vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.04  00:32:09
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 2
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     You use a magnetic or noncollinear calculation, but did not specify     |
|     the initial magnetic moment with the MAGMOM tag. Note that a            |
|     default of 1 will be used for all atoms. This ferromagnetic setup       |
|     may break the symmetry of the crystal, in particular it may rule        |
|     out finding an antiferromagnetic solution. Thence, we recommend         |
|     setting the initial magnetic moment manually or verifying carefully     |
|     that this magnetic setup is desired.                                    |
|                                                                             |
 -----------------------------------------------------------------------------

 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.385  0.428  0.533-  10 1.35   5 1.36   6 1.37   2 1.50
   2  0.442  0.528  0.392-   4 1.35   1 1.50   3 1.50
   3  0.583  0.520  0.327-   8 1.35   7 1.36   9 1.37   2 1.50
   4  0.352  0.576  0.275-   2 1.35
   5  0.262  0.488  0.575-   1 1.36
   6  0.369  0.263  0.490-   1 1.37
   7  0.618  0.669  0.258-   3 1.36
   8  0.671  0.483  0.451-   3 1.35
   9  0.596  0.401  0.206-   3 1.37
  10  0.465  0.435  0.669-   1 1.35
  11  0.472  0.827  0.565-  12 0.72
  12  0.431  0.899  0.576-  11 0.72
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.385081470  0.428211000  0.533219270
     0.442307460  0.527972990  0.391921790
     0.583396790  0.519852130  0.327259230
     0.352364700  0.576375740  0.275157590
     0.262413920  0.488185700  0.574635260
     0.369492060  0.263170350  0.490369180
     0.618365480  0.669111260  0.258273410
     0.670692360  0.482841080  0.451137750
     0.595954250  0.400912960  0.205505950
     0.465254830  0.434864470  0.669273060
     0.472205190  0.827111770  0.564779420
     0.430861630  0.899464900  0.576309770

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     44
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      2    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.57E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           12
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.38508147  0.42821100  0.53321927
   0.44230746  0.52797299  0.39192179
   0.58339679  0.51985213  0.32725923
   0.35236470  0.57637574  0.27515759
   0.26241392  0.48818570  0.57463526
   0.36949206  0.26317035  0.49036918
   0.61836548  0.66911126  0.25827341
   0.67069236  0.48284108  0.45113775
   0.59595425  0.40091296  0.20550595
   0.46525483  0.43486447  0.66927306
   0.47220519  0.82711177  0.56477942
   0.43086163  0.89946490  0.57630977
 
 position of ions in cartesian coordinates  (Angst):
   3.85081470  3.42568800  4.26575416
   4.42307460  4.22378392  3.13537432
   5.83396790  4.15881704  2.61807384
   3.52364700  4.61100592  2.20126072
   2.62413920  3.90548560  4.59708208
   3.69492060  2.10536280  3.92295344
   6.18365480  5.35289008  2.06618728
   6.70692360  3.86272864  3.60910200
   5.95954250  3.20730368  1.64404760
   4.65254830  3.47891576  5.35418448
   4.72205190  6.61689416  4.51823536
   4.30861630  7.19571920  4.61047816
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    91224. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1271. kBytes
   fftplans  :       5842. kBytes
   grid      :      20832. kBytes
   one-center:         73. kBytes
   wavefun   :      33206. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization      12.0000000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1352
 Maximum index for augmentation-charges          395 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  1672
 total energy-change (2. order) : 0.5879817E+03  (-0.2274961E+04)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5859.15767633
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.47936883
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00086562
  eigenvalues    EBANDS =      -427.14067578
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       587.98169432 eV

  energy without entropy =      587.98082871  energy(sigma->0) =      587.98140578


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  2108
 total energy-change (2. order) :-0.5525382E+03  (-0.5297519E+03)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5859.15767633
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.47936883
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00326954
  eigenvalues    EBANDS =      -979.68131787
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        35.44345616 eV

  energy without entropy =       35.44018662  energy(sigma->0) =       35.44236631


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  1688
 total energy-change (2. order) :-0.8732021E+02  (-0.8691412E+02)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5859.15767633
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.47936883
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00686924
  eigenvalues    EBANDS =     -1067.00513229
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -51.87675856 eV

