vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.11.30  15:23:01
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 0.77 0.72 0.32
   NPAR = 4

 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE F 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE F 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    14.049    0.15E-03    0.22E-03    0.24E-06
   0      8    10.150     8.945    0.21E-03    0.31E-03    0.30E-06
   1      8    10.150     7.086    0.42E-03    0.48E-03    0.23E-06
   1      8    10.150     6.747    0.37E-03    0.43E-03    0.21E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
  PAW_PBE C 08Apr2002                   :
 energy of atom  1       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
  PAW_PBE F 08Apr2002                   :
 energy of atom  2       EATOM= -659.6475
 kinetic energy error for atom=    0.1978 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.385  0.422  0.542-   6 1.35   5 1.36  10 1.36   2 1.54
   2  0.436  0.570  0.436-  11 1.11   4 1.38   1 1.54   3 1.54
   3  0.572  0.543  0.348-   9 1.35   8 1.36   7 1.36   2 1.54
   4  0.341  0.605  0.315-   2 1.38
   5  0.265  0.463  0.608-   1 1.36
   6  0.370  0.281  0.451-   1 1.35
   7  0.605  0.684  0.263-   3 1.36
   8  0.669  0.512  0.462-   3 1.36
   9  0.568  0.415  0.238-   3 1.35
  10  0.471  0.391  0.670-   1 1.36
  11  0.447  0.679  0.519-   2 1.11
  12  0.509  0.927  0.501-
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =     8.0000000000
 C/A-ratio  =     1.2500000000
  
  Lattice vectors:
  
 A1 = (   0.0000000000,   8.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,   8.0000000000)
 A3 = (  10.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


Analysis of constrained symmetry for selective dynamics:
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The constrained configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :     640.0000

  direct lattice vectors                    reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000

  position of ions in fractional coordinates (direct lattice)
     0.385220960  0.422356710  0.541928040
     0.436089290  0.569953730  0.435577610
     0.571782750  0.542794820  0.347988790
     0.341228010  0.605330270  0.314564890
     0.264637810  0.462948650  0.608389620
     0.370063900  0.280668210  0.451124260
     0.605190460  0.683951050  0.263150710
     0.669351440  0.512203180  0.461926530
     0.568273130  0.414759800  0.237601180
     0.470852190  0.390684690  0.669732350
     0.446794820  0.679460510  0.519084790
     0.508705870  0.927263090  0.501440800

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    2    2    2

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     0.500000000  0.000000000  0.000000000
     0.000000000  0.062500000  0.000000000     0.000000000  0.500000000  0.000000000
     0.000000000  0.000000000  0.062500000     0.000000000  0.000000000  0.500000000

  Length of vectors
     0.050000000  0.062500000  0.062500000

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      8 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.500000  0.000000  0.000000      1.000000
  0.000000  0.500000  0.000000      1.000000
  0.000000  0.000000  0.500000      1.000000
  0.500000  0.500000  0.000000      1.000000
  0.500000  0.000000  0.500000      1.000000
  0.000000  0.500000  0.500000      1.000000
  0.500000  0.500000  0.500000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
  0.050000  0.000000  0.000000      1.000000
  0.000000  0.062500  0.000000      1.000000
  0.000000  0.000000  0.062500      1.000000
  0.050000  0.062500  0.000000      1.000000
  0.050000  0.000000  0.062500      1.000000
  0.000000  0.062500  0.062500      1.000000
  0.050000  0.062500  0.062500      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      8   k-points in BZ     NKDIM =      8   number of bands    NBANDS=     40
   number of dos      NEDOS =    301   number of ions     NIONS =     12
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV =  80000
   max r-space proj   IRMAX =   1427   max aug-charges    IRDMAX=   1789
   dimension x,y,z NGX =    50 NGY =   40 NGZ =   40
   dimension x,y,z NGXF=   100 NGYF=   80 NGZF=   80
   support grid    NGXF=   100 NGYF=   80 NGZF=   80
   ions per type =               3   7   2
   NGX,Y,Z   is equivalent  to a cutoff of   8.31,  8.31,  8.31 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.62, 16.62, 16.62 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  16.31 13.05 13.05*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.229E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  12.01 19.00  1.00
  Ionic Valenz
   ZVAL   =   4.00  7.00  1.00
  Atomic Wigner-Seitz radii
   RWIGS  =   0.77  0.72  0.32
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00
   NELECT =      63.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.63E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =      53.33       359.91
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.755895  1.428435  7.774067  0.571378
  Thomas-Fermi vector in A             =   1.853893
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands            8
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.05000000  0.00000000  0.00000000       0.125
   0.00000000  0.06250000  0.00000000       0.125
   0.00000000  0.00000000  0.06250000       0.125
   0.05000000  0.06250000  0.00000000       0.125
   0.05000000  0.00000000  0.06250000       0.125
   0.00000000  0.06250000  0.06250000       0.125
   0.05000000  0.06250000  0.06250000       0.125
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       0.125
   0.50000000  0.00000000  0.00000000       0.125
   0.00000000  0.50000000  0.00000000       0.125
   0.00000000  0.00000000  0.50000000       0.125
   0.50000000  0.50000000  0.00000000       0.125
   0.50000000  0.00000000  0.50000000       0.125
   0.00000000  0.50000000  0.50000000       0.125
   0.50000000  0.50000000  0.50000000       0.125
 
