vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.11.30  15:23:03
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.387  0.422  0.544-   6 1.35  10 1.36   5 1.36   2 1.54
   2  0.436  0.568  0.435-  11 1.12   4 1.38   1 1.54   3 1.54
   3  0.572  0.545  0.347-   9 1.35   8 1.36   7 1.36   2 1.54
   4  0.340  0.604  0.315-   2 1.38
   5  0.266  0.462  0.610-   1 1.36
   6  0.373  0.279  0.455-   1 1.35
   7  0.603  0.687  0.262-   3 1.36
   8  0.670  0.517  0.461-   3 1.36
   9  0.570  0.416  0.237-   3 1.35
  10  0.474  0.394  0.671-   1 1.36
  11  0.446  0.679  0.518-   2 1.12
  12  0.486  0.879  0.548-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.387094330  0.421862140  0.543684890
     0.435936220  0.568205480  0.434539130
     0.571963240  0.544838810  0.346960480
     0.339964770  0.603506570  0.315067370
     0.266468970  0.462092410  0.610205340
     0.373345570  0.278989500  0.454774330
     0.602732170  0.686835110  0.262203130
     0.669785170  0.517224660  0.461195900
     0.569962670  0.416470830  0.237067210
     0.473607740  0.394337360  0.671379890
     0.446333520  0.679189740  0.518405480
     0.485531250  0.879102940  0.547995760

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     40
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.63E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands            8
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.38709433  0.42186214  0.54368489
   0.43593622  0.56820548  0.43453913
   0.57196324  0.54483881  0.34696048
   0.33996477  0.60350657  0.31506737
   0.26646897  0.46209241  0.61020534
   0.37334557  0.27898950  0.45477433
   0.60273217  0.68683511  0.26220313
   0.66978517  0.51722466  0.46119590
   0.56996267  0.41647083  0.23706721
   0.47360774  0.39433736  0.67137989
   0.44633352  0.67918974  0.51840548
   0.48553125  0.87910294  0.54799576
 
 position of ions in cartesian coordinates  (Angst):
   3.87094330  3.37489712  4.34947912
   4.35936220  4.54564384  3.47631304
   5.71963240  4.35871048  2.77568384
   3.39964770  4.82805256  2.52053896
   2.66468970  3.69673928  4.88164272
   3.73345570  2.23191600  3.63819464
   6.02732170  5.49468088  2.09762504
   6.69785170  4.13779728  3.68956720
   5.69962670  3.33176664  1.89653768
   4.73607740  3.15469888  5.37103912
   4.46333520  5.43351792  4.14724384
   4.85531250  7.03282352  4.38396608
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    65906. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1271. kBytes
   fftplans  :       5842. kBytes
   grid      :      13664. kBytes
   one-center:         36. kBytes
   wavefun   :      15093. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1347
 Maximum index for augmentation-charges          398 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   784
 total energy-change (2. order) : 0.5963924E+03  (-0.2283046E+04)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6018.28627260
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.57626655
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.00557582
  eigenvalues    EBANDS =      -417.89225432
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       596.39244922 eV

  energy without entropy =      596.39802505  energy(sigma->0) =      596.39430783


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   952
 total energy-change (2. order) :-0.5614541E+03  (-0.5414796E+03)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6018.28627260
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.57626655
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =         0.01519944
  eigenvalues    EBANDS =      -979.36709507
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        34.93838374 eV

  energy without entropy =       34.92318430  energy(sigma->0) =       34.93331726


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) :-0.9558782E+02  (-0.9514482E+02)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6018.28627260
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.57626655
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05563034
  eigenvalues    EBANDS =     -1074.88408396
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.64943493 eV

  energy without entropy =      -60.59380460  energy(sigma->0) =      -60.63089149


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   752
 total energy-change (2. order) :-0.1692065E+01  (-0.1686113E+01)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6018.28627260
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.57626655
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05533507
  eigenvalues    EBANDS =     -1076.57644410
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -62.34149980 eV

  energy without entropy =      -62.28616473  energy(sigma->0) =      -62.32305478


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   856
 total energy-change (2. order) :-0.4285714E-01  (-0.4283967E-01)
 number of electron      63.0000128 magnetization 
 augmentation part        9.5849096 magnetization 