  energy without entropy =      -51.88362780  energy(sigma->0) =      -51.87904831


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  1752
 total energy-change (2. order) :-0.1443778E+01  (-0.1436299E+01)
 number of electron      63.0000000 magnetization      12.0000000
 augmentation part       63.0000000 magnetization      12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5859.15767633
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.47936883
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00584656
  eigenvalues    EBANDS =     -1068.44788728
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.32053623 eV

  energy without entropy =      -53.32638279  energy(sigma->0) =      -53.32248508


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :  1864
 total energy-change (2. order) :-0.3730290E-01  (-0.3726683E-01)
 number of electron      63.0000230 magnetization       7.0184403
 augmentation part        9.6649425 magnetization       6.1629564

 Broyden mixing:
  rms(total) = 0.25790E+01    rms(broyden)= 0.25757E+01
  rms(prec ) = 0.27918E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5859.15767633
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       306.47936883
  PAW double counting   =      4102.18079837    -4139.55860478
  entropy T*S    EENTRO =         0.00584347
  eigenvalues    EBANDS =     -1068.48518708
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.35783912 eV

  energy without entropy =      -53.36368259  energy(sigma->0) =      -53.35978695


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  2104
 total energy-change (2. order) :-0.1273479E+05  (-0.1256016E+05)
 number of electron      63.0000116 magnetization       6.7055295
 augmentation part        7.5625517 magnetization       9.9148990

 Broyden mixing:
  rms(total) = 0.12081E+02    rms(broyden)= 0.11969E+02
  rms(prec ) = 0.14136E+02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.0792
  0.0792

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5933.51632452
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       329.99626650
  PAW double counting   =      4708.23863855    -4747.33221091
  entropy T*S    EENTRO =        -0.02160087
  eigenvalues    EBANDS =    -13750.68830221
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =    -12788.14591507 eV

  energy without entropy =   -12788.12431420  energy(sigma->0) =   -12788.13871478


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  1584
 total energy-change (2. order) : 0.1278212E+05  (-0.6399504E+03)
 number of electron      63.0000235 magnetization       5.0686118
 augmentation part        8.9844891 magnetization       3.6098232

 Broyden mixing:
  rms(total) = 0.18423E+01    rms(broyden)= 0.12775E+01
  rms(prec ) = 0.13632E+01
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3785
  0.6825  0.0744

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5913.01759507
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       332.84253248
  PAW double counting   =      4684.53343131    -4722.59145104
  entropy T*S    EENTRO =        -0.02389675
  eigenvalues    EBANDS =      -992.94197827
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        -6.02133896 eV

  energy without entropy =       -5.99744221  energy(sigma->0) =       -6.01337338


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  1652
 total energy-change (2. order) :-0.3780244E+02  (-0.1369559E+02)
 number of electron      63.0000228 magnetization       3.3896469
 augmentation part        9.2691570 magnetization       2.5198197

 Broyden mixing:
  rms(total) = 0.78643E+00    rms(broyden)= 0.74001E+00
  rms(prec ) = 0.83878E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5252
  0.9658  0.0759  0.5339

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5909.39851242
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       316.40047902
  PAW double counting   =      5012.95830764    -5051.16881511
  entropy T*S    EENTRO =        -0.00912682
  eigenvalues    EBANDS =     -1017.78373126
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -43.82378056 eV

  energy without entropy =      -43.81465374  energy(sigma->0) =      -43.82073828


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  1772
 total energy-change (2. order) :-0.1196669E+02  (-0.2003883E+01)
 number of electron      63.0000225 magnetization       1.9766399
 augmentation part        9.2077329 magnetization       1.0588595

 Broyden mixing:
  rms(total) = 0.46590E+00    rms(broyden)= 0.46196E+00
  rms(prec ) = 0.55391E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7425
  1.5049  0.0758  0.7554  0.6341

