vasp.6.2.1 16May21 (build Apr 11 2022 11:28:20) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:50:49-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu_ncl from s
 vn 16685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.03  23:33:32
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   LORBIT = 10
   LSORBIT = .TRUE.
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 -----------------------------------------------------------------------------
|                                                                             |
|           W    W    AA    RRRRR   N    N  II  N    N   GGGG   !!!           |
|           W    W   A  A   R    R  NN   N  II  NN   N  G    G  !!!           |
|           W    W  A    A  R    R  N N  N  II  N N  N  G       !!!           |
|           W WW W  AAAAAA  RRRRR   N  N N  II  N  N N  G  GGG   !            |
|           WW  WW  A    A  R   R   N   NN  II  N   NN  G    G                |
|           W    W  A    A  R    R  N    N  II  N    N   GGGG   !!!           |
|                                                                             |
|     You use a magnetic or noncollinear calculation, but did not specify     |
|     the initial magnetic moment with the MAGMOM tag. Note that a            |
|     default of 1 will be used for all atoms. This ferromagnetic setup       |
|     may break the symmetry of the crystal, in particular it may rule        |
|     out finding an antiferromagnetic solution. Thence, we recommend         |
|     setting the initial magnetic moment manually or verifying carefully     |
|     that this magnetic setup is desired.                                    |
|                                                                             |
 -----------------------------------------------------------------------------

 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.385  0.429  0.535-  10 1.36   5 1.36   6 1.37   2 1.50
   2  0.442  0.544  0.405-   4 1.37   1 1.50   3 1.50
   3  0.580  0.526  0.333-   8 1.36   9 1.37   7 1.37   2 1.50
   4  0.351  0.583  0.283-   2 1.37
   5  0.262  0.484  0.583-   1 1.36
   6  0.369  0.267  0.484-   1 1.37
   7  0.618  0.673  0.259-   3 1.37
   8  0.671  0.489  0.453-   3 1.36
   9  0.590  0.406  0.212-   3 1.37
  10  0.465  0.425  0.673-   1 1.36
  11  0.462  0.747  0.539-
  12  0.452  0.945  0.560-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of structural, dynamic, and magnetic symmetry:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The overall configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.385362990  0.429195990  0.534909340
     0.442152570  0.543827030  0.404568280
     0.580263550  0.526245800  0.332757500
     0.351087730  0.583182530  0.282722630
     0.262338000  0.484166470  0.582897770
     0.369328810  0.267138970  0.484450420
     0.618320710  0.673167660  0.258752750
     0.670935640  0.489391750  0.453426350
     0.590317050  0.405521080  0.212407900
     0.464668130  0.425185450  0.672604080
     0.462093240  0.746524310  0.538682990
     0.451521740  0.944527340  0.559661650

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     88
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      T non collinear calculations
   LSORBIT =      T    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.28E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =     10    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non collinear spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           56
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.38536299  0.42919599  0.53490934
   0.44215257  0.54382703  0.40456828
   0.58026355  0.52624580  0.33275750
   0.35108773  0.58318253  0.28272263
   0.26233800  0.48416647  0.58289777
   0.36932881  0.26713897  0.48445042
   0.61832071  0.67316766  0.25875275
   0.67093564  0.48939175  0.45342635
   0.59031705  0.40552108  0.21240790
   0.46466813  0.42518545  0.67260408
   0.46209324  0.74652431  0.53868299
   0.45152174  0.94452734  0.55966165
 
 position of ions in cartesian coordinates  (Angst):
   3.85362990  3.43356792  4.27927472
   4.42152570  4.35061624  3.23654624
   5.80263550  4.20996640  2.66206000
   3.51087730  4.66546024  2.26178104
   2.62338000  3.87333176  4.66318216
   3.69328810  2.13711176  3.87560336
   6.18320710  5.38534128  2.07002200
   6.70935640  3.91513400  3.62741080
   5.90317050  3.24416864  1.69926320
   4.64668130  3.40148360  5.38083264
   4.62093240  5.97219448  4.30946392
   4.51521740  7.55621872  4.47729320
 
 Euler angles ALPHA=     0.0000000  BETA=     0.0000000

 transformation matrix from SAXIS to cartesian coordinates
 ---------------------------------------------------------
     1.0000000 m_x     0.0000000 m_y     0.0000000 m_z
     0.0000000 m_x     1.0000000 m_y     0.0000000 m_z
     0.0000000 m_x     0.0000000 m_y     1.0000000 m_z

 transformation matrix from cartesian coordinates to SAXIS
 ---------------------------------------------------------
     1.0000000 m_x     0.0000000 m_y     0.0000000 m_z
     0.0000000 m_x     1.0000000 m_y     0.0000000 m_z
     0.0000000 m_x     0.0000000 m_y     1.0000000 m_z




--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   23266
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   23184
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   23172
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   23172
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   23240
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   23240
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   23400
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   23216

 maximum and minimum number of plane-waves per node :     23400    23172

 maximum number of plane-waves:     23400
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   160400. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1269. kBytes
   fftplans  :      11372. kBytes
   grid      :      51200. kBytes
   one-center:        147. kBytes
   wavefun   :      66412. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization      12.0000000     12.0000000     12.0000000
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1345
 Maximum index for augmentation-charges          395 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :  1664
 total energy-change (2. order) : 0.6555927E+03  (-0.2252478E+04)
 number of electron      63.0000000 magnetization      12.0000000     12.0000000     12.0000000
 augmentation part       63.0000000 magnetization      12.0000000     12.0000000     12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5894.95171742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.61392537
  PAW double counting   =      4080.95378129    -4117.40366957
  entropy T*S    EENTRO =        -0.00514578
  eigenvalues    EBANDS =      -377.35953504
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       655.59273917 eV

  energy without entropy =      655.59788495  energy(sigma->0) =      655.59445443


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :  2056
 total energy-change (2. order) :-0.5657094E+03  (-0.5329255E+03)
 number of electron      63.0000000 magnetization      12.0000000     12.0000000     12.0000000
 augmentation part       63.0000000 magnetization      12.0000000     12.0000000     12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5894.95171742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.61392537
  PAW double counting   =      4080.95378129    -4117.40366957
  entropy T*S    EENTRO =         0.00548618
  eigenvalues    EBANDS =      -943.07958095
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        89.88332523 eV

  energy without entropy =       89.87783904  energy(sigma->0) =       89.88149650


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :  1664
 total energy-change (2. order) :-0.1097694E+03  (-0.1089204E+03)
 number of electron      63.0000000 magnetization      12.0000000     12.0000000     12.0000000
 augmentation part       63.0000000 magnetization      12.0000000     12.0000000     12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5894.95171742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.61392537
  PAW double counting   =      4080.95378129    -4117.40366957
  entropy T*S    EENTRO =        -0.01013110
  eigenvalues    EBANDS =     -1052.83331409
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -19.88602519 eV

  energy without entropy =      -19.87589409  energy(sigma->0) =      -19.88264816


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :  1808
 total energy-change (2. order) :-0.3462509E+01  (-0.3383905E+01)
 number of electron      63.0000000 magnetization      12.0000000     12.0000000     12.0000000
 augmentation part       63.0000000 magnetization      12.0000000     12.0000000     12.0000000

