(total) = 0.78021E-01    rms(broyden)= 0.77969E-01
  rms(prec ) = 0.88652E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3915
  6.7151  2.4950  1.0267  1.0267  1.1731  1.1731  0.3805  0.7564  0.7564  0.5975
  0.5975  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13364.17486257
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -227.50406291
  PAW double counting   =     13398.77568090   -12842.38184740
  entropy T*S    EENTRO =         0.03223289
  eigenvalues    EBANDS =      -817.64757251
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.06183844 eV

  energy without entropy =     -179.09407132  energy(sigma->0) =     -179.07258273


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  1836
 total energy-change (2. order) : 0.7042140E+00  (-0.8126147E+00)
 number of electron     142.0000026 magnetization       0.8443444
 augmentation part       -6.2334028 magnetization       0.8471442

 Broyden mixing:
  rms(total) = 0.16711E+00    rms(broyden)= 0.16695E+00
  rms(prec ) = 0.18619E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3145
  6.8237  2.3834  1.0591  1.0591  1.0426  1.0426  0.9364  0.9364  0.5730  0.5730
  0.3801  0.2782  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13359.97946595
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -227.91504239
  PAW double counting   =     13386.83599948   -12830.45337876
  entropy T*S    EENTRO =         0.03210139
  eigenvalues    EBANDS =      -820.71643137
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -178.35762442 eV

  energy without entropy =     -178.38972582  energy(sigma->0) =     -178.36832489


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  2007
 total energy-change (2. order) :-0.1171476E+01  (-0.2008327E+00)
 number of electron     142.0000026 magnetization       0.6158787
 augmentation part       -6.2420819 magnetization       0.6436037

 Broyden mixing:
  rms(total) = 0.69709E-01    rms(broyden)= 0.69491E-01
  rms(prec ) = 0.78404E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3463
  7.1253  2.3686  1.8808  1.1605  1.1605  0.8902  0.8902  0.9391  0.6421  0.5919
  0.5919  0.3800  0.2269  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13359.43804954
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -227.98547859
  PAW double counting   =     13442.23751850   -12885.87910163
  entropy T*S    EENTRO =         0.03319923
  eigenvalues    EBANDS =      -822.33578177
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.52910064 eV

  energy without entropy =     -179.56229986  energy(sigma->0) =     -179.54016705


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :  2106
 total energy-change (2. order) :-0.1617911E+00  (-0.3281184E-01)
 number of electron     142.0000025 magnetization       0.4248192
 augmentation part       -6.2495547 magnetization       0.4509881

 Broyden mixing:
  rms(total) = 0.54106E-01    rms(broyden)= 0.54074E-01
  rms(prec ) = 0.60417E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3359
  7.2612  2.3448  2.3448  1.1616  1.1616  0.9412  0.9412  0.8744  0.6496  0.6075
  0.6075  0.3802  0.5188  0.2441  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13353.50013613
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.23170644
  PAW double counting   =     13426.51554513   -12870.17046650
  entropy T*S    EENTRO =         0.03271271
  eigenvalues    EBANDS =      -828.17543367
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.69089174 eV

  energy without entropy =     -179.72360445  energy(sigma->0) =     -179.70179597


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  2196
 total energy-change (2. order) :-0.1093060E+00  (-0.2801255E-02)
 number of electron     142.0000025 magnetization       0.2363463
 augmentation part       -6.2536965 magnetization       0.2647176

 Broyden mixing:
  rms(total) = 0.46926E-01    rms(broyden)= 0.46923E-01
  rms(prec ) = 0.51163E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3578
  7.3858  2.6015  2.6015  1.1481  1.1481  0.9687  0.9687  0.9278  0.7699  0.7699
  0.6481  0.5835  0.5835  0.3801  0.2387  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13348.84078964
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.43649531
  PAW double counting   =     13427.97147457   -12871.63401448
  entropy T*S    EENTRO =         0.03258552
  eigenvalues    EBANDS =      -832.73155153
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.80019770 eV

  energy without entropy =     -179.83278322  energy(sigma->0) =     -179.81105954


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  1953
 total energy-change (2. order) :-0.1301767E+00  (-0.1496487E-02)
 number of electron     142.0000025 magnetization       0.1780568
 augmentation part       -6.2549620 magnetization       0.2096009

 Broyden mixing:
  rms(total) = 0.40548E-01    rms(broyden)= 0.40547E-01
  rms(prec ) = 0.43435E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3847
  7.3764  2.8783  2.6942  1.6967  1.1444  1.1444  1.0142  0.8532  0.8532  0.7380
  0.7380  0.3801  0.5884  0.5884  0.6117  0.2393  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13344.46357182
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.65795107
  PAW double counting   =     13416.69694080   -12860.36266826
  entropy T*S    EENTRO =         0.03237015
  eigenvalues    EBANDS =      -837.01408740
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.93037443 eV

  energy without entropy =     -179.96274458  energy(sigma->0) =     -179.94116448


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  2070
 total energy-change (2. order) :-0.1292845E+00  (-0.8700677E-03)
 number of electron     142.0000025 magnetization       0.1069370
 augmentation part       -6.2551593 magnetization       0.1375653

 Broyden mixing:
  rms(total) = 0.40068E-01    rms(broyden)= 0.40065E-01
  rms(prec ) = 0.42522E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4279
  7.3356  3.9947  2.3982  2.0423  1.1709  1.1709  1.1360  0.9123  0.9123  0.7520
  0.7520  0.3801  0.7174  0.5835  0.5835  0.6217  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13341.96456807
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.81978670
  PAW double counting   =     13417.26171037   -12860.93352214
  entropy T*S    EENTRO =         0.03234723
  eigenvalues    EBANDS =      -839.47443279
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.05965894 eV

  energy without entropy =     -180.09200616  energy(sigma->0) =     -180.07044135


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  2142
 total energy-change (2. order) :-0.1021622E+00  (-0.7848548E-03)
 number of electron     142.0000025 magnetization       0.0671879
 augmentation part       -6.2549354 magnetization       0.0955150

 Broyden mixing:
  rms(total) = 0.37422E-01    rms(broyden)= 0.37418E-01
  rms(prec ) = 0.39656E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4477
  7.3275  4.5654  2.3269  2.3269  1.1608  1.1608  1.3081  0.9281  0.9281  0.8140
  0.8140  0.3801  0.7863  0.5889  0.5889  0.6313  0.6313  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13338.93956655
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.97871753
  PAW double counting   =     13406.56354702   -12850.24056100
  entropy T*S    EENTRO =         0.03223229
  eigenvalues    EBANDS =      -842.43734856
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.16182117 eV

  energy without entropy =     -180.19405346  energy(sigma->0) =     -180.17256527


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :  2241
 total energy-change (2. order) :-0.3492151E-01  (-0.2359630E-03)
 number of electron     142.0000025 magnetization       0.0385521
 augmentation part       -6.2534668 magnetization       0.0660550