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5922.88825330
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       312.91477024
  PAW double counting   =      5250.24176454    -5288.66853382
  entropy T*S    EENTRO =         0.00584069
  eigenvalues    EBANDS =     -1012.57368120
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.79047448 eV

  energy without entropy =      -55.79631517  energy(sigma->0) =      -55.79242137


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :  1736
 total energy-change (2. order) :-0.1619315E+01  (-0.4544583E+00)
 number of electron      63.0000224 magnetization       1.5001386
 augmentation part        9.0869164 magnetization       0.5978560

 Broyden mixing:
  rms(total) = 0.26411E+00    rms(broyden)= 0.26373E+00
  rms(prec ) = 0.29730E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7741
  1.5684  0.0758  1.0107  0.6079  0.6079

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5934.75251810
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.04669273
  PAW double counting   =      5454.37014024    -5492.39738410
  entropy T*S    EENTRO =         0.00583418
  eigenvalues    EBANDS =     -1000.86017297
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -57.40978963 eV

  energy without entropy =      -57.41562381  energy(sigma->0) =      -57.41173435


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  1696
 total energy-change (2. order) :-0.2821141E+01  (-0.9709626E-01)
 number of electron      63.0000225 magnetization       1.1466677
 augmentation part        9.1044767 magnetization       0.2551455

 Broyden mixing:
  rms(total) = 0.20618E+00    rms(broyden)= 0.20614E+00
  rms(prec ) = 0.24586E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8464
  1.9997  0.0758  0.8418  0.8418  0.7672  0.5519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5932.46124988
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.26533449
  PAW double counting   =      5529.78252405    -5567.57805303
  entropy T*S    EENTRO =         0.00583032
  eigenvalues    EBANDS =     -1005.42293523
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.23093090 eV

  energy without entropy =      -60.23676121  energy(sigma->0) =      -60.23287433


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  1716
 total energy-change (2. order) :-0.7639709E+00  (-0.1877374E-01)
 number of electron      63.0000225 magnetization       1.0399024
 augmentation part        9.1049103 magnetization       0.1567904

 Broyden mixing:
  rms(total) = 0.17952E+00    rms(broyden)= 0.17952E+00
  rms(prec ) = 0.21341E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9279
  2.1244  0.0758  1.1001  1.1001  0.8893  0.6028  0.6028

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5931.68846131
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.01724276
  PAW double counting   =      5579.62585453    -5617.39771282
  entropy T*S    EENTRO =         0.00583013
  eigenvalues    EBANDS =     -1006.73527343
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.99490176 eV

  energy without entropy =      -61.00073189  energy(sigma->0) =      -60.99684514


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  1928
 total energy-change (2. order) :-0.2583212E+04  (-0.2486035E+04)
 number of electron      63.0000126 magnetization       1.0300162
 augmentation part        8.2932585 magnetization       2.7630071

 Broyden mixing:
  rms(total) = 0.70560E+01    rms(broyden)= 0.69316E+01
  rms(prec ) = 0.79755E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8269
  2.1637  0.0758  1.1683  1.1683  0.8186  0.6081  0.6081  0.0043

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5930.00636219
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.88086984
  PAW double counting   =      5590.51239823    -5627.94858017
  entropy T*S    EENTRO =        -0.01485012
  eigenvalues    EBANDS =     -3591.80797752
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =     -2644.20688354 eV

  energy without entropy =    -2644.19203342  energy(sigma->0) =    -2644.20193350


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  1728
 total energy-change (2. order) : 0.1821724E+04  (-0.1580877E+04)
 number of electron      63.0000155 magnetization       1.0295658
 augmentation part        8.2914676 magnetization       3.6289165

 Broyden mixing:
  rms(total) = 0.69644E+01    rms(broyden)= 0.67089E+01
  rms(prec ) = 0.76802E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7350
  2.1708  1.1630  1.1630  0.0758  0.8255  0.6058  0.6058  0.0020  0.0035

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5929.98309959
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       313.93413448
  PAW double counting   =      5594.79328933    -5632.36707505
  entropy T*S    EENTRO =        -0.02443990
  eigenvalues    EBANDS =     -1774.01292060
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -822.48249295 eV

  energy without entropy =     -822.45805305  energy(sigma->0) =     -822.47434632


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :  1496
 total energy-change (2. order) : 0.7707663E+03  (-0.4393532E+03)
 number of electron      63.0000225 magnetization       1.0406361
 augmentation part        9.1181493 magnetization       0.1671454

