vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.19  22:12:13
 running on    3 total cores
 distrk:  each k-point on    3 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    3 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 2
   MAGMOM = 0.003 -0.042 -0.037 -0.015 -0.006 -1.266 3*-0.002 -0.004 0 -0.001 2*0 -0.002 4*0 -0.001 14*0
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.77 0.32
   NPAR = 3

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  3       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  4       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.560  0.558  0.479-   2 1.63   4 1.63   3 1.64   5 1.66
   2  0.602  0.613  0.362-   7 1.44   1 1.63
   3  0.628  0.610  0.586-   9 1.43   1 1.64
   4  0.582  0.424  0.479-  11 1.44   1 1.63
   5  0.425  0.582  0.490-  13 1.40   1 1.66
   6  0.367  0.679  0.792-
   7  0.550  0.697  0.295-  15 1.10  16 1.10   2 1.44   8 1.52
   8  0.637  0.773  0.246-  18 1.10  19 1.10  17 1.10   7 1.52
   9  0.626  0.726  0.614-  20 1.11  21 1.11   3 1.43  10 1.52
  10  0.645  0.742  0.738-  22 1.09  24 1.10  23 1.11   9 1.52
  11  0.682  0.367  0.445-  25 1.10  26 1.11   4 1.44  12 1.52
  12  0.770  0.364  0.535-  27 1.10  29 1.10  28 1.10  11 1.52
  13  0.361  0.557  0.585-  30 1.09  34 1.16   5 1.40  14 1.61
  14  0.283  0.660  0.620-  32 1.10  31 1.11  33 1.19  13 1.61
  15  0.502  0.655  0.228-   7 1.10
  16  0.489  0.744  0.346-   7 1.10
  17  0.597  0.837  0.193-   8 1.10
  18  0.696  0.726  0.194-   8 1.10
  19  0.684  0.816  0.312-   8 1.10
  20  0.691  0.770  0.566-   9 1.11
  21  0.544  0.763  0.591-   9 1.11
  22  0.648  0.830  0.759-  10 1.09
  23  0.725  0.703  0.762-  10 1.11
  24  0.578  0.701  0.786-  10 1.10
  25  0.656  0.282  0.422-  11 1.10
  26  0.715  0.407  0.368-  11 1.11
  27  0.843  0.317  0.507-  12 1.10
  28  0.737  0.324  0.611-  12 1.10
  29  0.797  0.449  0.558-  12 1.10
  30  0.409  0.529  0.656-  13 1.09
  31  0.225  0.623  0.681-  14 1.11
  32  0.236  0.680  0.543-  14 1.10
  33  0.314  0.747  0.655-  14 1.19
  34  0.304  0.482  0.561-  13 1.16
 
  LATTYP: Found a simple cubic cell.
 ALAT       =    12.0000000000
  
  Lattice vectors:
  
 A1 = (  12.0000000000,   0.0000000000,   0.0000000000)
 A2 = (   0.0000000000,  12.0000000000,   0.0000000000)
 A3 = (   0.0000000000,   0.0000000000,  12.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple cubic supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 48 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    1728.0000

  direct lattice vectors                    reciprocal lattice vectors
    12.000000000  0.000000000  0.000000000     0.083333333  0.000000000  0.000000000
     0.000000000 12.000000000  0.000000000     0.000000000  0.083333333  0.000000000
     0.000000000  0.000000000 12.000000000     0.000000000  0.000000000  0.083333333

  length of vectors
    12.000000000 12.000000000 12.000000000     0.083333333  0.083333333  0.083333333

  position of ions in fractional coordinates (direct lattice)
     0.560243460  0.557742750  0.479303820
     0.602160460  0.612832660  0.362383970
     0.628050830  0.609758150  0.586378810
     0.582079370  0.423612870  0.479205220
     0.424624490  0.582080960  0.489937800
     0.366649640  0.678589060  0.792447410
     0.549557320  0.696721320  0.295224090
     0.637146970  0.773088600  0.245738430
     0.626094140  0.725790820  0.613920040
     0.645374100  0.741696750  0.737677380
     0.681669760  0.367029910  0.444716390
     0.769974460  0.364058960  0.535244230
     0.360632220  0.557155080  0.584522040
     0.282643780  0.659948620  0.619803990
     0.502219270  0.654748280  0.228477010
     0.489190990  0.744253240  0.345867820
     0.597339320  0.836543070  0.192676070
     0.696422460  0.725735010  0.194304040
     0.684219480  0.816049600  0.311751080
     0.691225570  0.769794290  0.565860110
     0.544345650  0.763241800  0.590536820
     0.647676040  0.830337920  0.758507340
     0.725394650  0.703213510  0.762263230
     0.578276220  0.701235190  0.785980010
     0.656176590  0.281524370  0.422439360
     0.715020980  0.406660360  0.368423810
     0.842928870  0.316844440  0.506511090
     0.737092580  0.323571620  0.610966290
     0.796624190  0.448907980  0.557714210
     0.409242270  0.529250990  0.655859150
     0.224543760  0.623069600  0.681119880
     0.235766830  0.679884190  0.543251510
     0.314231570  0.747459300  0.654511190
     0.304125530  0.482147650  0.561239250