 Broyden mixing:
  rms(total) = 0.37116E-01    rms(broyden)= 0.37114E-01
  rms(prec ) = 0.39250E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5003
  7.2620  5.3414  2.5830  2.5830  1.5498  1.1746  1.1746  1.0390  1.0390  0.8484
  0.8484  0.8106  0.3801  0.6740  0.6740  0.5806  0.5806  0.6244  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.99094890
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.02276720
  PAW double counting   =     13399.11664521   -12842.79345648
  entropy T*S    EENTRO =         0.03216703
  eigenvalues    EBANDS =      -843.37697552
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.19674269 eV

  energy without entropy =     -180.22890972  energy(sigma->0) =     -180.20746503


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  2142
 total energy-change (2. order) :-0.4114492E-01  (-0.3055696E-03)
 number of electron     142.0000025 magnetization       0.0244019
 augmentation part       -6.2537767 magnetization       0.0504895

 Broyden mixing:
  rms(total) = 0.39078E-01    rms(broyden)= 0.39075E-01
  rms(prec ) = 0.41094E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5134
  6.9780  6.4619  2.6424  2.6424  1.8578  1.1713  1.1713  1.0254  1.0254  0.8597
  0.8597  0.3801  0.7548  0.6679  0.6679  0.5975  0.5975  0.5908  0.5908  0.2391
  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.05206669
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.05248638
  PAW double counting   =     13396.61587286   -12840.29909939
  entropy T*S    EENTRO =         0.03211324
  eigenvalues    EBANDS =      -844.32081440
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.23788760 eV

  energy without entropy =     -180.27000084  energy(sigma->0) =     -180.24859202


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  2241
 total energy-change (2. order) :-0.1415541E-01  (-0.1417321E-03)
 number of electron     142.0000025 magnetization       0.0157186
 augmentation part       -6.2541336 magnetization       0.0404620

 Broyden mixing:
  rms(total) = 0.41444E-01    rms(broyden)= 0.41442E-01
  rms(prec ) = 0.43538E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5138
  6.9661  6.9661  2.7299  2.7299  1.9086  1.1735  1.1735  1.0435  1.0435  0.8698
  0.8698  0.6934  0.6934  0.3801  0.7090  0.7090  0.5775  0.5775  0.6248  0.6248
  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.44450746
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.06740830
  PAW double counting   =     13395.28205895   -12838.96572572
  entropy T*S    EENTRO =         0.03207263
  eigenvalues    EBANDS =      -844.92712628
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.25204301 eV

  energy without entropy =     -180.28411564  energy(sigma->0) =     -180.26273389


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :  2340
 total energy-change (2. order) :-0.1225143E-01  (-0.5516030E-04)
 number of electron     142.0000025 magnetization       0.0107954
 augmentation part       -6.2538746 magnetization       0.0345586

 Broyden mixing:
  rms(total) = 0.42561E-01    rms(broyden)= 0.42560E-01
  rms(prec ) = 0.44749E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6008
  7.6043  7.6043  3.0328  3.0328  1.8228  1.1688  1.1688  1.2544  1.2544  1.0574
  1.0574  0.8221  0.8221  0.3801  0.7337  0.7337  0.5835  0.5835  0.6366  0.6366
  0.5878  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.09442137
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07703310
  PAW double counting   =     13390.67966883   -12834.36730573
  entropy T*S    EENTRO =         0.03204191
  eigenvalues    EBANDS =      -845.27583813
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.26429444 eV

  energy without entropy =     -180.29633634  energy(sigma->0) =     -180.27497507


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :  2187
 total energy-change (2. order) :-0.1110217E-01  (-0.1881468E-03)
 number of electron     142.0000025 magnetization       0.0117562
 augmentation part       -6.2537833 magnetization       0.0335360

 Broyden mixing:
  rms(total) = 0.44883E-01    rms(broyden)= 0.44880E-01
  rms(prec ) = 0.47132E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6429
  8.0839  8.0839  3.2070  3.2070  1.8607  1.5568  1.1730  1.1730  1.4069  1.0245
  1.0245  0.8325  0.8325  0.8155  0.7239  0.7239  0.3801  0.6381  0.6381  0.5863
  0.5863  0.6311  0.2391  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.65791496
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08676783
  PAW double counting   =     13385.15368828   -12828.84128956
  entropy T*S    EENTRO =         0.03199972
  eigenvalues    EBANDS =      -845.71370541
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.27539660 eV

  energy without entropy =     -180.30739632  energy(sigma->0) =     -180.28606317


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :  2025
 total energy-change (2. order) :-0.4856220E+00  (-0.2767690E-01)
 number of electron     142.0000026 magnetization       0.0125441
 augmentation part       -6.2398296 magnetization       0.0171870

 Broyden mixing:
  rms(total) = 0.20624E+00    rms(broyden)= 0.20614E+00
  rms(prec ) = 0.22356E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5693
  8.0485  8.0485  3.1233  3.1233  1.9866  1.4825  1.1737  1.1737  1.2936  1.0156
  1.0156  0.8350  0.8350  0.9168  0.7304  0.7304  0.3801  0.6421  0.6258  0.6258
  0.5876  0.5876  0.2391  0.0004  0.0124

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.52429294
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08834521
  PAW double counting   =     13384.94974996   -12828.64061631
  entropy T*S    EENTRO =         0.03336010
  eigenvalues    EBANDS =      -846.32946732
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.76101855 eV

  energy without entropy =     -180.79437865  energy(sigma->0) =     -180.77213859


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :  1809
 total energy-change (2. order) : 0.1404451E+01  (-0.1440446E+01)
 number of electron     142.0000025 magnetization       0.0085768
 augmentation part       -6.2576971 magnetization       0.0168030

 Broyden mixing:
  rms(total) = 0.16190E+00    rms(broyden)= 0.16160E+00
  rms(prec ) = 0.17881E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5076
  7.9520  7.9520  3.1422  3.1422  2.1078  1.1748  1.1748  1.3766  1.3766  1.0150
  1.0150  0.8240  0.8240  0.9092  0.3801  0.7203  0.7203  0.6529  0.6181  0.6181
  0.5927  0.5927  0.2391  0.0004  0.0717  0.0058

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.53213551
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08881270
  PAW double counting   =     13385.44354608   -12829.14085892
  entropy T*S    EENTRO =         0.03182687
  eigenvalues    EBANDS =      -844.90872656
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.35656757 eV

  energy without entropy =     -179.38839444  energy(sigma->0) =     -179.36717653


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :  1800
 total energy-change (2. order) :-0.8989691E+00  (-0.1006424E+00)
 number of electron     142.0000025 magnetization       0.0034137
 augmentation part       -6.2542840 magnetization       0.0249345

 Broyden mixing:
  rms(total) = 0.48591E-01    rms(broyden)= 0.48415E-01
  rms(prec ) = 0.50736E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4590
  7.9719  7.9719  3.1619  3.1619  2.1163  1.3619  1.3619  1.1742  1.1742  1.0185
  1.0185  0.8249  0.8249  0.8912  0.7279  0.7279  0.6538  0.6234  0.6234  0.5916
  0.5916  0.3801  0.2391  0.0972  0.0972  0.0004  0.0054

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.62477709
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08410572
  PAW double counting   =     13386.65654540   -12830.34920874
  entropy T*S    EENTRO =         0.03201084
  eigenvalues    EBANDS =      -845.72459455
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.25553670 eV

  energy without entropy =     -180.28754754  energy(sigma->0) =     -180.26620698


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :  1827
 total energy-change (2. order) : 0.1348549E+01  (-0.2366827E+01)
 number of electron     142.0000026 magnetization       0.0029606
 augmentation part       -6.2531604 magnetization      -0.0043565