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5894.95171742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.61392537
  PAW double counting   =      4080.95378129    -4117.40366957
  entropy T*S    EENTRO =         0.01664798
  eigenvalues    EBANDS =     -1056.32260199
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.34853402 eV

  energy without entropy =      -23.36518200  energy(sigma->0) =      -23.35408335


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.758   1.410   0.000   2.168
    2        0.872   1.961   0.000   2.833
    3        0.757   1.403   0.000   2.160
    4        1.786   4.508   0.000   6.295
    5        1.790   4.523   0.000   6.313
    6        1.792   4.541   0.000   6.333
    7        1.790   4.526   0.000   6.316
    8        1.789   4.519   0.000   6.308
    9        1.791   4.532   0.000   6.323
   10        1.790   4.525   0.000   6.315
   11        0.196   0.004   0.000   0.200
   12        0.265   0.001   0.000   0.266
--------------------------------------------------
tot         15.375  36.454   0.000  51.829



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.007  -0.002   0.000   0.006
    2        0.000  -0.063   0.000  -0.063
    3        0.007  -0.002   0.000   0.006
    4        0.003   0.022   0.000   0.025
    5        0.003   0.028   0.000   0.031
    6        0.002   0.023   0.000   0.026
    7        0.003   0.027   0.000   0.030
    8        0.003   0.029   0.000   0.032
    9        0.003   0.027   0.000   0.030
   10        0.003   0.027   0.000   0.030
   11        0.112   0.002   0.000   0.114
   12        0.153   0.000   0.000   0.154
--------------------------------------------------
tot          0.299   0.120   0.000   0.419



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.007  -0.002   0.000   0.006
    2        0.000  -0.064   0.000  -0.063
    3        0.007  -0.002   0.000   0.006
    4        0.003   0.022   0.000   0.025
    5        0.003   0.028   0.000   0.031
    6        0.002   0.023   0.000   0.026
    7        0.003   0.027   0.000   0.030
    8        0.003   0.029   0.000   0.032
    9        0.003   0.027   0.000   0.030
   10        0.003   0.027   0.000   0.030
   11        0.112   0.002   0.000   0.114
   12        0.153   0.000   0.000   0.154
--------------------------------------------------
tot          0.299   0.120   0.000   0.419



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.007  -0.001   0.000   0.006
    2        0.000  -0.063   0.000  -0.063
    3        0.007  -0.002   0.000   0.006
    4        0.003   0.022   0.000   0.025
    5        0.003   0.028   0.000   0.031
    6        0.002   0.023   0.000   0.026
    7        0.003   0.027   0.000   0.030
    8        0.003   0.029   0.000   0.032
    9        0.003   0.027   0.000   0.030
   10        0.003   0.027   0.000   0.030
   11        0.112   0.002   0.000   0.114
   12        0.153   0.000   0.000   0.154
--------------------------------------------------
tot          0.299   0.120   0.000   0.419
 

 eigenvalue-minimisations  :  2032
 total energy-change (2. order) :-0.1146256E+00  (-0.1142720E+00)
 number of electron      63.0000085 magnetization       6.8183622      6.8182358      6.8183608
 augmentation part        9.6376134 magnetization       6.3632919      6.3634806      6.3633045

 Broyden mixing:
  rms(total) = 0.40962E+01    rms(broyden)= 0.40939E+01
  rms(prec ) = 0.42154E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5894.95171742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       330.61392537
  PAW double counting   =      4080.95378129    -4117.40366957
  entropy T*S    EENTRO =         0.01724639
  eigenvalues    EBANDS =     -1056.43782597
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.46315958 eV

  energy without entropy =      -23.48040597  energy(sigma->0) =      -23.46890838


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :  1504
 total energy-change (2. order) : 0.4237458E+02  (-0.1216477E+02)
 number of electron      63.0000088 magnetization       4.1823150      4.1839638      4.1828018
 augmentation part        9.5037595 magnetization       3.2415185      3.2395552      3.2412486

 Broyden mixing:
  rms(total) = 0.13155E+01    rms(broyden)= 0.13141E+01
  rms(prec ) = 0.13974E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8696
  0.8696

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5963.10027016
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       363.58515720
  PAW double counting   =      4692.66018091    -4731.91367026
  entropy T*S    EENTRO =         0.01208930
  eigenvalues    EBANDS =      -976.07716637
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        18.91142095 eV

  energy without entropy =       18.89933165  energy(sigma->0) =       18.90739118


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :  1552
 total energy-change (2. order) :-0.4840450E+02  (-0.4845650E+01)
 number of electron      63.0000086 magnetization       2.4434310      2.4426594      2.4435828
 augmentation part        9.1494766 magnetization       1.6474109      1.6501088      1.6481350

 Broyden mixing:
  rms(total) = 0.64674E+00    rms(broyden)= 0.64645E+00
  rms(prec ) = 0.68405E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9878
  0.9878  0.9878

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -6004.01980117
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       331.42158396
  PAW double counting   =      5086.70524839    -5126.07618007
  entropy T*S    EENTRO =         0.00582183
  eigenvalues    EBANDS =      -951.27485669
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -29.49308343 eV

  energy without entropy =      -29.49890526  energy(sigma->0) =      -29.49502404


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :  1560
 total energy-change (2. order) :-0.1175651E+02  (-0.4337552E+00)
 number of electron      63.0000085 magnetization       1.1430830      1.1423963      1.1428591
 augmentation part        9.1295752 magnetization       0.4326045      0.4320751      0.4327645

 Broyden mixing:
  rms(total) = 0.35422E+00    rms(broyden)= 0.35405E+00
  rms(prec ) = 0.37849E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0656
  1.3154  1.1506  0.7309

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5999.53492046
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       322.39973616
  PAW double counting   =      5340.57784287    -5379.28945484
  entropy T*S    EENTRO =         0.00579813
  eigenvalues    EBANDS =      -959.15369691
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -41.24959471 eV

  energy without entropy =      -41.25539285  energy(sigma->0) =      -41.25152742


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :  1640
 total energy-change (2. order) :-0.1187332E+02  (-0.8364295E+00)
 number of electron      63.0000085 magnetization       0.8123107      0.8103089      0.8120366
 augmentation part        9.1274400 magnetization       0.1800369      0.1818530      0.1798934