 position of ions in fractional coordinates (direct lattice) 
   0.38522096  0.42235671  0.54192804
   0.43608929  0.56995373  0.43557761
   0.57178275  0.54279482  0.34798879
   0.34122801  0.60533027  0.31456489
   0.26463781  0.46294865  0.60838962
   0.37006390  0.28066821  0.45112426
   0.60519046  0.68395105  0.26315071
   0.66935144  0.51220318  0.46192653
   0.56827313  0.41475980  0.23760118
   0.47085219  0.39068469  0.66973235
   0.44679482  0.67946051  0.51908479
   0.50870587  0.92726309  0.50144080
 
 position of ions in cartesian coordinates  (Angst):
   3.85220960  3.37885368  4.33542432
   4.36089290  4.55962984  3.48462088
   5.71782750  4.34235856  2.78391032
   3.41228010  4.84264216  2.51651912
   2.64637810  3.70358920  4.86711696
   3.70063900  2.24534568  3.60899408
   6.05190460  5.47160840  2.10520568
   6.69351440  4.09762544  3.69541224
   5.68273130  3.31807840  1.90080944
   4.70852190  3.12547752  5.35785880
   4.46794820  5.43568408  4.15267832
   5.08705870  7.41810472  4.01152640
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   11633
 k-point  2 :   0.5000 0.0000 0.0000  plane waves:   11592
 k-point  3 :   0.0000 0.5000 0.0000  plane waves:   11586
 k-point  4 :   0.0000 0.0000 0.5000  plane waves:   11586
 k-point  5 :   0.5000 0.5000 0.0000  plane waves:   11620
 k-point  6 :   0.5000 0.0000 0.5000  plane waves:   11620
 k-point  7 :   0.0000 0.5000 0.5000  plane waves:   11700
 k-point  8 :   0.5000 0.5000 0.5000  plane waves:   11608

 maximum and minimum number of plane-waves per node :     11700    11586

 maximum number of plane-waves:     11700
 maximum index in each direction: 
   IXMAX=   16   IYMAX=   13   IZMAX=   13
   IXMIN=  -16   IYMIN=  -13   IZMIN=  -13

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to    70 to avoid them
 WARNING: aliasing errors must be expected set NGY to    54 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    54 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0    65908. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       1273. kBytes
   fftplans  :       5842. kBytes
   grid      :      13664. kBytes
   one-center:         36. kBytes
   wavefun   :      15093. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 33   NGY = 27   NGZ = 27
  (NGX  =100   NGY  = 80   NGZ  = 80)
  gives a total of  24057 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron      63.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1350
 Maximum index for augmentation-charges          398 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.206
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   776
 total energy-change (2. order) : 0.6070816E+03  (-0.2270423E+04)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6015.40821622
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.47709432
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.02054688
  eigenvalues    EBANDS =      -406.58583704
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       607.08160793 eV

  energy without entropy =      607.10215480  energy(sigma->0) =      607.08845689


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   960
 total energy-change (2. order) :-0.5706049E+03  (-0.5509485E+03)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6015.40821622
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.47709432
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.01722817
  eigenvalues    EBANDS =      -977.19400581
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        36.47675786 eV

  energy without entropy =       36.49398603  energy(sigma->0) =       36.48250058


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   744
 total energy-change (2. order) :-0.9715851E+02  (-0.9676786E+02)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6015.40821622
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.47709432
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05532544
  eigenvalues    EBANDS =     -1074.31441993
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -60.68175353 eV

  energy without entropy =      -60.62642809  energy(sigma->0) =      -60.66331171


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   760
 total energy-change (2. order) :-0.1658964E+01  (-0.1652503E+01)
 number of electron      63.0000000 magnetization 
 augmentation part       63.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6015.40821622
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.47709432
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05541264
  eigenvalues    EBANDS =     -1075.97329626
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -62.34071706 eV

  energy without entropy =      -62.28530442  energy(sigma->0) =      -62.32224618


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   824
 total energy-change (2. order) :-0.4183016E-01  (-0.4181641E-01)
 number of electron      63.0000273 magnetization 
 augmentation part        9.5866120 magnetization 

 Broyden mixing:
  rms(total) = 0.13318E+01    rms(broyden)= 0.13258E+01
  rms(prec ) = 0.15823E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6015.40821622
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       304.47709432
  PAW double counting   =      4104.28886790    -4141.72589677
  entropy T*S    EENTRO =        -0.05543244
  eigenvalues    EBANDS =     -1076.01510662
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -62.38254722 eV

  energy without entropy =      -62.32711478  energy(sigma->0) =      -62.36406974


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) : 0.2790656E+01  (-0.1007652E+01)
 number of electron      63.0000262 magnetization 
 augmentation part        9.1278078 magnetization 

 Broyden mixing:
  rms(total) = 0.68157E+00    rms(broyden)= 0.68053E+00
  rms(prec ) = 0.74510E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.2627
  1.2627