 Broyden mixing:
  rms(total) = 0.21389E+00    rms(broyden)= 0.21377E+00
  rms(prec ) = 0.23378E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4084
  7.9665  7.9665  3.1587  3.1587  2.1148  1.3610  1.3610  1.1744  1.1744  1.0210
  1.0210  0.8248  0.8248  0.8833  0.7295  0.7295  0.6555  0.6246  0.6246  0.5915
  0.5915  0.3801  0.2391  0.1001  0.1001  0.0535  0.0004  0.0054

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.55744741
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08650307
  PAW double counting   =     13383.71326123   -12827.38491754
  entropy T*S    EENTRO =         0.03099998
  eigenvalues    EBANDS =      -844.46097403
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -178.90698768 eV

  energy without entropy =     -178.93798766  energy(sigma->0) =     -178.91732101


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :  1917
 total energy-change (2. order) :-0.2291446E+01  (-0.5090337E+00)
 number of electron     142.0000027 magnetization       0.0030357
 augmentation part       -6.2288128 magnetization       0.0701611

 Broyden mixing:
  rms(total) = 0.25717E+00    rms(broyden)= 0.25695E+00
  rms(prec ) = 0.29798E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3478
  7.8704  7.8704  3.0590  3.0590  2.2569  1.1721  1.1721  1.2620  1.2620  1.0038
  1.0038  0.9300  0.8208  0.8208  0.7218  0.7218  0.6554  0.6554  0.5886  0.5886
  0.6140  0.3801  0.2391  0.1075  0.1075  0.0695  0.0695  0.0004  0.0054

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.57238725
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08403505
  PAW double counting   =     13384.30430987   -12827.84160329
  entropy T*S    EENTRO =         0.04195451
  eigenvalues    EBANDS =      -846.88526557
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -181.19843361 eV

  energy without entropy =     -181.24038812  energy(sigma->0) =     -181.21241845


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :  1944
 total energy-change (2. order) :-0.1426598E+01  (-0.1688738E+00)
 number of electron     142.0000029 magnetization       0.0030714
 augmentation part       -6.2025393 magnetization       0.0097898

 Broyden mixing:
  rms(total) = 0.42681E+00    rms(broyden)= 0.42676E+00
  rms(prec ) = 0.50276E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3056
  7.8745  7.8745  3.0566  3.0566  2.2474  1.1726  1.1726  1.2556  1.2556  1.0020
  1.0020  0.9555  0.8216  0.8216  0.7288  0.7288  0.6453  0.6453  0.5895  0.5895
  0.6182  0.3801  0.2391  0.1473  0.1473  0.1035  0.0320  0.0054  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.57066673
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08532655
  PAW double counting   =     13384.47188599   -12827.90548016
  entropy T*S    EENTRO =         0.03962445
  eigenvalues    EBANDS =      -848.41366185
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -182.62503168 eV

  energy without entropy =     -182.66465613  energy(sigma->0) =     -182.63823983


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :  2655
 total energy-change (2. order) :-0.5887871E+03  (-0.5635737E+03)
 number of electron     141.9999939 magnetization      -0.0003778
 augmentation part       -6.1952682 magnetization      -1.1241814

 Broyden mixing:
  rms(total) = 0.90243E+01    rms(broyden)= 0.87211E+01
  rms(prec ) = 0.95548E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2499
  7.7854  7.7854  3.0256  3.0256  2.2281  1.1712  1.1712  1.2226  1.2226  0.9930
  0.9930  0.8173  0.8173  0.9141  0.6899  0.6899  0.6667  0.6667  0.6175  0.5891
  0.5891  0.3801  0.2391  0.1505  0.1505  0.0993  0.0412  0.0054  0.0004  0.0001
  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.56606581
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.08460158
  PAW double counting   =     13385.09700706   -12828.16210553
  entropy T*S    EENTRO =        -0.02539781
  eigenvalues    EBANDS =     -1437.50959655
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -771.41216704 eV

  energy without entropy =     -771.38676924  energy(sigma->0) =     -771.40370111


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :  2061
 total energy-change (2. order) : 0.5985348E+03  (-0.8723146E+03)
 number of electron     142.0000024 magnetization      -0.1261509
 augmentation part       -6.2267215 magnetization      -0.1585486

 Broyden mixing:
  rms(total) = 0.18667E+01    rms(broyden)= 0.25149E+00
  rms(prec ) = 0.26030E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2109
  7.7849  7.7849  3.0216  3.0216  2.2391  1.1711  1.1711  1.2224  1.2224  0.9926
  0.9926  0.8173  0.8173  0.9137  0.6903  0.6903  0.6665  0.6665  0.6172  0.5891
  0.5891  0.3801  0.2391  0.1510  0.1510  0.0996  0.0410  0.0054  0.0002  0.0004
  0.0004  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.29271859
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -223.11692769
  PAW double counting   =     13385.76303027   -12829.55219091
  entropy T*S    EENTRO =         0.02982723
  eigenvalues    EBANDS =      -842.54694361
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -172.87733013 eV

  energy without entropy =     -172.90715736  energy(sigma->0) =     -172.88727254


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :  2052
 total energy-change (2. order) :-0.6627312E+01  (-0.1245766E+01)
 number of electron     142.0000025 magnetization       0.0325785
 augmentation part       -6.2542428 magnetization       0.0393840

 Broyden mixing:
  rms(total) = 0.38001E+00    rms(broyden)= 0.85647E-01
  rms(prec ) = 0.88548E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1759
  7.7856  7.7856  3.0194  3.0194  2.2469  1.1710  1.1710  1.2220  1.2220  0.9927
  0.9927  0.8171  0.8171  0.9134  0.6897  0.6897  0.6661  0.6661  0.6181  0.5892
  0.5892  0.3801  0.2391  0.1621  0.1621  0.0915  0.0655  0.0054  0.0051  0.0051
  0.0039  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13333.61193549
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.57451817
  PAW double counting   =     13680.66821809   -13124.67712376
  entropy T*S    EENTRO =         0.03207857
  eigenvalues    EBANDS =      -847.17995409
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.50464168 eV

  energy without entropy =     -179.53672025  energy(sigma->0) =     -179.51533454


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :  2241
 total energy-change (2. order) :-0.7285436E+00  (-0.6581485E-01)
 number of electron     142.0000026 magnetization       0.0516909
 augmentation part       -6.2446798 magnetization       0.0617790

 Broyden mixing:
  rms(total) = 0.11216E+00    rms(broyden)= 0.81984E-01
  rms(prec ) = 0.87553E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1668
  7.7602  7.7602  3.0193  3.0193  2.2387  1.1718  1.1718  1.2130  1.2130  0.4712
  0.9976  0.9976  0.8196  0.8196  0.9158  0.6939  0.6939  0.6609  0.6609  0.6242
  0.5897  0.5897  0.3801  0.2964  0.2964  0.2391  0.2035  0.1298  0.0084  0.0054
  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13333.18905256
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11431270
  PAW double counting   =     13599.87110332   -13043.58979762
  entropy T*S    EENTRO =         0.03177278
  eigenvalues    EBANDS =      -848.08149166
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.23318529 eV

  energy without entropy =     -180.26495806  energy(sigma->0) =     -180.24377621


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------



 eigenvalue-minimisations  :  2232
 total energy-change (2. order) :-0.2637612E+00  (-0.4455951E-02)
 number of electron     142.0000026 magnetization       0.0292845
 augmentation part       -6.2472468 magnetization       0.0391695

