vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.01  23:31:48
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.136  0.605  0.287-
   2  0.359  0.069  0.978-   8 1.27
   3  0.221  0.179  0.805-   8 1.35
   4  0.333  0.539  0.711-
   5  0.939  0.839  0.823-
   6  0.463  0.565  0.001-
   7  0.373  0.199  0.327-
   8  0.241  0.061  0.923-   2 1.27   3 1.35
   9  0.104  0.373  0.146-
  10  0.570  0.282  0.378-
  11  0.329  0.817  0.750-
  12  0.354  0.989  0.695-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.136240190  0.605168110  0.286907870
     0.359272890  0.069413980  0.978221750
     0.221473150  0.178671550  0.805010600
     0.333301790  0.539095730  0.711029770
     0.939423590  0.838946390  0.823045520
     0.463396090  0.564527670  0.000866960
     0.372889720  0.199360540  0.326630840
     0.240799240  0.060665030  0.923183570
     0.103950170  0.372603970  0.146499640
     0.570182420  0.281901500  0.377968520
     0.328549550  0.816561980  0.749922870
     0.354446300  0.989047490  0.694707780

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     40
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.63E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands            8
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.13624019  0.60516811  0.28690787
   0.35927289  0.06941398  0.97822175
   0.22147315  0.17867155  0.80501060
   0.33330179  0.53909573  0.71102977
   0.93942359  0.83894639  0.82304552
   0.46339609  0.56452767  0.00086696
   0.37288972  0.19936054  0.32663084
   0.24079924  0.06066503  0.92318357
   0.10395017  0.37260397  0.14649964
   0.57018242  0.28190150  0.37796852
   0.32854955  0.81656198  0.74992287
   0.35444630  0.98904749  0.69470778
 
 position of ions in cartesian coordinates  (Angst):
   1.36240190  4.84134488  2.29526296
   3.59272890  0.55531184  7.82577400
   2.21473150  1.42937240  6.44008480
   3.33301790  4.31276584  5.68823816
   9.39423590  6.71157112  6.58436416
   4.63396090  4.51622136  0.00693568
   3.72889720  1.59488432  2.61304672
   2.40799240  0.48532024  7.38546856
   1.03950170  2.98083176  1.17199712
   5.70182420  2.25521200  3.02374816
   3.28549550  6.53249584  5.99938296
   3.54446300  7.91237992  5.55766224
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    65904. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1269. kBytes
   fftplans  :       5842. kBytes
   grid      :      13664. kBytes
   one-center:         36. kBytes
   wavefun   :      15093. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1344
 Maximum index for augmentation-charges          392 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   720
 total energy-change (2. order) : 0.5469463E+03  (-0.2171930E+04)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3506.18617724
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.44531101
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.00664292
  eigenvalues    EBANDS =      -353.60035098
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       546.94633020 eV

  energy without entropy =      546.95297312  energy(sigma->0) =      546.94854451


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   912
 total energy-change (2. order) :-0.4975434E+03  (-0.4787518E+03)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3506.18617724
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.44531101
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.00771125
  eigenvalues    EBANDS =      -851.14265187
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        49.40296098 eV

  energy without entropy =       49.41067223  energy(sigma->0) =       49.40553139


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.8940881E+02  (-0.8698633E+02)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3506.18617724
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.44531101
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05469441
  eigenvalues    EBANDS =      -940.50447433
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -40.00584464 eV

  energy without entropy =      -39.95115023  energy(sigma->0) =      -39.98761317


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) :-0.2136846E+01  (-0.2097553E+01)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3506.18617724
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.44531101
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05557890
  eigenvalues    EBANDS =      -942.64043564
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -42.14269044 eV

  energy without entropy =      -42.08711154  energy(sigma->0) =      -42.12416414


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   760
 total energy-change (2. order) :-0.5438515E-01  (-0.5434227E-01)
 number of electron      63.0000380 magnetization 
 augmentation part        9.7629572 magnetization 

 Broyden mixing:
  rms(total) = 0.21192E+01    rms(broyden)= 0.21181E+01
  rms(prec ) = 0.35507E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3506.18617724
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.44531101
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05564855
  eigenvalues    EBANDS =      -942.69475113
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -42.19707558 eV

  energy without entropy =      -42.14142703  energy(sigma->0) =      -42.17852607


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) :-0.1256254E+02  (-0.1197730E+02)
 number of electron      63.0000249 magnetization 
 augmentation part        5.7736689 magnetization 

 Broyden mixing:
  rms(total) = 0.62294E+01    rms(broyden)= 0.62261E+01
  rms(prec ) = 0.98359E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2332
  0.2332

