vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.19  22:12:15
 running on    3 total cores
 distrk:  each k-point on    3 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    3 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 2
   MAGMOM = 0.003 -0.042 -0.037 -0.015 -0.006 -1.266 3*-0.002 -0.004 0 -0.001 2*0 -0.002 4*0 -0.001 14*0
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.77 0.32
   NPAR = 3

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  3       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  4       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.562  0.558  0.480-   2 1.62   3 1.63   4 1.63   5 1.68
   2  0.602  0.613  0.364-   7 1.44   1 1.62
   3  0.628  0.609  0.587-   9 1.44   1 1.63
   4  0.582  0.423  0.479-  11 1.44   1 1.63
   5  0.424  0.582  0.491-  13 1.38   1 1.68
   6  0.359  0.693  0.764-
   7  0.549  0.696  0.296-  15 1.10  16 1.11   2 1.44   8 1.52
   8  0.636  0.773  0.246-  18 1.10  19 1.10  17 1.10   7 1.52
   9  0.627  0.725  0.615-  20 1.10  21 1.12   3 1.44  10 1.51
  10  0.648  0.740  0.739-  22 1.10  24 1.10  23 1.10   9 1.51
  11  0.682  0.367  0.445-  25 1.10  26 1.11   4 1.44  12 1.52
  12  0.769  0.363  0.537-  27 1.10  29 1.10  28 1.10  11 1.52
  13  0.361  0.558  0.584-  30 1.10  34 1.17   5 1.38  14 1.54
  14  0.280  0.649  0.622-  31 1.02  32 1.16  13 1.54
  15  0.502  0.654  0.229-   7 1.10
  16  0.488  0.744  0.346-   7 1.11
  17  0.596  0.836  0.192-   8 1.10
  18  0.696  0.726  0.195-   8 1.10
  19  0.683  0.817  0.312-   8 1.10
  20  0.691  0.769  0.566-   9 1.10
  21  0.545  0.762  0.593-   9 1.12
  22  0.651  0.829  0.760-  10 1.10
  23  0.729  0.702  0.761-  10 1.10
  24  0.582  0.700  0.788-  10 1.10
  25  0.657  0.282  0.422-  11 1.10
  26  0.716  0.407  0.370-  11 1.11
  27  0.843  0.316  0.508-  12 1.10
  28  0.736  0.322  0.612-  12 1.10
  29  0.796  0.448  0.560-  12 1.10
  30  0.410  0.531  0.657-  13 1.10
  31  0.223  0.621  0.679-  14 1.02
  32  0.237  0.681  0.542-  14 1.16
  33  0.313  0.756  0.662-
  34  0.305  0.481  0.563-  13 1.17
 
  LATTYP: Found a simple cubic cell.
 ALAT       =    12.0000000000
  
  Lattice vectors:
  
 A1 = (  12.0000000000,   0.0000000000,   0.0000000000)
 A2 = (   0.0000000000,  12.0000000000,   0.0000000000)
 A3 = (   0.0000000000,   0.0000000000,  12.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    1728.0000

  direct lattice vectors                    reciprocal lattice vectors
    12.000000000  0.000000000  0.000000000     0.083333333  0.000000000  0.000000000
     0.000000000 12.000000000  0.000000000     0.000000000  0.083333333  0.000000000
     0.000000000  0.000000000 12.000000000     0.000000000  0.000000000  0.083333333

  length of vectors
    12.000000000 12.000000000 12.000000000     0.083333333  0.083333333  0.083333333

  position of ions in fractional coordinates (direct lattice)
     0.561885530  0.557802360  0.479890570
     0.602366080  0.613296890  0.363553020
     0.627955000  0.608665500  0.587159840
     0.582048060  0.423405040  0.479315370
     0.424086940  0.581619570  0.491019130
     0.359070810  0.692931490  0.763569850
     0.549195870  0.696302550  0.295632770
     0.636129700  0.773311250  0.245952240
     0.626934650  0.725231990  0.615229700
     0.648283990  0.740381230  0.738728150
     0.682123440  0.367075140  0.445110780
     0.769434040  0.362999190  0.536587080
     0.361221390  0.557572290  0.584108070
     0.280370400  0.649453680  0.622346960
     0.502257600  0.653739560  0.229183400
     0.488455200  0.743742560  0.346152410
     0.595873040  0.836084050  0.192466630
     0.695882730  0.726150190  0.194814420
     0.682793780  0.816991890  0.311755910
     0.690963600  0.769175630  0.565860320
     0.544561650  0.762363980  0.593498370
     0.650906340  0.829236630  0.759542490
     0.728952400  0.702275890  0.761439500
     0.582187620  0.700266460  0.787716890
     0.656732250  0.281832100  0.421700280
     0.716290200  0.407434980  0.369630670
     0.842643490  0.315971130  0.508101540
     0.735727350  0.321778310  0.611502380
     0.795945360  0.447573730  0.560202420
     0.409776120  0.530985010  0.657366350
     0.223172430  0.621461830  0.678853930
     0.236508360  0.680680280  0.542075620
     0.312861040  0.755898560  0.661726800
     0.305367380  0.480888050  0.562969070