 Broyden mixing:
  rms(total) = 0.97746E-01    rms(broyden)= 0.96468E-01
  rms(prec ) = 0.10603E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1461
  7.7679  7.7679  3.0154  3.0154  2.2483  1.1720  1.1720  1.2202  1.2202  0.9968
  0.9968  0.4088  0.4088  0.8193  0.8193  0.9096  0.6915  0.6915  0.6602  0.6602
  0.6278  0.5899  0.5899  0.3801  0.3105  0.3105  0.2391  0.2525  0.1270  0.0084
  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.07486114
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.12103898
  PAW double counting   =     13567.61797173   -13011.42292351
  entropy T*S    EENTRO =         0.03174123
  eigenvalues    EBANDS =      -847.36642896
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.49694645 eV

  energy without entropy =     -180.52868768  energy(sigma->0) =     -180.50752686


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  41)  ---------------------------------------



 eigenvalue-minimisations  :  2160
 total energy-change (2. order) :-0.1613029E+00  (-0.2223374E-02)
 number of electron     142.0000026 magnetization       0.0128118
 augmentation part       -6.2454155 magnetization       0.0203766

 Broyden mixing:
  rms(total) = 0.12360E+00    rms(broyden)= 0.12354E+00
  rms(prec ) = 0.13663E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1764
  7.8051  7.8051  2.9914  2.9914  2.2924  1.0488  1.0488  1.1757  1.1757  1.2257
  1.2257  1.0185  1.0185  0.9104  0.8235  0.8235  0.6994  0.6994  0.6590  0.6590
  0.5900  0.5900  0.6176  0.4639  0.4639  0.3801  0.3787  0.3787  0.2391  0.1263
  0.0084  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.25732944
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11841733
  PAW double counting   =     13550.01718334   -12993.87949541
  entropy T*S    EENTRO =         0.03183270
  eigenvalues    EBANDS =      -847.29061641
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.65824939 eV

  energy without entropy =     -180.69008208  energy(sigma->0) =     -180.66886028


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  42)  ---------------------------------------



 eigenvalue-minimisations  :  2043
 total energy-change (2. order) : 0.5629791E+00  (-0.1318826E+00)
 number of electron     142.0000025 magnetization       0.0121230
 augmentation part       -6.2577597 magnetization       0.0289289

 Broyden mixing:
  rms(total) = 0.87147E-01    rms(broyden)= 0.86960E-01
  rms(prec ) = 0.90795E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1785
  7.8993  7.8993  2.9801  2.9801  2.3049  1.3156  1.3156  1.1777  1.1777  1.2212
  1.2212  1.0322  1.0322  0.9320  0.8359  0.8359  0.7237  0.7237  0.6512  0.6512
  0.6210  0.5880  0.5880  0.5003  0.5003  0.3801  0.3983  0.3983  0.2391  0.3293
  0.1263  0.0084  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.35725234
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.12022976
  PAW double counting   =     13532.20976949   -12976.08825727
  entropy T*S    EENTRO =         0.03212800
  eigenvalues    EBANDS =      -846.61002159
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.09527030 eV

  energy without entropy =     -180.12739830  energy(sigma->0) =     -180.10597964


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  43)  ---------------------------------------



 eigenvalue-minimisations  :  2025
 total energy-change (2. order) :-0.5406721E+00  (-0.3807137E-01)
 number of electron     142.0000026 magnetization       0.0046614
 augmentation part       -6.2464917 magnetization       0.0150171

 Broyden mixing:
  rms(total) = 0.10530E+00    rms(broyden)= 0.10522E+00
  rms(prec ) = 0.11674E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1909
  8.0129  8.0129  2.9867  2.9867  2.2752  1.7369  1.7369  1.1878  1.1878  1.1939
  1.1939  1.0720  1.0720  0.8496  0.8496  0.5457  0.5457  0.8158  0.7580  0.7580
  0.6649  0.6649  0.6127  0.5874  0.5874  0.3801  0.4706  0.4706  0.2391  0.3245
  0.3245  0.1263  0.0084  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.41445118
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11964270
  PAW double counting   =     13518.98089114   -12962.86537717
  entropy T*S    EENTRO =         0.03174840
  eigenvalues    EBANDS =      -847.08770409
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.63594243 eV

  energy without entropy =     -180.66769083  energy(sigma->0) =     -180.64652523


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  44)  ---------------------------------------



 eigenvalue-minimisations  :  2034
 total energy-change (2. order) :-0.1230190E-01  (-0.2039903E-02)
 number of electron     142.0000026 magnetization       0.0028921
 augmentation part       -6.2461229 magnetization       0.0134094

 Broyden mixing:
  rms(total) = 0.11081E+00    rms(broyden)= 0.11080E+00
  rms(prec ) = 0.12282E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2146
  8.5985  8.0144  3.3588  2.5345  2.5345  2.1607  2.1607  1.0834  1.0834  1.1412
  1.1412  1.1326  1.1326  0.8572  0.8572  0.9332  0.5412  0.5412  0.6073  0.6073
  0.7290  0.7290  0.5866  0.5866  0.6045  0.5932  0.5932  0.3801  0.4080  0.3750
  0.3750  0.2391  0.1263  0.0084  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.57655197
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11703844
  PAW double counting   =     13499.98541407   -12943.85540375
  entropy T*S    EENTRO =         0.03176970
  eigenvalues    EBANDS =      -846.95502710
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.64824433 eV

  energy without entropy =     -180.68001403  energy(sigma->0) =     -180.65883423


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  45)  ---------------------------------------



 eigenvalue-minimisations  :  2097
 total energy-change (2. order) : 0.5414704E-01  (-0.5642674E-03)
 number of electron     142.0000026 magnetization       0.0026620
 augmentation part       -6.2478130 magnetization       0.0152057

 Broyden mixing:
  rms(total) = 0.94796E-01    rms(broyden)= 0.94795E-01
  rms(prec ) = 0.10506E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2328
  9.4432  7.7637  3.7196  2.6222  2.6222  2.0579  2.0579  1.3575  1.1341  1.1341
  1.0638  1.0638  0.9952  0.9952  0.8331  0.8331  0.7604  0.7604  0.5286  0.5286
  0.7474  0.7474  0.6648  0.6648  0.5957  0.5845  0.5845  0.4594  0.4594  0.3801
  0.2391  0.3790  0.3790  0.1263  0.0084  0.0054  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.70027391
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11463815
  PAW double counting   =     13489.66520204   -12933.52770475
  entropy T*S    EENTRO =         0.03173361
  eigenvalues    EBANDS =      -846.78700929
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.59409728 eV

  energy without entropy =     -180.62583090  energy(sigma->0) =     -180.60467516


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  46)  ---------------------------------------



 eigenvalue-minimisations  :  1908
 total energy-change (2. order) :-0.3031407E-01  (-0.2731940E-03)
 number of electron     142.0000026 magnetization       0.0018683
 augmentation part       -6.2468341 magnetization       0.0136146