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6065.76185491
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       308.23967436
  PAW double counting   =      4693.28661910    -4732.38094477
  entropy T*S    EENTRO =        -0.05510449
  eigenvalues    EBANDS =     -1024.97642344
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.59189155 eV

  energy without entropy =      -59.53678707  energy(sigma->0) =      -59.57352339


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   816
 total energy-change (2. order) : 0.1769881E+00  (-0.9545148E-01)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1292539 magnetization 

 Broyden mixing:
  rms(total) = 0.31915E+00    rms(broyden)= 0.31910E+00
  rms(prec ) = 0.35037E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5768
  1.0733  2.0803

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6075.11938058
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       308.93173982
  PAW double counting   =      5155.95642001    -5194.17124580
  entropy T*S    EENTRO =        -0.05503676
  eigenvalues    EBANDS =     -1017.01354273
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41490342 eV

  energy without entropy =      -59.35986667  energy(sigma->0) =      -59.39655784


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) : 0.4287271E-02  (-0.1373542E-01)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1422912 magnetization 

 Broyden mixing:
  rms(total) = 0.61153E-01    rms(broyden)= 0.61109E-01
  rms(prec ) = 0.72807E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5187
  2.4226  1.0668  1.0668

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6080.71883996
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.39813639
  PAW double counting   =      5560.67210585    -5598.29091139
  entropy T*S    EENTRO =        -0.05499707
  eigenvalues    EBANDS =     -1012.47225257
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41061615 eV

  energy without entropy =      -59.35561908  energy(sigma->0) =      -59.39228380


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   768
 total energy-change (2. order) :-0.1613113E-02  (-0.2050318E-02)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1287138 magnetization 

 Broyden mixing:
  rms(total) = 0.22049E-01    rms(broyden)= 0.22025E-01
  rms(prec ) = 0.27515E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5494
  2.4045  1.8032  0.9950  0.9950

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6083.31315922
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.60181841
  PAW double counting   =      5649.92146731    -5687.48257787
  entropy T*S    EENTRO =        -0.05499343
  eigenvalues    EBANDS =     -1010.14092706
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41222927 eV

  energy without entropy =      -59.35723584  energy(sigma->0) =      -59.39389812


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   832
 total energy-change (2. order) :-0.2865513E-03  (-0.2961399E-03)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1305427 magnetization 

 Broyden mixing:
  rms(total) = 0.77628E-02    rms(broyden)= 0.77576E-02
  rms(prec ) = 0.11880E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5208
  2.4377  1.0342  1.0342  1.5489  1.5489

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.99250960
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.58248328
  PAW double counting   =      5656.57967578    -5694.10670231
  entropy T*S    EENTRO =        -0.05500396
  eigenvalues    EBANDS =     -1010.47660160
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41251582 eV

  energy without entropy =      -59.35751186  energy(sigma->0) =      -59.39418117


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   760
 total energy-change (2. order) :-0.5121287E-03  (-0.3698539E-04)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1316851 magnetization 

 Broyden mixing:
  rms(total) = 0.27569E-02    rms(broyden)= 0.27554E-02
  rms(prec ) = 0.62969E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5463
  2.4978  2.2217  1.0413  1.0413  1.3222  1.1536

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.93325104
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57554333
  PAW double counting   =      5656.81902994    -5694.34461430
  entropy T*S    EENTRO =        -0.05500249
  eigenvalues    EBANDS =     -1010.53087597
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41302795 eV

  energy without entropy =      -59.35802546  energy(sigma->0) =      -59.39469378


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   744
 total energy-change (2. order) :-0.5392831E-03  (-0.1120354E-04)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1314107 magnetization 

 Broyden mixing:
  rms(total) = 0.15589E-02    rms(broyden)= 0.15576E-02
  rms(prec ) = 0.36219E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.5687
  2.6830  2.3093  1.4829  1.4829  0.9564  1.0331  1.0331

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.99761291
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57811907
  PAW double counting   =      5656.41902482    -5693.94866213
  entropy T*S    EENTRO =        -0.05500296
  eigenvalues    EBANDS =     -1010.46557571
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41356723 eV

  energy without entropy =      -59.35856427  energy(sigma->0) =      -59.39523291


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   680
 total energy-change (2. order) :-0.4445197E-03  (-0.6408076E-05)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1310401 magnetization 

 Broyden mixing:
  rms(total) = 0.91809E-03    rms(broyden)= 0.91713E-03
  rms(prec ) = 0.19880E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.6726
  3.2327  2.4581  2.0907  1.0224  1.0224  1.0484  1.2533  1.2533

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6083.04452921
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57991441
  PAW double counting   =      5655.72649794    -5693.25789909
  entropy T*S    EENTRO =        -0.05500289
  eigenvalues    EBANDS =     -1010.41913551
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41401175 eV

  energy without entropy =      -59.35900886  energy(sigma->0) =      -59.39567745


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   656
 total energy-change (2. order) :-0.2572792E-03  (-0.3294924E-05)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1312627 magnetization 

 Broyden mixing:
  rms(total) = 0.55421E-03    rms(broyden)= 0.55375E-03
  rms(prec ) = 0.10267E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.7227
  3.9161  2.5059  2.0986  1.5167  1.0247  1.0247  1.1410  1.1384  1.1384