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.041666667  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.041666667  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.041666667     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.041666667  0.041666667  0.041666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.041667  0.000000  0.000000      1.000000
  0.000000  0.041667  0.000000      1.000000
  0.000000  0.000000  0.041667      1.000000
  0.041667  0.041667  0.000000      1.000000
  0.000000  0.041667  0.041667      1.000000
  0.041667  0.000000  0.041667      1.000000
  0.041667  0.041667  0.041667      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     63
   number of dos      NEDOS =    301   number of ions     NIONS =     34
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 216000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   4378
   dimension x,y,z NGX =    60 NGY =   60 NGZ =   60
   dimension x,y,z NGXF=   120 NGYF=  120 NGZF=  120
   support grid    NGXF=   120 NGYF=  120 NGZF=  120
   ions per type =               1   5   8  20
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      2    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  19.57 19.57 19.57*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.329E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00 12.01  1.00
  Ionic Valenz
   ZVAL   =   4.00  6.00  4.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.77  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =      86.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.40E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      50.82       342.97
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.602180  1.137955  4.933757  0.362621
  Thomas-Fermi vector in A             =   1.654692
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           20
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     1728.00
      direct lattice vectors                 reciprocal lattice vectors
    12.000000000  0.000000000  0.000000000     0.083333333  0.000000000  0.000000000
     0.000000000 12.000000000  0.000000000     0.000000000  0.083333333  0.000000000
     0.000000000  0.000000000 12.000000000     0.000000000  0.000000000  0.083333333

  length of vectors
    12.000000000 12.000000000 12.000000000     0.083333333  0.083333333  0.083333333


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.04166667  0.00000000  0.00000000       0.125
   0.00000000  0.04166667  0.00000000       0.125
   0.00000000  0.00000000  0.04166667       0.125
   0.04166667  0.04166667  0.00000000       0.125
   0.00000000  0.04166667  0.04166667       0.125
   0.04166667  0.00000000  0.04166667       0.125
   0.04166667  0.04166667  0.04166667       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.56024346  0.55774275  0.47930382
   0.60216046  0.61283266  0.36238397
   0.62805083  0.60975815  0.58637881
   0.58207937  0.42361287  0.47920522
   0.42462449  0.58208096  0.48993780
   0.36664964  0.67858906  0.79244741
   0.54955732  0.69672132  0.29522409
   0.63714697  0.77308860  0.24573843
   0.62609414  0.72579082  0.61392004
   0.64537410  0.74169675  0.73767738
   0.68166976  0.36702991  0.44471639
   0.76997446  0.36405896  0.53524423
   0.36063222  0.55715508  0.58452204
   0.28264378  0.65994862  0.61980399
   0.50221927  0.65474828  0.22847701
   0.48919099  0.74425324  0.34586782
   0.59733932  0.83654307  0.19267607
   0.69642246  0.72573501  0.19430404
   0.68421948  0.81604960  0.31175108
   0.69122557  0.76979429  0.56586011
   0.54434565  0.76324180  0.59053682
   0.64767604  0.83033792  0.75850734
   0.72539465  0.70321351  0.76226323
   0.57827622  0.70123519  0.78598001
   0.65617659  0.28152437  0.42243936
   0.71502098  0.40666036  0.36842381
   0.84292887  0.31684444  0.50651109
   0.73709258  0.32357162  0.61096629
   0.79662419  0.44890798  0.55771421
   0.40924227  0.52925099  0.65585915
   0.22454376  0.62306960  0.68111988
   0.23576683  0.67988419  0.54325151
   0.31423157  0.74745930  0.65451119
   0.30412553  0.48214765  0.56123925
 
 position of ions in cartesian coordinates  (Angst):
   6.72292152  6.69291300  5.75164584
   7.22592552  7.35399192  4.34860764
   7.53660996  7.31709780  7.03654572
   6.98495244  5.08335444  5.75046264
   5.09549388  6.98497152  5.87925360
   4.39979568  8.14306872  9.50936892
   6.59468784  8.36065584  3.54268908
   7.64576364  9.27706320  2.94886116
   7.51312968  8.70948984  7.36704048
   7.74448920  8.90036100  8.85212856
   8.18003712  4.40435892  5.33659668
   9.23969352  4.36870752  6.42293076
   4.32758664  6.68586096  7.01426448
   3.39172536  7.91938344  7.43764788
   6.02663124  7.85697936  2.74172412
   5.87029188  8.93103888  4.15041384
   7.16807184 10.03851684  2.31211284
   8.35706952  8.70882012  2.33164848
   8.21063376  9.79259520  3.74101296
   8.29470684  9.23753148  6.79032132
   6.53214780  9.15890160  7.08644184
   7.77211248  9.96405504  9.10208808
   8.70473580  8.43856212  9.14715876
   6.93931464  8.41482228  9.43176012
   7.87411908  3.37829244  5.06927232
   8.58025176  4.87992432  4.42108572
  10.11514644  3.80213328  6.07813308
   8.84511096  3.88285944  7.33159548
   9.55949028  5.38689576  6.69257052
   4.91090724  6.35101188  7.87030980
   2.69452512  7.47683520  8.17343856
   2.82920196  8.15861028  6.51901812
   3.77077884  8.96951160  7.85413428
   3.64950636  5.78577180  6.73487100
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   31439
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   31464
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   31464
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   31464
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   31400
 k-point  6 :   0.0000 0.5000 0.5000  plane waves:   31400
 k-point  7 :   0.5000 0.0000 0.5000  plane waves:   31400
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   31408

 maximum and minimum number of plane-waves per node :     31464    31400

 maximum number of plane-waves:     31464
 maximum index in each direction: 
   IXMAX=   19   IYMAX=   19   IZMAX=   19
   IXMIN=  -20   IYMIN=  -20   IZMIN=  -20