 Broyden mixing:
  rms(total) = 0.12354E+01    rms(broyden)= 0.15101E+00
  rms(prec ) = 0.18002E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6858
  2.1503  1.2905  1.1066  0.0758  0.8154  0.5919  0.5919  0.2295  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5930.04045225
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       314.96939324
  PAW double counting   =      5594.10825733    -5631.63624882
  entropy T*S    EENTRO =         0.00582822
  eigenvalues    EBANDS =     -1004.30055477
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -51.71615867 eV

  energy without entropy =      -51.72198688  energy(sigma->0) =      -51.71810141


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  1672
 total energy-change (2. order) :-0.7627710E+01  (-0.3371559E+00)
 number of electron      63.0000224 magnetization       1.0330729
 augmentation part        9.1166176 magnetization       0.1628647

 Broyden mixing:
  rms(total) = 0.27334E+00    rms(broyden)= 0.12038E+00
  rms(prec ) = 0.14012E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7017
  2.2270  1.2447  1.1708  0.0758  0.7780  0.5454  0.5454  0.6086  0.5181  0.0050
  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5928.05402460
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.21892838
  PAW double counting   =      5597.62066544    -5635.14673462
  entropy T*S    EENTRO =         0.00582720
  eigenvalues    EBANDS =     -1009.16614865
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.34386846 eV

  energy without entropy =      -59.34969566  energy(sigma->0) =      -59.34581086


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  1684
 total energy-change (2. order) :-0.1562456E+01  (-0.8516303E-01)
 number of electron      63.0000225 magnetization       1.0217725
 augmentation part        9.1186827 magnetization       0.1480308

 Broyden mixing:
  rms(total) = 0.15220E+00    rms(broyden)= 0.14361E+00
  rms(prec ) = 0.17090E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7152
  2.3171  1.1779  1.1779  0.0758  0.5868  0.5868  0.7819  0.7819  0.6444  0.4464
  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5927.08179892
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.80346018
  PAW double counting   =      5603.45021966    -5640.92763469
  entropy T*S    EENTRO =         0.00582940
  eigenvalues    EBANDS =     -1011.33401873
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.90632471 eV

  energy without entropy =      -60.91215411  energy(sigma->0) =      -60.90826784


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  1736
 total energy-change (2. order) : 0.3341806E+00  (-0.9907995E-02)
 number of electron      63.0000225 magnetization       1.0253141
 augmentation part        9.1158335 magnetization       0.1511520

 Broyden mixing:
  rms(total) = 0.13318E+00    rms(broyden)= 0.13274E+00
  rms(prec ) = 0.15933E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7102
  2.3546  1.1846  1.1846  0.0758  0.6122  0.6122  0.8219  0.8219  0.6607  0.5101
  0.3893  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5927.21633363
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79692915
  PAW double counting   =      5602.50364281    -5639.98912082
  entropy T*S    EENTRO =         0.00583001
  eigenvalues    EBANDS =     -1010.85071003
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.57214414 eV

  energy without entropy =      -60.57797415  energy(sigma->0) =      -60.57408748


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  1808
 total energy-change (2. order) : 0.5792435E-01  (-0.9615776E-03)
 number of electron      63.0000225 magnetization       1.0302987
 augmentation part        9.1158747 magnetization       0.1559904

 Broyden mixing:
  rms(total) = 0.12740E+00    rms(broyden)= 0.12738E+00
  rms(prec ) = 0.15273E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7371
  2.3622  1.2695  1.2695  0.7692  0.7692  0.0758  0.8946  0.6625  0.6625  0.5514
  0.5514  0.4761  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5927.13311421
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79664415
  PAW double counting   =      5609.83169115    -5647.33317952
  entropy T*S    EENTRO =         0.00583047
  eigenvalues    EBANDS =     -1010.85971021
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.51421979 eV

  energy without entropy =      -60.52005027  energy(sigma->0) =      -60.51616328


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :  1480
 total energy-change (2. order) : 0.5936979E+01  (-0.5603793E+01)
 number of electron      63.0000222 magnetization       1.0317828
 augmentation part        9.1314729 magnetization       0.1419516

