vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.04  02:30:53
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 2
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     You use a magnetic or noncollinear calculation, but did not specify     |
|     the initial magnetic moment with the MAGMOM tag. Note that a            |
|     default of 1 will be used for all atoms. This ferromagnetic setup       |
|     may break the symmetry of the crystal, in particular it may rule        |
|     out finding an antiferromagnetic solution. Thence, we recommend         |
|     setting the initial magnetic moment manually or verifying carefully     |
|     that this magnetic setup is desired.                                    |
|                                                                             |
 -----------------------------------------------------------------------------

 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.384  0.427  0.535-   5 1.36  10 1.36   6 1.37   2 1.50
   2  0.441  0.533  0.397-   4 1.34   3 1.50   1 1.50
   3  0.581  0.524  0.331-   8 1.36   7 1.36   9 1.37   2 1.50
   4  0.351  0.585  0.284-   2 1.34
   5  0.262  0.484  0.582-   1 1.36
   6  0.369  0.264  0.484-   1 1.37
   7  0.617  0.672  0.258-   3 1.36
   8  0.670  0.489  0.453-   3 1.36
   9  0.592  0.403  0.210-   3 1.37
  10  0.466  0.425  0.671-   1 1.36
  11  0.465  0.810  0.558-  12 0.75
  12  0.452  0.902  0.555-  11 0.75
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.384449130  0.426657290  0.534759630
     0.440950400  0.533462070  0.397267650
     0.580905070  0.524363110  0.330608480
     0.350593240  0.584535180  0.283974490
     0.262417310  0.483950620  0.581550240
     0.368684840  0.263940190  0.483755500
     0.616675150  0.671666970  0.258434370
     0.669963110  0.488572050  0.453404970
     0.591829500  0.403101300  0.210213870
     0.465542760  0.425004180  0.670908880
     0.464734680  0.810427990  0.557670850
     0.451644940  0.902393420  0.555292760

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     44
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      2    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.57E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           12
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.38444913  0.42665729  0.53475963
   0.44095040  0.53346207  0.39726765
   0.58090507  0.52436311  0.33060848
   0.35059324  0.58453518  0.28397449
   0.26241731  0.48395062  0.58155024
   0.36868484  0.26394019  0.48375550
   0.61667515  0.67166697  0.25843437
   0.66996311  0.48857205  0.45340497
   0.59182950  0.40310130  0.21021387
   0.46554276  0.42500418  0.67090888
   0.46473468  0.81042799  0.55767085
   0.45164494  0.90239342  0.55529276
 
 position of ions in cartesian coordinates  (Angst):
   3.84449130  3.41325832  4.27807704
   4.40950400  4.26769656  3.17814120
   5.80905070  4.19490488  2.64486784
   3.50593240  4.67628144  2.27179592
   2.62417310  3.87160496  4.65240192
   3.68684840  2.11152152  3.87004400
   6.16675150  5.37333576  2.06747496
   6.69963110  3.90857640  3.62723976
   5.91829500  3.22481040  1.68171096
   4.65542760  3.40003344  5.36727104
   4.64734680  6.48342392  4.46136680
   4.51644940  7.21914736  4.44234208
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    91224. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1271. kBytes
   fftplans  :       5842. kBytes
   grid      :      20832. kBytes
   one-center:         73. kBytes
   wavefun   :      33206. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization      12.0000000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1348
 Maximum index for augmentation-charges          394 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  1672
 total energy-change (2. order) : 0.5877256E+03  (-0.2274505E+04)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5873.06144272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.49070757
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00103740
  eigenvalues    EBANDS =      -426.87532119
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       587.72561639 eV

  energy without entropy =      587.72457899  energy(sigma->0) =      587.72527059


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  2116
 total energy-change (2. order) :-0.5528649E+03  (-0.5296822E+03)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5873.06144272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.49070757
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00358044
  eigenvalues    EBANDS =      -979.74276991
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        34.86071071 eV

  energy without entropy =       34.85713027  energy(sigma->0) =       34.85951723


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  1656
 total energy-change (2. order) :-0.8708232E+02  (-0.8667956E+02)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5873.06144272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.49070757
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00667766
  eigenvalues    EBANDS =     -1066.82818922
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -52.22161138 eV