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.041666667  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.041666667  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.041666667     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.041666667  0.041666667  0.041666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.041667  0.000000  0.000000      1.000000
  0.000000  0.041667  0.000000      1.000000
  0.000000  0.000000  0.041667      1.000000
  0.041667  0.041667  0.000000      1.000000
  0.000000  0.041667  0.041667      1.000000
  0.041667  0.000000  0.041667      1.000000
  0.041667  0.041667  0.041667      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     63
   number of dos      NEDOS =    301   number of ions     NIONS =     34
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 216000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   4378
   dimension x,y,z NGX =    60 NGY =   60 NGZ =   60
   dimension x,y,z NGXF=   120 NGYF=  120 NGZF=  120
   support grid    NGXF=   120 NGYF=  120 NGZF=  120
   ions per type =               1   5   8  20
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      2    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  19.57 19.57 19.57*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.329E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00 12.01  1.00
  Ionic Valenz
   ZVAL   =   4.00  6.00  4.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.77  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =      86.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.40E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      50.82       342.97
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.602180  1.137955  4.933757  0.362621
  Thomas-Fermi vector in A             =   1.654692
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           20
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     1728.00
      direct lattice vectors                 reciprocal lattice vectors
    12.000000000  0.000000000  0.000000000     0.083333333  0.000000000  0.000000000
     0.000000000 12.000000000  0.000000000     0.000000000  0.083333333  0.000000000
     0.000000000  0.000000000 12.000000000     0.000000000  0.000000000  0.083333333

  length of vectors
    12.000000000 12.000000000 12.000000000     0.083333333  0.083333333  0.083333333


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.04166667  0.00000000  0.00000000       0.125
   0.00000000  0.04166667  0.00000000       0.125
   0.00000000  0.00000000  0.04166667       0.125
   0.04166667  0.04166667  0.00000000       0.125
   0.00000000  0.04166667  0.04166667       0.125
   0.04166667  0.00000000  0.04166667       0.125
   0.04166667  0.04166667  0.04166667       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.56188553  0.55780236  0.47989057
   0.60236608  0.61329689  0.36355302
   0.62795500  0.60866550  0.58715984
   0.58204806  0.42340504  0.47931537
   0.42408694  0.58161957  0.49101913
   0.35907081  0.69293149  0.76356985
   0.54919587  0.69630255  0.29563277
   0.63612970  0.77331125  0.24595224
   0.62693465  0.72523199  0.61522970
   0.64828399  0.74038123  0.73872815
   0.68212344  0.36707514  0.44511078
   0.76943404  0.36299919  0.53658708
   0.36122139  0.55757229  0.58410807
   0.28037040  0.64945368  0.62234696
   0.50225760  0.65373956  0.22918340
   0.48845520  0.74374256  0.34615241
   0.59587304  0.83608405  0.19246663
   0.69588273  0.72615019  0.19481442
   0.68279378  0.81699189  0.31175591
   0.69096360  0.76917563  0.56586032
   0.54456165  0.76236398  0.59349837
   0.65090634  0.82923663  0.75954249
   0.72895240  0.70227589  0.76143950
   0.58218762  0.70026646  0.78771689
   0.65673225  0.28183210  0.42170028
   0.71629020  0.40743498  0.36963067
   0.84264349  0.31597113  0.50810154
   0.73572735  0.32177831  0.61150238
   0.79594536  0.44757373  0.56020242
   0.40977612  0.53098501  0.65736635
   0.22317243  0.62146183  0.67885393
   0.23650836  0.68068028  0.54207562
   0.31286104  0.75589856  0.66172680
   0.30536738  0.48088805  0.56296907
 
 position of ions in cartesian coordinates  (Angst):
   6.74262636  6.69362832  5.75868684
   7.22839296  7.35956268  4.36263624
   7.53546000  7.30398600  7.04591808
   6.98457672  5.08086048  5.75178444
   5.08904328  6.97943484  5.89222956
   4.30884972  8.31517788  9.16283820
   6.59035044  8.35563060  3.54759324
   7.63355640  9.27973500  2.95142688
   7.52321580  8.70278388  7.38275640
   7.77940788  8.88457476  8.86473780
   8.18548128  4.40490168  5.34132936
   9.23320848  4.35599028  6.43904496
   4.33465668  6.69086748  7.00929684
   3.36444480  7.79344416  7.46816352
   6.02709120  7.84487472  2.75020080
   5.86146240  8.92491072  4.15382892
   7.15047648 10.03300860  2.30959956
   8.35059276  8.71380228  2.33777304
   8.19352536  9.80390268  3.74107092
   8.29156320  9.23010756  6.79032384
   6.53473980  9.14836776  7.12198044
   7.81087608  9.95083956  9.11450988
   8.74742880  8.42731068  9.13727400
   6.98625144  8.40319752  9.45260268
   7.88078700  3.38198520  5.06040336
   8.59548240  4.88921976  4.43556804
  10.11172188  3.79165356  6.09721848
   8.82872820  3.86133972  7.33802856
   9.55134432  5.37088476  6.72242904
   4.91731344  6.37182012  7.88839620
   2.67806916  7.45754196  8.14624716
   2.83810032  8.16816336  6.50490744
   3.75433248  9.07078272  7.94072160
   3.66440856  5.77065660  6.75562884
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   31439
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   31464
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   31464
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   31464
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   31400
 k-point  6 :   0.0000 0.5000 0.5000  plane waves:   31400
 k-point  7 :   0.5000 0.0000 0.5000  plane waves:   31400
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   31408

 maximum and minimum number of plane-waves per node :     31464    31400

 maximum number of plane-waves:     31464
 maximum index in each direction: 
   IXMAX=   19   IYMAX=   19   IZMAX=   19
   IXMIN=  -20   IYMIN=  -20   IZMIN=  -20