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3628.79800901
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       300.37081680
  PAW double counting   =      4512.54970179    -4553.61597772
  entropy T*S    EENTRO =        -0.23648154
  eigenvalues    EBANDS =      -835.76088340
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -54.75961388 eV

  energy without entropy =      -54.52313234  energy(sigma->0) =      -54.68078670


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.2200924E+02  (-0.7505595E+01)
 number of electron      63.0000423 magnetization 
 augmentation part        8.4425539 magnetization 

 Broyden mixing:
  rms(total) = 0.33892E+01    rms(broyden)= 0.33838E+01
  rms(prec ) = 0.51636E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2126
  0.2656  0.1596

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3552.73278418
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       296.53689710
  PAW double counting   =      4404.39470863    -4442.96829391
  entropy T*S    EENTRO =         0.02173125
  eigenvalues    EBANDS =      -888.73385304
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -32.75037494 eV

  energy without entropy =      -32.77210620  energy(sigma->0) =      -32.75761869


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   672
 total energy-change (2. order) : 0.2766371E+01  (-0.1408185E+01)
 number of electron      63.0000371 magnetization 
 augmentation part        8.8471259 magnetization 

 Broyden mixing:
  rms(total) = 0.23457E+01    rms(broyden)= 0.23411E+01
  rms(prec ) = 0.35780E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2035
  0.3062  0.1522  0.1522

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3542.35844510
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.88234562
  PAW double counting   =      4404.02793125    -4442.20823531
  entropy T*S    EENTRO =        -0.02780937
  eigenvalues    EBANDS =      -896.03101070
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -29.98400443 eV

  energy without entropy =      -29.95619506  energy(sigma->0) =      -29.97473464


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.6889949E+00  (-0.3090529E+01)
 number of electron      63.0000291 magnetization 
 augmentation part        8.7919323 magnetization 

 Broyden mixing:
  rms(total) = 0.23351E+01    rms(broyden)= 0.23335E+01
  rms(prec ) = 0.36619E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.1835
  0.3204  0.1543  0.1543  0.1052

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3540.19593749
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.70569041
  PAW double counting   =      4416.19329307    -4454.23483307
  entropy T*S    EENTRO =        -0.15526092
  eigenvalues    EBANDS =      -897.33918075
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -29.29500957 eV

  energy without entropy =      -29.13974864  energy(sigma->0) =      -29.24325592


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.1373636E+01  (-0.2125551E+01)
 number of electron      63.0000371 magnetization 
 augmentation part        9.1190290 magnetization 

 Broyden mixing:
  rms(total) = 0.14040E+01    rms(broyden)= 0.14000E+01
  rms(prec ) = 0.23773E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2152
  0.4888  0.1775  0.1775  0.1160  0.1160

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3540.18759776
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.62129090
  PAW double counting   =      4424.93245753    -4462.90291319
  entropy T*S    EENTRO =        -0.05297137
  eigenvalues    EBANDS =      -896.06285927
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -27.92137398 eV

  energy without entropy =      -27.86840261  energy(sigma->0) =      -27.90371686


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) : 0.2005941E+01  (-0.2641482E-01)
 number of electron      63.0000370 magnetization 
 augmentation part        9.0476302 magnetization 

 Broyden mixing:
  rms(total) = 0.13442E+01    rms(broyden)= 0.13435E+01
  rms(prec ) = 0.22601E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2421
  0.3858  0.3858  0.2043  0.2043  0.1563  0.1160

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3540.50852498
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.69857781
  PAW double counting   =      4450.52194057    -4488.41721979
  entropy T*S    EENTRO =         0.04810347
  eigenvalues    EBANDS =      -893.98952911
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -25.91543285 eV

  energy without entropy =      -25.96353631  energy(sigma->0) =      -25.93146734


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.7676636E+00  (-0.3017847E+00)
 number of electron      63.0000334 magnetization 
 augmentation part        9.0586594 magnetization 

 Broyden mixing:
  rms(total) = 0.14398E+01    rms(broyden)= 0.14358E+01
  rms(prec ) = 0.24556E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2980
  0.5112  0.5112  0.4678  0.1751  0.1751  0.1229  0.1229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3539.99899171
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.70473549
  PAW double counting   =      4460.53260112    -4498.35001914
  entropy T*S    EENTRO =        -0.01243527
  eigenvalues    EBANDS =      -893.75487896
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -25.14776928 eV

  energy without entropy =      -25.13533400  energy(sigma->0) =      -25.14362418


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.1059393E+01  (-0.2430793E-01)
 number of electron      63.0000303 magnetization 
 augmentation part        8.5927835 magnetization 

 Broyden mixing:
  rms(total) = 0.15354E+01    rms(broyden)= 0.15337E+01
  rms(prec ) = 0.24200E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3466
  0.8505  0.8505  0.2708  0.1914  0.1914  0.1804  0.1188  0.1188