  energy without entropy =      -52.22828904  energy(sigma->0) =      -52.22383727


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  1712
 total energy-change (2. order) :-0.1456400E+01  (-0.1448086E+01)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5873.06144272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.49070757
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00584956
  eigenvalues    EBANDS =     -1068.28376139
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.67801164 eV

  energy without entropy =      -53.68386121  energy(sigma->0) =      -53.67996150


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :  1840
 total energy-change (2. order) :-0.3855530E-01  (-0.3849754E-01)
 number of electron      63.0000075 magnetization       7.0184396
 augmentation part        9.6595247 magnetization       6.1649737

 Broyden mixing:
  rms(total) = 0.25714E+01    rms(broyden)= 0.25681E+01
  rms(prec ) = 0.27741E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5873.06144272
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.49070757
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00585639
  eigenvalues    EBANDS =     -1068.32232351
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.71656694 eV

  energy without entropy =      -53.72242333  energy(sigma->0) =      -53.71851907


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  2080
 total energy-change (2. order) :-0.3273765E+04  (-0.3281306E+04)
 number of electron      63.0000074 magnetization       6.5870310
 augmentation part        8.3457419 magnetization       6.3204405

 Broyden mixing:
  rms(total) = 0.67658E+01    rms(broyden)= 0.66252E+01
  rms(prec ) = 0.76786E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.1826
  0.1826

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5945.58405411
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       329.92552002
  PAW double counting   =      4707.79849549    -4746.72281471
  entropy T*S    EENTRO =         0.01020454
  eigenvalues    EBANDS =     -4291.45702315
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =     -3327.48123020 eV

  energy without entropy =    -3327.49143474  energy(sigma->0) =    -3327.48463171


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  1708
 total energy-change (2. order) :-0.3735990E+05  (-0.4102262E+05)
 number of electron      63.0000072 magnetization       6.2689336
 augmentation part        8.3434318 magnetization       7.8496376

 Broyden mixing:
  rms(total) = 0.73594E+01    rms(broyden)= 0.69671E+01
  rms(prec ) = 0.79355E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.1500
  0.2103  0.0898

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5927.37481297
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.85729811
  PAW double counting   =      4735.90141067    -4774.88290828
  entropy T*S    EENTRO =         0.00442550
  eigenvalues    EBANDS =    -41670.43735948
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =    -40687.38350472 eV

  energy without entropy =   -40687.38793022  energy(sigma->0) =   -40687.38497989


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  2064
 total energy-change (2. order) : 0.4064704E+05  (-0.6432815E+03)
 number of electron      63.0000059 magnetization       5.3046498
 augmentation part        9.1522901 magnetization       4.4324364

 Broyden mixing:
  rms(total) = 0.31549E+01    rms(broyden)= 0.27566E+01
  rms(prec ) = 0.28613E+01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2534
  0.5416  0.1093  0.1093

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5919.49352804
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       331.21550491
  PAW double counting   =      4770.56810178    -4808.11591723
  entropy T*S    EENTRO =         0.00139771
  eigenvalues    EBANDS =     -1033.06759959
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -40.34359874 eV

  energy without entropy =      -40.34499645  energy(sigma->0) =      -40.34406464


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  1620
 total energy-change (2. order) : 0.1331562E+01  (-0.2319086E+02)
 number of electron      63.0000070 magnetization       3.6352121
 augmentation part        9.2848783 magnetization       2.5702138

 Broyden mixing:
  rms(total) = 0.12053E+01    rms(broyden)= 0.11552E+01
  rms(prec ) = 0.12203E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3304
  0.8221  0.2307  0.1343  0.1343

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5921.03548222
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       321.83125294
  PAW double counting   =      5091.60713098    -5129.80431457
  entropy T*S    EENTRO =         0.00592162
  eigenvalues    EBANDS =     -1020.16498727
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -39.01203680 eV

  energy without entropy =      -39.01795842  energy(sigma->0) =      -39.01401067


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :  1656
 total energy-change (2. order) :-0.1373295E+02  (-0.2257018E+01)
 number of electron      63.0000068 magnetization       2.4942633
 augmentation part        9.1829635 magnetization       1.5133203