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    80 to avoid them
 WARNING: aliasing errors must be expected set NGY to    80 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    80 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   297349. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       2868. kBytes
   fftplans  :      20519. kBytes
   grid      :      73459. kBytes
   one-center:        208. kBytes
   wavefun   :     170295. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 39   NGY = 39   NGZ = 39
  (NGX  =120   NGY  =120   NGZ  =120)
  gives a total of  59319 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      86.0000000 magnetization      -1.3770000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1342
 Maximum index for augmentation-charges         1351 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.148
 Maximum number of real-space cells 3x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  2412
 total energy-change (2. order) : 0.6240339E+03  (-0.2516004E+04)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6645.44251904
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77251382
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.00120134
  eigenvalues    EBANDS =      -551.91414917
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       624.03391821 eV

  energy without entropy =      624.03271687  energy(sigma->0) =      624.03351776


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  3042
 total energy-change (2. order) :-0.6426535E+03  (-0.6105397E+03)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6645.44251904
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77251382
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.00220908
  eigenvalues    EBANDS =     -1194.56864757
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -18.61957245 eV

  energy without entropy =      -18.62178153  energy(sigma->0) =      -18.62030881


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  2646
 total energy-change (2. order) :-0.1754328E+03  (-0.1746157E+03)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6645.44251904
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77251382
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.01007630
  eigenvalues    EBANDS =     -1370.00934673
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -194.05240438 eV

  energy without entropy =     -194.06248069  energy(sigma->0) =     -194.05576315


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  2610
 total energy-change (2. order) :-0.7479988E+01  (-0.7452802E+01)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6645.44251904
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77251382
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.02126080
  eigenvalues    EBANDS =     -1377.50051972
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -201.53239288 eV

  energy without entropy =     -201.55365368  energy(sigma->0) =     -201.53947981


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :  2844
 total energy-change (2. order) :-0.1662230E+00  (-0.1660121E+00)
 number of electron      85.9999977 magnetization      -0.8875850
 augmentation part        4.7973658 magnetization      -0.9774680

 Broyden mixing:
  rms(total) = 0.26329E+01    rms(broyden)= 0.26285E+01
  rms(prec ) = 0.31515E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6645.44251904
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77251382
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.02135612
  eigenvalues    EBANDS =     -1377.66683806
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -201.69861590 eV

  energy without entropy =     -201.71997202  energy(sigma->0) =     -201.70573461


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  2457
 total energy-change (2. order) : 0.1659838E+02  (-0.3601503E+01)
 number of electron      85.9999980 magnetization      -0.5173508
 augmentation part        4.2302227 magnetization      -0.4427286

 Broyden mixing:
  rms(total) = 0.13023E+01    rms(broyden)= 0.13018E+01
  rms(prec ) = 0.14949E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1399
  1.1399

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6817.74541262
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.13721783
  PAW double counting   =      4257.76772017    -4255.91062784
  entropy T*S    EENTRO =         0.02308164
  eigenvalues    EBANDS =     -1197.11414022
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -185.10023724 eV

  energy without entropy =     -185.12331887  energy(sigma->0) =     -185.10793112


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  2610
 total energy-change (2. order) : 0.1652994E+01  (-0.6538106E+00)
 number of electron      85.9999977 magnetization      -0.2384590
 augmentation part        4.1651886 magnetization      -0.2356527

 Broyden mixing:
  rms(total) = 0.62768E+00    rms(broyden)= 0.62738E+00
  rms(prec ) = 0.72037E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3096
  0.8830  1.7362

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6901.18245178
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.25181069
  PAW double counting   =      5909.28649746    -5907.72514895
  entropy T*S    EENTRO =         0.00736539
  eigenvalues    EBANDS =     -1115.82723938
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.44724276 eV

  energy without entropy =     -183.45460815  energy(sigma->0) =     -183.44969789


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  2457
 total energy-change (2. order) : 0.2091821E+00  (-0.1237323E+00)
 number of electron      85.9999976 magnetization      -0.0848154
 augmentation part        4.1535683 magnetization      -0.1232807

 Broyden mixing:
  rms(total) = 0.24953E+00    rms(broyden)= 0.24911E+00
  rms(prec ) = 0.30881E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3489
  2.1173  1.1454  0.7839

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6942.87121947
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       297.32996446
  PAW double counting   =      6903.35670448    -6901.81684385
  entropy T*S    EENTRO =         0.01326375
  eigenvalues    EBANDS =     -1075.99185385
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.23806067 eV

  energy without entropy =     -183.25132441  energy(sigma->0) =     -183.24248191


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  2466
 total energy-change (2. order) :-0.3250612E-01  (-0.2943281E-01)
 number of electron      85.9999976 magnetization       0.0063640
 augmentation part        4.1581266 magnetization      -0.0798531

 Broyden mixing:
  rms(total) = 0.10672E+00    rms(broyden)= 0.10536E+00
  rms(prec ) = 0.15504E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3008
  2.1616  1.3765  0.9843  0.6808

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6963.05272272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.19547598
  PAW double counting   =      7237.13908782    -7235.57141098
  entropy T*S    EENTRO =         0.02333094
  eigenvalues    EBANDS =     -1056.74625164
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.27056679 eV

  energy without entropy =     -183.29389772  energy(sigma->0) =     -183.27834377


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :  2349
 total energy-change (2. order) :-0.3227023E-02  (-0.2186768E-01)
 number of electron      85.9999974 magnetization       0.0134051
 augmentation part        4.1413878 magnetization      -0.0125343

 Broyden mixing:
  rms(total) = 0.11025E+00    rms(broyden)= 0.10836E+00
  rms(prec ) = 0.13815E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1484
  2.0688  1.5208  0.8386  0.8386  0.4751

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6974.47413772
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.56633848
  PAW double counting   =      7276.43312932    -7274.84763251
  entropy T*S    EENTRO =         0.01157089
  eigenvalues    EBANDS =     -1045.70498608
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.27379381 eV

  energy without entropy =     -183.28536470  energy(sigma->0) =     -183.27765078


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  2286
 total energy-change (2. order) :-0.3456873E-01  (-0.7976707E-02)
 number of electron      85.9999974 magnetization       0.0389655
 augmentation part        4.1410873 magnetization      -0.0689984

 Broyden mixing:
  rms(total) = 0.93352E-01    rms(broyden)= 0.91845E-01
  rms(prec ) = 0.12131E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0290
  2.0096  1.5906  0.8130  0.8130  0.4738  0.4738