 Broyden mixing:
  rms(total) = 0.13278E+01    rms(broyden)= 0.13218E+01
  rms(prec ) = 0.15767E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6018.28627260
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.57626655
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05533116
  eigenvalues    EBANDS =     -1076.61930515
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -62.38435694 eV

  energy without entropy =      -62.32902579  energy(sigma->0) =      -62.36591322


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) : 0.2763357E+01  (-0.1005917E+01)
 number of electron      63.0000121 magnetization 
 augmentation part        9.1264374 magnetization 

 Broyden mixing:
  rms(total) = 0.67751E+00    rms(broyden)= 0.67647E+00
  rms(prec ) = 0.73885E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2619
  1.2619

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6068.40540900
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       308.32053160
  PAW double counting   =      4693.75854644    -4732.84769023
  entropy T*S    EENTRO =        -0.05486715
  eigenvalues    EBANDS =     -1025.82942607
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.62100013 eV

  energy without entropy =      -59.56613298  energy(sigma->0) =      -59.60271108


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   824
 total energy-change (2. order) : 0.1598082E+00  (-0.9413838E-01)
 number of electron      63.0000121 magnetization 
 augmentation part        9.1264571 magnetization 

 Broyden mixing:
  rms(total) = 0.31684E+00    rms(broyden)= 0.31679E+00
  rms(prec ) = 0.34672E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5759
  1.0767  2.0750

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6077.09784191
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       308.99745446
  PAW double counting   =      5156.07775901    -5194.28689950
  entropy T*S    EENTRO =        -0.05474108
  eigenvalues    EBANDS =     -1018.53423718
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46119193 eV

  energy without entropy =      -59.40645084  energy(sigma->0) =      -59.44294490


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.4480141E-03  (-0.1248806E-01)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1401134 magnetization 

 Broyden mixing:
  rms(total) = 0.61179E-01    rms(broyden)= 0.61142E-01
  rms(prec ) = 0.71800E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5190
  2.4284  1.0643  1.0643

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6081.52792662
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.43764123
  PAW double counting   =      5557.74706355    -5595.35502799
  entropy T*S    EENTRO =        -0.05469959
  eigenvalues    EBANDS =     -1015.14600481
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46163994 eV

  energy without entropy =      -59.40694035  energy(sigma->0) =      -59.44340674


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.2325783E-02  (-0.1972344E-02)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1266735 magnetization 

 Broyden mixing:
  rms(total) = 0.21107E-01    rms(broyden)= 0.21082E-01
  rms(prec ) = 0.25340E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5424
  2.4035  1.7725  0.9967  0.9967

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.84450627
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.64356927
  PAW double counting   =      5650.22049601    -5687.76743768
  entropy T*S    EENTRO =        -0.05469228
  eigenvalues    EBANDS =     -1013.09870905
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46396572 eV

  energy without entropy =      -59.40927344  energy(sigma->0) =      -59.44573496


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.2583715E-03  (-0.2619733E-03)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1289672 magnetization 

 Broyden mixing:
  rms(total) = 0.73063E-02    rms(broyden)= 0.73014E-02
  rms(prec ) = 0.10077E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5197
  2.4622  1.0336  1.0336  1.6588  1.4104

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.36993858
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.62308785
  PAW double counting   =      5655.53545593    -5693.05169133
  entropy T*S    EENTRO =        -0.05470506
  eigenvalues    EBANDS =     -1013.58374719
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46422409 eV

  energy without entropy =      -59.40951904  energy(sigma->0) =      -59.44598908


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.3613366E-03  (-0.2874969E-04)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1297415 magnetization 

 Broyden mixing:
  rms(total) = 0.25325E-02    rms(broyden)= 0.25313E-02
  rms(prec ) = 0.47547E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5465
  2.4783  2.2233  1.0305  1.0305  1.4001  1.1163

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.29098966
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61933927
  PAW double counting   =      5656.86135544    -5694.37807800
  entropy T*S    EENTRO =        -0.05470392
  eigenvalues    EBANDS =     -1013.65882284
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46458543 eV

  energy without entropy =      -59.40988151  energy(sigma->0) =      -59.44635079


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   760
 total energy-change (2. order) :-0.3375725E-03  (-0.7333007E-05)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1297225 magnetization 

