vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.12.01  23:31:43
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.331  0.480  0.025-   7 1.55
   2  0.520  0.348  0.198-
   3  0.257  0.900  0.734-
   4  0.758  0.192  0.842-   5 1.43
   5  0.820  0.076  0.731-   4 1.43
   6  0.371  0.693  0.416-
   7  0.184  0.496  0.081-   1 1.55
   8  0.974  0.107  0.478-
   9  0.145  0.098  0.129-
  10  0.218  0.805  0.257-
  11  0.447  0.746  0.573-
  12  0.484  0.942  0.519-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.331172330  0.480046630  0.024810780
     0.519525770  0.348462350  0.197505640
     0.257104970  0.900443680  0.733525260
     0.758479820  0.191917990  0.842445270
     0.820147300  0.075753660  0.731307280
     0.370745200  0.693451160  0.415905680
     0.183802580  0.495589010  0.081366040
     0.974240770  0.107257020  0.478488160
     0.145072620  0.097544960  0.128852330
     0.218015630  0.805249060  0.257351000
     0.446604140  0.745634050  0.573060280
     0.484109970  0.942456580  0.519225300

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     40
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.63E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands            8
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.33117233  0.48004663  0.02481078
   0.51952577  0.34846235  0.19750564
   0.25710497  0.90044368  0.73352526
   0.75847982  0.19191799  0.84244527
   0.82014730  0.07575366  0.73130728
   0.37074520  0.69345116  0.41590568
   0.18380258  0.49558901  0.08136604
   0.97424077  0.10725702  0.47848816
   0.14507262  0.09754496  0.12885233
   0.21801563  0.80524906  0.25735100
   0.44660414  0.74563405  0.57306028
   0.48410997  0.94245658  0.51922530
 
 position of ions in cartesian coordinates  (Angst):
   3.31172330  3.84037304  0.19848624
   5.19525770  2.78769880  1.58004512
   2.57104970  7.20354944  5.86820208
   7.58479820  1.53534392  6.73956216
   8.20147300  0.60602928  5.85045824
   3.70745200  5.54760928  3.32724544
   1.83802580  3.96471208  0.65092832
   9.74240770  0.85805616  3.82790528
   1.45072620  0.78035968  1.03081864
   2.18015630  6.44199248  2.05880800
   4.46604140  5.96507240  4.58448224
   4.84109970  7.53965264  4.15380240
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    65903. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1268. kBytes
   fftplans  :       5842. kBytes
   grid      :      13664. kBytes
   one-center:         36. kBytes
   wavefun   :      15093. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1344
 Maximum index for augmentation-charges          393 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   720
 total energy-change (2. order) : 0.5368379E+03  (-0.2152847E+04)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3370.83058879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.86294017
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.01371031
  eigenvalues    EBANDS =      -338.26292141
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       536.83792311 eV

  energy without entropy =      536.85163342  energy(sigma->0) =      536.84249321


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   912
 total energy-change (2. order) :-0.4793511E+03  (-0.4571324E+03)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3370.83058879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.86294017
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =         0.00308121
  eigenvalues    EBANDS =      -817.63085440
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        57.48678163 eV

  energy without entropy =       57.48370042  energy(sigma->0) =       57.48575456


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   776
 total energy-change (2. order) :-0.9346712E+02  (-0.8898269E+02)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3370.83058879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.86294017
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05021018
  eigenvalues    EBANDS =      -911.04468698
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -35.98034234 eV

  energy without entropy =      -35.93013216  energy(sigma->0) =      -35.96360561


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) :-0.3108041E+01  (-0.3042155E+01)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3370.83058879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.86294017
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05270389
  eigenvalues    EBANDS =      -914.15023390
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -39.08838296 eV

  energy without entropy =      -39.03567908  energy(sigma->0) =      -39.07081500


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   992
 total energy-change (2. order) :-0.1207043E+00  (-0.1198770E+00)
 number of electron      62.9999667 magnetization 
 augmentation part        9.3368073 magnetization 

 Broyden mixing:
  rms(total) = 0.19409E+01    rms(broyden)= 0.19366E+01
  rms(prec ) = 0.30699E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3370.83058879
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       291.86294017
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05280068
  eigenvalues    EBANDS =      -914.27084144
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -39.20908730 eV

  energy without entropy =      -39.15628662  energy(sigma->0) =      -39.19148707


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   816
 total energy-change (2. order) :-0.1176856E+02  (-0.7742840E+01)
 number of electron      62.9999858 magnetization 
 augmentation part        6.0246426 magnetization 