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6977.72399251
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.58400576
  PAW double counting   =      7256.39490638    -7254.78490961
  entropy T*S    EENTRO =         0.02387874
  eigenvalues    EBANDS =     -1042.54417510
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.30836254 eV

  energy without entropy =     -183.33224128  energy(sigma->0) =     -183.31632212


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  2475
 total energy-change (2. order) :-0.4077704E-02  (-0.4904674E-02)
 number of electron      85.9999973 magnetization       0.0732421
 augmentation part        4.1453735 magnetization      -0.0119451

 Broyden mixing:
  rms(total) = 0.71243E-01    rms(broyden)= 0.70252E-01
  rms(prec ) = 0.98430E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2002
  1.5887  1.5887  1.7634  1.4346  0.9066  0.7072  0.4125

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6981.06377851
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.63873439
  PAW double counting   =      7246.21055908    -7244.58111110
  entropy T*S    EENTRO =         0.02035727
  eigenvalues    EBANDS =     -1039.27912518
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.31244025 eV

  energy without entropy =     -183.33279751  energy(sigma->0) =     -183.31922600


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  2394
 total energy-change (2. order) : 0.1555919E-01  (-0.1414303E-01)
 number of electron      85.9999972 magnetization       0.0872661
 augmentation part        4.1469995 magnetization      -0.0115547

 Broyden mixing:
  rms(total) = 0.54852E-01    rms(broyden)= 0.52138E-01
  rms(prec ) = 0.72133E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2588
  1.7456  1.7456  2.0038  1.6755  0.9182  0.9182  0.6490  0.4143

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6988.63834573
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.78887239
  PAW double counting   =      7225.59058767    -7223.94275159
  entropy T*S    EENTRO =         0.02270524
  eigenvalues    EBANDS =     -1031.85987285
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.29688105 eV

  energy without entropy =     -183.31958629  energy(sigma->0) =     -183.30444947


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  2277
 total energy-change (2. order) :-0.2031038E-01  (-0.5197710E-02)
 number of electron      85.9999972 magnetization       0.1036404
 augmentation part        4.1458059 magnetization       0.0119840

 Broyden mixing:
  rms(total) = 0.36945E-01    rms(broyden)= 0.36157E-01
  rms(prec ) = 0.54029E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2709
  2.1039  2.1039  2.0730  1.6580  0.9017  0.9017  0.6428  0.6428  0.4101

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6992.27501073
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.84677971
  PAW double counting   =      7230.72157655    -7229.07746889
  entropy T*S    EENTRO =         0.02386374
  eigenvalues    EBANDS =     -1028.29885562
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.31719143 eV

  energy without entropy =     -183.34105517  energy(sigma->0) =     -183.32514601


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :  2259
 total energy-change (2. order) :-0.2503781E-02  (-0.3667766E-02)
 number of electron      85.9999972 magnetization       0.1003674
 augmentation part        4.1447970 magnetization       0.0169723

 Broyden mixing:
  rms(total) = 0.30984E-01    rms(broyden)= 0.29985E-01
  rms(prec ) = 0.42549E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3355
  2.5200  2.5200  2.1209  1.6105  0.8695  0.8695  0.8917  0.8917  0.6478  0.4133

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -6996.93319999
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.93240361
  PAW double counting   =      7230.85039619    -7229.19447516
  entropy T*S    EENTRO =         0.02433351
  eigenvalues    EBANDS =     -1023.74107719
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.31969521 eV

  energy without entropy =     -183.34402872  energy(sigma->0) =     -183.32780638


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  2304
 total energy-change (2. order) :-0.6181427E-02  (-0.6884140E-02)
 number of electron      85.9999971 magnetization       0.0864686
 augmentation part        4.1451664 magnetization       0.0461431

 Broyden mixing:
  rms(total) = 0.26549E-01    rms(broyden)= 0.24917E-01
  rms(prec ) = 0.32747E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4153
  3.1691  3.1691  2.1826  1.5291  1.0552  1.0552  0.8978  0.8978  0.6566  0.4105
  0.5458

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7000.83965932
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.97556831
  PAW double counting   =      7229.03734575    -7227.37958966
  entropy T*S    EENTRO =         0.02775103
  eigenvalues    EBANDS =     -1019.88921656
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.32587664 eV

  energy without entropy =     -183.35362767  energy(sigma->0) =     -183.33512698


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  2358
 total energy-change (2. order) :-0.6478057E-02  (-0.4461376E-02)
 number of electron      85.9999971 magnetization       0.0653990
 augmentation part        4.1429888 magnetization       0.0555250

 Broyden mixing:
  rms(total) = 0.29065E-01    rms(broyden)= 0.27782E-01
  rms(prec ) = 0.31941E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3981
  3.4347  3.4347  2.1964  1.5445  1.0992  1.0992  0.8901  0.8901  0.6792  0.4130
  0.5481  0.5481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7003.60998972
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01013941
  PAW double counting   =      7227.84802072    -7226.18968472
  entropy T*S    EENTRO =         0.02728822
  eigenvalues    EBANDS =     -1017.16005242
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33235470 eV

  energy without entropy =     -183.35964291  energy(sigma->0) =     -183.34145077


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  2394
 total energy-change (2. order) :-0.5222232E-02  (-0.1601616E-02)
 number of electron      85.9999972 magnetization       0.0776266
 augmentation part        4.1432762 magnetization       0.1018703

 Broyden mixing:
  rms(total) = 0.32209E-01    rms(broyden)= 0.31568E-01
  rms(prec ) = 0.34904E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4286
  3.3705  3.3705  1.5758  2.2190  1.5405  1.1848  1.1848  0.9233  0.9233  0.7189
  0.4117  0.5745  0.5745