 Broyden mixing:
  rms(total) = 0.17905E+00    rms(broyden)= 0.17886E+00
  rms(prec ) = 0.20557E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.1261
  1.5120  1.5120  0.8327  0.6478

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5989.13487193
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       312.65616893
  PAW double counting   =      5525.94415410    -5563.66478767
  entropy T*S    EENTRO =         0.00579837
  eigenvalues    EBANDS =      -972.67447780
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.12291567 eV

  energy without entropy =      -53.12871404  energy(sigma->0) =      -53.12484846


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.805   1.542   0.000   2.347
    2        0.829   1.579   0.000   2.408
    3        0.804   1.538   0.000   2.342
    4        1.783   4.363   0.000   6.146
    5        1.786   4.387   0.000   6.174
    6        1.787   4.382   0.000   6.169
    7        1.786   4.383   0.000   6.169
    8        1.787   4.390   0.000   6.176
    9        1.787   4.378   0.000   6.165
   10        1.787   4.390   0.000   6.177
   11        0.394   0.006   0.000   0.400
   12        0.377   0.002   0.000   0.378
--------------------------------------------------
tot         15.711  35.339   0.000  51.051



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.015  -0.120   0.000  -0.135
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.026   0.000  -0.027
    5       -0.000  -0.003   0.000  -0.003
    6       -0.000  -0.013   0.000  -0.013
    7       -0.000  -0.005   0.000  -0.005
    8       -0.000  -0.002   0.000  -0.002
    9       -0.000  -0.011   0.000  -0.011
   10       -0.000  -0.004   0.000  -0.004
   11        0.147   0.001   0.000   0.149
   12        0.218   0.001   0.000   0.218
--------------------------------------------------
tot          0.351  -0.178   0.000   0.172



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.015  -0.116   0.000  -0.132
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.023   0.000  -0.023
    5       -0.000  -0.003   0.000  -0.003
    6       -0.000  -0.012   0.000  -0.012
    7       -0.000  -0.005   0.000  -0.005
    8       -0.000  -0.002   0.000  -0.002
    9       -0.000  -0.010   0.000  -0.011
   10       -0.000  -0.004   0.000  -0.004
   11        0.150   0.001   0.000   0.151
   12        0.217   0.001   0.000   0.218
--------------------------------------------------
tot          0.353  -0.168   0.000   0.185



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.015  -0.121   0.000  -0.136
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.026   0.000  -0.026
    5       -0.000  -0.003   0.000  -0.003
    6       -0.000  -0.012   0.000  -0.013
    7       -0.000  -0.005   0.000  -0.005
    8       -0.000  -0.002   0.000  -0.002
    9       -0.000  -0.011   0.000  -0.011
   10       -0.000  -0.004   0.000  -0.004
   11        0.148   0.001   0.000   0.149
   12        0.218   0.001   0.000   0.218
--------------------------------------------------
tot          0.351  -0.178   0.000   0.173
 

 eigenvalue-minimisations  :  1880
 total energy-change (2. order) :-0.2589116E+01  (-0.2651740E+00)
 number of electron      63.0000085 magnetization       0.8135469      0.8100520      0.8131967
 augmentation part        9.1095112 magnetization       0.2081260      0.1824008      0.2069426

 Broyden mixing:
  rms(total) = 0.17005E+00    rms(broyden)= 0.16986E+00
  rms(prec ) = 0.21701E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9088
  1.5098  1.5098  0.8323  0.6482  0.0439

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5982.89785501
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.66483644
  PAW double counting   =      5576.20058960    -5613.85548706
  entropy T*S    EENTRO =         0.01226024
  eigenvalues    EBANDS =      -979.58147602
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.71203150 eV

  energy without entropy =      -55.72429173  energy(sigma->0) =      -55.71611824


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  1704
 total energy-change (2. order) : 0.1475871E+00  (-0.3354953E-01)
 number of electron      63.0000085 magnetization       0.8217428      0.8095561      0.8210150
 augmentation part        9.1108151 magnetization       0.1992043      0.1744908      0.1979530

 Broyden mixing:
  rms(total) = 0.15563E+00    rms(broyden)= 0.15562E+00
  rms(prec ) = 0.19922E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9463
  1.5388  1.5388  0.6119  0.7758  0.6061  0.6061

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5983.69213789
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.74918508
  PAW double counting   =      5576.98059384    -5614.64211293
  entropy T*S    EENTRO =         0.01094633
  eigenvalues    EBANDS =      -978.71601917
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.56444441 eV

  energy without entropy =      -55.57539074  energy(sigma->0) =      -55.56809319


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :  1448
 total energy-change (2. order) : 0.1340077E+01  (-0.7708556E+00)
 number of electron      63.0000085 magnetization       0.6896835      0.6672651      0.6884581
 augmentation part        9.1210990 magnetization       0.0779622      0.0662562      0.0774919

 Broyden mixing:
  rms(total) = 0.82094E-01    rms(broyden)= 0.81989E-01
  rms(prec ) = 0.98285E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9422
  1.8242  0.6557  1.3917  0.8583  0.7171  0.6529  0.4958

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5982.71341866
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.40297618
  PAW double counting   =      5575.40753091    -5612.99235289
  entropy T*S    EENTRO =         0.00596902
  eigenvalues    EBANDS =      -979.08017243
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.22436756 eV

  energy without entropy =      -54.23033657  energy(sigma->0) =      -54.22635723


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :  1592
 total energy-change (2. order) :-0.1084398E+01  (-0.9141180E-01)
 number of electron      63.0000085 magnetization       0.6165135      0.5975739      0.6155548
 augmentation part        9.1219121 magnetization       0.0123672     -0.0110237      0.0113646

 Broyden mixing:
  rms(total) = 0.47115E-01    rms(broyden)= 0.47027E-01
  rms(prec ) = 0.57948E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9755
  1.9939  0.6249  1.2904  1.2904  0.8385  0.6015  0.5823  0.5823

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5979.24710905
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.36469630
  PAW double counting   =      5594.68319004    -5632.24913678
  entropy T*S    EENTRO =         0.00579947
  eigenvalues    EBANDS =      -982.61130577
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.30876547 eV

  energy without entropy =      -55.31456494  energy(sigma->0) =      -55.31069863


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :  1744
 total energy-change (2. order) : 0.1283882E+00  (-0.1408392E-01)
 number of electron      63.0000085 magnetization       0.6053259      0.5809492      0.6039176
 augmentation part        9.1209561 magnetization      -0.0035758     -0.0151901     -0.0038665

 Broyden mixing:
  rms(total) = 0.44397E-01    rms(broyden)= 0.44378E-01
  rms(prec ) = 0.54450E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9847
  2.1343  0.6337  1.3870  1.3870  0.8570  0.6925  0.6925  0.6244  0.4541