 Broyden mixing:
  rms(total) = 0.56786E+01    rms(broyden)= 0.56757E+01
  rms(prec ) = 0.89427E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.2333
  0.2333

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3484.86045994
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       296.86406712
  PAW double counting   =      4387.13507246    -4427.12132778
  entropy T*S    EENTRO =        -0.10076707
  eigenvalues    EBANDS =      -814.41346518
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -50.97764807 eV

  energy without entropy =      -50.87688101  energy(sigma->0) =      -50.94405905


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   656
 total energy-change (2. order) : 0.2045205E+02  (-0.1027147E+02)
 number of electron      62.9999684 magnetization 
 augmentation part        8.9358899 magnetization 

 Broyden mixing:
  rms(total) = 0.14257E+01    rms(broyden)= 0.14183E+01
  rms(prec ) = 0.23414E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5024
  0.8056  0.1992

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3410.16108752
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.90765835
  PAW double counting   =      4290.33068450    -4328.20275656
  entropy T*S    EENTRO =        -0.00734737
  eigenvalues    EBANDS =      -867.91198621
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -30.52560250 eV

  energy without entropy =      -30.51825513  energy(sigma->0) =      -30.52315338


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.2819534E+01  (-0.2196858E+00)
 number of electron      62.9999683 magnetization 
 augmentation part        8.9682161 magnetization 

 Broyden mixing:
  rms(total) = 0.12875E+01    rms(broyden)= 0.12871E+01
  rms(prec ) = 0.21995E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8265
  1.6738  0.2085  0.5974

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3417.19480567
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.84124159
  PAW double counting   =      4338.97111530    -4376.55507797
  entropy T*S    EENTRO =        -0.00889236
  eigenvalues    EBANDS =      -858.27888138
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -27.70606817 eV

  energy without entropy =      -27.69717581  energy(sigma->0) =      -27.70310405


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   664
 total energy-change (2. order) : 0.3968047E+01  (-0.2962655E+00)
 number of electron      62.9999729 magnetization 
 augmentation part        8.1523293 magnetization 

 Broyden mixing:
  rms(total) = 0.18770E+01    rms(broyden)= 0.18751E+01
  rms(prec ) = 0.29001E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6261
  1.6904  0.5923  0.2086  0.0129

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3434.52114787
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.23509731
  PAW double counting   =      4414.49257242    -4451.80617629
  entropy T*S    EENTRO =        -0.15525565
  eigenvalues    EBANDS =      -837.50234387
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.73802165 eV

  energy without entropy =      -23.58276600  energy(sigma->0) =      -23.68626977


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   712
 total energy-change (2. order) : 0.3646217E+00  (-0.1628423E+00)
 number of electron      62.9999694 magnetization 
 augmentation part        8.6020326 magnetization 

 Broyden mixing:
  rms(total) = 0.75452E+00    rms(broyden)= 0.75284E+00
  rms(prec ) = 0.12583E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5579
  1.7174  0.6721  0.2077  0.1613  0.0309

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3434.09379503
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.26646149
  PAW double counting   =      4413.08795062    -4450.39247377
  entropy T*S    EENTRO =         0.01726332
  eigenvalues    EBANDS =      -837.77803886
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.37339992 eV

  energy without entropy =      -23.39066324  energy(sigma->0) =      -23.37915436


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :  1016
 total energy-change (2. order) : 0.2607130E+00  (-0.1052058E+00)
 number of electron      62.9999721 magnetization 
 augmentation part        8.1270810 magnetization 

 Broyden mixing:
  rms(total) = 0.12494E+01    rms(broyden)= 0.12487E+01
  rms(prec ) = 0.18589E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4773
  1.7317  0.6776  0.2077  0.1808  0.0258  0.0402

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3436.14260215
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.26979887
  PAW double counting   =      4419.08671592    -4456.33388424
  entropy T*S    EENTRO =        -0.20588524
  eigenvalues    EBANDS =      -835.30606235
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.11268689 eV

  energy without entropy =      -22.90680165  energy(sigma->0) =      -23.04405848


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) : 0.3769952E-01  (-0.1659486E-02)
 number of electron      62.9999721 magnetization 
 augmentation part        8.1346416 magnetization 

 Broyden mixing:
  rms(total) = 0.12293E+01    rms(broyden)= 0.12293E+01
  rms(prec ) = 0.18288E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4474
  1.8624  0.6135  0.2085  0.1602  0.1602  0.1034  0.0234