 Broyden mixing:
  rms(total) = 0.11697E-02    rms(broyden)= 0.11687E-02
  rms(prec ) = 0.26187E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5466
  2.6220  2.2837  1.4578  1.4578  0.9530  1.0257  1.0257

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.26881722
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61971510
  PAW double counting   =      5656.14203035    -5693.66259749
  entropy T*S    EENTRO =        -0.05470484
  eigenvalues    EBANDS =     -1013.67786318
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46492300 eV

  energy without entropy =      -59.41021816  energy(sigma->0) =      -59.44668806


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   704
 total energy-change (2. order) :-0.2432388E-03  (-0.3142781E-05)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1294123 magnetization 

 Broyden mixing:
  rms(total) = 0.73138E-03    rms(broyden)= 0.73055E-03
  rms(prec ) = 0.15818E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5957
  2.8411  2.4167  1.9668  1.0030  1.0030  1.1417  1.1966  1.1966

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.27213228
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.62132637
  PAW double counting   =      5655.91887797    -5693.44070025
  entropy T*S    EENTRO =        -0.05470509
  eigenvalues    EBANDS =     -1013.67514724
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46516624 eV

  energy without entropy =      -59.41046115  energy(sigma->0) =      -59.44693121


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   536
 total energy-change (2. order) :-0.1615769E-03  (-0.1600901E-05)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1295263 magnetization 

 Broyden mixing:
  rms(total) = 0.39154E-03    rms(broyden)= 0.39132E-03
  rms(prec ) = 0.81822E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6449
  3.3674  2.4862  2.1411  1.3068  1.3068  1.0142  1.0142  1.0834  1.0834

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.23852302
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61970373
  PAW double counting   =      5655.40500315    -5692.92603120
  entropy T*S    EENTRO =        -0.05470476
  eigenvalues    EBANDS =     -1013.70809000
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46532782 eV

  energy without entropy =      -59.41062306  energy(sigma->0) =      -59.44709290


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   568
 total energy-change (2. order) :-0.7004434E-04  (-0.6944809E-06)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1295080 magnetization 

 Broyden mixing:
  rms(total) = 0.26861E-03    rms(broyden)= 0.26853E-03
  rms(prec ) = 0.49737E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7720
  4.2900  2.6086  2.3090  1.9070  1.2282  1.2282  1.1497  0.9539  1.0229  1.0229

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.21985523
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61924981
  PAW double counting   =      5655.41310042    -5692.93357573
  entropy T*S    EENTRO =        -0.05470479
  eigenvalues    EBANDS =     -1013.72692662
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46539786 eV

  energy without entropy =      -59.41069308  energy(sigma->0) =      -59.44716294


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   496
 total energy-change (2. order) :-0.4566193E-04  (-0.5034967E-06)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1294554 magnetization 

 Broyden mixing:
  rms(total) = 0.14209E-03    rms(broyden)= 0.14190E-03
  rms(prec ) = 0.25488E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7914
  4.9478  2.7774  2.4195  2.0123  1.1792  1.1792  1.0218  1.0117  1.0117  1.0726
  1.0726

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.20133461
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61891299
  PAW double counting   =      5655.57437049    -5693.09437925
  entropy T*S    EENTRO =        -0.05470483
  eigenvalues    EBANDS =     -1013.74562259
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46544353 eV

  energy without entropy =      -59.41073869  energy(sigma->0) =      -59.44720858


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   512
 total energy-change (2. order) :-0.1016392E-04  (-0.1091091E-06)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1294661 magnetization 

 Broyden mixing:
  rms(total) = 0.10257E-03    rms(broyden)= 0.10254E-03
  rms(prec ) = 0.18006E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8603
  5.5196  2.8446  2.4498  2.0537  1.5456  1.5456  1.1730  1.1730  0.9978  0.9978
  1.0114  1.0114

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.19244628
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61866463
  PAW double counting   =      5655.60129184    -5693.12121161
  entropy T*S    EENTRO =        -0.05470478
  eigenvalues    EBANDS =     -1013.75436176
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46545369 eV

  energy without entropy =      -59.41074891  energy(sigma->0) =      -59.44721876


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   456
 total energy-change (2. order) :-0.1041718E-04  (-0.1352929E-06)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1295023 magnetization 