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5977.37759671
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.36950720
  PAW double counting   =      5604.10499053    -5641.60363107
  entropy T*S    EENTRO =         0.00579988
  eigenvalues    EBANDS =      -984.42454741
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.18037725 eV

  energy without entropy =      -55.18617713  energy(sigma->0) =      -55.18231055


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.808   1.553   0.000   2.361
    2        0.832   1.635   0.000   2.467
    3        0.807   1.548   0.000   2.355
    4        1.782   4.366   0.000   6.149
    5        1.787   4.387   0.000   6.174
    6        1.787   4.385   0.000   6.172
    7        1.787   4.383   0.000   6.170
    8        1.787   4.389   0.000   6.177
    9        1.787   4.381   0.000   6.168
   10        1.788   4.390   0.000   6.178
   11        0.343   0.005   0.000   0.348
   12        0.379   0.002   0.000   0.380
--------------------------------------------------
tot         15.675  35.424   0.000  51.099



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.022  -0.173   0.000  -0.195
    3        0.001   0.001   0.000   0.003
    4       -0.000  -0.032   0.000  -0.032
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.011   0.000  -0.012
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.012   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.195   0.002   0.000   0.197
   12        0.218   0.001   0.000   0.219
--------------------------------------------------
tot          0.393  -0.229   0.000   0.164



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.022  -0.172   0.000  -0.194
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.030   0.000  -0.031
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.011   0.000  -0.011
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.190   0.002   0.000   0.192
   12        0.219   0.001   0.000   0.220
--------------------------------------------------
tot          0.389  -0.224   0.000   0.165



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.022  -0.173   0.000  -0.195
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.031   0.000  -0.031
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.011   0.000  -0.012
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.012   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.195   0.002   0.000   0.197
   12        0.218   0.001   0.000   0.219
--------------------------------------------------
tot          0.392  -0.228   0.000   0.165
 

 eigenvalue-minimisations  :  1632
 total energy-change (2. order) : 0.4586516E+00  (-0.1250660E-01)
 number of electron      63.0000085 magnetization       0.6039618      0.5803104      0.6027439
 augmentation part        9.1226315 magnetization       0.0014439     -0.0270889     -0.0001064

 Broyden mixing:
  rms(total) = 0.52928E-01    rms(broyden)= 0.52923E-01
  rms(prec ) = 0.63578E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9626
  2.1610  0.6406  1.3800  1.3800  1.0433  0.8160  0.7274  0.5536  0.4620  0.4620

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5976.88814768
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.73141688
  PAW double counting   =      5605.66283013    -5643.14273450
  entropy T*S    EENTRO =         0.00579922
  eigenvalues    EBANDS =      -984.83599001
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.72172564 eV

  energy without entropy =      -54.72752485  energy(sigma->0) =      -54.72365871


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :  1520
 total energy-change (2. order) : 0.4733494E+00  (-0.1087580E-01)
 number of electron      63.0000085 magnetization       0.6074549      0.5802022      0.6059424
 augmentation part        9.1238866 magnetization      -0.0000333     -0.0199970     -0.0006752

 Broyden mixing:
  rms(total) = 0.61737E-01    rms(broyden)= 0.61733E-01
  rms(prec ) = 0.74772E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9356
  2.1334  0.6440  1.3892  1.3892  1.1008  0.8010  0.8010  0.5371  0.5371  0.5650
  0.3935

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5976.97992859
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.12399297
  PAW double counting   =      5606.07418672    -5643.54488989
  entropy T*S    EENTRO =         0.00579865
  eigenvalues    EBANDS =      -984.67263645
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.24837628 eV

  energy without entropy =      -54.25417493  energy(sigma->0) =      -54.25030916


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :  1720
 total energy-change (2. order) : 0.3797649E+00  (-0.3426395E-02)
 number of electron      63.0000085 magnetization       0.6085566      0.5802646      0.6070620
 augmentation part        9.1238108 magnetization       0.0020970     -0.0226435      0.0006126

 Broyden mixing:
  rms(total) = 0.71717E-01    rms(broyden)= 0.71716E-01
  rms(prec ) = 0.86593E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8847
  2.1244  0.6454  1.3388  1.3388  1.0650  0.8214  0.8214  0.5866  0.5866  0.5736
  0.4216  0.2925

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5977.17604748
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.45989595
  PAW double counting   =      5606.26071779    -5643.72209678
  entropy T*S    EENTRO =         0.00579855
  eigenvalues    EBANDS =      -984.44197976
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.86861141 eV

  energy without entropy =      -53.87440996  energy(sigma->0) =      -53.87054426


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :  1848
 total energy-change (2. order) : 0.1352096E+00  (-0.5151927E-03)
 number of electron      63.0000085 magnetization       0.6032442      0.5791283      0.6021542
 augmentation part        9.1238423 magnetization      -0.0036681     -0.0240485     -0.0043838

 Broyden mixing:
  rms(total) = 0.74980E-01    rms(broyden)= 0.74979E-01
  rms(prec ) = 0.90600E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8455
  2.1265  0.6441  1.3706  1.3706  1.0545  0.8234  0.8234  0.6124  0.6124  0.5695
  0.4302  0.3149  0.2394

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5977.27055450
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.58091985
  PAW double counting   =      5606.40498663    -5643.86291700
  entropy T*S    EENTRO =         0.00579853
  eigenvalues    EBANDS =      -984.33673569
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -53.73340186 eV

  energy without entropy =      -53.73920039  energy(sigma->0) =      -53.73533470


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :  1568
 total energy-change (2. order) :-0.5355749E+00  (-0.3544868E-02)
 number of electron      63.0000085 magnetization       0.5827120      0.5747263      0.5814997
 augmentation part        9.1239618 magnetization      -0.0243039     -0.0284420     -0.0237312

 Broyden mixing:
  rms(total) = 0.60593E-01    rms(broyden)= 0.60592E-01
  rms(prec ) = 0.73799E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.0019
  2.0151  2.1477  1.6383  1.6383  0.6495  1.1022  0.8828  0.8828  0.6496  0.6496
  0.5988  0.4610  0.3734  0.3378

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5976.81262586
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       311.09520943
  PAW double counting   =      5605.79345841    -5643.26899826
  entropy T*S    EENTRO =         0.00579865
  eigenvalues    EBANDS =      -984.82691948
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.26897679 eV

  energy without entropy =      -54.27477544  energy(sigma->0) =      -54.27090968


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.808   1.552   0.000   2.360
    2        0.831   1.627   0.000   2.458
    3        0.807   1.547   0.000   2.354
    4        1.783   4.367   0.000   6.149
    5        1.787   4.387   0.000   6.174
    6        1.787   4.385   0.000   6.173
    7        1.787   4.383   0.000   6.170
    8        1.787   4.389   0.000   6.177
    9        1.787   4.381   0.000   6.168
   10        1.788   4.390   0.000   6.178
   11        0.342   0.008   0.000   0.350
   12        0.377   0.002   0.000   0.378
--------------------------------------------------
tot         15.671  35.419   0.000  51.090