 Broyden mixing:
  rms(total) = 0.10633E+00    rms(broyden)= 0.10633E+00
  rms(prec ) = 0.11783E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2448
  9.9338  7.7194  3.9739  2.7769  2.7769  2.0568  2.0568  1.3965  1.1208  1.1208
  1.0232  1.0232  1.0988  1.0988  0.8804  0.8804  0.8128  0.8128  0.5263  0.5263
  0.7379  0.7379  0.6253  0.6253  0.6180  0.5812  0.5812  0.3801  0.5020  0.4796
  0.4796  0.2391  0.3422  0.3422  0.1263  0.0084  0.0054  0.0050  0.0050  0.0004
  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.77530830
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11290506
  PAW double counting   =     13483.54813994   -12927.40105097
  entropy T*S    EENTRO =         0.03176200
  eigenvalues    EBANDS =      -846.75364213
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.62441135 eV

  energy without entropy =     -180.65617335  energy(sigma->0) =     -180.63499869


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  47)  ---------------------------------------



 eigenvalue-minimisations  :  1962
 total energy-change (2. order) : 0.4710894E-02  (-0.2282624E-04)
 number of electron     142.0000026 magnetization      -0.0012341
 augmentation part       -6.2468299 magnetization       0.0107820

 Broyden mixing:
  rms(total) = 0.10683E+00    rms(broyden)= 0.10683E+00
  rms(prec ) = 0.11823E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2527
  9.6964  7.7052  3.8940  2.7255  2.7255  2.5529  2.5529  1.3443  1.3443  1.1563
  1.1563  1.0063  1.0063  0.9580  0.9580  0.9885  0.8310  0.8310  0.5280  0.5280
  0.6947  0.6947  0.6679  0.6679  0.6119  0.6119  0.5910  0.5910  0.5685  0.3801
  0.4477  0.4477  0.2391  0.3797  0.3797  0.1263  0.0084  0.0054  0.0050  0.0050
  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13334.84638520
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.11115977
  PAW double counting   =     13475.26564781   -12919.11054198
  entropy T*S    EENTRO =         0.03176600
  eigenvalues    EBANDS =      -846.68762048
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.61970046 eV

  energy without entropy =     -180.65146646  energy(sigma->0) =     -180.63028913


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  48)  ---------------------------------------



 eigenvalue-minimisations  :  1908
 total energy-change (2. order) : 0.1143435E+01  (-0.8799965E+00)
 number of electron     142.0000025 magnetization      -0.0004433
 augmentation part       -6.2567047 magnetization       0.0058627

 Broyden mixing:
  rms(total) = 0.17996E+00    rms(broyden)= 0.17977E+00
  rms(prec ) = 0.19511E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2296
  9.8838  7.6667  3.9378  2.7231  2.7231  2.5222  2.5222  1.4046  1.4046  1.1533
  1.1533  1.0231  1.0231  0.9377  0.9377  0.8678  0.8162  0.8162  0.7082  0.7082
  0.5284  0.5284  0.6761  0.6761  0.6385  0.6385  0.5885  0.5885  0.5822  0.3801
  0.4475  0.4475  0.2391  0.3696  0.3696  0.1263  0.0907  0.0084  0.0054  0.0050
  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.01880816
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.10676508
  PAW double counting   =     13455.91452694   -12899.73108808
  entropy T*S    EENTRO =         0.03184658
  eigenvalues    EBANDS =      -845.40457108
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -179.47626571 eV

  energy without entropy =     -179.50811229  energy(sigma->0) =     -179.48688123


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  49)  ---------------------------------------



 eigenvalue-minimisations  :  1836
 total energy-change (2. order) :-0.1088717E+01  (-0.1575821E+00)
 number of electron     142.0000026 magnetization       0.0016858
 augmentation part       -6.2480886 magnetization       0.0157018

 Broyden mixing:
  rms(total) = 0.10814E+00    rms(broyden)= 0.10795E+00
  rms(prec ) = 0.11790E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2122
 10.0797  7.6343  4.1140  2.7002  2.7002  2.4518  2.4518  1.4109  1.4109  1.1518
  1.1518  1.0397  1.0397  0.9348  0.9348  0.8858  0.8165  0.8165  0.6817  0.6817
  0.5290  0.5290  0.6771  0.6771  0.6367  0.6367  0.5888  0.5888  0.5843  0.4450
  0.4450  0.3801  0.1941  0.1941  0.2391  0.3767  0.3767  0.1263  0.0084  0.0054
  0.0050  0.0050  0.0004  0.0003

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.05776249
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.10281783
  PAW double counting   =     13459.94254714   -12903.77730722
  entropy T*S    EENTRO =         0.03176045
  eigenvalues    EBANDS =      -846.43999640
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.56498318 eV

  energy without entropy =     -180.59674363  energy(sigma->0) =     -180.57557000


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  50)  ---------------------------------------



 eigenvalue-minimisations  :  1962
 total energy-change (2. order) :-0.3937785E-01  (-0.1996603E-01)
 number of electron     142.0000026 magnetization       0.0049744
 augmentation part       -6.2477000 magnetization       0.0188919

 Broyden mixing:
  rms(total) = 0.10223E+00    rms(broyden)= 0.10222E+00
  rms(prec ) = 0.11295E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0958
  7.0616  7.0616  3.0042  2.8207  2.2929  2.2929  1.4215  1.1762  1.1762  1.0436
  1.0436  0.6396  0.6396  0.8540  0.8540  0.7705  0.7705  0.2733  0.2733  0.0853
  0.0853  0.0212  0.0212  0.0039  0.0003  0.0000  0.6265  0.6265  0.4690  0.4690
  0.7280  0.7280  0.4349  0.4349  0.4656  0.6692  0.6692  0.6160  0.6160  0.5918

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.12587561
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.10304893
  PAW double counting   =     13460.17285069   -12904.01253740
  entropy T*S    EENTRO =         0.03177739
  eigenvalues    EBANDS =      -846.40612034
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.60436104 eV

  energy without entropy =     -180.63613843  energy(sigma->0) =     -180.61495350


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  51)  ---------------------------------------



 eigenvalue-minimisations  :  2142
 total energy-change (2. order) : 0.3983131E+00  (-0.2402968E-01)
 number of electron     142.0000025 magnetization      -0.0011438
 augmentation part       -6.2522895 magnetization       0.0277622

 Broyden mixing:
  rms(total) = 0.44447E-01    rms(broyden)= 0.44291E-01
  rms(prec ) = 0.45286E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1033
  7.0936  7.0936  3.2895  2.5425  2.3888  2.3888  1.6535  1.1908  1.1908  0.9654
  0.9654  1.0170  1.0170  0.3085  0.3085  0.8375  0.8375  0.6843  0.6843  0.4918
  0.4918  0.1037  0.1037  0.0195  0.0037  0.0021  0.0021  0.0000  0.7671  0.7671
  0.5557  0.5557  0.3878  0.4604  0.5221  0.5221  0.6251  0.6251  0.6275  0.5715
  0.5715