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6083.01355351
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57741936
  PAW double counting   =      5655.05026715    -5692.58008319
  entropy T*S    EENTRO =        -0.05500247
  eigenvalues    EBANDS =     -1010.44945897
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41426903 eV

  energy without entropy =      -59.35926656  energy(sigma->0) =      -59.39593487


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   568
 total energy-change (2. order) :-0.8228129E-04  (-0.6328282E-06)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1311469 magnetization 

 Broyden mixing:
  rms(total) = 0.25300E-03    rms(broyden)= 0.25287E-03
  rms(prec ) = 0.57447E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8511
  4.9009  2.6857  2.3397  2.0073  1.1751  1.1751  1.0429  1.0429  0.9893  1.1527

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.99715993
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57730899
  PAW double counting   =      5655.18548079    -5692.71490178
  entropy T*S    EENTRO =        -0.05500262
  eigenvalues    EBANDS =     -1010.46621936
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41435131 eV

  energy without entropy =      -59.35934869  energy(sigma->0) =      -59.39601710


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   528
 total energy-change (2. order) :-0.5793957E-04  (-0.7545636E-06)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1311281 magnetization 

 Broyden mixing:
  rms(total) = 0.18230E-03    rms(broyden)= 0.18216E-03
  rms(prec ) = 0.32892E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.8259
  5.1926  2.8203  2.4293  1.9859  1.0918  1.0918  1.2315  1.2315  0.9533  1.0285
  1.0285

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.96309892
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57646448
  PAW double counting   =      5655.41287600    -5692.94139499
  entropy T*S    EENTRO =        -0.05500266
  eigenvalues    EBANDS =     -1010.50039575
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41440925 eV

  energy without entropy =      -59.35940659  energy(sigma->0) =      -59.39607503


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   512
 total energy-change (2. order) :-0.1248919E-04  (-0.1180290E-06)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1311434 magnetization 

 Broyden mixing:
  rms(total) = 0.10126E-03    rms(broyden)= 0.10124E-03
  rms(prec ) = 0.21197E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.9096
  5.7575  3.0082  2.4743  2.1571  1.8915  1.3696  1.1310  1.1310  0.9783  0.9783
  1.0193  1.0193

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.95141699
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57625070
  PAW double counting   =      5655.42394831    -5692.95249217
  entropy T*S    EENTRO =        -0.05500259
  eigenvalues    EBANDS =     -1010.51185160
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41442174 eV

  energy without entropy =      -59.35941915  energy(sigma->0) =      -59.39608754


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   464
 total energy-change (2. order) :-0.1320148E-04  (-0.1782443E-06)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1311739 magnetization 

 Broyden mixing:
  rms(total) = 0.96976E-04    rms(broyden)= 0.96910E-04
  rms(prec ) = 0.14954E-03
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   1.9183
  6.0242  3.3750  2.5533  2.1447  2.0849  1.1418  1.1418  1.2223  1.2223  1.0333
  1.0333  0.9805  0.9805

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.93500907
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57604641
  PAW double counting   =      5655.37629628    -5692.90508620
  entropy T*S    EENTRO =        -0.05500258
  eigenvalues    EBANDS =     -1010.52782237
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41443494 eV

  energy without entropy =      -59.35943236  energy(sigma->0) =      -59.39610075


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   488
 total energy-change (2. order) :-0.5091474E-05  (-0.5072596E-07)
 number of electron      63.0000263 magnetization 
 augmentation part        9.1311739 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =        23.83307581
  Ewald energy   TEWEN  =      1655.73617316
  -Hartree energ DENC   =     -6082.93002138
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       309.57614111
  PAW double counting   =      5655.38471626    -5692.91364325
  entropy T*S    EENTRO =        -0.05500263
  eigenvalues    EBANDS =     -1010.53277274
  atomic energy  EATOM  =      5082.48689363
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       -59.41444003 eV

  energy without entropy =      -59.35943740  energy(sigma->0) =      -59.39610582


--------------------------------------------------------------------------------------------------------




 average (electrostatic) potential at core
  the test charge radii are     0.6991  0.7167  0.5201
  (the norm of the test charge is              1.0000)
       1 -64.4118       2 -61.4929       3 -64.3974       4 -85.7312       5 -86.1762
       6 -86.2236       7 -86.1731       8 -86.2363       9 -86.1953      10 -86.2500
      11 -42.9558      12 -41.4875
 
 
 