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7004.35615420
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.00809158
  PAW double counting   =      7227.14474023    -7225.48546437
  entropy T*S    EENTRO =         0.02946067
  eigenvalues    EBANDS =     -1016.42017466
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33757693 eV

  energy without entropy =     -183.36703760  energy(sigma->0) =     -183.34739715


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  2250
 total energy-change (2. order) :-0.2076424E-04  (-0.1435171E-03)
 number of electron      85.9999971 magnetization       0.0928444
 augmentation part        4.1429231 magnetization       0.0993717

 Broyden mixing:
  rms(total) = 0.30887E-01    rms(broyden)= 0.30873E-01
  rms(prec ) = 0.34277E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3776
  3.4420  3.4420  1.9353  2.2364  1.5205  1.1963  1.1963  0.9218  0.9218  0.7186
  0.4119  0.5677  0.5677  0.2078

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7004.34376162
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.00986542
  PAW double counting   =      7226.64597228    -7224.98691409
  entropy T*S    EENTRO =         0.02882471
  eigenvalues    EBANDS =     -1016.43350821
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33759769 eV

  energy without entropy =     -183.36642241  energy(sigma->0) =     -183.34720593


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :  2484
 total energy-change (2. order) : 0.4338366E-03  (-0.7382472E-04)
 number of electron      85.9999971 magnetization       0.1459511
 augmentation part        4.1427659 magnetization       0.1335538

 Broyden mixing:
  rms(total) = 0.29472E-01    rms(broyden)= 0.29403E-01
  rms(prec ) = 0.32849E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4981
  3.1596  3.7521  3.7521  2.2627  1.2532  1.2532  1.4729  0.7624  0.7624  0.9297
  0.8401  0.7431  0.4115  0.5825  0.5338

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7004.49616266
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01258511
  PAW double counting   =      7226.53745533    -7224.87807897
  entropy T*S    EENTRO =         0.02808364
  eigenvalues    EBANDS =     -1016.28297012
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33716386 eV

  energy without entropy =     -183.36524749  energy(sigma->0) =     -183.34652507


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  2241
 total energy-change (2. order) : 0.1153395E-02  (-0.9545552E-03)
 number of electron      85.9999971 magnetization       0.1823249
 augmentation part        4.1433994 magnetization       0.1172594

 Broyden mixing:
  rms(total) = 0.32543E-01    rms(broyden)= 0.32092E-01
  rms(prec ) = 0.34961E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5006
  3.9675  3.7898  3.7898  2.2568  1.2954  1.2954  1.4934  0.8499  0.8499  0.9393
  0.7895  0.7895  0.5820  0.5108  0.4133  0.3966

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7005.07546775
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01668711
  PAW double counting   =      7226.60751437    -7224.94635652
  entropy T*S    EENTRO =         0.02710162
  eigenvalues    EBANDS =     -1015.70741309
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33601046 eV

  energy without entropy =     -183.36311208  energy(sigma->0) =     -183.34504433


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  2457
 total energy-change (2. order) : 0.2439469E-04  (-0.3628027E-03)
 number of electron      85.9999971 magnetization       0.1046755
 augmentation part        4.1436074 magnetization       0.0339881

 Broyden mixing:
  rms(total) = 0.47515E-01    rms(broyden)= 0.47433E-01
  rms(prec ) = 0.49951E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4654
  4.4255  4.4255  2.2730  1.4460  1.4460  1.4467  1.4467  1.4886  1.0244  0.9285
  0.9285  0.7479  0.7479  0.4113  0.5962  0.5962  0.5332

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7004.94560408
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01547074
  PAW double counting   =      7226.88049629    -7225.21901116
  entropy T*S    EENTRO =         0.02495845
  eigenvalues    EBANDS =     -1015.83422012
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33598607 eV

  energy without entropy =     -183.36094451  energy(sigma->0) =     -183.34430555


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  2250
 total energy-change (2. order) :-0.6425148E-02  (-0.2855783E-02)
 number of electron      85.9999971 magnetization       0.1304250
 augmentation part        4.1432681 magnetization       0.0840167

 Broyden mixing:
  rms(total) = 0.21919E-01    rms(broyden)= 0.21233E-01
  rms(prec ) = 0.25727E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4371
  4.7475  4.7475  2.2937  1.3802  1.3802  1.4867  1.4867  1.5035  1.0182  0.9161
  0.9161  0.7698  0.7062  0.6083  0.6083  0.4616  0.4125  0.4249

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7005.45353785
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01292876
  PAW double counting   =      7227.56477380    -7225.90543541
  entropy T*S    EENTRO =         0.03087305
  eigenvalues    EBANDS =     -1015.33393737
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34241121 eV

  energy without entropy =     -183.37328426  energy(sigma->0) =     -183.35270223


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  2052
 total energy-change (2. order) :-0.2152356E-02  (-0.5592603E-03)
 number of electron      85.9999971 magnetization       0.1399629
 augmentation part        4.1428197 magnetization       0.0631055

 Broyden mixing:
  rms(total) = 0.21174E-01    rms(broyden)= 0.20970E-01
  rms(prec ) = 0.24568E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5027
  5.5214  5.5214  2.2826  1.3210  1.3210  1.5916  1.5916  1.5916  0.9637  0.9637
  1.0368  0.8106  0.6602  0.6602  0.6819  0.4114  0.5728  0.5728  0.4760

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7005.83754495
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01447545
  PAW double counting   =      7228.10344487    -7226.44368109
  entropy T*S    EENTRO =         0.03103487
  eigenvalues    EBANDS =     -1014.95421654
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34456357 eV

  energy without entropy =     -183.37559844  energy(sigma->0) =     -183.35490853


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :  2439
 total energy-change (2. order) :-0.1789097E-02  (-0.1097273E-02)
 number of electron      85.9999971 magnetization       0.1228001
 augmentation part        4.1425941 magnetization       0.0292749