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.84523751
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.03528232
  PAW double counting   =     13275.31832409   -12718.99654732
  entropy T*S    EENTRO =         0.03214002
  eigenvalues    EBANDS =      -843.51803806
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.20604793 eV

  energy without entropy =     -180.23818796  energy(sigma->0) =     -180.21676127


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  52)  ---------------------------------------



 eigenvalue-minimisations  :  1953
 total energy-change (2. order) :-0.9871751E-02  (-0.2007151E-02)
 number of electron     142.0000025 magnetization      -0.0016862
 augmentation part       -6.2560200 magnetization       0.0267801

 Broyden mixing:
  rms(total) = 0.40016E-01    rms(broyden)= 0.40006E-01
  rms(prec ) = 0.41278E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1149
  7.1567  7.1567  3.2367  3.2367  2.1584  2.1085  2.1085  1.2542  1.2542  1.1045
  1.1045  0.9695  0.9695  0.3047  0.3047  0.5047  0.5047  0.7919  0.7919  0.7996
  0.7996  0.6872  0.6872  0.0905  0.0905  0.0214  0.0037  0.0020  0.0020  0.0000
  0.5843  0.5843  0.4087  0.4087  0.5397  0.5397  0.4690  0.6179  0.6179  0.6029
  0.6239  0.6239

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.45441712
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.03978981
  PAW double counting   =     13293.38788250   -12737.06873038
  entropy T*S    EENTRO =         0.03213376
  eigenvalues    EBANDS =      -843.91159181
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.21591969 eV

  energy without entropy =     -180.24805345  energy(sigma->0) =     -180.22663094


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  53)  ---------------------------------------



 eigenvalue-minimisations  :  2187
 total energy-change (2. order) :-0.2169833E-02  (-0.5878018E-04)
 number of electron     142.0000025 magnetization      -0.0035615
 augmentation part       -6.2562204 magnetization       0.0239395

 Broyden mixing:
  rms(total) = 0.37377E-01    rms(broyden)= 0.37377E-01
  rms(prec ) = 0.38812E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1324
  7.3148  7.3148  3.4301  3.4301  2.1080  2.1080  2.0951  1.3413  1.3413  1.1372
  1.1372  1.0258  1.0258  0.8928  0.8928  0.3058  0.3058  0.8092  0.8092  0.5488
  0.5488  0.6232  0.6232  0.1020  0.1020  0.0201  0.0039  0.0021  0.0021  0.0000
  0.5656  0.5656  0.3971  0.3971  0.6639  0.6639  0.4751  0.5147  0.5823  0.5823
  0.6478  0.6176  0.6176

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.06691713
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.04683525
  PAW double counting   =     13315.64148742   -12759.32372935
  entropy T*S    EENTRO =         0.03212347
  eigenvalues    EBANDS =      -844.29281184
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.21808952 eV

  energy without entropy =     -180.25021298  energy(sigma->0) =     -180.22879734


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  54)  ---------------------------------------



 eigenvalue-minimisations  :  2124
 total energy-change (2. order) :-0.1451614E-02  (-0.5478022E-04)
 number of electron     142.0000025 magnetization      -0.0043224
 augmentation part       -6.2553818 magnetization       0.0221198

 Broyden mixing:
  rms(total) = 0.35166E-01    rms(broyden)= 0.35165E-01
  rms(prec ) = 0.36655E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1477
  7.5228  7.5228  3.5704  3.4773  2.0653  2.0653  2.0971  1.3431  1.3431  1.1432
  1.1432  1.2008  1.2008  0.3372  0.3372  0.9163  0.9163  0.1162  0.1162  0.0181
  0.0041  0.0022  0.0022  0.0000  0.5353  0.5353  0.6774  0.6774  0.8045  0.8045
  0.5594  0.5594  0.3835  0.3835  0.7052  0.7052  0.4685  0.6716  0.5801  0.5801
  0.6359  0.6359  0.5678  0.5678

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.62881209
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.05610006
  PAW double counting   =     13327.65558258   -12771.33767013
  entropy T*S    EENTRO =         0.03211560
  eigenvalues    EBANDS =      -844.72325020
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.21954113 eV

  energy without entropy =     -180.25165673  energy(sigma->0) =     -180.23024633


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  55)  ---------------------------------------



 eigenvalue-minimisations  :  2295
 total energy-change (2. order) :-0.5568477E-03  (-0.2862060E-04)
 number of electron     142.0000025 magnetization      -0.0049815
 augmentation part       -6.2544100 magnetization       0.0209704

 Broyden mixing:
  rms(total) = 0.34579E-01    rms(broyden)= 0.34579E-01
  rms(prec ) = 0.36123E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0332
  7.5082  4.6169  2.8400  2.8400  1.9266  1.9266  1.3196  1.3196  1.1776  0.9723
  0.9723  0.9970  0.9970  0.3194  0.3194  0.5084  0.5084  0.7882  0.7882  0.5953
  0.5953  0.7426  0.7426  0.6520  0.6520  0.6684  0.6684  0.6477  0.4264  0.4264
  0.5595  0.5595  0.5273  0.0949  0.0949  0.0216  0.0035  0.0023  0.0023  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.46285431
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.06000179
  PAW double counting   =     13329.20817912   -12772.88932986
  entropy T*S    EENTRO =         0.03210863
  eigenvalues    EBANDS =      -844.88679294
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.22009798 eV

  energy without entropy =     -180.25220661  energy(sigma->0) =     -180.23080086


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  56)  ---------------------------------------



 eigenvalue-minimisations  :  2475
 total energy-change (2. order) :-0.3243167E+04  (-0.3033448E+04)
 number of electron     141.9999988 magnetization      -0.0046290
 augmentation part       -6.1880336 magnetization      -2.6630500

 Broyden mixing:
  rms(total) = 0.67793E+01    rms(broyden)= 0.65510E+01
  rms(prec ) = 0.68751E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0137
  7.5108  4.6265  2.8337  2.8337  1.9040  1.9040  1.3507  1.3507  1.2277  1.2277
  1.0014  1.0014  0.3205  0.3205  0.5000  0.5000  0.8776  0.8776  0.6021  0.6021
  0.7644  0.7644  0.6957  0.6957  0.6925  0.6925  0.6145  0.6145  0.4439  0.4439
  0.5394  0.5016  0.5016  0.0967  0.0967  0.0216  0.0040  0.0022  0.0022  0.0001
  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.34685391
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.06265549
  PAW double counting   =     13335.97465101   -12779.65437172
  entropy T*S    EENTRO =        -0.00119567
  eigenvalues    EBANDS =     -4088.13543373
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =     -3423.38726633 eV

  energy without entropy =    -3423.38607067  energy(sigma->0) =    -3423.38686778


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  57)  ---------------------------------------



 eigenvalue-minimisations  :  2034
 total energy-change (2. order) : 0.3258157E+04  (-0.5497790E+03)
 number of electron     142.0000024 magnetization       0.1083044
 augmentation part       -6.2186748 magnetization      -2.3743295