 Broyden mixing:
  rms(total) = 0.91037E-04    rms(broyden)= 0.90943E-04
  rms(prec ) = 0.13150E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8644
  5.7426  3.0710  2.5504  2.1051  2.1051  1.1094  1.1094  1.2855  0.9950  1.0645
  1.0645  1.0175  1.0175

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.18075149
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61842581
  PAW double counting   =      5655.56519314    -5693.08526561
  entropy T*S    EENTRO =        -0.05470475
  eigenvalues    EBANDS =     -1013.76567548
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46546411 eV

  energy without entropy =      -59.41075935  energy(sigma->0) =      -59.44722919


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   488
 total energy-change (2. order) :-0.4234536E-05  (-0.3814733E-07)
 number of electron      63.0000122 magnetization 
 augmentation part        9.1295023 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1659.11734484
  -Hartree energ DENC   =     -6083.17797437
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.61851239
  PAW double counting   =      5655.56828728    -5693.08851656
  entropy T*S    EENTRO =        -0.05470480
  eigenvalues    EBANDS =     -1013.76838656
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.46546834 eV

  energy without entropy =      -59.41076354  energy(sigma->0) =      -59.44723341


--------------------------------------------------------------------------------------------------------




 average (electrostatic) potential at core
  the test charge radii are     0.6991  0.7167  0.5201
  (the norm of the test charge is              1.0000)
       1 -64.4695       2 -61.5634       3 -64.4442       4 -85.8544       5 -86.2145
       6 -86.2794       7 -86.1929       8 -86.2710       9 -86.2429      10 -86.2918
      11 -42.9486      12 -41.3523
 
 
 
 E-fermi :  -5.4605     XC(G=0):  -2.7183     alpha+bet : -1.2619


 k-point     1 :       0.0000    0.0000    0.0000
  band No.  band energies     occupation 
      1     -32.6939      2.00000
      2     -32.5457      2.00000
      3     -30.5937      2.00000
      4     -30.4090      2.00000
      5     -30.3492      2.00000
      6     -30.3045      2.00000
      7     -30.2804      2.00000
      8     -19.8739      2.00000
      9     -17.3250      2.00000
     10     -16.0111      2.00000
     11     -14.5155      2.00000
     12     -14.5059      2.00000
     13     -14.3849      2.00000
     14     -14.0665      2.00000
     15     -13.7519      2.00000
     16     -13.2208      2.00000
     17     -12.3761      2.00000
     18     -10.7976      2.00000
     19     -10.7738      2.00000
     20     -10.6727      2.00000
     21     -10.5862      2.00000
     22     -10.1963      2.00000
     23     -10.1411      2.00000
     24      -9.9202      2.00000
     25      -9.7741      2.00000
     26      -9.6003      2.00000
     27      -9.4450      2.00000
     28      -9.2232      2.00000
     29      -9.1017      2.00000
     30      -8.5146      2.00000
     31      -8.1942      2.00000
     32      -5.4816      1.17689
     33      -0.0587      0.00000
     34       0.3659      0.00000
     35       1.3167      0.00000
     36       1.7430      0.00000
     37       1.8020      0.00000
     38       1.9576      0.00000
     39       2.3738      0.00000
     40       2.7179      0.00000

 k-point     2 :       0.5000    0.0000    0.0000
  band No.  band energies     occupation 
      1     -32.6938      2.00000
      2     -32.5453      2.00000
      3     -30.5933      2.00000
      4     -30.4080      2.00000
      5     -30.3489      2.00000
      6     -30.3033      2.00000
      7     -30.2799      2.00000
      8     -19.8738      2.00000
      9     -17.3249      2.00000
     10     -16.0106      2.00000
     11     -14.5151      2.00000
     12     -14.5051      2.00000
     13     -14.3847      2.00000
     14     -14.0663      2.00000
     15     -13.7512      2.00000
     16     -13.2206      2.00000
     17     -12.3754      2.00000
     18     -10.7978      2.00000
     19     -10.7736      2.00000
     20     -10.6717      2.00000
     21     -10.5855      2.00000
     22     -10.1962      2.00000
     23     -10.1403      2.00000
     24      -9.9197      2.00000
     25      -9.7735      2.00000
     26      -9.5996      2.00000
     27      -9.4444      2.00000
     28      -9.2222      2.00000
     29      -9.1010      2.00000
     30      -8.5142      2.00000
     31      -8.1931      2.00000
     32      -5.4813      1.17470
     33      -0.0894      0.00000
     34       0.6160      0.00000
     35       0.8455      0.00000
     36       1.6550      0.00000
     37       1.8265      0.00000
     38       2.3868      0.00000
     39       2.6598      0.00000
     40       2.7420      0.00000