 Broyden mixing:
  rms(total) = 0.19536E-01    rms(broyden)= 0.19175E-01
  rms(prec ) = 0.23988E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5308
  5.6305  5.6305  2.1113  2.2261  1.7178  1.7178  1.6441  0.8922  1.0456  1.0456
  0.9789  0.8712  0.8712  0.7737  0.7737  0.6376  0.6376  0.4114  0.4992  0.4992

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7006.32872584
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01645395
  PAW double counting   =      7226.95911222    -7225.29952193
  entropy T*S    EENTRO =         0.03389180
  eigenvalues    EBANDS =     -1014.46948668
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34635267 eV

  energy without entropy =     -183.38024447  energy(sigma->0) =     -183.35764993


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  2250
 total energy-change (2. order) :-0.1021571E-02  (-0.1134858E-03)
 number of electron      85.9999971 magnetization       0.0109336
 augmentation part        4.1420614 magnetization      -0.0727078

 Broyden mixing:
  rms(total) = 0.17298E-01    rms(broyden)= 0.17261E-01
  rms(prec ) = 0.22300E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4669
  5.7027  5.7027  2.2320  1.3779  1.3779  1.6797  1.6797  1.6377  0.9769  0.9769
  0.8870  0.8870  0.9473  0.7970  0.7970  0.6322  0.6322  0.4114  0.5006  0.5006
  0.4685

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7006.36382233
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01662339
  PAW double counting   =      7227.14812558    -7225.48850259
  entropy T*S    EENTRO =         0.03330724
  eigenvalues    EBANDS =     -1014.43502934
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34737424 eV

  energy without entropy =     -183.38068148  energy(sigma->0) =     -183.35847665


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  2349
 total energy-change (2. order) : 0.1696640E-02  (-0.2446318E-02)
 number of electron      85.9999972 magnetization      -0.0441987
 augmentation part        4.1422525 magnetization      -0.0056121

 Broyden mixing:
  rms(total) = 0.30653E-01    rms(broyden)= 0.28402E-01
  rms(prec ) = 0.30313E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5412
  6.3713  4.4357  2.8745  2.8745  2.2414  1.5686  1.5686  1.5980  0.7704  1.0351
  1.0351  0.9609  0.9609  0.8275  0.8275  0.6711  0.6711  0.4114  0.6230  0.5741
  0.5397  0.4661

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7006.60772666
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.01728539
  PAW double counting   =      7230.06734382    -7228.40469424
  entropy T*S    EENTRO =         0.02827250
  eigenvalues    EBANDS =     -1014.18808221
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34567760 eV

  energy without entropy =     -183.37395010  energy(sigma->0) =     -183.35510176


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :  2475
 total energy-change (2. order) :-0.9755092E-03  (-0.7463861E-03)
 number of electron      85.9999973 magnetization      -0.1946736
 augmentation part        4.1424897 magnetization      -0.1284072

 Broyden mixing:
  rms(total) = 0.40929E-01    rms(broyden)= 0.40401E-01
  rms(prec ) = 0.41586E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5136
  5.2960  5.2960  3.1670  3.1670  2.2241  1.5765  1.5765  1.6361  0.7700  0.9958
  0.9958  0.9940  0.9940  0.8376  0.8376  0.6645  0.6645  0.6976  0.6180  0.4114
  0.4992  0.4464  0.4464

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7007.24883859
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02458714
  PAW double counting   =      7227.09216553    -7225.42677618
  entropy T*S    EENTRO =         0.01925599
  eigenvalues    EBANDS =     -1013.54897082
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34665311 eV

  energy without entropy =     -183.36590910  energy(sigma->0) =     -183.35307177


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :  2385
 total energy-change (2. order) : 0.1412554E-01  (-0.2300211E-02)
 number of electron      85.9999973 magnetization      -0.1998723
 augmentation part        4.1409833 magnetization      -0.1944497

 Broyden mixing:
  rms(total) = 0.10026E+00    rms(broyden)= 0.10019E+00
  rms(prec ) = 0.10146E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4833
  6.5692  4.6349  3.1268  3.1268  2.2453  1.5954  1.5954  1.6311  0.7726  1.0172
  1.0172  0.9971  0.9971  0.7907  0.7907  0.6764  0.6764  0.6836  0.6189  0.4114
  0.4996  0.4576  0.3339  0.3339

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7007.34242611
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.04217536
  PAW double counting   =      7228.46998556    -7226.80548191
  entropy T*S    EENTRO =         0.00891116
  eigenvalues    EBANDS =     -1013.44761543
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33252757 eV

  energy without entropy =     -183.34143873  energy(sigma->0) =     -183.33549796


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :  2385
 total energy-change (2. order) :-0.1671587E-02  (-0.1383756E-02)
 number of electron      85.9999973 magnetization      -0.1344417
 augmentation part        4.1412508 magnetization      -0.1303171

 Broyden mixing:
  rms(total) = 0.10358E+00    rms(broyden)= 0.10350E+00
  rms(prec ) = 0.10559E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4641
  7.4935  4.2982  2.6414  2.6414  2.2309  1.6044  1.6044  1.6783  0.7764  1.0885
  1.0885  0.5428  0.5428  0.8602  0.8602  0.9535  0.9535  0.7154  0.7154  0.7117
  0.6185  0.4114  0.5398  0.5160  0.5160

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7007.47494619
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.04161919
  PAW double counting   =      7230.08248799    -7228.41754043
  entropy T*S    EENTRO =         0.00915420
  eigenvalues    EBANDS =     -1013.31689773
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.33419916 eV

  energy without entropy =     -183.34335335  energy(sigma->0) =     -183.33725056


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :  2547
 total energy-change (2. order) :-0.1249747E-01  (-0.8190957E-03)
 number of electron      85.9999973 magnetization      -0.0761792
 augmentation part        4.1413222 magnetization      -0.0366881