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.019  -0.155   0.000  -0.175
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.030   0.000  -0.030
    5       -0.000  -0.001   0.000  -0.002
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.011
   10       -0.000  -0.001   0.000  -0.001
   11        0.183   0.000   0.000   0.183
   12        0.217   0.001   0.000   0.218
--------------------------------------------------
tot          0.383  -0.207   0.000   0.176



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.001   0.000   0.003
    2       -0.019  -0.155   0.000  -0.174
    3        0.001   0.001   0.000   0.002
    4       -0.000  -0.030   0.000  -0.031
    5       -0.000  -0.001   0.000  -0.002
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.003   0.000  -0.003
    8       -0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.011
   10       -0.000  -0.001   0.000  -0.001
   11        0.182  -0.000   0.000   0.182
   12        0.217   0.001   0.000   0.218
--------------------------------------------------
tot          0.382  -0.208   0.000   0.174



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.019  -0.154   0.000  -0.173
    3        0.001   0.001   0.000   0.003
    4       -0.000  -0.030   0.000  -0.030
    5       -0.000  -0.001   0.000  -0.002
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.003   0.000  -0.003
    8       -0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.011
   10       -0.000  -0.001   0.000  -0.001
   11        0.183   0.000   0.000   0.183
   12        0.218   0.001   0.000   0.218
--------------------------------------------------
tot          0.383  -0.207   0.000   0.177
 

 eigenvalue-minimisations  :  1696
 total energy-change (2. order) :-0.1832755E+01  (-0.1465119E+00)
 number of electron      63.0000085 magnetization       0.5776305      0.5721329      0.5771895
 augmentation part        9.1216749 magnetization      -0.0231798     -0.0289137     -0.0253089

 Broyden mixing:
  rms(total) = 0.36579E-01    rms(broyden)= 0.36490E-01
  rms(prec ) = 0.44686E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9855
  2.3697  2.1819  1.6233  1.6233  0.6493  1.0082  1.0082  0.9407  0.6332  0.6038
  0.6038  0.4587  0.3727  0.3727  0.3336

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.86175238
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.58296934
  PAW double counting   =      5604.18032567    -5641.71722165
  entropy T*S    EENTRO =         0.00582196
  eigenvalues    EBANDS =      -987.03697537
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.10173211 eV

  energy without entropy =      -56.10755407  energy(sigma->0) =      -56.10367276


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  1632
 total energy-change (2. order) :-0.2274687E+00  (-0.3906191E-01)
 number of electron      63.0000085 magnetization       0.5778150      0.5715485      0.5767463
 augmentation part        9.1187502 magnetization      -0.0249232     -0.0278347     -0.0232835

 Broyden mixing:
  rms(total) = 0.54234E-01    rms(broyden)= 0.54177E-01
  rms(prec ) = 0.66519E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9579
  2.5750  2.1966  1.6142  1.6142  0.6492  1.0619  1.0619  0.8896  0.6184  0.5822
  0.5822  0.5107  0.3507  0.3507  0.3601  0.3090

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.20341513
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.47938695
  PAW double counting   =      5604.06291216    -5641.60469646
  entropy T*S    EENTRO =         0.00644561
  eigenvalues    EBANDS =      -987.81493426
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.32920080 eV

  energy without entropy =      -56.33564641  energy(sigma->0) =      -56.33134933


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :  1624
 total energy-change (2. order) :-0.7665355E-01  (-0.5637644E-02)
 number of electron      63.0000085 magnetization       0.5781090      0.5717754      0.5771837
 augmentation part        9.1165629 magnetization      -0.0245593     -0.0311132     -0.0272423

 Broyden mixing:
  rms(total) = 0.66737E-01    rms(broyden)= 0.66720E-01
  rms(prec ) = 0.83348E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9388
  2.7536  2.1981  1.5933  1.5933  0.6492  1.0822  1.0822  0.8868  0.6136  0.6136
  0.5548  0.5548  0.3997  0.3997  0.3681  0.3087  0.3087

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.00190091
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.46294222
  PAW double counting   =      5603.78358763    -5641.32551189
  entropy T*S    EENTRO =         0.00741878
  eigenvalues    EBANDS =      -988.07749050
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.40585434 eV

  energy without entropy =      -56.41327313  energy(sigma->0) =      -56.40832727


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :  1648
 total energy-change (2. order) :-0.2256905E-01  (-0.8289005E-03)
 number of electron      63.0000085 magnetization       0.5743770      0.5686545      0.5741259
 augmentation part        9.1158616 magnetization      -0.0308701     -0.0362869     -0.0315132

 Broyden mixing:
  rms(total) = 0.70786E-01    rms(broyden)= 0.70783E-01
  rms(prec ) = 0.88537E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9091
  2.7061  2.2214  1.6388  1.6388  0.6492  1.0665  1.0665  0.8855  0.6259  0.6259
  0.5442  0.5442  0.4447  0.4447  0.3765  0.3347  0.2922  0.2590

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5973.90707083
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.45525974
  PAW double counting   =      5603.52307329    -5641.06399402
  entropy T*S    EENTRO =         0.00796132
  eigenvalues    EBANDS =      -988.18875322
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.42842340 eV

  energy without entropy =      -56.43638471  energy(sigma->0) =      -56.43107717


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :  1520
 total energy-change (2. order) : 0.4486195E-01  (-0.4805256E-02)
 number of electron      63.0000085 magnetization       0.5720884      0.5652785      0.5709499
 augmentation part        9.1167007 magnetization      -0.0326597     -0.0360687     -0.0291526

 Broyden mixing:
  rms(total) = 0.64773E-01    rms(broyden)= 0.64771E-01
  rms(prec ) = 0.80616E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9151
  2.6174  2.2726  1.6618  1.6618  0.6478  0.6877  1.0682  1.0682  0.8713  0.5728
  0.5728  0.6483  0.6483  0.5300  0.5300  0.3739  0.3739  0.3337  0.2466