 Broyden mixing:
  rms(total) = 0.14887E+01    rms(broyden)= 0.52676E+00
  rms(prec ) = 0.56914E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9921
  7.5190  4.6154  2.8124  2.8124  1.9723  1.9723  1.3311  1.3311  1.2892  1.2304
  0.9988  0.9988  0.3207  0.3207  0.4882  0.4882  0.8784  0.8784  0.6009  0.6009
  0.7910  0.7910  0.7180  0.7180  0.6729  0.6729  0.6148  0.6148  0.4406  0.4406
  0.5490  0.4765  0.4765  0.0987  0.0987  0.0223  0.0028  0.0028  0.0040  0.0007
  0.0007  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13337.16769964
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -223.45697496
  PAW double counting   =     13267.97306891   -12711.65925024
  entropy T*S    EENTRO =        -0.01009139
  eigenvalues    EBANDS =      -834.74753036
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -165.22988451 eV

  energy without entropy =     -165.21979312  energy(sigma->0) =     -165.22652072


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  58)  ---------------------------------------



 eigenvalue-minimisations  :  2385
 total energy-change (2. order) :-0.1258697E+02  (-0.4551106E+01)
 number of electron     142.0000025 magnetization       0.1786951
 augmentation part       -6.2519297 magnetization      -0.2259883

 Broyden mixing:
  rms(total) = 0.30214E+00    rms(broyden)= 0.11554E+00
  rms(prec ) = 0.12494E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9701
  7.5190  4.6140  2.8106  2.8106  1.9753  1.9753  1.3279  1.3279  1.2916  1.2356
  0.9983  0.9983  0.3192  0.3192  0.4890  0.4890  0.8830  0.8830  0.5998  0.5998
  0.7877  0.7877  0.7178  0.7178  0.6741  0.6741  0.6164  0.6164  0.4406  0.4406
  0.5426  0.4811  0.4811  0.1009  0.1009  0.0284  0.0137  0.0137  0.0060  0.0013
  0.0013  0.0000  0.0040

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.12513431
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -228.23787084
  PAW double counting   =     13336.82534497   -12780.59570432
  entropy T*S    EENTRO =         0.00749066
  eigenvalues    EBANDS =      -843.52957768
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -177.81685835 eV

  energy without entropy =     -177.82434901  energy(sigma->0) =     -177.81935524


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  59)  ---------------------------------------



 eigenvalue-minimisations  :  2124
 total energy-change (2. order) :-0.2348834E+01  (-0.7414243E+00)
 number of electron     142.0000025 magnetization       0.1695991
 augmentation part       -6.2527246 magnetization       0.1746197

 Broyden mixing:
  rms(total) = 0.80224E-01    rms(broyden)= 0.55248E-01
  rms(prec ) = 0.59341E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9530
  7.5396  4.5485  2.8145  2.8145  1.9738  1.9738  1.3225  1.3225  1.3038  1.2259
  1.0015  1.0015  0.8720  0.8720  0.4888  0.4888  0.3180  0.3180  0.1169  0.7875
  0.7875  0.5999  0.5999  0.7184  0.7184  0.6750  0.6750  0.6153  0.6153  0.5444
  0.4401  0.4401  0.4809  0.4809  0.0831  0.0831  0.1217  0.1217  0.0173  0.0019
  0.0019  0.0000  0.0016  0.0039

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.74372134
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.05157930
  PAW double counting   =     13451.17018031   -12894.89355621
  entropy T*S    EENTRO =         0.03161833
  eigenvalues    EBANDS =      -845.51722732
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.16569237 eV

  energy without entropy =     -180.19731070  energy(sigma->0) =     -180.17623181


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  60)  ---------------------------------------



 eigenvalue-minimisations  :  2214
 total energy-change (2. order) :-0.5163745E-01  (-0.5208730E-01)
 number of electron     142.0000025 magnetization       0.1507288
 augmentation part       -6.2536466 magnetization       0.1626958

 Broyden mixing:
  rms(total) = 0.49912E-01    rms(broyden)= 0.48425E-01
  rms(prec ) = 0.52634E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8560
  6.2712  3.1417  2.9964  1.8770  1.8770  1.3919  1.3919  0.6457  1.2399  1.0508
  0.9522  0.9522  0.7072  0.7072  0.7377  0.7377  0.5051  0.5051  0.7341  0.6787
  0.6787  0.2925  0.2925  0.5462  0.5462  0.5948  0.5253  0.3946  0.3946  0.3769
  0.1161  0.1161  0.2156  0.0326  0.0061  0.0046  0.0028  0.0028  0.0014  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.86664103
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.06893441
  PAW double counting   =     13425.91875907   -12869.59720303
  entropy T*S    EENTRO =         0.03160062
  eigenvalues    EBANDS =      -845.47350420
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.21732982 eV

  energy without entropy =     -180.24893044  energy(sigma->0) =     -180.22786336


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  61)  ---------------------------------------



 eigenvalue-minimisations  :  2196
 total energy-change (2. order) : 0.2956931E-02  (-0.2066494E-02)
 number of electron     142.0000025 magnetization       0.1371050
 augmentation part       -6.2544759 magnetization       0.1518733

 Broyden mixing:
  rms(total) = 0.44632E-01    rms(broyden)= 0.44572E-01
  rms(prec ) = 0.48439E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8597
  6.2622  3.1816  2.9707  1.1458  1.8744  1.8744  1.3699  1.3699  1.2230  1.0842
  0.9405  0.9405  0.7089  0.7089  0.7756  0.7756  0.3676  0.3676  0.5049  0.5049
  0.7272  0.6804  0.6804  0.5487  0.5487  0.5965  0.5249  0.3786  0.3786  0.3480
  0.3480  0.1737  0.1737  0.1472  0.0184  0.0081  0.0081  0.0031  0.0019  0.0019
  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13336.03071445
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07087694
  PAW double counting   =     13404.02358182   -12847.70087871
  entropy T*S    EENTRO =         0.03168990
  eigenvalues    EBANDS =      -845.30576767
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.21437288 eV

  energy without entropy =     -180.24606278  energy(sigma->0) =     -180.22493618


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  62)  ---------------------------------------



 eigenvalue-minimisations  :  2115
 total energy-change (2. order) :-0.6143205E-01  (-0.4927365E-03)
 number of electron     142.0000025 magnetization       0.1270713
 augmentation part       -6.2538715 magnetization       0.1426035

 Broyden mixing:
  rms(total) = 0.54974E-01    rms(broyden)= 0.54969E-01
  rms(prec ) = 0.60327E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9123
  6.2651  2.9117  3.1016  2.9207  1.8890  1.8890  1.4038  1.4038  1.2536  0.8133
  0.8133  0.8882  0.8882  0.9284  0.9284  0.8966  0.2519  0.2519  0.6311  0.6311
  0.5003  0.5003  0.6743  0.6743  0.6830  0.5067  0.5067  0.5744  0.5744  0.5976
  0.4100  0.4100  0.5253  0.1232  0.0385  0.0385  0.0055  0.0047  0.0047  0.0021
  0.0000  0.0018

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.96816251
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07276298
  PAW double counting   =     13392.32916277   -12836.00723586
  entropy T*S    EENTRO =         0.03167623
  eigenvalues    EBANDS =      -845.42707576
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.27580493 eV

  energy without entropy =     -180.30748116  energy(sigma->0) =     -180.28636367


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  63)  ---------------------------------------



 eigenvalue-minimisations  :  2133
 total energy-change (2. order) : 0.5538338E-01  (-0.3406549E-03)
 number of electron     142.0000025 magnetization       0.1193765
 augmentation part       -6.2544203 magnetization       0.1354896