 Broyden mixing:
  rms(total) = 0.56426E-01    rms(broyden)= 0.56283E-01
  rms(prec ) = 0.58786E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4392
  6.8952  4.6934  2.3085  2.3085  1.9128  1.9128  2.0262  2.0262  0.7764  1.2334
  1.2334  1.1483  0.9015  0.9015  0.5364  0.5364  0.7195  0.7195  0.7252  0.7252
  0.4114  0.6035  0.5719  0.5719  0.5104  0.5104

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7007.74138092
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.03474217
  PAW double counting   =      7227.63001063    -7225.96682883
  entropy T*S    EENTRO =         0.01656087
  eigenvalues    EBANDS =     -1013.06172436
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.34669663 eV

  energy without entropy =     -183.36325750  energy(sigma->0) =     -183.35221692


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :  2466
 total energy-change (2. order) :-0.5779000E-02  (-0.7020998E-03)
 number of electron      85.9999971 magnetization      -0.1155375
 augmentation part        4.1412960 magnetization      -0.0038082

 Broyden mixing:
  rms(total) = 0.27607E-01    rms(broyden)= 0.26907E-01
  rms(prec ) = 0.30032E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3861
  5.3958  5.3958  2.4337  2.4337  2.0351  2.0351  2.0307  2.0307  0.7762  1.2867
  1.2867  1.0930  0.5122  0.5122  0.8691  0.8691  0.7271  0.7271  0.7207  0.7207
  0.6004  0.5523  0.5523  0.4114  0.5176  0.5176  0.3818

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.07789475
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.03086889
  PAW double counting   =      7223.21140955    -7221.55058271
  entropy T*S    EENTRO =         0.03242022
  eigenvalues    EBANDS =     -1012.74062064
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35247563 eV

  energy without entropy =     -183.38489585  energy(sigma->0) =     -183.36328237


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :  2205
 total energy-change (2. order) :-0.4595634E-03  (-0.2637586E-03)
 number of electron      85.9999972 magnetization      -0.0720627
 augmentation part        4.1410183 magnetization      -0.0018599

 Broyden mixing:
  rms(total) = 0.35250E-01    rms(broyden)= 0.35200E-01
  rms(prec ) = 0.37191E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3718
  5.6080  5.6080  2.3195  2.3195  2.0358  2.0358  2.0053  2.0053  0.7761  1.2944
  1.2944  1.1212  0.9539  0.9539  0.5289  0.5289  0.7684  0.7684  0.6223  0.6223
  0.6898  0.6898  0.6148  0.4114  0.5067  0.5067  0.5002  0.3210

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7007.98841934
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.03185587
  PAW double counting   =      7223.14199553    -7221.48125481
  entropy T*S    EENTRO =         0.02360675
  eigenvalues    EBANDS =     -1012.82264301
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35293519 eV

  energy without entropy =     -183.37654195  energy(sigma->0) =     -183.36080411


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :  2268
 total energy-change (2. order) :-0.1153013E-02  (-0.1979225E-03)
 number of electron      85.9999971 magnetization      -0.0720039
 augmentation part        4.1416859 magnetization       0.0445624

 Broyden mixing:
  rms(total) = 0.29491E-01    rms(broyden)= 0.29355E-01
  rms(prec ) = 0.31827E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3564
  5.7695  5.3755  2.3938  2.3938  2.0106  2.0106  2.0730  1.8652  0.7763  1.3101
  1.3101  1.1901  0.7725  0.7725  0.9529  0.9529  0.5429  0.5429  0.7625  0.7625
  0.6772  0.6772  0.4114  0.6135  0.6135  0.5724  0.5180  0.5180  0.1946

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.20487301
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02883303
  PAW double counting   =      7222.32250452    -7220.66162067
  entropy T*S    EENTRO =         0.03339050
  eigenvalues    EBANDS =     -1012.61424639
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35408821 eV

  energy without entropy =     -183.38747871  energy(sigma->0) =     -183.36521837


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :  2349
 total energy-change (2. order) :-0.5231053E-03  (-0.4979191E-04)
 number of electron      85.9999971 magnetization      -0.0993153
 augmentation part        4.1419035 magnetization       0.0179990

 Broyden mixing:
  rms(total) = 0.30901E-01    rms(broyden)= 0.30893E-01
  rms(prec ) = 0.32995E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3544
  5.3883  5.3883  2.5124  2.5124  2.2237  1.8910  1.8910  1.9123  0.7764  1.4104
  1.4104  1.0502  1.0502  1.1693  0.5519  0.5519  0.8462  0.8462  0.8980  0.8980
  0.6460  0.6460  0.6762  0.6762  0.4114  0.6001  0.5352  0.5233  0.5233  0.2159

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.22549229
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02767253
  PAW double counting   =      7223.36213085    -7221.70103391
  entropy T*S    EENTRO =         0.03354612
  eigenvalues    EBANDS =     -1012.59335842
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35461131 eV

  energy without entropy =     -183.38815743  energy(sigma->0) =     -183.36579335


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :  2439
 total energy-change (2. order) :-0.2567736E-02  (-0.6050032E-03)
 number of electron      85.9999972 magnetization      -0.0946532
 augmentation part        4.1426143 magnetization      -0.0051763

 Broyden mixing:
  rms(total) = 0.87718E-02    rms(broyden)= 0.81455E-02
  rms(prec ) = 0.88601E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3322
  6.6636  2.5355  2.5355  3.1114  2.5631  2.2023  2.2023  0.7764  1.6899  1.3996
  1.3996  1.4222  1.0331  1.0331  0.5507  0.5507  0.8190  0.8190  0.8486  0.8486
  0.7185  0.7185  0.6848  0.6848  0.6725  0.6321  0.4114  0.5207  0.5207  0.5154
  0.2151