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    80 to avoid them
 WARNING: aliasing errors must be expected set NGY to    80 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    80 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   297347. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       2866. kBytes
   fftplans  :      20519. kBytes
   grid      :      73459. kBytes
   one-center:        208. kBytes
   wavefun   :     170295. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 39   NGY = 39   NGZ = 39
  (NGX  =120   NGY  =120   NGZ  =120)
  gives a total of  59319 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      86.0000000 magnetization      -1.3770000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1337
 Maximum index for augmentation-charges         1351 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.148
 Maximum number of real-space cells 3x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  2412
 total energy-change (2. order) : 0.6209799E+03  (-0.2514677E+04)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6586.34491607
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.38097109
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =        -0.00117909
  eigenvalues    EBANDS =      -551.46203058
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       620.97986819 eV

  energy without entropy =      620.98104728  energy(sigma->0) =      620.98026122


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  3006
 total energy-change (2. order) :-0.6398352E+03  (-0.6081272E+03)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6586.34491607
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.38097109
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =         0.00850168
  eigenvalues    EBANDS =     -1191.30692214
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -18.85534261 eV

  energy without entropy =      -18.86384429  energy(sigma->0) =      -18.85817650


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  2538
 total energy-change (2. order) :-0.1748709E+03  (-0.1739093E+03)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6586.34491607
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.38097109
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =        -0.04072490
  eigenvalues    EBANDS =     -1366.12864037
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -193.72628741 eV

  energy without entropy =     -193.68556251  energy(sigma->0) =     -193.71271245


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  2718
 total energy-change (2. order) :-0.8399500E+01  (-0.8364193E+01)
 number of electron      86.0000000 magnetization      -1.3770000
 augmentation part       86.0000000 magnetization      -1.3770000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6586.34491607
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.38097109
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =        -0.04569295
  eigenvalues    EBANDS =     -1374.52317215
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -202.12578725 eV

  energy without entropy =     -202.08009430  energy(sigma->0) =     -202.11055626


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :  2853
 total energy-change (2. order) :-0.1521604E+00  (-0.1519832E+00)
 number of electron      85.9999949 magnetization      -1.5914788
 augmentation part        4.7289851 magnetization      -0.0119553

 Broyden mixing:
  rms(total) = 0.25413E+01    rms(broyden)= 0.25383E+01
  rms(prec ) = 0.30788E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6586.34491607
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.38097109
  PAW double counting   =      2731.49734365    -2727.62239620
  entropy T*S    EENTRO =        -0.04561481
  eigenvalues    EBANDS =     -1374.67541064
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -202.27794760 eV

  energy without entropy =     -202.23233279  energy(sigma->0) =     -202.26274266


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  2556
 total energy-change (2. order) : 0.1577364E+02  (-0.3651009E+01)
 number of electron      85.9999961 magnetization      -1.7755770
 augmentation part        4.2378221 magnetization      -0.2130091

 Broyden mixing:
  rms(total) = 0.12622E+01    rms(broyden)= 0.12617E+01
  rms(prec ) = 0.14533E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1134
  1.1134

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6753.55151825
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       290.34770142
  PAW double counting   =      4236.23188079    -4234.16479367
  entropy T*S    EENTRO =        -0.05074482
  eigenvalues    EBANDS =     -1199.84891147
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -186.50431061 eV

  energy without entropy =     -186.45356579  energy(sigma->0) =     -186.48739567


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  2637
 total energy-change (2. order) : 0.2109732E+01  (-0.6260225E+00)
 number of electron      85.9999979 magnetization      -1.8917473
 augmentation part        4.1503654 magnetization      -0.3016282

 Broyden mixing:
  rms(total) = 0.71191E+00    rms(broyden)= 0.70864E+00
  rms(prec ) = 0.79738E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2136
  0.9325  1.4947

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6837.34480621
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.92614158
  PAW double counting   =      5865.44177573    -5863.86369942
  entropy T*S    EENTRO =         0.01299157
  eigenvalues    EBANDS =     -1118.09905712
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -184.39457848 eV

  energy without entropy =     -184.40757005  energy(sigma->0) =     -184.39890900


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  2547
 total energy-change (2. order) : 0.4963293E+00  (-0.1343328E+00)
 number of electron      85.9999980 magnetization      -1.9471822
 augmentation part        4.1680187 magnetization      -0.3688272

 Broyden mixing:
  rms(total) = 0.33106E+00    rms(broyden)= 0.33053E+00
  rms(prec ) = 0.38445E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2232
  1.9154  1.0265  0.7278

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6874.10735847
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       297.17416223
  PAW double counting   =      6759.39721021    -6757.67978048
  entropy T*S    EENTRO =         0.01773202
  eigenvalues    EBANDS =     -1083.23229007
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.89824916 eV

  energy without entropy =     -183.91598118  energy(sigma->0) =     -183.90415984


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  2430
 total energy-change (2. order) : 0.9634930E-02  (-0.3069581E-01)
 number of electron      85.9999979 magnetization      -1.9805584
 augmentation part        4.1518888 magnetization      -0.3843978

 Broyden mixing:
  rms(total) = 0.10571E+00    rms(broyden)= 0.10563E+00
  rms(prec ) = 0.15751E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3056
  2.1906  1.3532  0.9270  0.7515

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6897.62508058
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.26025269
  PAW double counting   =      7144.86967013    -7143.29311444
  entropy T*S    EENTRO =         0.02122942
  eigenvalues    EBANDS =     -1060.65364684
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.88861423 eV

  energy without entropy =     -183.90984365  energy(sigma->0) =     -183.89569071


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :  2421
 total energy-change (2. order) : 0.2375618E-01  (-0.8891618E-02)
 number of electron      85.9999980 magnetization      -1.9826591
 augmentation part        4.1431947 magnetization      -0.4089286

 Broyden mixing:
  rms(total) = 0.64730E-01    rms(broyden)= 0.64640E-01
  rms(prec ) = 0.10826E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2195
  2.1589  1.6018  0.8197  0.8197  0.6977

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6911.06443461
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.77098390
  PAW double counting   =      7252.64052443    -7251.00524320
  entropy T*S    EENTRO =         0.02152454
  eigenvalues    EBANDS =     -1047.76028851
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86485805 eV

  energy without entropy =     -183.88638259  energy(sigma->0) =     -183.87203290


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  2511
 total energy-change (2. order) : 0.7185778E-02  (-0.4161766E-02)
 number of electron      85.9999978 magnetization      -1.9957451
 augmentation part        4.1419919 magnetization      -0.3816773

 Broyden mixing:
  rms(total) = 0.61496E-01    rms(broyden)= 0.61317E-01
  rms(prec ) = 0.99760E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1026
  2.1610  1.6252  0.8298  0.8298  0.7310  0.4390

