vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.01  23:31:45
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.738  0.639  0.310-
   2  0.055  0.618  0.806-
   3  0.296  0.582  0.746-
   4  0.333  0.820  0.719-  11 0.91
   5  0.604  0.780  0.645-
   6  0.183  0.201  0.872-
   7  0.500  0.793  0.324-
   8  0.842  0.497  0.939-
   9  0.850  0.198  0.830-
  10  0.889  0.020  0.658-
  11  0.396  0.776  0.649-   4 0.91
  12  0.429  0.962  0.594-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.737857960  0.638959710  0.309746780
     0.054994060  0.617675760  0.805843520
     0.295993760  0.581863020  0.746014100
     0.333300740  0.820469760  0.718736840
     0.604295920  0.779970390  0.644707150
     0.182622870  0.200669560  0.872321140
     0.500007610  0.792828390  0.323617550
     0.842280330  0.496680170  0.938934260
     0.849918210  0.198397640  0.830421870
     0.889039380  0.019856060  0.658140350
     0.396009320  0.776031730  0.648858530
     0.428539830  0.962424110  0.594432080

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     40
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.63E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands            8
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.73785796  0.63895971  0.30974678
   0.05499406  0.61767576  0.80584352
   0.29599376  0.58186302  0.74601410
   0.33330074  0.82046976  0.71873684
   0.60429592  0.77997039  0.64470715
   0.18262287  0.20066956  0.87232114
   0.50000761  0.79282839  0.32361755
   0.84228033  0.49668017  0.93893426
   0.84991821  0.19839764  0.83042187
   0.88903938  0.01985606  0.65814035
   0.39600932  0.77603173  0.64885853
   0.42853983  0.96242411  0.59443208
 
 position of ions in cartesian coordinates  (Angst):
   7.37857960  5.11167768  2.47797424
   0.54994060  4.94140608  6.44674816
   2.95993760  4.65490416  5.96811280
   3.33300740  6.56375808  5.74989472
   6.04295920  6.23976312  5.15765720
   1.82622870  1.60535648  6.97856912
   5.00007610  6.34262712  2.58894040
   8.42280330  3.97344136  7.51147408
   8.49918210  1.58718112  6.64337496
   8.89039380  0.15884848  5.26512280
   3.96009320  6.20825384  5.19086824
   4.28539830  7.69939288  4.75545664
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    65901. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1266. kBytes
   fftplans  :       5842. kBytes
   grid      :      13664. kBytes
   one-center:         36. kBytes
   wavefun   :      15093. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1341
 Maximum index for augmentation-charges          396 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.5572982E+03  (-0.2138781E+04)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3250.51736919
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.53056688
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =         0.00308719
  eigenvalues    EBANDS =      -324.04245365
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       557.29821046 eV

  energy without entropy =      557.29512326  energy(sigma->0) =      557.29718139


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   912
 total energy-change (2. order) :-0.4981393E+03  (-0.4767351E+03)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3250.51736919
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.53056688
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.00652065
  eigenvalues    EBANDS =      -822.17219033
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        59.15886593 eV

  energy without entropy =       59.16538658  energy(sigma->0) =       59.16103948


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) :-0.9878392E+02  (-0.9236308E+02)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3250.51736919
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.53056688
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.03087582
  eigenvalues    EBANDS =      -920.93175946
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -39.62505836 eV

  energy without entropy =      -39.59418255  energy(sigma->0) =      -39.61476642


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   776
 total energy-change (2. order) :-0.3129005E+01  (-0.3055155E+01)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3250.51736919
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.53056688
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.03246609
  eigenvalues    EBANDS =      -924.05917432
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -42.75406350 eV

  energy without entropy =      -42.72159740  energy(sigma->0) =      -42.74324146


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   928
 total energy-change (2. order) :-0.1204455E+00  (-0.1201781E+00)
 number of electron      62.9999928 magnetization 
 augmentation part        9.8633551 magnetization 

 Broyden mixing:
  rms(total) = 0.21457E+01    rms(broyden)= 0.21446E+01
  rms(prec ) = 0.35122E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3250.51736919
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.53056688
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.03289578
  eigenvalues    EBANDS =      -924.17919013
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -42.87450900 eV

  energy without entropy =      -42.84161321  energy(sigma->0) =      -42.86354374


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   688
 total energy-change (2. order) :-0.1619172E+02  (-0.1156737E+02)
 number of electron      62.9999874 magnetization 
 augmentation part        5.4065955 magnetization 