 Broyden mixing:
  rms(total) = 0.59678E+00    rms(broyden)= 0.59228E+00
  rms(prec ) = 0.63952E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4395
  0.8709  0.7562  0.3183  0.1262  0.1262

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5934.80417863
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       315.29843582
  PAW double counting   =      5317.87986703    -5356.51680491
  entropy T*S    EENTRO =         0.00587924
  eigenvalues    EBANDS =     -1013.15663167
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -52.74499139 eV

  energy without entropy =      -52.75087064  energy(sigma->0) =      -52.74695114


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  1792
 total energy-change (2. order) :-0.5015944E+01  (-0.2830007E+00)
 number of electron      63.0000067 magnetization       1.5329718
 augmentation part        9.1302075 magnetization       0.6060409

 Broyden mixing:
  rms(total) = 0.41927E+00    rms(broyden)= 0.41900E+00
  rms(prec ) = 0.44383E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5915
  1.1717  1.1717  0.6365  0.3172  0.1259  0.1259

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5940.55123168
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       312.03387196
  PAW double counting   =      5424.05713152    -5462.37927312
  entropy T*S    EENTRO =         0.00586827
  eigenvalues    EBANDS =     -1009.47574394
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -57.76093527 eV

  energy without entropy =      -57.76680353  energy(sigma->0) =      -57.76289136


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  1624
 total energy-change (2. order) :-0.2776784E+01  (-0.7279878E-01)
 number of electron      63.0000068 magnetization       1.0664535
 augmentation part        9.1332641 magnetization       0.1753596

 Broyden mixing:
  rms(total) = 0.23635E+00    rms(broyden)= 0.23631E+00
  rms(prec ) = 0.25683E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7134
  1.9242  0.9599  0.9245  0.1259  0.1259  0.3193  0.6143

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5939.14024320
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.22151451
  PAW double counting   =      5526.33954664    -5564.13450697
  entropy T*S    EENTRO =         0.00586480
  eigenvalues    EBANDS =     -1012.37833638
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.53771887 eV

  energy without entropy =      -60.54358367  energy(sigma->0) =      -60.53967380


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  1540
 total energy-change (2. order) : 0.5615310E+01  (-0.1696912E+03)
 number of electron      63.0000072 magnetization       1.0857381
 augmentation part        9.2152584 magnetization       0.1236862

 Broyden mixing:
  rms(total) = 0.85466E+00    rms(broyden)= 0.85402E+00
  rms(prec ) = 0.11397E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6464
  1.8154  1.0778  1.0271  0.5895  0.3205  0.1259  0.1259  0.0891

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5937.54462064
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.87999576
  PAW double counting   =      5593.23437240    -5630.29064119
  entropy T*S    EENTRO =         0.00580176
  eigenvalues    EBANDS =     -1008.75575857
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.92240875 eV

  energy without entropy =      -54.92821051  energy(sigma->0) =      -54.92434267


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  1616
 total energy-change (2. order) :-0.5284616E+01  (-0.3949221E+01)
 number of electron      63.0000069 magnetization       1.0626661
 augmentation part        9.1306681 magnetization       0.1865636

 Broyden mixing:
  rms(total) = 0.21374E+00    rms(broyden)= 0.21208E+00
  rms(prec ) = 0.24038E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6514
  1.7509  1.3984  0.9853  0.6069  0.4763  0.3186  0.1259  0.1259  0.0742

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5937.93993992
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.83539877
  PAW double counting   =      5602.72279068    -5640.30931322
  entropy T*S    EENTRO =         0.00586527
  eigenvalues    EBANDS =     -1013.07026812
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.20702479 eV

  energy without entropy =      -60.21289006  energy(sigma->0) =      -60.20897988


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :  1648
 total energy-change (2. order) :-0.2574529E+00  (-0.3122279E+00)
 number of electron      63.0000068 magnetization       1.0269804
 augmentation part        9.1314519 magnetization       0.1531528