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6915.84985868
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.84934513
  PAW double counting   =      7237.24160100    -7235.60977582
  entropy T*S    EENTRO =         0.02052692
  eigenvalues    EBANDS =     -1043.04158622
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85767227 eV

  energy without entropy =     -183.87819920  energy(sigma->0) =     -183.86451458


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  2340
 total energy-change (2. order) : 0.5735433E-02  (-0.1755744E-02)
 number of electron      85.9999980 magnetization      -2.0074821
 augmentation part        4.1444907 magnetization      -0.4192593

 Broyden mixing:
  rms(total) = 0.27452E-01    rms(broyden)= 0.27301E-01
  rms(prec ) = 0.63915E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1932
  2.1647  2.1647  1.0752  1.0752  0.7710  0.6717  0.4302

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6920.92689920
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       298.94973521
  PAW double counting   =      7229.79034808    -7228.14064111
  entropy T*S    EENTRO =         0.02067289
  eigenvalues    EBANDS =     -1038.07722810
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85193684 eV

  energy without entropy =     -183.87260973  energy(sigma->0) =     -183.85882780


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  2277
 total energy-change (2. order) : 0.3853952E-02  (-0.1240247E-02)
 number of electron      85.9999980 magnetization      -2.0114493
 augmentation part        4.1445435 magnetization      -0.4188227

 Broyden mixing:
  rms(total) = 0.17731E-01    rms(broyden)= 0.17630E-01
  rms(prec ) = 0.39534E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2406
  2.4753  2.4753  1.2089  0.9535  0.9535  0.7501  0.6568  0.4514

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6931.44728085
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.13509811
  PAW double counting   =      7213.29384111    -7211.62364763
  entropy T*S    EENTRO =         0.02124631
  eigenvalues    EBANDS =     -1027.75941531
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.84808289 eV

  energy without entropy =     -183.86932920  energy(sigma->0) =     -183.85516499


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  2205
 total energy-change (2. order) :-0.2039392E-02  (-0.6254007E-03)
 number of electron      85.9999980 magnetization      -2.0154072
 augmentation part        4.1411175 magnetization      -0.4136483

 Broyden mixing:
  rms(total) = 0.13914E-01    rms(broyden)= 0.13877E-01
  rms(prec ) = 0.27369E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2707
  2.6213  2.6213  1.2379  1.2379  0.9535  0.9535  0.7236  0.6293  0.4576

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6937.38055915
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22037681
  PAW double counting   =      7198.98583783    -7197.32013642
  entropy T*S    EENTRO =         0.02164124
  eigenvalues    EBANDS =     -1021.90935798
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85012228 eV

  energy without entropy =     -183.87176352  energy(sigma->0) =     -183.85733603


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :  2277
 total energy-change (2. order) :-0.4618492E-02  (-0.2750783E-03)
 number of electron      85.9999980 magnetization      -2.0181089
 augmentation part        4.1399436 magnetization      -0.4164190

 Broyden mixing:
  rms(total) = 0.11224E-01    rms(broyden)= 0.11153E-01
  rms(prec ) = 0.19978E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2737
  2.6529  2.6529  1.4501  1.4501  0.9621  0.9621  0.7603  0.7603  0.6276  0.4589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6940.32748310
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23934417
  PAW double counting   =      7193.04300952    -7191.37521247
  entropy T*S    EENTRO =         0.02178924
  eigenvalues    EBANDS =     -1018.98826352
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85474077 eV

  energy without entropy =     -183.87653001  energy(sigma->0) =     -183.86200385


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  2277
 total energy-change (2. order) :-0.4729969E-02  (-0.1512103E-03)
 number of electron      85.9999980 magnetization      -2.0195689
 augmentation part        4.1401897 magnetization      -0.4155500

 Broyden mixing:
  rms(total) = 0.11474E-01    rms(broyden)= 0.11343E-01
  rms(prec ) = 0.16682E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2168
  2.6193  2.6193  1.3803  1.3803  1.0024  1.0024  0.7978  0.7978  0.6637  0.6637
  0.4584

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6942.10443985
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.24482817
  PAW double counting   =      7194.85059904    -7193.17870538
  entropy T*S    EENTRO =         0.02179601
  eigenvalues    EBANDS =     -1017.22562412
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85947074 eV

  energy without entropy =     -183.88126676  energy(sigma->0) =     -183.86673608


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  2439
 total energy-change (2. order) :-0.3037646E-02  (-0.1106828E-03)
 number of electron      85.9999979 magnetization      -2.0197114
 augmentation part        4.1402460 magnetization      -0.4141073

 Broyden mixing:
  rms(total) = 0.13473E-01    rms(broyden)= 0.13310E-01
  rms(prec ) = 0.17167E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1173
  2.6179  2.6179  1.3672  1.3672  0.9942  0.9942  0.7934  0.7934  0.6637  0.6637
  0.4583  0.0763

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6942.67374620
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.24362488
  PAW double counting   =      7195.66505724    -7193.99384530
  entropy T*S    EENTRO =         0.02182231
  eigenvalues    EBANDS =     -1016.65749671
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86250839 eV

  energy without entropy =     -183.88433070  energy(sigma->0) =     -183.86978249


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  2385
 total energy-change (2. order) :-0.1037209E-03  (-0.7469645E-05)
 number of electron      85.9999979 magnetization      -2.0198957
 augmentation part        4.1402008 magnetization      -0.4144420

 Broyden mixing:
  rms(total) = 0.13687E-01    rms(broyden)= 0.13664E-01
  rms(prec ) = 0.17450E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.3282
  1.9438  2.7428  2.7428  1.6071  1.6071  1.0704  1.0704  1.0030  1.0030  0.4582
  0.7327  0.6428  0.6428