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.06883308
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.47223704
  PAW double counting   =      5604.32089903    -5641.86461936
  entropy T*S    EENTRO =         0.00704024
  eigenvalues    EBANDS =      -987.99538563
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.38356145 eV

  energy without entropy =      -56.39060169  energy(sigma->0) =      -56.38590820


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.808   1.552   0.000   2.360
    2        0.830   1.619   0.000   2.449
    3        0.807   1.547   0.000   2.354
    4        1.783   4.365   0.000   6.148
    5        1.787   4.387   0.000   6.174
    6        1.787   4.385   0.000   6.172
    7        1.787   4.383   0.000   6.170
    8        1.787   4.389   0.000   6.176
    9        1.787   4.380   0.000   6.168
   10        1.788   4.390   0.000   6.177
   11        0.344   0.010   0.000   0.354
   12        0.377   0.002   0.000   0.379
--------------------------------------------------
tot         15.673  35.408   0.000  51.081



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.145   0.000  -0.162
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.029   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.001
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.176  -0.001   0.000   0.175
   12        0.218   0.001   0.000   0.218
--------------------------------------------------
tot          0.378  -0.194   0.000   0.183



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.145   0.000  -0.163
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.029   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.001
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.176  -0.001   0.000   0.175
   12        0.217   0.001   0.000   0.218
--------------------------------------------------
tot          0.377  -0.195   0.000   0.181



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.144   0.000  -0.162
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.029   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.001
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.002
    8       -0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.176  -0.001   0.000   0.175
   12        0.218   0.001   0.000   0.219
--------------------------------------------------
tot          0.377  -0.194   0.000   0.183
 

 eigenvalue-minimisations  :  1592
 total energy-change (2. order) : 0.1444224E+00  (-0.1796208E-01)
 number of electron      63.0000085 magnetization       0.5685276      0.5626134      0.5678369
 augmentation part        9.1186240 magnetization      -0.0318689     -0.0366277     -0.0323684

 Broyden mixing:
  rms(total) = 0.48789E-01    rms(broyden)= 0.48777E-01
  rms(prec ) = 0.59937E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9117
  2.4360  2.3261  1.6801  1.6801  1.0633  0.6489  1.0752  1.0752  0.6692  0.6692
  0.8681  0.6260  0.6260  0.5778  0.5121  0.3773  0.3773  0.3392  0.3392  0.2683

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.22385461
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.52505575
  PAW double counting   =      5604.96883920    -5642.51393583
  entropy T*S    EENTRO =         0.00610640
  eigenvalues    EBANDS =      -987.74645027
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.23913903 eV

  energy without entropy =      -56.24524543  energy(sigma->0) =      -56.24117449


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :  1512
 total energy-change (2. order) : 0.1310567E-01  (-0.5185666E-02)
 number of electron      63.0000085 magnetization       0.5632746      0.5606797      0.5624555
 augmentation part        9.1191308 magnetization      -0.0389184     -0.0388093     -0.0362166

 Broyden mixing:
  rms(total) = 0.44283E-01    rms(broyden)= 0.44279E-01
  rms(prec ) = 0.55643E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9193
  2.2251  2.3794  1.4382  1.7370  1.7370  0.6490  0.7839  0.7839  1.0164  1.0164
  0.9125  0.5054  0.5054  0.6290  0.6290  0.5320  0.5320  0.3872  0.3349  0.3202
  0.2517

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.31640340
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.53409709
  PAW double counting   =      5605.60905220    -5643.15484400
  entropy T*S    EENTRO =         0.00598934
  eigenvalues    EBANDS =      -987.64902491
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.22603335 eV

  energy without entropy =      -56.23202270  energy(sigma->0) =      -56.22802980


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :  1600
 total energy-change (2. order) :-0.2031609E+00  (-0.5977509E-01)
 number of electron      63.0000085 magnetization       0.5633522      0.5606791      0.5625086
 augmentation part        9.1149129 magnetization      -0.0464618     -0.0479989     -0.0472230

 Broyden mixing:
  rms(total) = 0.87424E-01    rms(broyden)= 0.87397E-01
  rms(prec ) = 0.11106E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8776
  2.2243  2.3793  1.4392  1.7370  1.7370  0.6490  1.0165  1.0165  0.7841  0.7841
  0.9124  0.5054  0.5054  0.6292  0.6292  0.5318  0.5318  0.3872  0.3347  0.3203
  0.2517  0.0011

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.17132981
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.48886946
  PAW double counting   =      5606.09204652    -5643.63628628
  entropy T*S    EENTRO =         0.00874643
  eigenvalues    EBANDS =      -987.95634089
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.42919423 eV

  energy without entropy =      -56.43794067  energy(sigma->0) =      -56.43210971


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :  1560
 total energy-change (2. order) : 0.2753850E-01  (-0.5289199E-02)
 number of electron      63.0000085 magnetization       0.5633267      0.5606048      0.5624892
 augmentation part        9.1154722 magnetization      -0.0426315     -0.0439271     -0.0433164

 Broyden mixing:
  rms(total) = 0.79296E-01    rms(broyden)= 0.79296E-01
  rms(prec ) = 0.10034E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8515
  2.1348  2.3751  1.5065  1.7278  1.7278  0.6490  0.8258  0.8258  1.0148  1.0148
  0.9087  0.5152  0.5152  0.6268  0.6268  0.5300  0.5300  0.3871  0.3328  0.3231
  0.2508  0.0818  0.1548

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.16977223
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.48733951
  PAW double counting   =      5606.07816616    -5643.62244590
  entropy T*S    EENTRO =         0.00788166
  eigenvalues    EBANDS =      -987.92792526
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.40165573 eV

  energy without entropy =      -56.40953739  energy(sigma->0) =      -56.40428295


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :  1688
 total energy-change (2. order) : 0.1863710E-01  (-0.7652237E-03)
 number of electron      63.0000085 magnetization       0.5607123      0.5579800      0.5599659
 augmentation part        9.1159953 magnetization      -0.0436911     -0.0449369     -0.0442594

 Broyden mixing:
  rms(total) = 0.74185E-01    rms(broyden)= 0.74185E-01
  rms(prec ) = 0.93838E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8411
  2.4127  1.8142  1.8142  1.7703  1.7703  0.6490  0.8900  0.8900  0.9346  0.9346
  0.9116  0.6183  0.6183  0.6019  0.5025  0.5025  0.4803  0.3414  0.3414  0.3599
  0.3599  0.3180  0.2501  0.1011

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.18434514
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.49022316
  PAW double counting   =      5606.11894506    -5643.66323413
  entropy T*S    EENTRO =         0.00746234
  eigenvalues    EBANDS =      -987.89717026
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.38301863 eV

  energy without entropy =      -56.39048098  energy(sigma->0) =      -56.38550608


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.808   1.552   0.000   2.360
    2        0.830   1.614   0.000   2.444
    3        0.807   1.547   0.000   2.354
    4        1.783   4.364   0.000   6.147
    5        1.787   4.386   0.000   6.174
    6        1.787   4.385   0.000   6.172
    7        1.787   4.383   0.000   6.170
    8        1.787   4.389   0.000   6.176
    9        1.787   4.380   0.000   6.167
   10        1.788   4.390   0.000   6.178
   11        0.350   0.010   0.000   0.359
   12        0.378   0.002   0.000   0.380
--------------------------------------------------
tot         15.679  35.401   0.000  51.080