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3540.16089837
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.69069903
  PAW double counting   =      4488.41598260    -4526.13312936
  entropy T*S    EENTRO =        -0.18309868
  eigenvalues    EBANDS =      -892.44915118
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -24.08837677 eV

  energy without entropy =      -23.90527809  energy(sigma->0) =      -24.02734388


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   736
 total energy-change (2. order) : 0.5725146E+00  (-0.5193934E+00)
 number of electron      63.0000366 magnetization 
 augmentation part        8.2161435 magnetization 

 Broyden mixing:
  rms(total) = 0.21212E+01    rms(broyden)= 0.21160E+01
  rms(prec ) = 0.31986E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3306
  0.8608  0.8608  0.2953  0.1997  0.1997  0.1253  0.1253  0.1541  0.1541

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3539.82712410
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.62605824
  PAW double counting   =      4517.91444591    -4555.40848469
  entropy T*S    EENTRO =        -0.07030408
  eigenvalues    EBANDS =      -892.48167259
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.51586213 eV

  energy without entropy =      -23.44555804  energy(sigma->0) =      -23.49242743


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   720
 total energy-change (2. order) : 0.7400632E+00  (-0.7333457E-01)
 number of electron      63.0000347 magnetization 
 augmentation part        8.3049550 magnetization 

 Broyden mixing:
  rms(total) = 0.12652E+01    rms(broyden)= 0.12593E+01
  rms(prec ) = 0.17891E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2984
  0.8623  0.8623  0.2931  0.2009  0.2009  0.1253  0.1253  0.1540  0.1540  0.0061

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3539.41410710
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.65861911
  PAW double counting   =      4525.00131158    -4562.42292267
  entropy T*S    EENTRO =         0.01946215
  eigenvalues    EBANDS =      -892.34938115
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.77579888 eV

  energy without entropy =      -22.79526103  energy(sigma->0) =      -22.78228626


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   656
 total energy-change (2. order) : 0.1738796E+00  (-0.2075195E-02)
 number of electron      63.0000353 magnetization 
 augmentation part        8.3528012 magnetization 

 Broyden mixing:
  rms(total) = 0.12263E+01    rms(broyden)= 0.12257E+01
  rms(prec ) = 0.17463E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4295
  1.2745  1.2745  0.5498  0.2858  0.2858  0.2265  0.2265  0.1753  0.1753  0.1251
  0.1251

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3539.05214190
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.68271356
  PAW double counting   =      4524.90693680    -4562.31159702
  entropy T*S    EENTRO =         0.04797018
  eigenvalues    EBANDS =      -892.60702007
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.60191927 eV

  energy without entropy =      -22.64988945  energy(sigma->0) =      -22.61790933


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) :-0.6475056E+00  (-0.2783846E+00)
 number of electron      63.0000324 magnetization 
 augmentation part        7.6118107 magnetization 

 Broyden mixing:
  rms(total) = 0.37042E+01    rms(broyden)= 0.37022E+01
  rms(prec ) = 0.57338E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3971
  1.2946  1.2946  0.5503  0.2831  0.2831  0.2248  0.2248  0.1738  0.1738  0.1250
  0.1250  0.0128

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3536.47592416
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.47555693
  PAW double counting   =      4542.82264502    -4579.98261819
  entropy T*S    EENTRO =        -0.01551222
  eigenvalues    EBANDS =      -895.80479146
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.24942489 eV

  energy without entropy =      -23.23391267  energy(sigma->0) =      -23.24425415


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.6972392E-01  (-0.3777732E-02)
 number of electron      63.0000324 magnetization 
 augmentation part        7.6275041 magnetization 

 Broyden mixing:
  rms(total) = 0.36220E+01    rms(broyden)= 0.36219E+01
  rms(prec ) = 0.56069E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3937
  1.1042  1.1042  0.9817  0.3381  0.3381  0.2261  0.2261  0.1641  0.1641  0.1249
  0.1249  0.1108  0.1108

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3536.46057410
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.47857991
  PAW double counting   =      4543.09075985    -4580.24980449
  entropy T*S    EENTRO =        -0.02649015
  eigenvalues    EBANDS =      -895.74339119
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.17970097 eV

  energy without entropy =      -23.15321083  energy(sigma->0) =      -23.17087092


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   720
 total energy-change (2. order) :-0.9321656E+00  (-0.3686915E+00)
 number of electron      63.0000283 magnetization 
 augmentation part        7.2166536 magnetization 

 Broyden mixing:
  rms(total) = 0.35232E+01    rms(broyden)= 0.35224E+01
  rms(prec ) = 0.55702E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3780
  1.2191  1.2191  0.8450  0.3450  0.3450  0.2229  0.2229  0.1592  0.1592  0.1249
  0.1249  0.1314  0.1314  0.0415