 E-fermi :  -5.5717     XC(G=0):  -2.7200     alpha+bet : -1.2619


 k-point     1 :       0.0000    0.0000    0.0000
  band No.  band energies     occupation 
      1     -32.6495      2.00000
      2     -32.5021      2.00000
      3     -30.5155      2.00000
      4     -30.3457      2.00000
      5     -30.2952      2.00000
      6     -30.2603      2.00000
      7     -30.2227      2.00000
      8     -19.8147      2.00000
      9     -17.2726      2.00000
     10     -15.9706      2.00000
     11     -14.4631      2.00000
     12     -14.4550      2.00000
     13     -14.3367      2.00000
     14     -14.0186      2.00000
     15     -13.6999      2.00000
     16     -13.1518      2.00000
     17     -12.2899      2.00000
     18     -10.7617      2.00000
     19     -10.7406      2.00000
     20     -10.6303      2.00000
     21     -10.5516      2.00000
     22     -10.1313      2.00000
     23     -10.0951      2.00000
     24      -9.8806      2.00000
     25      -9.7248      2.00000
     26      -9.5437      2.00000
     27      -9.4041      2.00000
     28      -9.1849      2.00000
     29      -9.0632      2.00000
     30      -8.3674      2.00000
     31      -8.1335      2.00000
     32      -5.5908      1.16141
     33      -0.0214      0.00000
     34       0.3684      0.00000
     35       1.2222      0.00000
     36       1.7594      0.00000
     37       1.8554      0.00000
     38       1.9728      0.00000
     39       2.2867      0.00000
     40       2.6646      0.00000

 k-point     2 :       0.5000    0.0000    0.0000
  band No.  band energies     occupation 
      1     -32.6493      2.00000
      2     -32.5019      2.00000
      3     -30.5152      2.00000
      4     -30.3448      2.00000
      5     -30.2948      2.00000
      6     -30.2594      2.00000
      7     -30.2218      2.00000
      8     -19.8146      2.00000
      9     -17.2726      2.00000
     10     -15.9700      2.00000
     11     -14.4628      2.00000
     12     -14.4543      2.00000
     13     -14.3364      2.00000
     14     -14.0185      2.00000
     15     -13.6993      2.00000
     16     -13.1516      2.00000
     17     -12.2892      2.00000
     18     -10.7617      2.00000
     19     -10.7404      2.00000
     20     -10.6295      2.00000
     21     -10.5511      2.00000
     22     -10.1309      2.00000
     23     -10.0941      2.00000
     24      -9.8799      2.00000
     25      -9.7241      2.00000
     26      -9.5431      2.00000
     27      -9.4040      2.00000
     28      -9.1840      2.00000
     29      -9.0623      2.00000
     30      -8.3668      2.00000
     31      -8.1325      2.00000
     32      -5.5906      1.15935
     33      -0.0554      0.00000
     34       0.6059      0.00000
     35       0.8434      0.00000
     36       1.5779      0.00000
     37       1.9002      0.00000
     38       2.2776      0.00000
     39       2.6701      0.00000
     40       2.7329      0.00000

 k-point     3 :       0.0000    0.5000    0.0000
  band No.  band energies     occupation 
      1     -32.6490      2.00000
      2     -32.5015      2.00000
      3     -30.5151      2.00000
      4     -30.3450      2.00000
      5     -30.2947      2.00000
      6     -30.2599      2.00000
      7     -30.2219      2.00000
      8     -19.8148      2.00000
      9     -17.2724      2.00000
     10     -15.9692      2.00000
     11     -14.4629      2.00000
     12     -14.4536      2.00000
     13     -14.3359      2.00000
     14     -14.0188      2.00000
     15     -13.6996      2.00000
     16     -13.1511      2.00000
     17     -12.2921      2.00000
     18     -10.7614      2.00000
     19     -10.7423      2.00000
     20     -10.6294      2.00000
     21     -10.5517      2.00000
     22     -10.1302      2.00000
     23     -10.0968      2.00000
     24      -9.8801      2.00000
     25      -9.7246      2.00000
     26      -9.5430      2.00000
     27      -9.4020      2.00000
     28      -9.1870      2.00000
     29      -9.0614      2.00000
     30      -8.3748      2.00000
     31      -8.1320      2.00000
     32      -5.5537      0.84834
     33       0.0331      0.00000
     34       0.6059      0.00000
     35       1.1346      0.00000
     36       1.3616      0.00000
     37       1.7938      0.00000
     38       2.1777      0.00000
     39       2.2785      0.00000
     40       2.3657      0.00000

 k-point     4 :       0.0000    0.0000    0.5000
  band No.  band energies     occupation 
      1     -32.6488      2.00000
      2     -32.5017      2.00000
      3     -30.5152      2.00000
      4     -30.3454      2.00000
      5     -30.2944      2.00000
      6     -30.2597      2.00000
      7     -30.2220      2.00000
      8     -19.8144      2.00000
      9     -17.2731      2.00000
     10     -15.9692      2.00000
     11     -14.4637      2.00000
     12     -14.4554      2.00000
     13     -14.3363      2.00000
     14     -14.0171      2.00000
     15     -13.7000      2.00000
     16     -13.1512      2.00000
     17     -12.2900      2.00000
     18     -10.7639      2.00000
     19     -10.7387      2.00000
     20     -10.6294      2.00000
     21     -10.5482      2.00000
     22     -10.1312      2.00000
     23     -10.0936      2.00000
     24      -9.8808      2.00000
     25      -9.7245      2.00000
     26      -9.5422      2.00000
     27      -9.4039      2.00000
     28      -9.1854      2.00000
     29      -9.0614      2.00000
     30      -8.3672      2.00000
     31      -8.1331      2.00000
     32      -5.5893      1.14859
     33      -0.0770      0.00000
     34       0.7855      0.00000
     35       1.0500      0.00000
     36       1.3558      0.00000
     37       2.0494      0.00000
     38       2.0685      0.00000
     39       2.3611      0.00000
     40       2.4559      0.00000