 Broyden mixing:
  rms(total) = 0.45246E+00    rms(broyden)= 0.45227E+00
  rms(prec ) = 0.53862E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6871
  2.3494  1.2703  1.2703  0.7761  0.7761  0.0758  0.8226  0.7071  0.6513  0.5618
  0.5618  0.4749  0.0006  0.0038  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.95195903
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79570921
  PAW double counting   =      5601.81474041    -5639.29416837
  entropy T*S    EENTRO =         0.00761516
  eigenvalues    EBANDS =     -1005.12679705
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.57724129 eV

  energy without entropy =      -54.58485645  energy(sigma->0) =      -54.57977968


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  1488
 total energy-change (2. order) :-0.5362740E+01  (-0.3052517E+01)
 number of electron      63.0000224 magnetization       1.0324114
 augmentation part        9.1164134 magnetization       0.1583064

 Broyden mixing:
  rms(total) = 0.13516E+00    rms(broyden)= 0.13465E+00
  rms(prec ) = 0.15560E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6477
  2.3575  1.2674  1.2674  0.7808  0.7808  0.0758  0.8328  0.5664  0.5664  0.7013
  0.6526  0.4720  0.0259  0.0107  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.89523686
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79777151
  PAW double counting   =      5646.27016310    -5683.95831361
  entropy T*S    EENTRO =         0.00583560
  eigenvalues    EBANDS =     -1010.33781908
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.93998095 eV

  energy without entropy =      -59.94581655  energy(sigma->0) =      -59.94192615


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  1536
 total energy-change (2. order) :-0.4199878E+00  (-0.5958228E-01)
 number of electron      63.0000225 magnetization       1.0314104
 augmentation part        9.1167479 magnetization       0.1567850

 Broyden mixing:
  rms(total) = 0.12259E+00    rms(broyden)= 0.12257E+00
  rms(prec ) = 0.14461E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6167
  2.3652  1.2436  1.2436  0.8206  0.8206  0.7954  0.7313  0.6582  0.5165  0.5165
  0.4556  0.0758  0.1109  0.1109  0.0143  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.87819908
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.78968540
  PAW double counting   =      5631.44164153    -5669.03567189
  entropy T*S    EENTRO =         0.00583288
  eigenvalues    EBANDS =     -1010.86087601
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.35996877 eV

  energy without entropy =      -60.36580166  energy(sigma->0) =      -60.36191307


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  1632
 total energy-change (2. order) : 0.2087361E+00  (-0.4775793E-02)
 number of electron      63.0000225 magnetization       1.0312277
 augmentation part        9.1163111 magnetization       0.1568755

 Broyden mixing:
  rms(total) = 0.11361E+00    rms(broyden)= 0.11361E+00
  rms(prec ) = 0.13479E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6111
  2.3851  1.2309  1.2309  0.8593  0.8593  0.8424  0.6623  0.6623  0.5533  0.5533
  0.4601  0.0758  0.2662  0.2662  0.0722  0.0146  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.79028786
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79286122
  PAW double counting   =      5622.81328237    -5660.39243760
  entropy T*S    EENTRO =         0.00583257
  eigenvalues    EBANDS =     -1010.75810177
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.15123267 eV

  energy without entropy =      -60.15706524  energy(sigma->0) =      -60.15317686


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  1716
 total energy-change (2. order) : 0.1392017E+00  (-0.1765859E-02)
 number of electron      63.0000225 magnetization       1.0331200
 augmentation part        9.1159275 magnetization       0.1589379