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3538.57376637
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.61039069
  PAW double counting   =      4554.28233517    -4591.51700072
  entropy T*S    EENTRO =        -0.04506465
  eigenvalues    EBANDS =      -894.59997990
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -24.11186657 eV

  energy without entropy =      -24.06680193  energy(sigma->0) =      -24.09684502


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.8747320E+00  (-0.7105165E-02)
 number of electron      63.0000282 magnetization 
 augmentation part        7.2915249 magnetization 

 Broyden mixing:
  rms(total) = 0.31247E+01    rms(broyden)= 0.31246E+01
  rms(prec ) = 0.49511E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3540
  1.2063  1.2063  0.8317  0.3492  0.3492  0.2268  0.2268  0.1626  0.1626  0.1251
  0.1251  0.1133  0.1133  0.0560  0.0560

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3538.02497745
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.66608818
  PAW double counting   =      4549.59343177    -4586.84169596
  entropy T*S    EENTRO =        -0.11535923
  eigenvalues    EBANDS =      -894.24584104
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.23713454 eV

  energy without entropy =      -23.12177531  energy(sigma->0) =      -23.19868147


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   800
 total energy-change (2. order) : 0.1490411E-01  (-0.5813973E-03)
 number of electron      63.0000284 magnetization 
 augmentation part        7.2949649 magnetization 

 Broyden mixing:
  rms(total) = 0.31254E+01    rms(broyden)= 0.31254E+01
  rms(prec ) = 0.49511E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3857
  1.1276  1.1276  0.9253  0.5322  0.5322  0.2325  0.2325  0.2066  0.2066  0.1882
  0.1882  0.1752  0.1752  0.1249  0.1249  0.0713

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3537.91346971
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.66469712
  PAW double counting   =      4549.67324144    -4586.92030222
  entropy T*S    EENTRO =        -0.12018410
  eigenvalues    EBANDS =      -894.33743216
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.22223043 eV

  energy without entropy =      -23.10204634  energy(sigma->0) =      -23.18216907


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   896
 total energy-change (2. order) : 0.1143175E+00  (-0.8342264E-01)
 number of electron      63.0000311 magnetization 
 augmentation part        7.4775311 magnetization 

 Broyden mixing:
  rms(total) = 0.34434E+01    rms(broyden)= 0.34431E+01
  rms(prec ) = 0.53786E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4292
  1.5234  0.9968  0.9968  0.8037  0.8037  0.2160  0.2160  0.2276  0.2276  0.2163
  0.2163  0.1785  0.1785  0.1736  0.1250  0.1250  0.0719

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3535.30359556
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.53748477
  PAW double counting   =      4551.03518707    -4588.22446078
  entropy T*S    EENTRO =        -0.04056153
  eigenvalues    EBANDS =      -896.84318609
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.10791293 eV

  energy without entropy =      -23.06735140  energy(sigma->0) =      -23.09439242


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   736
 total energy-change (2. order) :-0.1856335E+00  (-0.2191997E+00)
 number of electron      63.0000225 magnetization 
 augmentation part        7.4199351 magnetization 

 Broyden mixing:
  rms(total) = 0.39648E+01    rms(broyden)= 0.39617E+01
  rms(prec ) = 0.62261E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4409
  1.7483  1.0684  1.0684  0.7693  0.7693  0.3384  0.2425  0.2425  0.2029  0.2029
  0.2309  0.1796  0.1796  0.1862  0.1862  0.1249  0.1249  0.0718

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3529.80931629
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.25082234
  PAW double counting   =      4551.22288632    -4588.29868847
  entropy T*S    EENTRO =        -0.22752030
  eigenvalues    EBANDS =      -902.16294924
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.29354644 eV

  energy without entropy =      -23.06602614  energy(sigma->0) =      -23.21770634


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) : 0.9596154E+00  (-0.2526297E+00)
 number of electron      63.0000299 magnetization 
 augmentation part        8.0811388 magnetization 

 Broyden mixing:
  rms(total) = 0.24954E+01    rms(broyden)= 0.24942E+01
  rms(prec ) = 0.38076E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4464
  1.9844  1.1136  1.1136  0.6029  0.5792  0.5792  0.3795  0.2051  0.2051  0.2358
  0.2358  0.1815  0.1815  0.1940  0.1940  0.1249  0.1249  0.1743  0.0718

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      -955.58875025
  -Hartree energ DENC   =     -3526.18573939
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.14905485
  PAW double counting   =      4553.78084195    -4590.77550320
  entropy T*S    EENTRO =        -0.32353295
  eigenvalues    EBANDS =      -904.71027152
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.33393107 eV

  energy without entropy =      -22.01039812  energy(sigma->0) =      -22.22608675


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------