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.143   0.000  -0.161
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.029   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.002
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.002
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.175  -0.001   0.000   0.174
   12        0.219   0.001   0.000   0.219
--------------------------------------------------
tot          0.377  -0.194   0.000   0.183



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.144   0.000  -0.162
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.029   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.001
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.002
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.175  -0.001   0.000   0.174
   12        0.218   0.001   0.000   0.219
--------------------------------------------------
tot          0.376  -0.194   0.000   0.182



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.018  -0.144   0.000  -0.162
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.028   0.000  -0.029
    5       -0.000  -0.001   0.000  -0.001
    6       -0.000  -0.010   0.000  -0.010
    7       -0.000  -0.002   0.000  -0.002
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.010   0.000  -0.010
   10       -0.000  -0.001   0.000  -0.001
   11        0.174  -0.001   0.000   0.173
   12        0.219   0.001   0.000   0.220
--------------------------------------------------
tot          0.377  -0.193   0.000   0.183
 

 eigenvalue-minimisations  :  1480
 total energy-change (2. order) : 0.1125997E+00  (-0.2208076E-01)
 number of electron      63.0000085 magnetization       0.5570456      0.5533635      0.5563846
 augmentation part        9.1175573 magnetization      -0.0443048     -0.0453058     -0.0440004

 Broyden mixing:
  rms(total) = 0.57614E-01    rms(broyden)= 0.57605E-01
  rms(prec ) = 0.72879E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8572
  2.4439  1.8268  1.8268  1.8029  1.8029  0.6490  1.0180  1.0180  0.9908  0.9908
  0.8622  0.6709  0.6709  0.6245  0.6245  0.4819  0.4819  0.4899  0.4899  0.3848
  0.3191  0.3027  0.3027  0.2517  0.1012

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.34177543
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.52795184
  PAW double counting   =      5606.78200811    -5644.33013396
  entropy T*S    EENTRO =         0.00618649
  eigenvalues    EBANDS =      -987.65975634
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -56.27041896 eV

  energy without entropy =      -56.27660546  energy(sigma->0) =      -56.27248113


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :  1600
 total energy-change (2. order) : 0.3487989E+00  (-0.7504684E-01)
 number of electron      63.0000085 magnetization       0.5551305      0.5515053      0.5544582
 augmentation part        9.1186762 magnetization      -0.0465578     -0.0486811     -0.0463143

 Broyden mixing:
  rms(total) = 0.46064E-01    rms(broyden)= 0.46040E-01
  rms(prec ) = 0.57997E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8475
  2.5037  1.8244  1.8244  1.8390  1.8390  0.6490  1.0932  1.0932  0.9641  0.9641
  0.8682  0.6862  0.6862  0.6974  0.5899  0.4475  0.4475  0.5066  0.5066  0.3970
  0.3047  0.3047  0.3432  0.3019  0.2526  0.1009

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.87165378
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.73042208
  PAW double counting   =      5608.73505793    -5646.28342469
  entropy T*S    EENTRO =         0.00580871
  eigenvalues    EBANDS =      -986.98293061
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.92162004 eV

  energy without entropy =      -55.92742875  energy(sigma->0) =      -55.92355628


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :  1776
 total energy-change (2. order) : 0.1141274E+00  (-0.9462495E-02)
 number of electron      63.0000085 magnetization       0.5522470      0.5497853      0.5515602
 augmentation part        9.1192858 magnetization      -0.0508017     -0.0519763     -0.0500874

 Broyden mixing:
  rms(total) = 0.42041E-01    rms(broyden)= 0.42019E-01
  rms(prec ) = 0.54504E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8363
  2.5567  1.8256  1.8256  1.8557  1.8557  0.6490  1.0714  1.0714  1.0516  1.0516
  0.8829  0.6547  0.6547  0.7150  0.6255  0.4313  0.4313  0.4993  0.4993  0.1009
  0.3787  0.3787  0.3535  0.3479  0.2766  0.2766  0.2578

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.21253295
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.84156915
  PAW double counting   =      5610.03481722    -5647.58070445
  entropy T*S    EENTRO =         0.00580329
  eigenvalues    EBANDS =      -986.64154521
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.80749263 eV

  energy without entropy =      -55.81329592  energy(sigma->0) =      -55.80942706


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :  1600
 total energy-change (2. order) : 0.8853163E-01  (-0.7781380E-02)
 number of electron      63.0000085 magnetization       0.5506901      0.5485958      0.5498107
 augmentation part        9.1194823 magnetization      -0.0538725     -0.0529096     -0.0521761

 Broyden mixing:
  rms(total) = 0.42507E-01    rms(broyden)= 0.42502E-01
  rms(prec ) = 0.54748E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8232
  2.5534  1.8189  1.8189  1.8570  1.8570  1.1081  1.1081  0.6490  1.0997  1.0997
  0.8632  0.7304  0.6392  0.6392  0.6326  0.4305  0.4305  0.4625  0.4625  0.4544
  0.4544  0.1009  0.3857  0.3257  0.2644  0.2644  0.2892  0.2514

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.40030877
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.88968374
  PAW double counting   =      5611.17777910    -5648.72031841
  entropy T*S    EENTRO =         0.00579962
  eigenvalues    EBANDS =      -986.41669661
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.71896101 eV

  energy without entropy =      -55.72476063  energy(sigma->0) =      -55.72089421


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :  1744
 total energy-change (2. order) : 0.1032504E+00  (-0.2324747E-02)
 number of electron      63.0000085 magnetization       0.5497145      0.5481630      0.5487534
 augmentation part        9.1194979 magnetization      -0.0553661     -0.0547105     -0.0533580

 Broyden mixing:
  rms(total) = 0.46712E-01    rms(broyden)= 0.46708E-01
  rms(prec ) = 0.60048E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8023
  2.5506  1.8167  1.8167  1.8550  1.8550  1.1113  1.1113  0.6490  1.1133  1.1133
  0.8609  0.7296  0.6399  0.6399  0.6316  0.4203  0.4203  0.4435  0.4435  0.4657
  0.4657  0.1009  0.3866  0.3290  0.2695  0.2695  0.2910  0.2494  0.2189