 Broyden mixing:
  rms(total) = 0.10622E+00    rms(broyden)= 0.10622E+00
  rms(prec ) = 0.12591E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6375
  2.3913  1.1123  1.1123  1.1527  1.1527  0.9178  0.6518  0.6518  0.5984  0.5984
  0.4139  0.4139  0.3864  0.3864  0.0758  0.0770  0.0145  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.67289177
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79504534
  PAW double counting   =      5620.47766990    -5658.04188960
  entropy T*S    EENTRO =         0.00583207
  eigenvalues    EBANDS =     -1010.75341531
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.01203097 eV

  energy without entropy =      -60.01786305  energy(sigma->0) =      -60.01397500


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :  1456
 total energy-change (2. order) : 0.3209831E+01  (-0.9557184E+00)
 number of electron      63.0000222 magnetization       1.0328889
 augmentation part        9.1148511 magnetization       0.1602055

 Broyden mixing:
  rms(total) = 0.25186E+00    rms(broyden)= 0.25180E+00
  rms(prec ) = 0.29585E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6145
  2.4002  1.1084  1.1084  1.1894  1.1894  0.8568  0.6036  0.6036  0.6550  0.6550
  0.4485  0.4485  0.4061  0.4061  0.0758  0.0769  0.0372  0.0145  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.14852155
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.78672644
  PAW double counting   =      5632.95554759    -5670.58448228
  entropy T*S    EENTRO =         0.00583439
  eigenvalues    EBANDS =     -1007.99492312
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.80220015 eV

  energy without entropy =      -56.80803453  energy(sigma->0) =      -56.80414494


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  1476
 total energy-change (2. order) :-0.3847632E+01  (-0.8323043E+00)
 number of electron      63.0000225 magnetization       1.0315312
 augmentation part        9.1161710 magnetization       0.1572642

 Broyden mixing:
  rms(total) = 0.11169E+00    rms(broyden)= 0.11158E+00
  rms(prec ) = 0.13248E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6504
  2.4283  1.4193  1.4193  1.2001  1.2001  0.7331  0.7331  0.7064  0.7064  0.6908
  0.5698  0.4000  0.4000  0.4149  0.4149  0.0758  0.0488  0.0768  0.0145  0.0006
  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.11183546
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.79288250
  PAW double counting   =      5611.46323059    -5648.95687150
  entropy T*S    EENTRO =         0.00583075
  eigenvalues    EBANDS =     -1012.02068715
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.64983189 eV

  energy without entropy =      -60.65566264  energy(sigma->0) =      -60.65177548


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  1584
 total energy-change (2. order) :-0.6836229E-01  (-0.1145882E-01)
 number of electron      63.0000225 magnetization       1.0304117
 augmentation part        9.1169760 magnetization       0.1556176

 Broyden mixing:
  rms(total) = 0.11270E+00    rms(broyden)= 0.11269E+00
  rms(prec ) = 0.13583E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6680
  2.5325  1.8590  1.8590  1.0429  1.0429  0.7092  0.7092  0.7807  0.6718  0.6718
  0.4215  0.4215  0.4873  0.4873  0.3880  0.3880  0.0758  0.0504  0.0768  0.0145
  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.05740312
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.78636754
  PAW double counting   =      5613.33883980    -5650.80545913
  entropy T*S    EENTRO =         0.00583065
  eigenvalues    EBANDS =     -1012.16398830
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.71819418 eV

  energy without entropy =      -60.72402483  energy(sigma->0) =      -60.72013773


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :  1828
 total energy-change (2. order) :-0.2197230E-01  (-0.1666011E-03)
 number of electron      63.0000225 magnetization       1.0282065
 augmentation part        9.1171506 magnetization       0.1533646

 Broyden mixing:
  rms(total) = 0.11043E+00    rms(broyden)= 0.11043E+00
  rms(prec ) = 0.13334E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6776
  2.5487  2.0052  2.0052  1.0318  1.0318  0.6813  0.6813  0.7829  0.5040  0.5040
  0.6650  0.6650  0.4397  0.4397  0.5442  0.0758  0.4363  0.3954  0.0506  0.0768
  0.0145  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5925.95924604
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.78651756
  PAW double counting   =      5626.76996927    -5664.23423875
  entropy T*S    EENTRO =         0.00583078
  eigenvalues    EBANDS =     -1012.28661767
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.74016648 eV

  energy without entropy =      -60.74599726  energy(sigma->0) =      -60.74211007


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :  1616
 total energy-change (2. order) : 0.6729052E-01  (-0.1810400E-03)
 number of electron      63.0000225 magnetization       1.0251377
 augmentation part        9.1176179 magnetization       0.1504654