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6942.66579842
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.24298520
  PAW double counting   =      7195.66307355    -7193.99182629
  entropy T*S    EENTRO =         0.02182964
  eigenvalues    EBANDS =     -1016.66495119
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86261211 eV

  energy without entropy =     -183.88444175  energy(sigma->0) =     -183.86988866


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  2178
 total energy-change (2. order) : 0.3139647E-02  (-0.3031464E-03)
 number of electron      85.9999980 magnetization      -2.0212292
 augmentation part        4.1401900 magnetization      -0.4144997

 Broyden mixing:
  rms(total) = 0.11704E-01    rms(broyden)= 0.11358E-01
  rms(prec ) = 0.15230E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4156
  3.2403  3.2457  2.7330  1.6658  1.6658  1.0138  1.0138  1.1071  1.1071  0.6894
  0.6696  0.6696  0.4583  0.5390

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6943.09609131
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25021856
  PAW double counting   =      7194.53854758    -7192.86838414
  entropy T*S    EENTRO =         0.02190680
  eigenvalues    EBANDS =     -1016.23774534
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85947246 eV

  energy without entropy =     -183.88137926  energy(sigma->0) =     -183.86677473


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :  2277
 total energy-change (2. order) : 0.1574548E-02  (-0.5651730E-03)
 number of electron      85.9999981 magnetization      -2.0214768
 augmentation part        4.1402664 magnetization      -0.4138166

 Broyden mixing:
  rms(total) = 0.11654E-01    rms(broyden)= 0.10766E-01
  rms(prec ) = 0.14381E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.4556
  4.1119  3.7818  2.5018  1.5495  1.5495  1.0980  1.0980  0.8781  0.8781  0.9693
  0.9693  0.4582  0.7037  0.6435  0.6435

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6943.79988664
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25792264
  PAW double counting   =      7193.50794190    -7191.83738912
  entropy T*S    EENTRO =         0.02191487
  eigenvalues    EBANDS =     -1015.54047695
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85789791 eV

  energy without entropy =     -183.87981278  energy(sigma->0) =     -183.86520287


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  2565
 total energy-change (2. order) :-0.1075141E-02  (-0.1080636E-03)
 number of electron      85.9999981 magnetization      -2.0220781
 augmentation part        4.1401237 magnetization      -0.4143266

 Broyden mixing:
  rms(total) = 0.10367E-01    rms(broyden)= 0.10071E-01
  rms(prec ) = 0.13799E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6153
  5.5798  4.3679  2.4213  1.9504  1.5904  1.5904  1.2089  1.0143  1.0143  0.9722
  0.9722  0.4583  0.7273  0.7273  0.6252  0.6252

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6943.89393043
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25951435
  PAW double counting   =      7193.25774581    -7191.58676240
  entropy T*S    EENTRO =         0.02188235
  eigenvalues    EBANDS =     -1015.44949813
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85897306 eV

  energy without entropy =     -183.88085541  energy(sigma->0) =     -183.86626717


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  2295
 total energy-change (2. order) :-0.6497207E-04  (-0.2460972E-03)
 number of electron      85.9999982 magnetization      -2.0257192
 augmentation part        4.1399967 magnetization      -0.4170030

 Broyden mixing:
  rms(total) = 0.87182E-02    rms(broyden)= 0.81810E-02
  rms(prec ) = 0.12157E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6684
  6.5952  4.6934  2.4384  2.0883  1.8654  1.8654  1.1693  1.0069  1.0069  0.9763
  0.9763  0.4582  0.6933  0.6933  0.6265  0.6046  0.6046

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6943.93980981
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25941323
  PAW double counting   =      7193.42033437    -7191.74892000
  entropy T*S    EENTRO =         0.02190072
  eigenvalues    EBANDS =     -1015.40403192
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85903803 eV

  energy without entropy =     -183.88093874  energy(sigma->0) =     -183.86633827


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  2178
 total energy-change (2. order) :-0.1262693E-02  (-0.1386772E-02)
 number of electron      85.9999983 magnetization      -2.0305703
 augmentation part        4.1400022 magnetization      -0.4189216

 Broyden mixing:
  rms(total) = 0.96690E-02    rms(broyden)= 0.73592E-02
  rms(prec ) = 0.10194E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7170
  7.6124  4.9000  2.5418  2.1678  1.9552  1.9552  1.1138  0.9976  0.9976  1.0263
  1.0263  0.7460  0.7460  0.4582  0.7104  0.7104  0.6208  0.6208

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.33559104
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25444698
  PAW double counting   =      7194.99256185    -7193.32032960
  entropy T*S    EENTRO =         0.02199004
  eigenvalues    EBANDS =     -1015.00545434
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86030072 eV

  energy without entropy =     -183.88229076  energy(sigma->0) =     -183.86763073


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  2304
 total energy-change (2. order) : 0.1242441E-02  (-0.3046086E-02)
 number of electron      85.9999986 magnetization      -2.0308955
 augmentation part        4.1400458 magnetization      -0.4161244

 Broyden mixing:
  rms(total) = 0.15980E-01    rms(broyden)= 0.12795E-01
  rms(prec ) = 0.14362E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6351
  6.7135  4.9520  2.4708  2.2030  1.9507  1.9507  0.9612  1.1704  1.0121  1.0121
  0.9786  0.9786  0.7933  0.7933  0.4582  0.7072  0.7072  0.6266  0.6266

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.73536395
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.25248796
  PAW double counting   =      7196.42040940    -7194.74776165
  entropy T*S    EENTRO =         0.02196471
  eigenvalues    EBANDS =     -1014.60287014
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.85905828 eV

  energy without entropy =     -183.88102299  energy(sigma->0) =     -183.86637985


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :  2448
 total energy-change (2. order) :-0.6698032E-02  (-0.1663388E-03)
 number of electron      85.9999986 magnetization      -2.0306464
 augmentation part        4.1400263 magnetization      -0.4155803