 Broyden mixing:
  rms(total) = 0.42696E-01    rms(broyden)= 0.42695E-01
  rms(prec ) = 0.46539E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8786
  6.2610  3.1047  2.9007  1.8846  1.8531  1.8531  1.4007  1.4007  1.2364  0.7476
  0.7476  0.9756  0.9410  0.9410  0.8123  0.8123  0.6647  0.6647  0.5448  0.5448
  0.3620  0.3620  0.7654  0.6699  0.6699  0.4585  0.4585  0.4509  0.4509  0.5995
  0.5657  0.5657  0.5226  0.3550  0.0843  0.0570  0.0570  0.0133  0.0133  0.0028
  0.0018  0.0018  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.84863522
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07704378
  PAW double counting   =     13383.49608759   -12827.17298508
  entropy T*S    EENTRO =         0.03175766
  eigenvalues    EBANDS =      -845.48819588
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.22042155 eV

  energy without entropy =     -180.25217921  energy(sigma->0) =     -180.23100743


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  64)  ---------------------------------------



 eigenvalue-minimisations  :  2133
 total energy-change (2. order) :-0.2475808E+00  (-0.7071014E-02)
 number of electron     142.0000026 magnetization       0.1161753
 augmentation part       -6.2497305 magnetization       0.1302523

 Broyden mixing:
  rms(total) = 0.10196E+00    rms(broyden)= 0.10195E+00
  rms(prec ) = 0.11290E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8767
  6.3370  2.3158  2.9887  2.9887  1.8538  1.8538  1.4618  1.4618  1.2706  0.8079
  0.8079  0.9372  0.9372  0.9313  0.5720  0.5720  0.7972  0.7972  0.6665  0.6665
  0.7652  0.6564  0.6564  0.4500  0.4500  0.3217  0.3217  0.6016  0.5698  0.5698
  0.4604  0.4604  0.5042  0.3684  0.1289  0.1289  0.0848  0.0215  0.0097  0.0097
  0.0047  0.0023  0.0023  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.83419665
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07758748
  PAW double counting   =     13383.03333032   -12826.71117285
  entropy T*S    EENTRO =         0.03159752
  eigenvalues    EBANDS =      -845.74856637
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.46800236 eV

  energy without entropy =     -180.49959988  energy(sigma->0) =     -180.47853486


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  65)  ---------------------------------------



 eigenvalue-minimisations  :  2052
 total energy-change (2. order) : 0.2422321E+00  (-0.9685989E-02)
 number of electron     142.0000025 magnetization       0.1100520
 augmentation part       -6.2539735 magnetization       0.1268982

 Broyden mixing:
  rms(total) = 0.43491E-01    rms(broyden)= 0.43475E-01
  rms(prec ) = 0.47446E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7529
  4.7797  1.4656  1.4656  1.9102  1.9102  1.0099  1.3826  1.3826  1.3787  1.1208
  0.9061  0.9061  0.9841  0.7672  0.7672  0.6876  0.6876  0.6932  0.6588  0.3362
  0.3362  0.5677  0.5677  0.4806  0.4806  0.4499  0.4499  0.5180  0.4256  0.1074
  0.1493  0.1493  0.1073  0.1073  0.0064  0.0064  0.0038  0.0000  0.0019  0.0017

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.82473181
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07775900
  PAW double counting   =     13377.17125261   -12820.84845589
  entropy T*S    EENTRO =         0.03178574
  eigenvalues    EBANDS =      -845.51645513
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.22577030 eV

  energy without entropy =     -180.25755604  energy(sigma->0) =     -180.23636555


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  66)  ---------------------------------------



 eigenvalue-minimisations  :  2025
 total energy-change (2. order) : 0.1193780E-02  (-0.3592431E-03)
 number of electron     142.0000025 magnetization       0.1043882
 augmentation part       -6.2539935 magnetization       0.1216268

 Broyden mixing:
  rms(total) = 0.41491E-01    rms(broyden)= 0.41490E-01
  rms(prec ) = 0.45509E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7818
  4.9035  2.2318  2.2318  1.9020  1.9020  1.3527  1.3527  0.5388  1.3725  0.9842
  0.9842  1.1089  1.0667  0.2152  0.6856  0.6856  0.7150  0.7150  0.2462  0.2462
  0.4393  0.4393  0.5634  0.5634  0.6886  0.6565  0.5557  0.5557  0.4337  0.4337
  0.5068  0.4516  0.2056  0.0460  0.0460  0.0095  0.0095  0.0026  0.0017  0.0000
  0.0032

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.84538582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07756033
  PAW double counting   =     13378.29120281   -12821.96869246
  entropy T*S    EENTRO =         0.03180016
  eigenvalues    EBANDS =      -845.49453405
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.22457652 eV

  energy without entropy =     -180.25637668  energy(sigma->0) =     -180.23517658


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  67)  ---------------------------------------



 eigenvalue-minimisations  :  2124
 total energy-change (2. order) :-0.3706903E-03  (-0.1389719E-04)
 number of electron     142.0000025 magnetization       0.0967404
 augmentation part       -6.2539293 magnetization       0.1142778

 Broyden mixing:
  rms(total) = 0.41283E-01    rms(broyden)= 0.41283E-01
  rms(prec ) = 0.45369E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8368
  5.1876  2.9923  2.9923  1.9212  1.9212  1.4332  1.4332  1.3445  1.1870  1.1870
  1.1594  1.0881  0.2669  0.2669  0.7358  0.7358  0.6728  0.6728  0.7066  0.7066
  0.7111  0.2736  0.2736  0.6567  0.4129  0.4129  0.5099  0.5099  0.5472  0.5472
  0.5227  0.4307  0.3956  0.1855  0.0624  0.0624  0.0068  0.0068  0.0036  0.0000
  0.0021  0.0016

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        27.86983208
  Ewald energy   TEWEN  =      9458.38122438
  -Hartree energ DENC   =    -13335.83479489
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =      -229.07754303
  PAW double counting   =     13378.24966483   -12821.92764428
  entropy T*S    EENTRO =         0.03180724
  eigenvalues    EBANDS =      -845.50503025
  atomic energy  EATOM  =      4187.58753671
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.22494721 eV

  energy without entropy =     -180.25675445  energy(sigma->0) =     -180.23554963


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  68)  ---------------------------------------


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|                                                                             |
|     EEEEEEE  RRRRRR   RRRRRR   OOOOOOO  RRRRRR      ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     EEEEE    RRRRRR   RRRRRR   O     O  RRRRRR       #       #       #      |
|     E        R   R    R   R    O     O  R   R                               |
|     E        R    R   R    R   O     O  R    R      ###     ###     ###     |
|     EEEEEEE  R     R  R     R  OOOOOOO  R     R     ###     ###     ###     |
|                                                                             |
|     Error EDDDAV: Call to ZHEGV failed. Returncode = 8 1 9                  |
|                                                                             |
|       ---->  I REFUSE TO CONTINUE WITH THIS SICK JOB ... BYE!!! <----       |
|                                                                             |
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