 Broyden mixing:
  rms(total) = 0.67368E+01    rms(broyden)= 0.67334E+01
  rms(prec ) = 0.10813E+02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2219
  0.2219

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3418.01556133
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       299.15724450
  PAW double counting   =      4481.28655465    -4522.89823856
  entropy T*S    EENTRO =        -0.10323345
  eigenvalues    EBANDS =      -776.25440110
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.06622719 eV

  energy without entropy =      -58.96299375  energy(sigma->0) =      -59.03181605


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) : 0.2637416E+02  (-0.8647638E+01)
 number of electron      62.9999944 magnetization 
 augmentation part        8.0443949 magnetization 

 Broyden mixing:
  rms(total) = 0.32088E+01    rms(broyden)= 0.32024E+01
  rms(prec ) = 0.48220E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2191
  0.2644  0.1737

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3329.69467962
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       295.36340583
  PAW double counting   =      4353.44278739    -4392.48730302
  entropy T*S    EENTRO =        -0.01044917
  eigenvalues    EBANDS =      -837.06723455
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -32.69206505 eV

  energy without entropy =      -32.68161587  energy(sigma->0) =      -32.68858199


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   672
 total energy-change (2. order) : 0.2310880E+01  (-0.3034032E+01)
 number of electron      62.9999932 magnetization 
 augmentation part        9.2042055 magnetization 

 Broyden mixing:
  rms(total) = 0.16457E+01    rms(broyden)= 0.16421E+01
  rms(prec ) = 0.28243E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2925
  0.5190  0.1792  0.1792

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3312.18665217
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.32454212
  PAW double counting   =      4332.60539848    -4370.99656615
  entropy T*S    EENTRO =        -0.05797760
  eigenvalues    EBANDS =      -851.83133736
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -30.38118460 eV

  energy without entropy =      -30.32320700  energy(sigma->0) =      -30.36185873


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   688
 total energy-change (2. order) : 0.2958502E+01  (-0.1024067E+00)
 number of electron      62.9999936 magnetization 
 augmentation part        9.2297731 magnetization 

 Broyden mixing:
  rms(total) = 0.14475E+01    rms(broyden)= 0.14471E+01
  rms(prec ) = 0.24976E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3287
  0.6167  0.2352  0.2352  0.2276

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3316.38126504
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.22011835
  PAW double counting   =      4358.05575305    -4396.21231788
  entropy T*S    EENTRO =        -0.04859640
  eigenvalues    EBANDS =      -844.81778249
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -27.42268232 eV

  energy without entropy =      -27.37408592  energy(sigma->0) =      -27.40648352


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   760
 total energy-change (2. order) : 0.2183044E+01  (-0.9212684E-01)
 number of electron      62.9999935 magnetization 
 augmentation part        8.9835593 magnetization 

 Broyden mixing:
  rms(total) = 0.11873E+01    rms(broyden)= 0.11868E+01
  rms(prec ) = 0.20231E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2754
  0.5657  0.2629  0.2629  0.1792  0.1062

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3323.78359913
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.39168292
  PAW double counting   =      4387.74204936    -4425.82116151
  entropy T*S    EENTRO =         0.01465348
  eigenvalues    EBANDS =      -835.54467167
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -25.23963847 eV

  energy without entropy =      -25.25429195  energy(sigma->0) =      -25.24452296


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   800
 total energy-change (2. order) : 0.1984529E+00  (-0.1034221E-01)
 number of electron      62.9999935 magnetization 
 augmentation part        9.0216635 magnetization 

 Broyden mixing:
  rms(total) = 0.11875E+01    rms(broyden)= 0.11875E+01
  rms(prec ) = 0.20546E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4324
  0.6384  0.6384  0.6784  0.2055  0.2055  0.2280

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3323.57356761
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.37466120
  PAW double counting   =      4387.62648282    -4425.67018198
  entropy T*S    EENTRO =         0.00833264
  eigenvalues    EBANDS =      -835.56832073
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -25.04118556 eV

  energy without entropy =      -25.04951821  energy(sigma->0) =      -25.04396311


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   896
 total energy-change (2. order) : 0.1257572E+01  (-0.1834543E+00)
 number of electron      62.9999949 magnetization 
 augmentation part        8.4980791 magnetization 