 Broyden mixing:
  rms(total) = 0.13674E-01    rms(broyden)= 0.13289E-01
  rms(prec ) = 0.14814E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5699
  6.6153  4.9654  2.5071  2.1985  1.9362  1.9362  1.1774  1.0120  1.0120  1.0206
  1.0206  0.7862  0.7862  0.4582  0.7018  0.7018  0.6260  0.6260  0.6557  0.6557

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.73722199
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.24807690
  PAW double counting   =      7196.32188935    -7194.64926509
  entropy T*S    EENTRO =         0.02195991
  eigenvalues    EBANDS =     -1014.60327079
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86575631 eV

  energy without entropy =     -183.88771622  energy(sigma->0) =     -183.87307628


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  2259
 total energy-change (2. order) :-0.2182955E-02  (-0.6650444E-04)
 number of electron      85.9999985 magnetization      -2.0325765
 augmentation part        4.1401654 magnetization      -0.4174481

 Broyden mixing:
  rms(total) = 0.10750E-01    rms(broyden)= 0.10738E-01
  rms(prec ) = 0.12303E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7112
  8.2605  5.5356  2.8552  2.2768  1.9532  1.9532  1.1183  1.1183  1.2374  1.2374
  1.1402  0.9849  0.9849  0.8218  0.8218  0.7586  0.4582  0.6447  0.6447  0.6093
  0.5202

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.68711185
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.24242918
  PAW double counting   =      7196.51185519    -7194.83879612
  entropy T*S    EENTRO =         0.02196713
  eigenvalues    EBANDS =     -1014.65035818
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86793927 eV

  energy without entropy =     -183.88990639  energy(sigma->0) =     -183.87526164


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  2259
 total energy-change (2. order) :-0.1774451E-02  (-0.3678560E-04)
 number of electron      85.9999986 magnetization      -2.0328896
 augmentation part        4.1404049 magnetization      -0.4170858

 Broyden mixing:
  rms(total) = 0.70764E-02    rms(broyden)= 0.70461E-02
  rms(prec ) = 0.83396E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7048
  8.5058  5.6051  2.9832  2.2775  1.9095  1.9095  1.3321  1.3321  1.2878  1.2878
  1.0008  1.0008  0.9915  0.9388  0.8090  0.8090  0.4582  0.6454  0.6454  0.6166
  0.5795  0.5795

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.73195431
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23438809
  PAW double counting   =      7198.04096276    -7196.36751262
  entropy T*S    EENTRO =         0.02187150
  eigenvalues    EBANDS =     -1014.59954454
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86971372 eV

  energy without entropy =     -183.89158522  energy(sigma->0) =     -183.87700422


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :  2367
 total energy-change (2. order) : 0.2408852E-02  (-0.2394834E-02)
 number of electron      85.9999984 magnetization      -2.0349940
 augmentation part        4.1401462 magnetization      -0.4206082

 Broyden mixing:
  rms(total) = 0.14286E-01    rms(broyden)= 0.12304E-01
  rms(prec ) = 0.12998E-01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7378
  9.2714  6.1295  3.2238  2.2548  1.8240  1.8240  1.5265  1.5265  1.0285  1.0285
  1.2092  1.0925  1.0925  0.8741  0.8741  0.8171  0.4582  0.7098  0.7098  0.6426
  0.6426  0.6047  0.6047

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.68023879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22460873
  PAW double counting   =      7198.89085276    -7197.21789867
  entropy T*S    EENTRO =         0.02177938
  eigenvalues    EBANDS =     -1014.63848367
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86730487 eV

  energy without entropy =     -183.88908424  energy(sigma->0) =     -183.87456466


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :  2403
 total energy-change (2. order) :-0.3817642E-02  (-0.1120520E-02)
 number of electron      85.9999985 magnetization      -2.0361411
 augmentation part        4.1399711 magnetization      -0.4213608

 Broyden mixing:
  rms(total) = 0.95674E-02    rms(broyden)= 0.88869E-02
  rms(prec ) = 0.93732E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7775
  9.8361  6.6008  3.7287  1.9486  1.9486  2.1391  2.1391  0.9514  0.9514  1.3695
  1.3695  1.0335  1.0335  0.9764  0.9764  0.7645  0.7645  0.7777  0.4582  0.6311
  0.6311  0.6074  0.5115  0.5115

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.85579479
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22796757
  PAW double counting   =      7198.16802486    -7196.49576320
  entropy T*S    EENTRO =         0.02185674
  eigenvalues    EBANDS =     -1014.46948907
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87112251 eV

  energy without entropy =     -183.89297924  energy(sigma->0) =     -183.87840809


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :  2376
 total energy-change (2. order) :-0.7108521E-05  (-0.4574104E-03)
 number of electron      85.9999986 magnetization      -2.0372429
 augmentation part        4.1399170 magnetization      -0.4214522

 Broyden mixing:
  rms(total) = 0.79074E-02    rms(broyden)= 0.69364E-02
  rms(prec ) = 0.73252E-02
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8470
 10.5697  7.1645  4.3693  2.3262  2.3262  1.9511  1.9511  1.6570  0.9811  0.9811
  1.1970  1.1079  1.1079  0.9720  0.9720  0.7771  0.7771  0.7850  0.4582  0.6365
  0.6365  0.6440  0.6440  0.6078  0.5751

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.91214915
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22864435
  PAW double counting   =      7197.49114146    -7195.81897551
  entropy T*S    EENTRO =         0.02188672
  eigenvalues    EBANDS =     -1014.41375288
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87112962 eV

  energy without entropy =     -183.89301634  energy(sigma->0) =     -183.87842519


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :  2403
 total energy-change (2. order) : 0.1506899E-02  (-0.9965876E-03)
 number of electron      85.9999987 magnetization      -2.0371939
 augmentation part        4.1400252 magnetization      -0.4200668