 k-point     3 :       0.0000    0.5000    0.0000
  band No.  band energies     occupation 
      1     -32.6934      2.00000
      2     -32.5451      2.00000
      3     -30.5932      2.00000
      4     -30.4081      2.00000
      5     -30.3489      2.00000
      6     -30.3037      2.00000
      7     -30.2798      2.00000
      8     -19.8740      2.00000
      9     -17.3247      2.00000
     10     -16.0098      2.00000
     11     -14.5154      2.00000
     12     -14.5040      2.00000
     13     -14.3843      2.00000
     14     -14.0667      2.00000
     15     -13.7514      2.00000
     16     -13.2201      2.00000
     17     -12.3781      2.00000
     18     -10.7986      2.00000
     19     -10.7754      2.00000
     20     -10.6715      2.00000
     21     -10.5858      2.00000
     22     -10.1953      2.00000
     23     -10.1410      2.00000
     24      -9.9195      2.00000
     25      -9.7742      2.00000
     26      -9.5995      2.00000
     27      -9.4437      2.00000
     28      -9.2243      2.00000
     29      -9.1004      2.00000
     30      -8.5254      2.00000
     31      -8.1930      2.00000
     32      -5.4405      0.83167
     33      -0.0029      0.00000
     34       0.6184      0.00000
     35       1.0696      0.00000
     36       1.4796      0.00000
     37       1.8650      0.00000
     38       2.1672      0.00000
     39       2.2567      0.00000
     40       2.4305      0.00000

 k-point     4 :       0.0000    0.0000    0.5000
  band No.  band energies     occupation 
      1     -32.6931      2.00000
      2     -32.5453      2.00000
      3     -30.5933      2.00000
      4     -30.4086      2.00000
      5     -30.3485      2.00000
      6     -30.3039      2.00000
      7     -30.2798      2.00000
      8     -19.8735      2.00000
      9     -17.3255      2.00000
     10     -16.0097      2.00000
     11     -14.5163      2.00000
     12     -14.5062      2.00000
     13     -14.3844      2.00000
     14     -14.0650      2.00000
     15     -13.7519      2.00000
     16     -13.2201      2.00000
     17     -12.3762      2.00000
     18     -10.8003      2.00000
     19     -10.7716      2.00000
     20     -10.6717      2.00000
     21     -10.5826      2.00000
     22     -10.1964      2.00000
     23     -10.1395      2.00000
     24      -9.9204      2.00000
     25      -9.7738      2.00000
     26      -9.5988      2.00000
     27      -9.4446      2.00000
     28      -9.2236      2.00000
     29      -9.1001      2.00000
     30      -8.5145      2.00000
     31      -8.1940      2.00000
     32      -5.4799      1.16340
     33      -0.1196      0.00000
     34       0.8587      0.00000
     35       0.9944      0.00000
     36       1.4587      0.00000
     37       2.0066      0.00000
     38       2.0693      0.00000
     39       2.3316      0.00000
     40       2.4390      0.00000

 k-point     5 :       0.5000    0.5000    0.0000
  band No.  band energies     occupation 
      1     -32.6939      2.00000
      2     -32.5453      2.00000
      3     -30.5943      2.00000
      4     -30.4082      2.00000
      5     -30.3493      2.00000
      6     -30.3042      2.00000
      7     -30.2803      2.00000
      8     -19.8740      2.00000
      9     -17.3249      2.00000
     10     -16.0101      2.00000
     11     -14.5154      2.00000
     12     -14.5045      2.00000
     13     -14.3845      2.00000
     14     -14.0671      2.00000
     15     -13.7514      2.00000
     16     -13.2206      2.00000
     17     -12.3785      2.00000
     18     -10.7993      2.00000
     19     -10.7759      2.00000
     20     -10.6718      2.00000
     21     -10.5864      2.00000
     22     -10.1958      2.00000
     23     -10.1418      2.00000
     24      -9.9203      2.00000
     25      -9.7749      2.00000
     26      -9.5995      2.00000
     27      -9.4443      2.00000
     28      -9.2245      2.00000
     29      -9.1012      2.00000
     30      -8.5256      2.00000
     31      -8.1930      2.00000
     32      -5.4408      0.83363
     33      -0.0300      0.00000
     34       0.7832      0.00000
     35       1.1984      0.00000
     36       1.3206      0.00000
     37       1.4413      0.00000
     38       1.9424      0.00000
     39       2.2538      0.00000
     40       2.4885      0.00000