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.70432068
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.98399313
  PAW double counting   =      5612.42573616    -5649.96699850
  entropy T*S    EENTRO =         0.00579895
  eigenvalues    EBANDS =      -986.10501995
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.61571057 eV

  energy without entropy =      -55.62150952  energy(sigma->0) =      -55.61764355


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------





 total charge

# of ion       s       p       d       tot
------------------------------------------
    1        0.808   1.552   0.000   2.360
    2        0.830   1.627   0.000   2.457
    3        0.807   1.547   0.000   2.354
    4        1.782   4.364   0.000   6.146
    5        1.787   4.386   0.000   6.174
    6        1.787   4.385   0.000   6.172
    7        1.787   4.383   0.000   6.170
    8        1.787   4.389   0.000   6.176
    9        1.787   4.380   0.000   6.168
   10        1.788   4.390   0.000   6.178
   11        0.345   0.006   0.000   0.351
   12        0.382   0.002   0.000   0.384
--------------------------------------------------
tot         15.679  35.412   0.000  51.091



 magnetization (x)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.022  -0.170   0.000  -0.191
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.031   0.000  -0.032
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.012   0.000  -0.012
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.192   0.001   0.000   0.194
   12        0.221   0.001   0.000   0.222
--------------------------------------------------
tot          0.393  -0.224   0.000   0.169



 magnetization (y)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.021  -0.167   0.000  -0.188
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.031   0.000  -0.031
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.011   0.000  -0.012
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.190   0.001   0.000   0.191
   12        0.220   0.001   0.000   0.221
--------------------------------------------------
tot          0.390  -0.221   0.000   0.169



 magnetization (z)

# of ion       s       p       d       tot
------------------------------------------
    1        0.001   0.002   0.000   0.003
    2       -0.022  -0.169   0.000  -0.190
    3        0.001   0.002   0.000   0.003
    4       -0.000  -0.031   0.000  -0.032
    5       -0.000  -0.002   0.000  -0.002
    6       -0.000  -0.012   0.000  -0.012
    7       -0.000  -0.003   0.000  -0.003
    8        0.000  -0.001   0.000  -0.001
    9       -0.000  -0.011   0.000  -0.012
   10       -0.000  -0.001   0.000  -0.001
   11        0.191   0.001   0.000   0.192
   12        0.221   0.001   0.000   0.222
--------------------------------------------------
tot          0.392  -0.224   0.000   0.168
 

 eigenvalue-minimisations  :  1592
 total energy-change (2. order) : 0.7154856E-01  (-0.1564054E-02)
 number of electron      63.0000085 magnetization       0.5506319      0.5486401      0.5497556
 augmentation part        9.1194842 magnetization      -0.0549216     -0.0546126     -0.0526119

 Broyden mixing:
  rms(total) = 0.49333E-01    rms(broyden)= 0.49332E-01
  rms(prec ) = 0.63272E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8071
  2.5584  1.8123  1.8123  1.8573  1.8573  1.1560  1.1560  0.6490  1.1003  1.1003
  0.5289  0.8630  0.7279  0.6444  0.6444  0.6333  0.4902  0.4902  0.4802  0.4802
  0.4706  0.4706  0.1009  0.3900  0.2999  0.2999  0.3332  0.2993  0.2539  0.2539

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.90327441
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       310.04090873
  PAW double counting   =      5613.15982981    -5650.69964278
  entropy T*S    EENTRO =         0.00579870
  eigenvalues    EBANDS =      -985.89288240
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.54416201 eV

  energy without entropy =      -55.54996071  energy(sigma->0) =      -55.54609491


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :  1552
 total energy-change (2. order) :-0.7126042E-01  (-0.1340880E-02)
 number of electron      63.0000085 magnetization       0.5519823      0.5492270      0.5511798
 augmentation part        9.1195865 magnetization      -0.0533567     -0.0537205     -0.0510134

 Broyden mixing:
  rms(total) = 0.46052E-01    rms(broyden)= 0.46052E-01
  rms(prec ) = 0.59455E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8214
  2.5725  1.6276  1.6276  1.8583  1.8583  1.3665  1.2588  1.2588  0.6490  1.0868
  1.0868  0.8667  0.6999  0.6999  0.5504  0.5504  0.7073  0.6370  0.4759  0.4759
  0.4935  0.4935  0.1009  0.3657  0.3657  0.3228  0.3228  0.2971  0.2518  0.2674
  0.2674

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.70972348
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.98462327
  PAW double counting   =      5612.48938926    -5650.03067506
  entropy T*S    EENTRO =         0.00579895
  eigenvalues    EBANDS =      -986.09993570
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.61542243 eV

  energy without entropy =      -55.62122138  energy(sigma->0) =      -55.61735541


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :  1632
 total energy-change (2. order) :-0.1454228E+00  (-0.5225204E-02)
 number of electron      63.0000085 magnetization       0.5536130      0.5506505      0.5527005
 augmentation part        9.1195281 magnetization      -0.0509644     -0.0520695     -0.0484461

 Broyden mixing:
  rms(total) = 0.41839E-01    rms(broyden)= 0.41836E-01
  rms(prec ) = 0.54084E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8444
  2.4917  2.5825  1.4377  1.4377  1.8635  1.8635  1.3558  1.3558  0.6490  1.0659
  1.0659  0.8699  0.7648  0.7648  0.5991  0.5991  0.6918  0.6315  0.4669  0.4669
  0.5046  0.5046  0.1009  0.4043  0.4043  0.3684  0.2915  0.2915  0.3221  0.2943
  0.2551  0.2551

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5975.30759434
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.86850833
  PAW double counting   =      5611.32139396    -5648.86527296
  entropy T*S    EENTRO =         0.00580069
  eigenvalues    EBANDS =      -986.52878127
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.76084527 eV

  energy without entropy =      -55.76664596  energy(sigma->0) =      -55.76277883


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :  1672
 total energy-change (2. order) :-0.2308443E+00  (-0.1423588E-01)
 number of electron      63.0000085 magnetization       0.5567657      0.5536663      0.5560489
 augmentation part        9.1192978 magnetization      -0.0464559     -0.0471654     -0.0447185

 Broyden mixing:
  rms(total) = 0.35563E-01    rms(broyden)= 0.35550E-01
  rms(prec ) = 0.45749E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8754
  3.2459  2.6066  1.4658  1.4658  1.8859  1.8859  1.4740  1.4740  0.6490  1.0517
  1.0517  0.8769  0.8769  0.8671  0.6072  0.6072  0.6866  0.6446  0.4848  0.4848
  0.5033  0.5033  0.4720  0.4720  0.1009  0.3931  0.3572  0.3017  0.3017  0.3090
  0.2532  0.2633  0.2633

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1527.42513088
  -Hartree energ DENC   =     -5974.59902258
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.68385454
  PAW double counting   =      5609.46582290    -5647.01422364
  entropy T*S    EENTRO =         0.00582525
  eigenvalues    EBANDS =      -987.27904636
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -55.99168958 eV

  energy without entropy =      -55.99751483  energy(sigma->0) =      -55.99363133


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------