 k-point     5 :       0.5000    0.5000    0.0000
  band No.  band energies     occupation 
      1     -32.6495      2.00000
      2     -32.5017      2.00000
      3     -30.5161      2.00000
      4     -30.3449      2.00000
      5     -30.2953      2.00000
      6     -30.2603      2.00000
      7     -30.2223      2.00000
      8     -19.8148      2.00000
      9     -17.2726      2.00000
     10     -15.9695      2.00000
     11     -14.4630      2.00000
     12     -14.4539      2.00000
     13     -14.3360      2.00000
     14     -14.0193      2.00000
     15     -13.6995      2.00000
     16     -13.1516      2.00000
     17     -12.2924      2.00000
     18     -10.7621      2.00000
     19     -10.7428      2.00000
     20     -10.6296      2.00000
     21     -10.5523      2.00000
     22     -10.1308      2.00000
     23     -10.0975      2.00000
     24      -9.8808      2.00000
     25      -9.7251      2.00000
     26      -9.5431      2.00000
     27      -9.4028      2.00000
     28      -9.1872      2.00000
     29      -9.0620      2.00000
     30      -8.3752      2.00000
     31      -8.1323      2.00000
     32      -5.5537      0.84897
     33       0.0078      0.00000
     34       0.7546      0.00000
     35       1.2024      0.00000
     36       1.3468      0.00000
     37       1.4611      0.00000
     38       1.7412      0.00000
     39       2.2520      0.00000
     40       2.4930      0.00000

 k-point     6 :       0.5000    0.0000    0.5000
  band No.  band energies     occupation 
      1     -32.6491      2.00000
      2     -32.5025      2.00000
      3     -30.5152      2.00000
      4     -30.3458      2.00000
      5     -30.2952      2.00000
      6     -30.2599      2.00000
      7     -30.2224      2.00000
      8     -19.8145      2.00000
      9     -17.2734      2.00000
     10     -15.9694      2.00000
     11     -14.4638      2.00000
     12     -14.4557      2.00000
     13     -14.3368      2.00000
     14     -14.0175      2.00000
     15     -13.7002      2.00000
     16     -13.1516      2.00000
     17     -12.2900      2.00000
     18     -10.7652      2.00000
     19     -10.7389      2.00000
     20     -10.6296      2.00000
     21     -10.5483      2.00000
     22     -10.1323      2.00000
     23     -10.0941      2.00000
     24      -9.8812      2.00000
     25      -9.7248      2.00000
     26      -9.5429      2.00000
     27      -9.4046      2.00000
     28      -9.1861      2.00000
     29      -9.0621      2.00000
     30      -8.3679      2.00000
     31      -8.1334      2.00000
     32      -5.5893      1.14894
     33      -0.0872      0.00000
     34       0.8225      0.00000
     35       1.3028      0.00000
     36       1.3842      0.00000
     37       1.4595      0.00000
     38       1.7468      0.00000
     39       2.2937      0.00000
     40       2.6383      0.00000

 k-point     7 :       0.0000    0.5000    0.5000
  band No.  band energies     occupation 
      1     -32.6502      2.00000
      2     -32.5027      2.00000
      3     -30.5169      2.00000
      4     -30.3462      2.00000
      5     -30.2959      2.00000
      6     -30.2618      2.00000
      7     -30.2230      2.00000
      8     -19.8149      2.00000
      9     -17.2737      2.00000
     10     -15.9690      2.00000
     11     -14.4645      2.00000
     12     -14.4550      2.00000
     13     -14.3370      2.00000
     14     -14.0184      2.00000
     15     -13.7007      2.00000
     16     -13.1520      2.00000
     17     -12.2935      2.00000
     18     -10.7662      2.00000
     19     -10.7419      2.00000
     20     -10.6305      2.00000
     21     -10.5503      2.00000
     22     -10.1322      2.00000
     23     -10.0979      2.00000
     24      -9.8830      2.00000
     25      -9.7271      2.00000
     26      -9.5439      2.00000
     27      -9.4036      2.00000
     28      -9.1898      2.00000
     29      -9.0626      2.00000
     30      -8.3769      2.00000
     31      -8.1345      2.00000
     32      -5.5532      0.84417
     33       0.0005      0.00000
     34       0.8695      0.00000
     35       1.2821      0.00000
     36       1.3973      0.00000
     37       1.7437      0.00000
     38       1.7747      0.00000
     39       2.0336      0.00000
     40       2.5524      0.00000