 k-point     6 :       0.5000    0.0000    0.5000
  band No.  band energies     occupation 
      1     -32.6935      2.00000
      2     -32.5460      2.00000
      3     -30.5934      2.00000
      4     -30.4090      2.00000
      5     -30.3492      2.00000
      6     -30.3041      2.00000
      7     -30.2803      2.00000
      8     -19.8736      2.00000
      9     -17.3257      2.00000
     10     -16.0100      2.00000
     11     -14.5164      2.00000
     12     -14.5065      2.00000
     13     -14.3850      2.00000
     14     -14.0654      2.00000
     15     -13.7522      2.00000
     16     -13.2205      2.00000
     17     -12.3762      2.00000
     18     -10.8015      2.00000
     19     -10.7720      2.00000
     20     -10.6718      2.00000
     21     -10.5826      2.00000
     22     -10.1975      2.00000
     23     -10.1401      2.00000
     24      -9.9209      2.00000
     25      -9.7742      2.00000
     26      -9.5995      2.00000
     27      -9.4452      2.00000
     28      -9.2243      2.00000
     29      -9.1009      2.00000
     30      -8.5152      2.00000
     31      -8.1941      2.00000
     32      -5.4801      1.16510
     33      -0.1282      0.00000
     34       0.8859      0.00000
     35       1.3031      0.00000
     36       1.4044      0.00000
     37       1.4654      0.00000
     38       1.7147      0.00000
     39       2.3064      0.00000
     40       2.7018      0.00000

 k-point     7 :       0.0000    0.5000    0.5000
  band No.  band energies     occupation 
      1     -32.6946      2.00000
      2     -32.5463      2.00000
      3     -30.5951      2.00000
      4     -30.4094      2.00000
      5     -30.3499      2.00000
      6     -30.3058      2.00000
      7     -30.2810      2.00000
      8     -19.8740      2.00000
      9     -17.3261      2.00000
     10     -16.0095      2.00000
     11     -14.5171      2.00000
     12     -14.5054      2.00000
     13     -14.3853      2.00000
     14     -14.0661      2.00000
     15     -13.7527      2.00000
     16     -13.2210      2.00000
     17     -12.3796      2.00000
     18     -10.8035      2.00000
     19     -10.7750      2.00000
     20     -10.6724      2.00000
     21     -10.5844      2.00000
     22     -10.1974      2.00000
     23     -10.1421      2.00000
     24      -9.9223      2.00000
     25      -9.7768      2.00000
     26      -9.6004      2.00000
     27      -9.4451      2.00000
     28      -9.2269      2.00000
     29      -9.1019      2.00000
     30      -8.5273      2.00000
     31      -8.1953      2.00000
     32      -5.4403      0.82997
     33      -0.0422      0.00000
     34       0.9920      0.00000
     35       1.2873      0.00000
     36       1.3565      0.00000
     37       1.6690      0.00000
     38       1.7967      0.00000
     39       2.0990      0.00000
     40       2.5699      0.00000

 k-point     8 :       0.5000    0.5000    0.5000
  band No.  band energies     occupation 
      1     -32.6938      2.00000
      2     -32.5455      2.00000
      3     -30.5936      2.00000
      4     -30.4084      2.00000
      5     -30.3485      2.00000
      6     -30.3044      2.00000
      7     -30.2800      2.00000
      8     -19.8739      2.00000
      9     -17.3257      2.00000
     10     -16.0090      2.00000
     11     -14.5165      2.00000
     12     -14.5050      2.00000
     13     -14.3845      2.00000
     14     -14.0655      2.00000
     15     -13.7518      2.00000
     16     -13.2201      2.00000
     17     -12.3787      2.00000
     18     -10.8021      2.00000
     19     -10.7744      2.00000
     20     -10.6716      2.00000
     21     -10.5829      2.00000
     22     -10.1971      2.00000
     23     -10.1409      2.00000
     24      -9.9211      2.00000
     25      -9.7751      2.00000
     26      -9.5991      2.00000
     27      -9.4439      2.00000
     28      -9.2255      2.00000
     29      -9.0999      2.00000
     30      -8.5259      2.00000
     31      -8.1934      2.00000
     32      -5.4397      0.82462
     33      -0.0532      0.00000
     34       1.0521      0.00000
     35       1.4132      0.00000
     36       1.4772      0.00000
     37       1.6278      0.00000
     38       1.7947      0.00000
     39       1.9643      0.00000
     40       2.1493      0.00000