 Broyden mixing:
  rms(total) = 0.10272E+00    rms(broyden)= 0.10272E+00
  rms(prec ) = 0.12458E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7160
  2.5282  2.1418  2.1418  0.8421  0.8421  1.0436  1.0436  0.7645  0.7645  0.7921
  0.4150  0.4150  0.6454  0.6454  0.5449  0.5449  0.4227  0.4227  0.0758  0.0506
  0.0768  0.0145  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5925.75964843
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.78459790
  PAW double counting   =      5624.12332945    -5661.58338982
  entropy T*S    EENTRO =         0.00583098
  eigenvalues    EBANDS =     -1012.42121442
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.67287596 eV

  energy without entropy =      -60.67870694  energy(sigma->0) =      -60.67481962


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :  1652
 total energy-change (2. order) : 0.6442357E-01  (-0.2439884E-03)
 number of electron      63.0000225 magnetization       1.0216560
 augmentation part        9.1187585 magnetization       0.1472728

 Broyden mixing:
  rms(total) = 0.90322E-01    rms(broyden)= 0.90322E-01
  rms(prec ) = 0.11031E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8425
  3.2349  3.2349  2.5622  1.1080  1.1080  0.7927  0.7927  1.0673  1.0673  0.9847
  0.4202  0.4202  0.6268  0.6268  0.6719  0.6719  0.6009  0.4241  0.4241  0.0758
  0.0506  0.0768  0.0145  0.0050  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5925.23215253
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.77757626
  PAW double counting   =      5612.74991313    -5650.20920666
  entropy T*S    EENTRO =         0.00583133
  eigenvalues    EBANDS =     -1012.87803231
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.60845238 eV

  energy without entropy =      -60.61428371  energy(sigma->0) =      -60.61039616


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :  1704
 total energy-change (2. order) : 0.1885977E-01  (-0.1020521E-03)
 number of electron      63.0000225 magnetization       1.0205978
 augmentation part        9.1195486 magnetization       0.1463621

 Broyden mixing:
  rms(total) = 0.81900E-01    rms(broyden)= 0.81900E-01
  rms(prec ) = 0.10017E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8991
  5.1333  2.8648  2.5942  1.2603  1.2603  0.8138  0.8138  0.9847  0.9847  0.8541
  0.4199  0.4199  0.7013  0.7013  0.6525  0.6525  0.5981  0.5981  0.4224  0.4224
  0.0758  0.0506  0.0768  0.0145  0.0006  0.0050

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5924.73871643
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.77215033
  PAW double counting   =      5618.75572963    -5656.21340845
  entropy T*S    EENTRO =         0.00583151
  eigenvalues    EBANDS =     -1013.34879760
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.58959262 eV

  energy without entropy =      -60.59542413  energy(sigma->0) =      -60.59153645


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :  1712
 total energy-change (2. order) :-0.2473051E+04  (-0.2349439E+04)
 number of electron      63.0000148 magnetization       1.0185806
 augmentation part        8.3385764 magnetization       3.7540114

 Broyden mixing:
  rms(total) = 0.67341E+01    rms(broyden)= 0.65134E+01
  rms(prec ) = 0.74422E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8652
  5.0981  2.8737  2.6034  1.2619  1.2619  0.8140  0.8140  0.9826  0.9826  0.8576
  0.4199  0.4199  0.7015  0.7015  0.6510  0.6510  0.5987  0.5987  0.0758  0.4224
  0.4224  0.0768  0.0506  0.0145  0.0050  0.0000  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5924.58364389
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.77159587
  PAW double counting   =      5615.99857241    -5653.46986776
  entropy T*S    EENTRO =        -0.01197503
  eigenvalues    EBANDS =     -3486.52306569
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =     -2533.64076569 eV

  energy without entropy =    -2533.62879066  energy(sigma->0) =    -2533.63677402


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :  1600
 total energy-change (2. order) : 0.2482836E+04  (-0.5023896E+03)
 number of electron      63.0000224 magnetization       1.0109447
 augmentation part        9.1009538 magnetization       0.1605226