 Broyden mixing:
  rms(total) = 0.13142E+00    rms(broyden)= 0.13124E+00
  rms(prec ) = 0.14485E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6717
  2.0398  1.4121  0.9307  0.6687  0.6687  0.1259  0.1259  0.3229  0.3459  0.0767

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5937.11083223
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.77531081
  PAW double counting   =      5611.21535705    -5648.81941536
  entropy T*S    EENTRO =         0.00586378
  eigenvalues    EBANDS =     -1014.07920349
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.46447771 eV

  energy without entropy =      -60.47034148  energy(sigma->0) =      -60.46643230


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  1604
 total energy-change (2. order) :-0.1541001E+00  (-0.4523249E-02)
 number of electron      63.0000068 magnetization       1.0049129
 augmentation part        9.1307784 magnetization       0.1316426

 Broyden mixing:
  rms(total) = 0.10758E+00    rms(broyden)= 0.10757E+00
  rms(prec ) = 0.12279E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7456
  2.1298  1.9219  0.9328  0.8181  0.8181  0.1259  0.1259  0.3188  0.4670  0.4670
  0.0765

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5936.48009417
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.71682352
  PAW double counting   =      5624.18651456    -5661.71827709
  entropy T*S    EENTRO =         0.00586207
  eigenvalues    EBANDS =     -1014.87784848
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.61857785 eV

  energy without entropy =      -60.62443992  energy(sigma->0) =      -60.62053187


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  2032
 total energy-change (2. order) :-0.8492090E+05  (-0.7595345E+05)
 number of electron      63.0000059 magnetization       1.0089649
 augmentation part        6.6015301 magnetization      -7.5277010

 Broyden mixing:
  rms(total) = 0.11407E+02    rms(broyden)= 0.11313E+02
  rms(prec ) = 0.12188E+02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6834
  2.1244  1.9283  0.9258  0.8200  0.8200  0.4673  0.4673  0.3188  0.1259  0.1259
  0.0765  0.0000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5936.27816339
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.70216699
  PAW double counting   =      5659.28943448    -5699.17105471
  entropy T*S    EENTRO =        -0.00436202
  eigenvalues    EBANDS =    -85933.60185311
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =    -84981.51539002 eV

  energy without entropy =   -84981.51102800  energy(sigma->0) =   -84981.51393602


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  1552
 total energy-change (2. order) : 0.8499820E+05  (-0.6285749E+03)
 number of electron      63.0000069 magnetization       1.0964042
 augmentation part        8.2808256 magnetization      -2.9721490

 Broyden mixing:
  rms(total) = 0.20577E+01    rms(broyden)= 0.16992E+01
  rms(prec ) = 0.20316E+01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6311
  2.0787  1.9851  0.8727  0.8417  0.8417  0.4678  0.4678  0.3188  0.1259  0.1259
  0.0765  0.0004  0.0004

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5936.47898959
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       314.26726694
  PAW double counting   =      5631.97273177    -5669.49700342
  entropy T*S    EENTRO =         0.00608779
  eigenvalues    EBANDS =      -942.13418355
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        16.68435167 eV

  energy without entropy =       16.67826388  energy(sigma->0) =       16.68232241


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  1724
 total energy-change (2. order) :-0.6916005E+02  (-0.4115080E+02)
 number of electron      63.0000067 magnetization       0.9282713
 augmentation part        8.9219196 magnetization       0.2753566

 Broyden mixing:
  rms(total) = 0.40755E+00    rms(broyden)= 0.32500E+00
  rms(prec ) = 0.36349E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5883
  2.1331  1.9377  0.8790  0.8399  0.8399  0.4684  0.4684  0.3188  0.1259  0.1259
  0.0765  0.0110  0.0110  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5933.55023229
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.06545916
  PAW double counting   =      5622.47438404    -5659.97016406
  entropy T*S    EENTRO =         0.00077789
  eigenvalues    EBANDS =     -1010.04436776
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -52.47570129 eV

  energy without entropy =      -52.47647918  energy(sigma->0) =      -52.47596059


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :  1668
 total energy-change (2. order) :-0.7716126E+01  (-0.7055191E+01)
 number of electron      63.0000068 magnetization       0.9731867
 augmentation part        9.1461131 magnetization       0.1133153