--------------------------------------------------------------------------------------------------------


 soft charge-density along one line, spin component           1
         0         1         2         3         4         5         6         7         8         9
 total charge-density along one line
 
 pseudopotential strength for first ion, spin component:           1
 10.569  14.064  -0.006   0.005  -0.003   0.020  -0.016   0.009
 14.064  18.713  -0.008   0.007  -0.004   0.026  -0.021   0.011
 -0.006  -0.008  -4.693  -0.007   0.004   9.198   0.013  -0.007
  0.005   0.007  -0.007  -4.695  -0.003   0.013   9.204   0.006
 -0.003  -0.004   0.004  -0.003  -4.699  -0.007   0.006   9.211
  0.020   0.026   9.198   0.013  -0.007 -20.190  -0.026   0.015
 -0.016  -0.021   0.013   9.204   0.006  -0.026 -20.200  -0.013
  0.009   0.011  -0.007   0.006   9.211   0.015  -0.013 -20.214
 total augmentation occupancy for first ion, spin component:           1
  7.599  -3.663  -0.183   0.148  -0.084  -0.051   0.041  -0.023
 -3.663   2.005   0.215  -0.175   0.098   0.037  -0.030   0.017
 -0.183   0.215   1.482  -0.085   0.050   0.134   0.009  -0.004
  0.148  -0.175  -0.085   1.437  -0.039   0.009   0.136   0.004
 -0.084   0.098   0.050  -0.039   1.387  -0.004   0.004   0.140
 -0.051   0.037   0.134   0.009  -0.004   0.016   0.003  -0.001
  0.041  -0.030   0.009   0.136   0.004   0.003   0.017   0.001
 -0.023   0.017  -0.004   0.004   0.140  -0.001   0.001   0.018


------------------------ aborting loop because EDIFF is reached ----------------------------------------



  FORCE on cell =-STRESS in cart. coord.  units (eV):
  Direction    XX          YY          ZZ          XY          YZ          ZX
  --------------------------------------------------------------------------------------
  Alpha Z    23.83308    23.83308    23.83308
  Ewald     -78.98217   590.71779  1147.37835   147.13726  -321.83626  -199.19137
  Hartree  1401.51342  2105.50874  2576.14508   151.44047  -291.52324  -257.44794
  E(xc)    -329.72384  -329.65565  -329.56887    -0.06074     0.13098     0.45488
  Local   -2195.46221 -3570.20900 -4585.93974  -306.11565   621.46475   485.95642
  n-local  -293.95358  -295.17652  -294.15288    -0.38048    -0.53259     1.03836
  augment   123.88470   124.31812   122.70702     1.01620    -0.81364    -3.64331
  Kinetic  1340.40943  1342.38803  1331.34058     6.87296    -6.50509   -26.87232
  Fock        0.00000     0.00000     0.00000     0.00000     0.00000     0.00000
  -------------------------------------------------------------------------------------
  Total       -8.4811713     -8.2754138     -8.2573871     -0.0899835      0.3849179      0.2947230
  in kB      -21.2317818    -20.7166881    -20.6715599     -0.2252650      0.9636043      0.7378103
  external PRESSURE =     -20.8733433 kB  Pullay stress =       0.0000000 kB