 k-point     8 :       0.5000    0.5000    0.5000
  band No.  band energies     occupation 
      1     -32.6495      2.00000
      2     -32.5018      2.00000
      3     -30.5155      2.00000
      4     -30.3453      2.00000
      5     -30.2944      2.00000
      6     -30.2605      2.00000
      7     -30.2220      2.00000
      8     -19.8147      2.00000
      9     -17.2733      2.00000
     10     -15.9685      2.00000
     11     -14.4639      2.00000
     12     -14.4546      2.00000
     13     -14.3361      2.00000
     14     -14.0177      2.00000
     15     -13.6998      2.00000
     16     -13.1512      2.00000
     17     -12.2926      2.00000
     18     -10.7649      2.00000
     19     -10.7415      2.00000
     20     -10.6295      2.00000
     21     -10.5488      2.00000
     22     -10.1317      2.00000
     23     -10.0968      2.00000
     24      -9.8819      2.00000
     25      -9.7255      2.00000
     26      -9.5426      2.00000
     27      -9.4024      2.00000
     28      -9.1882      2.00000
     29      -9.0606      2.00000
     30      -8.3755      2.00000
     31      -8.1326      2.00000
     32      -5.5527      0.84023
     33      -0.0106      0.00000
     34       0.9171      0.00000
     35       1.4425      0.00000
     36       1.5043      0.00000
     37       1.6085      0.00000
     38       1.8059      0.00000
     39       1.9783      0.00000
     40       2.1732      0.00000


--------------------------------------------------------------------------------------------------------


 soft charge-density along one line, spin component           1
         0         1         2         3         4         5         6         7         8         9
 total charge-density along one line
 
 pseudopotential strength for first ion, spin component:           1
 10.565  14.059  -0.007   0.005  -0.003   0.020  -0.016   0.009
 14.059  18.707  -0.009   0.007  -0.004   0.026  -0.021   0.012
 -0.007  -0.009  -4.689  -0.006   0.004   9.192   0.013  -0.008
  0.005   0.007  -0.006  -4.692  -0.003   0.013   9.198   0.006
 -0.003  -0.004   0.004  -0.003  -4.696  -0.008   0.006   9.205
  0.020   0.026   9.192   0.013  -0.008 -20.177  -0.025   0.015
 -0.016  -0.021   0.013   9.198   0.006  -0.025 -20.190  -0.013
  0.009   0.012  -0.008   0.006   9.205   0.015  -0.013 -20.202
 total augmentation occupancy for first ion, spin component:           1
  7.574  -3.647  -0.187   0.150  -0.092  -0.052   0.041  -0.025
 -3.647   1.996   0.221  -0.176   0.105   0.038  -0.030   0.018
 -0.187   0.221   1.483  -0.087   0.054   0.133   0.008  -0.004
  0.150  -0.176  -0.087   1.430  -0.041   0.008   0.136   0.004
 -0.092   0.105   0.054  -0.041   1.387  -0.004   0.004   0.140
 -0.052   0.038   0.133   0.008  -0.004   0.015   0.003  -0.002
  0.041  -0.030   0.008   0.136   0.004   0.003   0.017   0.001
 -0.025   0.018  -0.004   0.004   0.140  -0.002   0.001   0.018


------------------------ aborting loop because EDIFF is reached ----------------------------------------



  FORCE on cell =-STRESS in cart. coord.  units (eV):
  Direction    XX          YY          ZZ          XY          YZ          ZX
  --------------------------------------------------------------------------------------
  Alpha Z    23.83308    23.83308    23.83308
  Ewald     -56.00946   598.61635  1113.12587   139.86365  -330.34506  -204.65973
  Hartree  1425.86841  2112.13856  2544.90850   145.65411  -297.17678  -261.32606
  E(xc)    -329.68555  -329.69087  -329.52100    -0.07834     0.09021     0.44104
  Local   -2242.98444 -3585.23337 -4519.66019  -293.01999   634.89277   495.18367
  n-local  -294.01460  -295.24330  -294.15944    -0.37771    -0.56255     1.07097
  augment   123.92536   124.38196   122.63930     1.00526    -0.71526    -3.62928
  Kinetic  1340.65163  1342.75408  1330.57448     6.84263    -5.98038   -26.66207
  Fock        0.00000     0.00000     0.00000     0.00000     0.00000     0.00000
  -------------------------------------------------------------------------------------
  Total       -8.4155929     -8.4435105     -8.2594129     -0.1103803      0.2029486      0.4185391
  in kB      -21.0676128    -21.1375018    -20.6766314     -0.2763263      0.5080619      1.0477716
  external PRESSURE =     -20.9605820 kB  Pullay stress =       0.0000000 kB


 VOLUME and BASIS-vectors are now :
 -----------------------------------------------------------------------------
  energy-cutoff  :      400.00
  volume of cell :      640.00
      direct lattice vectors                 reciprocal lattice vectors
    10.000000000  0.000000000  0.000000000     0.100000000  0.000000000  0.000000000
     0.000000000  8.000000000  0.000000000     0.000000000  0.125000000  0.000000000
     0.000000000  0.000000000  8.000000000     0.000000000  0.000000000  0.125000000

  length of vectors
    10.000000000  8.000000000  8.000000000     0.100000000  0.125000000  0.125000000