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.08756888
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02450398
  PAW double counting   =      7225.32354125    -7223.66110240
  entropy T*S    EENTRO =         0.02617110
  eigenvalues    EBANDS =     -1012.72464790
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35717905 eV

  energy without entropy =     -183.38335015  energy(sigma->0) =     -183.36590275


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :  2637
 total energy-change (2. order) :-0.1163760E-02  (-0.2554600E-03)
 number of electron      85.9999972 magnetization      -0.0935512
 augmentation part        4.1429366 magnetization      -0.0079766

 Broyden mixing:
  rms(total) = 0.69189E-02    rms(broyden)= 0.65504E-02
  rms(prec ) = 0.73674E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3182
  6.9788  2.5410  2.5410  3.2064  2.4553  2.2780  2.2780  0.7764  1.4399  1.4399
  1.3885  1.3885  1.0299  1.0299  0.5514  0.5514  0.8742  0.8742  0.8551  0.8551
  0.7467  0.7467  0.6500  0.6500  0.6916  0.6311  0.4114  0.5347  0.5347  0.5188
  0.5188  0.2152

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.09443191
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02430447
  PAW double counting   =      7225.44967714    -7223.78681739
  entropy T*S    EENTRO =         0.02449843
  eigenvalues    EBANDS =     -1012.71749735
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35834281 eV

  energy without entropy =     -183.38284124  energy(sigma->0) =     -183.36650895


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :  2286
 total energy-change (2. order) :-0.8109884E-03  (-0.1963928E-04)
 number of electron      85.9999972 magnetization      -0.1173051
 augmentation part        4.1426273 magnetization      -0.0306259

 Broyden mixing:
  rms(total) = 0.75778E-02    rms(broyden)= 0.75646E-02
  rms(prec ) = 0.81102E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3238
  7.2560  2.5397  2.5397  3.0512  2.3532  2.3532  2.4093  1.5665  1.5665  0.7764
  1.2686  1.2686  1.1632  1.1632  0.9326  0.9326  0.5512  0.5512  0.8884  0.8884
  0.6830  0.6830  0.7093  0.7093  0.7712  0.4114  0.6438  0.6438  0.6329  0.5263
  0.5190  0.5190  0.2151

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.11243333
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02398311
  PAW double counting   =      7225.40665533    -7223.74419398
  entropy T*S    EENTRO =         0.02454155
  eigenvalues    EBANDS =     -1012.69963028
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35915380 eV

  energy without entropy =     -183.38369534  energy(sigma->0) =     -183.36733431


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :  2421
 total energy-change (2. order) :-0.2179223E-03  (-0.5616529E-04)
 number of electron      85.9999972 magnetization      -0.1030190
 augmentation part        4.1422377 magnetization      -0.0375390

 Broyden mixing:
  rms(total) = 0.17787E-01    rms(broyden)= 0.17737E-01
  rms(prec ) = 0.18165E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3296
  7.2763  2.5432  2.5432  3.0727  2.2212  2.2212  2.2203  1.4963  1.4963  1.6085
  1.6085  0.7764  1.3889  1.3889  0.9504  0.9504  0.5510  0.5510  0.9530  0.9530
  0.7190  0.7190  0.7186  0.7186  0.7179  0.7179  0.4114  0.6798  0.6273  0.6273
  0.5238  0.5238  0.5172  0.2151

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.13467221
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02451841
  PAW double counting   =      7224.78213660    -7223.12002037
  entropy T*S    EENTRO =         0.02032495
  eigenvalues    EBANDS =     -1012.67358291
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35937172 eV

  energy without entropy =     -183.37969667  energy(sigma->0) =     -183.36614670


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------



 eigenvalue-minimisations  :  2223
 total energy-change (2. order) :-0.5893597E-03  (-0.1774038E-04)
 number of electron      85.9999972 magnetization      -0.1055926
 augmentation part        4.1423140 magnetization      -0.0242135

 Broyden mixing:
  rms(total) = 0.17190E-02    rms(broyden)= 0.15652E-02
  rms(prec ) = 0.19630E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3445
  7.4221  3.4202  2.5432  2.5432  2.2653  2.2653  1.9763  1.9763  1.5934  1.5934
  0.7764  1.5931  1.5931  1.2334  1.0062  1.0062  0.5510  0.5510  0.9624  0.9624
  0.6963  0.6963  0.7561  0.7561  0.7836  0.7836  0.6769  0.6769  0.4114  0.6229
  0.5802  0.5226  0.5226  0.5239  0.2151

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.11582998
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02244670
  PAW double counting   =      7224.14813426    -7222.48613104
  entropy T*S    EENTRO =         0.02335511
  eigenvalues    EBANDS =     -1012.69385994
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.35996108 eV

  energy without entropy =     -183.38331619  energy(sigma->0) =     -183.36774612


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  41)  ---------------------------------------



 eigenvalue-minimisations  :  2493
 total energy-change (2. order) :-0.3078672E-03  (-0.2883956E-04)
 number of electron      85.9999972 magnetization      -0.1044388
 augmentation part        4.1421969 magnetization      -0.0222900

 Broyden mixing:
  rms(total) = 0.31952E-02    rms(broyden)= 0.31447E-02
  rms(prec ) = 0.33634E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3477
  7.4146  4.0579  2.5433  2.5433  2.1872  2.1872  2.1211  2.1211  1.7584  0.7764
  1.4324  1.4324  1.3922  1.3922  1.0488  1.0488  0.5510  0.5510  1.0046  1.0046
  0.8823  0.8823  0.7125  0.7125  0.6570  0.6570  0.7246  0.7246  0.4114  0.6193
  0.5949  0.5949  0.5230  0.5230  0.5138  0.2151

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3828.98641792
  -Hartree energ DENC   =     -7008.11470728
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.02157069
  PAW double counting   =      7224.18657624    -7222.52485669
  entropy T*S    EENTRO =         0.02374881
  eigenvalues    EBANDS =     -1012.69452453
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.36026895 eV

  energy without entropy =     -183.38401776  energy(sigma->0) =     -183.36818522


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