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3436.11756639
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.29489804
  PAW double counting   =      4419.01376108    -4456.26050896
  entropy T*S    EENTRO =        -0.20414293
  eigenvalues    EBANDS =      -835.32066052
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.07498737 eV

  energy without entropy =      -22.87084445  energy(sigma->0) =      -23.00693973


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.5495765E+00  (-0.7365510E-01)
 number of electron      62.9999754 magnetization 
 augmentation part        7.5468572 magnetization 

 Broyden mixing:
  rms(total) = 0.29468E+01    rms(broyden)= 0.29461E+01
  rms(prec ) = 0.47032E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4076
  1.8594  0.6234  0.1734  0.1734  0.2077  0.1722  0.0286  0.0221

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3437.84317126
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.30055775
  PAW double counting   =      4424.66531239    -4461.83810495
  entropy T*S    EENTRO =        -0.15327760
  eigenvalues    EBANDS =      -834.27511254
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.62456390 eV

  energy without entropy =      -23.47128630  energy(sigma->0) =      -23.57347137


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) :-0.1343228E+00  (-0.6182885E-02)
 number of electron      62.9999761 magnetization 
 augmentation part        7.4930718 magnetization 

 Broyden mixing:
  rms(total) = 0.32401E+01    rms(broyden)= 0.32401E+01
  rms(prec ) = 0.51951E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4091
  1.8575  0.6361  0.3117  0.3117  0.2081  0.2081  0.0855  0.0229  0.0404

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3437.87836768
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.34619398
  PAW double counting   =      4425.18496673    -4462.35872791
  entropy T*S    EENTRO =        -0.11626333
  eigenvalues    EBANDS =      -834.45592085
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.75888674 eV

  energy without entropy =      -23.64262341  energy(sigma->0) =      -23.72013230


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.1454927E+00  (-0.7472380E-02)
 number of electron      62.9999750 magnetization 
 augmentation part        7.6460123 magnetization 

 Broyden mixing:
  rms(total) = 0.29247E+01    rms(broyden)= 0.29246E+01
  rms(prec ) = 0.46971E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3884
  1.8633  0.6304  0.3691  0.3691  0.2085  0.2085  0.0875  0.0875  0.0373  0.0229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3437.24779488
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.33841399
  PAW double counting   =      4423.06822327    -4460.23259329
  entropy T*S    EENTRO =        -0.14300672
  eigenvalues    EBANDS =      -834.91586876
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.61339409 eV

  energy without entropy =      -23.47038736  energy(sigma->0) =      -23.56572518


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) :-0.6265228E-01  (-0.4800764E-03)
 number of electron      62.9999751 magnetization 
 augmentation part        7.6282493 magnetization 

 Broyden mixing:
  rms(total) = 0.29899E+01    rms(broyden)= 0.29899E+01
  rms(prec ) = 0.48093E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4000
  1.8904  0.6339  0.4050  0.3529  0.3529  0.2260  0.1974  0.1810  0.0995  0.0381
  0.0229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3437.36493172
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.33511318
  PAW double counting   =      4423.80203979    -4460.97194080
  entropy T*S    EENTRO =        -0.12991689
  eigenvalues    EBANDS =      -834.86564224
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.67604637 eV

  energy without entropy =      -23.54612947  energy(sigma->0) =      -23.63274074


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   664
 total energy-change (2. order) :-0.2606869E+00  (-0.4263107E-02)
 number of electron      62.9999760 magnetization 
 augmentation part        7.5136994 magnetization 

 Broyden mixing:
  rms(total) = 0.33065E+01    rms(broyden)= 0.33064E+01
  rms(prec ) = 0.53191E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3917
  1.8913  0.6308  0.3649  0.3649  0.3269  0.3269  0.2520  0.2011  0.1829  0.0976
  0.0229  0.0382

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3438.12927338
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.37444049
  PAW double counting   =      4427.07752882    -4464.27003419
  entropy T*S    EENTRO =        -0.09171144
  eigenvalues    EBANDS =      -834.41691588
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.93673328 eV

  energy without entropy =      -23.84502183  energy(sigma->0) =      -23.90616280


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   656
 total energy-change (2. order) : 0.2649931E+00  (-0.4206192E-02)
 number of electron      62.9999760 magnetization 
 augmentation part        7.5073484 magnetization 

 Broyden mixing:
  rms(total) = 0.32159E+01    rms(broyden)= 0.32158E+01
  rms(prec ) = 0.51525E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5550
  1.9096  1.1836  1.1836  0.5378  0.5378  0.6308  0.3451  0.3451  0.2049  0.1794
  0.0968  0.0382  0.0229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3437.84999427
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       294.33410681
  PAW double counting   =      4424.46282595    -4461.60778201
  entropy T*S    EENTRO =        -0.12798168
  eigenvalues    EBANDS =      -834.40214731
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.67174020 eV

  energy without entropy =      -23.54375852  energy(sigma->0) =      -23.62907964


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   672
 total energy-change (2. order) :-0.5338515E-01  (-0.1009590E+01)
 number of electron      62.9999706 magnetization 
 augmentation part        8.4896798 magnetization 