 Broyden mixing:
  rms(total) = 0.13875E+00    rms(broyden)= 0.12412E+00
  rms(prec ) = 0.13664E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6237
  2.2407  2.2407  0.8862  0.8273  0.8273  0.5568  0.5568  0.1259  0.1259  0.3159
  0.2771  0.2771  0.0765  0.0205  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5930.93405667
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.50320776
  PAW double counting   =      5642.01521983    -5679.21451975
  entropy T*S    EENTRO =         0.00585648
  eigenvalues    EBANDS =     -1020.11597686
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.19182749 eV

  energy without entropy =      -60.19768397  energy(sigma->0) =      -60.19377965


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  1700
 total energy-change (2. order) :-0.3285824E+00  (-0.1780180E+00)
 number of electron      63.0000068 magnetization       0.9813449
 augmentation part        9.1408047 magnetization       0.1157987

 Broyden mixing:
  rms(total) = 0.10716E+00    rms(broyden)= 0.10630E+00
  rms(prec ) = 0.12035E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7108
  2.7404  2.5323  0.9937  0.9937  0.9890  0.6618  0.6618  0.5707  0.3193  0.3666
  0.1259  0.1259  0.1935  0.0765  0.0206  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5931.35408526
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.45773291
  PAW double counting   =      5635.49802164    -5672.76439571
  entropy T*S    EENTRO =         0.00585667
  eigenvalues    EBANDS =     -1019.91198189
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.52040989 eV

  energy without entropy =      -60.52626656  energy(sigma->0) =      -60.52236212


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  1720
 total energy-change (2. order) :-0.1451592E-01  (-0.5296239E-02)
 number of electron      63.0000068 magnetization       0.9944908
 augmentation part        9.1392044 magnetization       0.1282637

 Broyden mixing:
  rms(total) = 0.98273E-01    rms(broyden)= 0.98232E-01
  rms(prec ) = 0.11253E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7472
  3.1147  2.4252  1.1155  1.1155  0.9503  0.7696  0.7696  0.6064  0.6064  0.3195
  0.3685  0.1259  0.1259  0.1914  0.0765  0.0206  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5931.77266821
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.47494009
  PAW double counting   =      5633.99951159    -5671.29298526
  entropy T*S    EENTRO =         0.00585680
  eigenvalues    EBANDS =     -1019.49802256
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.53492581 eV

  energy without entropy =      -60.54078261  energy(sigma->0) =      -60.53687808


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  1764
 total energy-change (2. order) :-0.1612948E-02  (-0.2625250E-03)
 number of electron      63.0000068 magnetization       1.0070169
 augmentation part        9.1383641 magnetization       0.1400708

 Broyden mixing:
  rms(total) = 0.92370E-01    rms(broyden)= 0.92368E-01
  rms(prec ) = 0.10698E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7663
  3.0100  2.5583  1.2432  1.2432  0.9136  0.9136  0.8891  0.6149  0.6149  0.5652
  0.3194  0.3658  0.1259  0.1259  0.1922  0.0765  0.0206  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5932.09245196
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.49151973
  PAW double counting   =      5631.22826629    -5668.55023581
  entropy T*S    EENTRO =         0.00585705
  eigenvalues    EBANDS =     -1019.16793580
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.53653876 eV

  energy without entropy =      -60.54239581  energy(sigma->0) =      -60.53849111


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  1724
 total energy-change (2. order) :-0.1298038E-01  (-0.6018452E-04)
 number of electron      63.0000068 magnetization       1.0229096
 augmentation part        9.1368784 magnetization       0.1551410

 Broyden mixing:
  rms(total) = 0.87645E-01    rms(broyden)= 0.87644E-01
  rms(prec ) = 0.10255E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7921
  2.8391  2.5794  1.3095  1.3095  1.1539  1.1539  0.9651  0.6471  0.6471  0.6087
  0.6087  0.3194  0.3674  0.1259  0.1259  0.1920  0.0765  0.0206  0.0005