 Broyden mixing:
  rms(total) = 0.13758E+01    rms(broyden)= 0.16545E+00
  rms(prec ) = 0.19034E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8347
  5.1033  2.8818  2.5983  1.2694  1.2694  0.9819  0.9819  0.8136  0.8136  0.8507
  0.7009  0.7009  0.6488  0.6488  0.5982  0.5982  0.4199  0.4199  0.4224  0.4224
  0.0758  0.0768  0.0506  0.0145  0.0050  0.0025  0.0025  0.0006

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5925.33576700
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       315.42148954
  PAW double counting   =      5616.20936587    -5653.66262354
  entropy T*S    EENTRO =        -0.01001417
  eigenvalues    EBANDS =     -1008.60522883
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -50.80515975 eV

  energy without entropy =      -50.79514559  energy(sigma->0) =      -50.80182170


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :  1704
 total energy-change (2. order) :-0.2554846E+01  (-0.9301874E+01)
 number of electron      63.0000220 magnetization       1.0122552
 augmentation part        9.2299099 magnetization       0.0428230

 Broyden mixing:
  rms(total) = 0.89525E+00    rms(broyden)= 0.85418E+00
  rms(prec ) = 0.11635E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8155
  5.4534  2.8686  2.5353  1.2588  1.2588  0.9843  0.9843  0.8095  0.8095  0.7979
  0.6986  0.6986  0.6850  0.6550  0.5938  0.5938  0.4199  0.4199  0.4224  0.4224
  0.0758  0.0768  0.0506  0.0197  0.0197  0.0006  0.0050  0.0170  0.0145

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.25587218
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.24849378
  PAW double counting   =      5621.34251923    -5658.91911766
  entropy T*S    EENTRO =         0.00583333
  eigenvalues    EBANDS =     -1004.95948046
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.36000557 eV

  energy without entropy =      -53.36583891  energy(sigma->0) =      -53.36195002


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :  1644
 total energy-change (2. order) :-0.7003018E+01  (-0.2478948E+01)
 number of electron      63.0000223 magnetization       1.0142453
 augmentation part        9.1280195 magnetization       0.1479766

 Broyden mixing:
  rms(total) = 0.15328E+00    rms(broyden)= 0.13741E+00
  rms(prec ) = 0.15975E+00
  weight for this iteration     100.00
  WARNING: grid for Broyden might be to small

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8013
  5.8113  2.6263  2.6263  1.3386  1.1741  0.9963  0.9963  0.8167  0.8167  0.7136
  0.7136  0.7396  0.7396  0.6341  0.5958  0.5958  0.4199  0.4199  0.4223  0.4223
  0.0758  0.0697  0.0697  0.0768  0.0506  0.0243  0.0315  0.0006  0.0050  0.0145

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1498.85764895
  -Hartree energ DENC   =     -5926.85781640
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.81023761
  PAW double counting   =      5625.25943921    -5662.82779646
  entropy T*S    EENTRO =         0.00583330
  eigenvalues    EBANDS =     -1010.93053935
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.36302371 eV

  energy without entropy =      -60.36885700  energy(sigma->0) =      -60.36496814


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------


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|                                                                             |
|     EEEEEEE  RRRRRR   RRRRRR   OOOOOOO  RRRRRR      ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     E        R     R  R     R  O     O  R     R     ###     ###     ###     |
|     EEEEE    RRRRRR   RRRRRR   O     O  RRRRRR       #       #       #      |
|     E        R   R    R   R    O     O  R   R                               |
|     E        R    R   R    R   O     O  R    R      ###     ###     ###     |
|     EEEEEEE  R     R  R     R  OOOOOOO  R     R     ###     ###     ###     |
|                                                                             |
|     Error EDDDAV: Call to ZHEGV failed. Returncode = 7 1 8                  |
|                                                                             |
|       ---->  I REFUSE TO CONTINUE WITH THIS SICK JOB ... BYE!!! <----       |
|                                                                             |
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