 VOLUME and BASIS-vectors are now :
 -----------------------------------------------------------------------------
  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 FORCES acting on ions
    electron-ion (+dipol)            ewald-force                    non-local-force                 convergence-correction
 -----------------------------------------------------------------------------------------------
   0.494E+02 -.566E+01 -.388E+02   -.465E+02 0.124E+02 0.334E+02   -.294E+01 -.658E+01 0.539E+01   0.389E-03 -.134E-03 -.355E-05
   0.163E+02 -.134E+03 -.756E+02   -.113E+02 0.134E+03 0.816E+02   -.513E+01 -.244E+00 -.620E+01   0.436E-03 -.272E-03 0.176E-03
   -.491E+02 -.403E+02 0.129E+02   0.409E+02 0.411E+02 -.883E+01   0.804E+01 -.765E+00 -.399E+01   -.137E-03 -.236E-03 0.300E-04
   0.404E+03 -.216E+03 0.292E+03   -.442E+03 0.227E+03 -.328E+03   0.373E+02 -.118E+02 0.365E+02   0.476E-03 -.161E-03 -.279E-03
   0.521E+03 -.792E+02 -.257E+03   -.571E+03 0.916E+02 0.279E+03   0.496E+02 -.124E+02 -.220E+02   0.131E-02 -.216E-03 -.166E-03
   0.173E+03 0.485E+03 0.167E+03   -.179E+03 -.533E+03 -.196E+03   0.611E+01 0.475E+02 0.293E+02   0.586E-03 0.421E-03 0.595E-04
   -.230E+03 -.431E+03 0.273E+03   0.243E+03 0.477E+03 -.301E+03   -.132E+02 -.460E+02 0.281E+02   -.752E-03 -.599E-03 0.337E-03
   -.513E+03 0.261E+02 -.264E+03   0.554E+03 -.352E+02 0.301E+03   -.409E+02 0.904E+01 -.368E+02   -.140E-02 0.445E-04 -.554E-03
   -.147E+03 0.348E+03 0.391E+03   0.147E+03 -.390E+03 -.428E+03   0.454E+00 0.425E+02 0.370E+02   -.594E-03 0.231E-03 0.267E-03
   -.227E+03 0.134E+03 -.446E+03   0.262E+03 -.143E+03 0.489E+03   -.350E+02 0.973E+01 -.424E+02   -.417E-03 0.166E-03 -.427E-03
   0.242E+01 -.847E+02 -.558E+02   -.188E+01 0.894E+02 0.592E+02   -.438E+00 -.425E+01 -.326E+01   0.499E-04 -.142E-04 0.454E-05
   -.373E+01 -.280E+02 -.189E+02   0.374E+01 0.281E+02 0.190E+02   -.654E-01 -.278E+00 -.219E-01   -.782E-05 -.145E-04 -.307E-04
 -----------------------------------------------------------------------------------------------
   -.379E+01 -.264E+02 -.216E+02   0.156E-12 0.462E-13 -.959E-13   0.379E+01 0.264E+02 0.216E+02   -.680E-04 -.785E-03 -.586E-03
 
 
 POSITION                                       TOTAL-FORCE (eV/Angst)
 -----------------------------------------------------------------------------------
      3.87094      3.37490      4.34948         0.010843      0.125879     -0.056490
      4.35936      4.54564      3.47631        -0.093832     -0.075678     -0.151061
      5.71963      4.35871      2.77568        -0.106599      0.051678      0.052270
      3.39965      4.82805      2.52054         0.115418     -0.113510      0.077787
      2.66469      3.69674      4.88164        -0.014947     -0.056065     -0.017503
      3.73346      2.23192      3.63819        -0.028740     -0.096709      0.035879
      6.02732      5.49468      2.09763        -0.013496     -0.039268     -0.030683
      6.69785      4.13780      3.68957         0.018834     -0.039941     -0.026630
      5.69963      3.33177      1.89654         0.065492     -0.043126     -0.047242
      4.73608      3.15470      5.37104         0.001424     -0.055767     -0.005039
      4.46334      5.43352      4.14724         0.100768      0.476430      0.132802
      4.85531      7.03282      4.38397        -0.055167     -0.133923      0.035909
 -----------------------------------------------------------------------------------
    total drift:                               -0.004912     -0.015468     -0.001702


--------------------------------------------------------------------------------------------------------



  FREE ENERGIE OF THE ION-ELECTRON SYSTEM (eV)
  ---------------------------------------------------
  free  energy   TOTEN  =       -59.4654683412 eV

  energy  without entropy=      -59.4107635450  energy(sigma->0) =      -59.44723341
 


--------------------------------------------------------------------------------------------------------




--------------------------------------------------------------------------------------------------------



volume of typ            1:     0.9 %

volume of typ            2:     1.7 %

volume of typ            3:     0.0 %