 Broyden mixing:
  rms(total) = 0.82795E-02    rms(broyden)= 0.62837E-02
  rms(prec ) = 0.66788E-02
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8282
 10.7454  7.2398  4.7029  2.4169  2.4169  1.9365  1.9365  1.8509  0.9854  0.9854
  1.1135  1.1135  1.1510  0.9782  0.9782  0.6782  0.6782  0.7779  0.7779  0.7644
  0.4582  0.6446  0.6446  0.6076  0.5644  0.3854

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.97866562
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23277789
  PAW double counting   =      7197.32602101    -7195.65381763
  entropy T*S    EENTRO =         0.02188208
  eigenvalues    EBANDS =     -1014.34989584
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.86962272 eV

  energy without entropy =     -183.89150480  energy(sigma->0) =     -183.87691674


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :  2304
 total energy-change (2. order) :-0.3134833E-02  (-0.6875386E-04)
 number of electron      85.9999987 magnetization      -2.0373398
 augmentation part        4.1400963 magnetization      -0.4201674

 Broyden mixing:
  rms(total) = 0.56726E-02    rms(broyden)= 0.53257E-02
  rms(prec ) = 0.55886E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8741
 11.0815  7.4512  5.4084  2.5778  2.5778  1.9311  1.9311  1.9902  1.0170  1.0170
  1.1556  1.1556  1.1652  0.8891  0.8891  0.9805  0.9805  0.7672  0.7672  0.7716
  0.4582  0.5851  0.5851  0.6348  0.6348  0.6078  0.5891

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.98129061
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22968519
  PAW double counting   =      7197.10087476    -7195.42875501
  entropy T*S    EENTRO =         0.02188668
  eigenvalues    EBANDS =     -1014.34723396
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87275755 eV

  energy without entropy =     -183.89464423  energy(sigma->0) =     -183.88005311


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :  2241
 total energy-change (2. order) :-0.1105423E-03  (-0.1113184E-03)
 number of electron      85.9999987 magnetization      -2.0374826
 augmentation part        4.1400532 magnetization      -0.4200757

 Broyden mixing:
  rms(total) = 0.56954E-02    rms(broyden)= 0.53719E-02
  rms(prec ) = 0.56123E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8529
 11.2135  7.4133  5.7716  2.6454  2.6454  1.9276  1.9276  2.0164  1.0281  1.0281
  0.9946  0.9946  1.1678  1.1678  1.1898  0.9821  0.9821  0.7620  0.7620  0.7726
  0.4582  0.6035  0.6035  0.6374  0.6374  0.6104  0.5731  0.3648

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6944.99869491
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23028445
  PAW double counting   =      7196.97751992    -7195.30523720
  entropy T*S    EENTRO =         0.02187490
  eigenvalues    EBANDS =     -1014.33069063
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87286809 eV

  energy without entropy =     -183.89474299  energy(sigma->0) =     -183.88015973


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :  2286
 total energy-change (2. order) :-0.1937188E-03  (-0.7656960E-04)
 number of electron      85.9999988 magnetization      -2.0376146
 augmentation part        4.1400279 magnetization      -0.4199939

 Broyden mixing:
  rms(total) = 0.53171E-02    rms(broyden)= 0.50739E-02
  rms(prec ) = 0.53286E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8337
 11.3152  7.0837  6.1341  2.6906  2.6906  1.9254  1.9254  2.0101  1.0356  1.0356
  1.1413  1.1413  1.1647  1.1647  1.2071  0.9865  0.9865  0.5938  0.5938  0.7664
  0.7664  0.7711  0.4582  0.5639  0.5639  0.6357  0.6357  0.6117  0.5780

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.01265955
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23061693
  PAW double counting   =      7196.85886173    -7195.18665020
  entropy T*S    EENTRO =         0.02187381
  eigenvalues    EBANDS =     -1014.31717992
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87306181 eV

  energy without entropy =     -183.89493562  energy(sigma->0) =     -183.88035308


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :  2268
 total energy-change (2. order) :-0.2351114E-03  (-0.2970826E-04)
 number of electron      85.9999988 magnetization      -2.0377166
 augmentation part        4.1400104 magnetization      -0.4199551

 Broyden mixing:
  rms(total) = 0.49663E-02    rms(broyden)= 0.48448E-02
  rms(prec ) = 0.50779E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8513
 11.4420  6.4866  6.4866  2.6947  2.6947  1.9910  1.9910  1.8345  1.8345  1.9691
  1.0209  1.0209  1.1961  1.1398  1.1398  0.9914  0.9914  0.8238  0.8238  0.7652
  0.7652  0.7697  0.4582  0.6214  0.6214  0.6359  0.6359  0.6109  0.5818  0.4994

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.02378948
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23070661
  PAW double counting   =      7196.84066853    -7195.16846875
  entropy T*S    EENTRO =         0.02187900
  eigenvalues    EBANDS =     -1014.30636821
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87329692 eV

  energy without entropy =     -183.89517592  energy(sigma->0) =     -183.88058992


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :  1980
 total energy-change (2. order) :-0.1384815E-03  (-0.2520598E-04)
 number of electron      85.9999988 magnetization      -2.0384551
 augmentation part        4.1400240 magnetization      -0.4205790

 Broyden mixing:
  rms(total) = 0.49235E-02    rms(broyden)= 0.48418E-02
  rms(prec ) = 0.50218E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.9629
 11.8494  7.1950  7.1950  4.3184  3.4115  1.9784  1.9784  2.1589  1.9791  1.9791
  1.0204  1.0204  1.1813  1.1319  1.1319  0.9533  0.9533  0.8927  0.8927  0.7619
  0.7619  0.7677  0.4582  0.6383  0.6383  0.6353  0.6353  0.5971  0.5971  0.5695
  0.5695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.03539668
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.22983852
  PAW double counting   =      7196.90568540    -7195.23345946
  entropy T*S    EENTRO =         0.02189259
  eigenvalues    EBANDS =     -1014.29407117
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87343540 eV

  energy without entropy =     -183.89532800  energy(sigma->0) =     -183.88073293


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :  2196
 total energy-change (2. order) : 0.1599798E-02  (-0.5316205E-03)
 number of electron      85.9999988 magnetization      -2.0385602
 augmentation part        4.1400023 magnetization      -0.4199697