 Broyden mixing:
  rms(total) = 0.13699E+01    rms(broyden)= 0.13658E+01
  rms(prec ) = 0.23813E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5451
  2.1241  1.0866  1.0866  0.5327  0.5327  0.6284  0.4028  0.4028  0.2917  0.2035
  0.1814  0.0968  0.0382  0.0229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3431.61634963
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.76413917
  PAW double counting   =      4388.77330356    -4425.30400002
  entropy T*S    EENTRO =        -0.07309053
  eigenvalues    EBANDS =      -840.78836020
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.72512536 eV

  energy without entropy =      -23.65203482  energy(sigma->0) =      -23.70076185


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   776
 total energy-change (2. order) : 0.2741098E+00  (-0.1147028E+00)
 number of electron      62.9999765 magnetization 
 augmentation part        7.6169405 magnetization 

 Broyden mixing:
  rms(total) = 0.23402E+01    rms(broyden)= 0.23386E+01
  rms(prec ) = 0.37779E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5095
  2.0890  1.0537  1.0537  0.5395  0.5395  0.6236  0.4112  0.4112  0.3040  0.2035
  0.1812  0.0968  0.0229  0.0382  0.0743

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3435.22793398
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.78701454
  PAW double counting   =      4400.08663797    -4436.56331548
  entropy T*S    EENTRO =        -0.26330471
  eigenvalues    EBANDS =      -836.78934619
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.45101554 eV

  energy without entropy =      -23.18771083  energy(sigma->0) =      -23.36324731


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   864
 total energy-change (2. order) : 0.1907386E+00  (-0.1599834E+00)
 number of electron      62.9999731 magnetization 
 augmentation part        8.1649260 magnetization 

 Broyden mixing:
  rms(total) = 0.16747E+01    rms(broyden)= 0.16739E+01
  rms(prec ) = 0.29081E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4978
  2.1240  1.0907  1.0907  0.5468  0.5468  0.6599  0.3908  0.3908  0.3301  0.2038
  0.1805  0.1612  0.0229  0.0382  0.0969  0.0900

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3434.00352084
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.77721617
  PAW double counting   =      4391.50631301    -4427.86945562
  entropy T*S    EENTRO =        -0.03822469
  eigenvalues    EBANDS =      -838.15183729
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.26027695 eV

  energy without entropy =      -23.22205226  energy(sigma->0) =      -23.24753539


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   640
 total energy-change (2. order) :-0.1664531E+00  (-0.4238827E-02)
 number of electron      62.9999732 magnetization 
 augmentation part        8.1621240 magnetization 

 Broyden mixing:
  rms(total) = 0.17578E+01    rms(broyden)= 0.17578E+01
  rms(prec ) = 0.30618E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4818
  2.1043  1.0796  1.0796  0.6423  0.5469  0.5469  0.3897  0.3897  0.3341  0.2241
  0.2241  0.2039  0.1802  0.0969  0.0229  0.0382  0.0877

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3434.30161021
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.80504934
  PAW double counting   =      4391.07231734    -4427.42945939
  entropy T*S    EENTRO =        -0.01677855
  eigenvalues    EBANDS =      -838.07548084
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.42673000 eV

  energy without entropy =      -23.40995146  energy(sigma->0) =      -23.42113716


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) : 0.1338039E+00  (-0.2275880E-01)
 number of electron      62.9999722 magnetization 
 augmentation part        8.2672416 magnetization 

 Broyden mixing:
  rms(total) = 0.16062E+01    rms(broyden)= 0.16059E+01
  rms(prec ) = 0.28179E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4789
  2.1115  1.0953  1.0953  0.5389  0.5389  0.6266  0.3704  0.3704  0.3817  0.3817
  0.3284  0.2036  0.1812  0.1545  0.0229  0.0382  0.0968  0.0844

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =     -1114.80073713
  -Hartree energ DENC   =     -3432.82872138
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       293.71707985
  PAW double counting   =      4384.71281937    -4421.00047897
  entropy T*S    EENTRO =        -0.01102198
  eigenvalues    EBANDS =      -839.40183528
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -23.29292609 eV

  energy without entropy =      -23.28190411  energy(sigma->0) =      -23.28925209


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------