 Broyden mixing:
  rms(total) = 0.10111E+01    rms(broyden)= 0.10066E+01
  rms(prec ) = 0.13943E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3765
  0.6916  0.6216  0.6216  0.2458  0.2043  0.2043  0.0464

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3328.47706663
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.38494885
  PAW double counting   =      4405.17239184    -4443.05245061
  entropy T*S    EENTRO =         0.01748597
  eigenvalues    EBANDS =      -829.59033147
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.78361396 eV

  energy without entropy =      -23.80109993  energy(sigma->0) =      -23.78944262


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   736
 total energy-change (2. order) : 0.1432916E+00  (-0.5776372E-02)
 number of electron      62.9999948 magnetization 
 augmentation part        8.5528139 magnetization 

 Broyden mixing:
  rms(total) = 0.93229E+00    rms(broyden)= 0.93220E+00
  rms(prec ) = 0.13113E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3728
  0.7365  0.6820  0.6820  0.2588  0.2041  0.2041  0.1074  0.1074

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3327.85246992
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.47455048
  PAW double counting   =      4403.58002029    -4441.46587722
  entropy T*S    EENTRO =         0.00804000
  eigenvalues    EBANDS =      -830.14599410
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.64032239 eV

  energy without entropy =      -23.64836239  energy(sigma->0) =      -23.64300239


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   672
 total energy-change (2. order) : 0.4940785E-01  (-0.1477767E-01)
 number of electron      62.9999941 magnetization 
 augmentation part        8.5475421 magnetization 

 Broyden mixing:
  rms(total) = 0.10375E+01    rms(broyden)= 0.10373E+01
  rms(prec ) = 0.15641E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4406
  1.0413  1.0413  0.6575  0.2453  0.2214  0.2214  0.2311  0.2311  0.0753

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3327.50294040
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.44192496
  PAW double counting   =      4403.35105926    -4441.19918180
  entropy T*S    EENTRO =        -0.00033644
  eigenvalues    EBANDS =      -830.44284822
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.59091454 eV

  energy without entropy =      -23.59057811  energy(sigma->0) =      -23.59080240


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   720
 total energy-change (2. order) : 0.8662191E+00  (-0.7620704E-01)
 number of electron      62.9999954 magnetization 
 augmentation part        8.2569712 magnetization 

 Broyden mixing:
  rms(total) = 0.98000E+00    rms(broyden)= 0.97699E+00
  rms(prec ) = 0.13111E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3996
  1.0365  1.0365  0.6605  0.2398  0.2200  0.2200  0.2392  0.2392  0.0741  0.0302

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3327.52344953
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.22339750
  PAW double counting   =      4404.50268505    -4442.09261105
  entropy T*S    EENTRO =        -0.09065467
  eigenvalues    EBANDS =      -829.50547078
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.72469540 eV

  energy without entropy =      -22.63404073  energy(sigma->0) =      -22.69447717


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   728
 total energy-change (2. order) : 0.1078436E+00  (-0.2767898E-01)
 number of electron      62.9999960 magnetization 
 augmentation part        8.4312240 magnetization 

 Broyden mixing:
  rms(total) = 0.90859E+00    rms(broyden)= 0.90794E+00
  rms(prec ) = 0.11995E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4334
  1.1843  1.1843  0.6761  0.4196  0.4196  0.1975  0.1975  0.1817  0.1133  0.1133
  0.0796

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3326.84522351
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.24594566
  PAW double counting   =      4403.69477852    -4441.26132610
  entropy T*S    EENTRO =         0.02498154
  eigenvalues    EBANDS =      -830.23741601
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.61685182 eV

  energy without entropy =      -22.64183335  energy(sigma->0) =      -22.62517900


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   664
 total energy-change (2. order) :-0.1027708E+01  (-0.5611134E+00)
 number of electron      62.9999902 magnetization 
 augmentation part        7.5847665 magnetization 

 Broyden mixing:
  rms(total) = 0.37114E+01    rms(broyden)= 0.37090E+01
  rms(prec ) = 0.58484E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4042
  1.2024  1.2024  0.6488  0.4296  0.4296  0.1996  0.1996  0.1891  0.1282  0.1282
  0.0785  0.0147