 FORCES acting on ions
    electron-ion (+dipol)            ewald-force                    non-local-force                 convergence-correction
 -----------------------------------------------------------------------------------------------
   0.494E+02 -.930E+01 -.400E+02   -.462E+02 0.162E+02 0.346E+02   -.315E+01 -.682E+01 0.538E+01   0.282E-03 -.299E-04 -.165E-04
   0.142E+02 -.141E+03 -.816E+02   -.927E+01 0.141E+03 0.876E+02   -.490E+01 -.279E+00 -.608E+01   0.362E-03 -.228E-03 0.963E-05
   -.490E+02 -.421E+02 0.106E+02   0.407E+02 0.431E+02 -.645E+01   0.822E+01 -.943E+00 -.410E+01   -.139E-03 -.167E-03 -.996E-04
   0.400E+03 -.223E+03 0.292E+03   -.436E+03 0.234E+03 -.329E+03   0.367E+02 -.117E+02 0.369E+02   0.624E-03 -.209E-03 -.386E-03
   0.520E+03 -.838E+02 -.257E+03   -.570E+03 0.962E+02 0.279E+03   0.495E+02 -.125E+02 -.218E+02   0.149E-02 -.147E-03 -.182E-03
   0.182E+03 0.480E+03 0.172E+03   -.189E+03 -.527E+03 -.202E+03   0.676E+01 0.468E+02 0.297E+02   0.796E-03 0.542E-03 -.171E-04
   -.239E+03 -.427E+03 0.272E+03   0.253E+03 0.472E+03 -.300E+03   -.142E+02 -.454E+02 0.281E+02   -.827E-03 -.674E-03 0.318E-03
   -.511E+03 0.338E+02 -.266E+03   0.552E+03 -.439E+02 0.303E+03   -.407E+02 0.101E+02 -.366E+02   -.153E-02 0.446E-04 -.663E-03
   -.143E+03 0.346E+03 0.393E+03   0.142E+03 -.389E+03 -.430E+03   0.104E+01 0.423E+02 0.371E+02   -.435E-03 0.264E-03 0.175E-03
   -.222E+03 0.141E+03 -.447E+03   0.257E+03 -.152E+03 0.489E+03   -.345E+02 0.111E+02 -.422E+02   -.271E-03 0.282E-03 -.349E-03
   0.120E+01 -.870E+02 -.578E+02   -.650E+00 0.918E+02 0.612E+02   -.514E+00 -.457E+01 -.346E+01   0.684E-04 -.101E-04 -.702E-05
   -.721E+01 -.167E+02 -.125E+02   0.722E+01 0.168E+02 0.125E+02   -.373E-01 -.127E+00 0.273E-01   -.156E-04 -.162E-04 -.411E-04
 -----------------------------------------------------------------------------------------------
   -.429E+01 -.280E+02 -.229E+02   -.711E-13 0.213E-13 -.218E-12   0.429E+01 0.280E+02 0.229E+02   0.397E-03 -.349E-03 -.126E-02
 
 
 POSITION                                       TOTAL-FORCE (eV/Angst)
 -----------------------------------------------------------------------------------
      3.85221      3.37885      4.33542         0.007912      0.042369     -0.028479
      4.36089      4.55963      3.48462        -0.008120     -0.039739     -0.032828
      5.71783      4.34236      2.78391        -0.041036      0.011211      0.021553
      3.41228      4.84264      2.51652         0.022797     -0.034473      0.011657
      2.64638      3.70359      4.86712        -0.014706     -0.017288     -0.005408
      3.70064      2.24535      3.60899        -0.007260     -0.032407      0.012105
      6.05190      5.47161      2.10521        -0.009145     -0.005188     -0.018644
      6.69351      4.09763      3.69541         0.011763     -0.008251     -0.007297
      5.68273      3.31808      1.90081         0.021787     -0.017109     -0.012490
      4.70852      3.12548      5.35786         0.000534     -0.023452      0.006268
      4.46795      5.43568      4.15268         0.039631      0.152003      0.023401
      5.08706      7.41810      4.01153        -0.024157     -0.027678      0.030163
 -----------------------------------------------------------------------------------
    total drift:                               -0.001708     -0.004517     -0.003500


--------------------------------------------------------------------------------------------------------



  FREE ENERGIE OF THE ION-ELECTRON SYSTEM (eV)
  ---------------------------------------------------
  free  energy   TOTEN  =       -59.4144400312 eV

  energy  without entropy=      -59.3594373967  energy(sigma->0) =      -59.39610582
 


--------------------------------------------------------------------------------------------------------




--------------------------------------------------------------------------------------------------------



volume of typ            1:     0.9 %

volume of typ            2:     1.7 %

volume of typ            3:     0.0 %
 
total charge     
 
# of ion       s       p       d       tot
------------------------------------------
    1        0.654   1.299   0.111   2.065
    2        0.675   1.419   0.051   2.144
    3        0.654   1.299   0.111   2.065
    4        1.480   3.714   0.011   5.204
    5        1.483   3.725   0.012   5.219
    6        1.483   3.725   0.012   5.220
    7        1.483   3.723   0.012   5.218
    8        1.483   3.725   0.012   5.219
    9        1.483   3.726   0.012   5.220
   10        1.483   3.725   0.012   5.219
   11        0.162   0.002   0.000   0.164
   12        0.097   0.000   0.000   0.097
--------------------------------------------------
tot          12.62   30.08    0.35   43.06