 Broyden mixing:
  rms(total) = 0.60242E-02    rms(broyden)= 0.49719E-02
  rms(prec ) = 0.52037E-02
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   2.0151
 11.9731  8.8509  8.8509  4.6192  3.0648  2.2625  1.9806  1.9806  1.8882  1.8882
  1.0202  1.0202  1.1731  1.1180  1.1180  0.9035  0.9035  0.9472  0.9472  0.7744
  0.7744  0.7705  0.5931  0.5931  0.4582  0.6440  0.6440  0.6052  0.6052  0.5704
  0.5704  0.3717

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.08597140
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23294646
  PAW double counting   =      7196.83848296    -7195.16632067
  entropy T*S    EENTRO =         0.02189698
  eigenvalues    EBANDS =     -1014.24494532
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87183561 eV

  energy without entropy =     -183.89373259  energy(sigma->0) =     -183.87913460


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :  2367
 total energy-change (2. order) :-0.1391165E-02  (-0.3459656E-04)
 number of electron      85.9999988 magnetization      -2.0391343
 augmentation part        4.1400168 magnetization      -0.4204752

 Broyden mixing:
  rms(total) = 0.44457E-02    rms(broyden)= 0.42753E-02
  rms(prec ) = 0.44871E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   2.1847
 15.4114 12.1507  8.4138  5.1951  3.0667  2.4334  1.9687  1.9687  1.9462  1.5770
  1.0204  1.0204  1.1294  1.1294  1.0836  0.9460  0.9460  0.9244  0.9244  0.8101
  0.7645  0.7645  0.5743  0.5743  0.6927  0.6927  0.4582  0.6323  0.6323  0.6091
  0.5655  0.5655  0.5037

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.08801351
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23172500
  PAW double counting   =      7196.86244154    -7195.19024927
  entropy T*S    EENTRO =         0.02190022
  eigenvalues    EBANDS =     -1014.24310614
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87322677 eV

  energy without entropy =     -183.89512699  energy(sigma->0) =     -183.88052684


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :  2196
 total energy-change (2. order) : 0.7111254E-03  (-0.2342282E-03)
 number of electron      85.9999989 magnetization      -2.0393254
 augmentation part        4.1399893 magnetization      -0.4202339

 Broyden mixing:
  rms(total) = 0.56536E-02    rms(broyden)= 0.51408E-02
  rms(prec ) = 0.54041E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   2.2585
 19.0766 12.2024  8.4038  5.3063  3.0882  2.4702  1.9687  1.9687  2.0429  1.0205
  1.0205  1.5295  1.1316  1.1316  0.9411  0.9411  1.0368  0.9342  0.9342  0.7513
  0.7513  0.7880  0.7880  0.7967  0.6893  0.6893  0.4582  0.6388  0.6388  0.5723
  0.5723  0.6055  0.5752  0.3249

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.11809916
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23349225
  PAW double counting   =      7196.90353827    -7195.23142594
  entropy T*S    EENTRO =         0.02189625
  eigenvalues    EBANDS =     -1014.21399271
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87251564 eV

  energy without entropy =     -183.89441189  energy(sigma->0) =     -183.87981439


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------



 eigenvalue-minimisations  :  2367
 total energy-change (2. order) :-0.6065456E-03  (-0.3700463E-04)
 number of electron      85.9999989 magnetization      -2.0395298
 augmentation part        4.1399812 magnetization      -0.4203019

 Broyden mixing:
  rms(total) = 0.50485E-02    rms(broyden)= 0.49037E-02
  rms(prec ) = 0.51686E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   2.2877
 21.4299 12.2201  8.5413  5.3848  3.0918  2.4687  1.9674  1.9674  2.0848  1.0206
  1.0206  1.5740  1.1321  1.1321  0.8537  0.8537  0.9270  0.9270  0.9654  0.9654
  1.0434  0.7479  0.7479  0.7750  0.6997  0.6997  0.6411  0.6411  0.4582  0.6100
  0.5576  0.5447  0.5447  0.4152  0.4152

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.12377471
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23317762
  PAW double counting   =      7196.90937488    -7195.23729212
  entropy T*S    EENTRO =         0.02189690
  eigenvalues    EBANDS =     -1014.20858016
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87312219 eV

  energy without entropy =     -183.89501909  energy(sigma->0) =     -183.88042116


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  41)  ---------------------------------------



 eigenvalue-minimisations  :  2034
 total energy-change (2. order) :-0.9743847E-04  (-0.3007823E-04)
 number of electron      85.9999989 magnetization      -2.0403007
 augmentation part        4.1399910 magnetization      -0.4209058

 Broyden mixing:
  rms(total) = 0.47770E-02    rms(broyden)= 0.46735E-02
  rms(prec ) = 0.49070E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   2.4473
 27.3149 12.2543  8.8082  5.5317  3.2211  2.4259  2.1912  1.9646  1.9646  1.7620
  1.0207  1.0207  1.1796  1.1796  0.9767  0.9767  1.1167  0.9623  0.9623  0.9709
  0.9709  0.6932  0.6932  0.7868  0.7622  0.7622  0.6280  0.6280  0.4582  0.6347
  0.6176  0.6176  0.5791  0.5791  0.5473  0.3409

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        16.78333521
  Ewald energy   TEWEN  =      3766.77656950
  -Hartree energ DENC   =     -6945.12845188
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.23289431
  PAW double counting   =      7196.89931095    -7195.22724265
  entropy T*S    EENTRO =         0.02190098
  eigenvalues    EBANDS =     -1014.20370673
  atomic energy  EATOM  =      3690.97217068
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -183.87321963 eV

  energy without entropy =     -183.89512061  energy(sigma->0) =     -183.88051996


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