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3326.84722873
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.18370073
  PAW double counting   =      4406.25774531    -4443.72194955
  entropy T*S    EENTRO =        -0.04612142
  eigenvalues    EBANDS =      -831.23211395
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.64455953 eV

  energy without entropy =      -23.59843812  energy(sigma->0) =      -23.62918573


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   784
 total energy-change (2. order) : 0.6530650E+00  (-0.3411712E-01)
 number of electron      62.9999918 magnetization 
 augmentation part        7.9592052 magnetization 

 Broyden mixing:
  rms(total) = 0.27759E+01    rms(broyden)= 0.27752E+01
  rms(prec ) = 0.43019E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4737
  1.5331  1.5331  0.6003  0.6003  0.5708  0.1996  0.1996  0.2199  0.2199  0.1847
  0.1847  0.0770  0.0351

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3324.53638946
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.12116100
  PAW double counting   =      4399.69639810    -4437.13096334
  entropy T*S    EENTRO =        -0.19314583
  eigenvalues    EBANDS =      -832.70996313
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -22.99149458 eV

  energy without entropy =      -22.79834875  energy(sigma->0) =      -22.92711264


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.2957006E+01  (-0.4238351E+00)
 number of electron      62.9999875 magnetization 
 augmentation part        7.5267703 magnetization 

 Broyden mixing:
  rms(total) = 0.41441E+01    rms(broyden)= 0.41429E+01
  rms(prec ) = 0.66049E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4874
  1.4548  1.4548  1.0168  0.6513  0.6513  0.2866  0.2866  0.1801  0.1801  0.1973
  0.1973  0.1551  0.0771  0.0344

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3322.57992852
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.88434314
  PAW double counting   =      4397.62265388    -4434.80265051
  entropy T*S    EENTRO =        -0.07542670
  eigenvalues    EBANDS =      -837.75889999
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -25.94850062 eV

  energy without entropy =      -25.87307392  energy(sigma->0) =      -25.92335838


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   904
 total energy-change (2. order) :-0.1912902E+01  (-0.5104805E-01)
 number of electron      62.9999884 magnetization 
 augmentation part        7.2685648 magnetization 

 Broyden mixing:
  rms(total) = 0.42591E+01    rms(broyden)= 0.42587E+01
  rms(prec ) = 0.68210E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4973
  1.5634  1.5634  0.8883  0.7463  0.7463  0.3324  0.3324  0.2267  0.2141  0.2141
  0.1765  0.1765  0.1676  0.0771  0.0345

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3326.10818091
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.92474915
  PAW double counting   =      4412.14463233    -4449.21623903
  entropy T*S    EENTRO =         0.10111269
  eigenvalues    EBANDS =      -836.46888469
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -27.86140237 eV

  energy without entropy =      -27.96251506  energy(sigma->0) =      -27.89510660


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :  1048
 total energy-change (2. order) : 0.7081672E+00  (-0.1417371E-01)
 number of electron      62.9999888 magnetization 
 augmentation part        7.2982254 magnetization 

 Broyden mixing:
  rms(total) = 0.42378E+01    rms(broyden)= 0.42378E+01
  rms(prec ) = 0.67927E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4898
  1.6312  1.6312  0.8416  0.8416  0.6660  0.4010  0.4010  0.2188  0.2188  0.1817
  0.1817  0.2067  0.1775  0.0771  0.1262  0.0345

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3325.81888362
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.95675458
  PAW double counting   =      4412.95541780    -4449.98529051
  entropy T*S    EENTRO =         0.12191371
  eigenvalues    EBANDS =      -836.14455524
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -27.15323519 eV

  energy without entropy =      -27.27514891  energy(sigma->0) =      -27.19387310


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   936
 total energy-change (2. order) : 0.1112448E+01  (-0.1286947E-01)
 number of electron      62.9999890 magnetization 
 augmentation part        7.3303848 magnetization 

 Broyden mixing:
  rms(total) = 0.41641E+01    rms(broyden)= 0.41641E+01
  rms(prec ) = 0.66816E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5412
  1.8219  1.8219  1.1089  1.1089  0.6062  0.4933  0.4933  0.2855  0.2855  0.2077
  0.2077  0.1795  0.1795  0.1640  0.0771  0.1242  0.0345

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1228.55856136
  -Hartree energ DENC   =     -3324.96985144
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.91788311
  PAW double counting   =      4411.40400139    -4448.39296737
  entropy T*S    EENTRO =         0.12742823
  eigenvalues    EBANDS =      -835.88868941
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -26.04078739 eV

  energy without entropy =      -26.16821562  energy(sigma->0) =      -26.08326347


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------