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5932.39125404
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.50915106
  PAW double counting   =      5629.25117086    -5666.60411402
  entropy T*S    EENTRO =         0.00585728
  eigenvalues    EBANDS =     -1018.86877201
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.54951914 eV

  energy without entropy =      -60.55537642  energy(sigma->0) =      -60.55147156


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :  1484
 total energy-change (2. order) : 0.5553182E+01  (-0.8241799E+02)
 number of electron      63.0000072 magnetization       1.0178733
 augmentation part        9.2253002 magnetization       0.0572439

 Broyden mixing:
  rms(total) = 0.82774E+00    rms(broyden)= 0.82703E+00
  rms(prec ) = 0.11179E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7571
  3.1077  2.4359  1.3298  1.3298  1.0879  1.0879  0.9578  0.6602  0.6602  0.5998
  0.5998  0.3194  0.3683  0.1259  0.1259  0.1920  0.0765  0.0005  0.0206  0.0551

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5932.86344595
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.54008055
  PAW double counting   =      5628.60119004    -5665.54075925
  entropy T*S    EENTRO =         0.00580554
  eigenvalues    EBANDS =     -1013.28764954
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.99633689 eV

  energy without entropy =      -55.00214243  energy(sigma->0) =      -54.99827207


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  1576
 total energy-change (2. order) :-0.6032971E+01  (-0.3915151E+01)
 number of electron      63.0000068 magnetization       1.0079636
 augmentation part        9.1340909 magnetization       0.1395198

 Broyden mixing:
  rms(total) = 0.23330E+00    rms(broyden)= 0.23174E+00
  rms(prec ) = 0.27067E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7204
  3.1089  2.4330  1.3266  1.3266  1.0862  1.0862  0.9579  0.6585  0.6585  0.5994
  0.5994  0.3194  0.3683  0.1259  0.1259  0.1920  0.0765  0.0508  0.0206  0.0005
  0.0072

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5932.84192628
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.54456315
  PAW double counting   =      5629.33353037    -5666.72968282
  entropy T*S    EENTRO =         0.00585761
  eigenvalues    EBANDS =     -1018.89009199
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -61.02930822 eV

  energy without entropy =      -61.03516583  energy(sigma->0) =      -61.03126076


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  1532
 total energy-change (2. order) : 0.4122234E+00  (-0.5086311E+00)
 number of electron      63.0000068 magnetization       1.0278762
 augmentation part        9.1352323 magnetization       0.1603916

 Broyden mixing:
  rms(total) = 0.89158E-01    rms(broyden)= 0.88904E-01
  rms(prec ) = 0.10432E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7077
  3.1180  2.3960  1.4188  1.4188  1.0566  1.0566  0.9200  0.6750  0.6750  0.5940
  0.5940  0.3678  0.3194  0.1259  0.1259  0.1920  0.1644  0.1644  0.0765  0.0005
  0.0206  0.0892

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1512.22847230
  -Hartree energ DENC   =     -5932.65095036
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.51912862
  PAW double counting   =      5630.29591013    -5667.66775274
  entropy T*S    EENTRO =         0.00585757
  eigenvalues    EBANDS =     -1018.66771976
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.61708480 eV

  energy without entropy =      -60.62294236  energy(sigma->0) =      -60.61903732


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------


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|                                                                             |
|     EEEEEEE  RRRRRR   RRRRRR   OOOOOOO  RRRRRR      ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     EEEEE    RRRRRR   RRRRRR   O     O  RRRRRR       #       #       #      |
|     E        R   R    R   R    O     O  R   R                               |
|     E        R    R   R    R   O     O  R    R      ###     ###     ###     |
|     EEEEEEE  R     R  R     R  OOOOOOO  R     R     ###     ###     ###     |
|                                                                             |
|     Error EDDDAV: Call to ZHEGV failed. Returncode = 7 1 8                  |
|                                                                             |
|       ---->  I REFUSE TO CONTINUE WITH THIS SICK JOB ... BYE!!! <----       |
|                                                                             |
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