vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.10.21  20:23:53
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.32 0.77
   NPAR = 4

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  4       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.776  0.846  0.677-   2 2.23
   2  0.818  0.952  0.765-   1 2.23
   3  0.947  0.019  0.377-
   4  0.222  0.511  0.335-   6 1.47  12 1.62
   5  0.686  0.029  0.148-  24 1.54
   6  0.165  0.529  0.394-   4 1.47
   7  0.005  0.273  0.651-  21 0.98
   8  0.450  0.396  0.289-  13 0.97
   9  0.551  0.982  0.524-
  10  0.663  0.456  0.561-  32 0.99
  11  0.941  0.717  0.092-  37 1.00
  12  0.294  0.463  0.320-  25 0.99   4 1.62
  13  0.466  0.410  0.230-   8 0.97
  14  0.202  0.941  0.282-  40 1.15
  15  0.154  0.492  0.741-
  16  0.703  0.066  0.358-  27 0.73
  17  0.588  0.362  0.781-  33 0.76
  18  0.002  0.410  0.121-  38 1.07
  19  0.940  0.526  0.573-
  20  0.595  0.309  0.134-  34 0.76
  21  0.957  0.269  0.637-   7 0.98
  22  0.316  0.180  0.011-
  23  0.528  0.239  0.677-  41 1.15
  24  0.722  0.106  0.197-   5 1.54
  25  0.341  0.440  0.318-  12 0.99
  26  0.663  0.533  0.015-
  27  0.724  0.089  0.391-  16 0.73
  28  0.164  0.007  0.632-  43 1.15
  29  0.988  0.604  0.003-
  30  0.679  0.676  0.325-  42 1.15
  31  0.025  0.226  0.997-  39 1.05
  32  0.642  0.403  0.532-  10 0.99
  33  0.572  0.324  0.807-  17 0.76
  34  0.623  0.304  0.100-  20 0.76
  35  0.125  0.491  0.777-
  36  0.509  0.858  0.884-
  37  0.944  0.778  0.065-  11 1.00
  38  0.011  0.353  0.080-  18 1.07  39 1.24
  39  0.020  0.284  0.036-  31 1.05  38 1.24
  40  0.153  0.979  0.290-  14 1.15
  41  0.584  0.250  0.675-  23 1.15
  42  0.656  0.710  0.263-  30 1.15
  43  0.135  0.995  0.697-  28 1.15
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =    15.0000000000
 C/A-ratio  =     1.3333333333
  
  Lattice vectors:
  
 A1 = (   0.0000000000,  15.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  15.0000000000)
 A3 = (  20.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    4500.0000

  direct lattice vectors                    reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667

  position of ions in fractional coordinates (direct lattice)
     0.775538970  0.845821170  0.676762100
     0.817560050  0.951715680  0.765257510
     0.946953130  0.018571170  0.376973060
     0.222441800  0.510874960  0.335446970
     0.686377470  0.028754990  0.147898550
     0.164916400  0.529388190  0.394075690
     0.005019860  0.273007610  0.650795020
     0.449543690  0.395731540  0.288773850
     0.551004210  0.982298550  0.524087240
     0.662859430  0.456182880  0.560505730
     0.941408700  0.717023280  0.091731280
     0.294201770  0.463360150  0.320471920
     0.466294600  0.409883010  0.229635710
     0.201774800  0.940730960  0.281909030
     0.153666900  0.491784060  0.740565520
     0.703012330  0.066279800  0.357831750
     0.587677540  0.361864210  0.780644910
     0.001558570  0.410326790  0.121181870
     0.939859550  0.525780930  0.573259690
     0.595019580  0.309153460  0.134492370
     0.957206890  0.268974180  0.636505470
     0.316455350  0.179730580  0.010914720
     0.527706950  0.239330240  0.676610710
     0.721827260  0.106072690  0.196818220
     0.340537730  0.440291750  0.318015330
     0.662732330  0.532840280  0.014648410
     0.724037250  0.088632640  0.390502980
     0.164266330  0.006957420  0.631858690
     0.987674960  0.603789840  0.002986720
     0.678943050  0.675840780  0.324996280
     0.024898790  0.226193990  0.996719190
     0.641892170  0.403279590  0.532206240
     0.571527300  0.324187470  0.806521370
     0.622585360  0.303521750  0.099941260
     0.125336430  0.491079260  0.777009710
     0.509416780  0.858385180  0.883672230
     0.944316800  0.777958060  0.064977340
     0.010537010  0.353251140  0.079539700
     0.019660800  0.284091150  0.035804080
     0.152533740  0.979372680  0.289837840
     0.584423490  0.250322010  0.675290220
     0.655949510  0.709670990  0.263393430
     0.134569070  0.994597070  0.696570910

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34
                35          35
                36          36
                37          37
                38          38
                39          39
                40          40
                41          41
                42          42
                43          43

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    1    1    1

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     1.000000000  0.000000000  0.000000000
     0.000000000  0.066666667  0.000000000     0.000000000  1.000000000  0.000000000
     0.000000000  0.000000000  0.066666667     0.000000000  0.000000000  1.000000000

  Length of vectors
     0.050000000  0.066666667  0.066666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      1 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      1   k-points in BZ     NKDIM =      1   number of bands    NBANDS=     80
   number of dos      NEDOS =    301   number of ions     NIONS =     43
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 627200
   max r-space proj   IRMAX =   1586   max aug-charges    IRDMAX=   4859
   dimension x,y,z NGX =    98 NGY =   80 NGZ =   80
   dimension x,y,z NGXF=   196 NGYF=  160 NGZF=  160
   support grid    NGXF=   196 NGYF=  160 NGZF=  160
   ions per type =               5   7  25   6
   NGX,Y,Z   is equivalent  to a cutoff of   8.15,  8.87,  8.87 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.29, 17.73, 17.73 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  32.61 24.46 24.46*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.914E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00  1.00 12.01
  Ionic Valenz
   ZVAL   =   4.00  6.00  1.00  4.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.32  0.77
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =     111.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.31E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =     104.65       706.22
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.476553  0.900556  3.089927  0.227103
  Thomas-Fermi vector in A             =   1.472006
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           24
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     4500.00
      direct lattice vectors                 reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 position of ions in fractional coordinates (direct lattice) 
   0.77553897  0.84582117  0.67676210
   0.81756005  0.95171568  0.76525751
   0.94695313  0.01857117  0.37697306
   0.22244180  0.51087496  0.33544697
   0.68637747  0.02875499  0.14789855
   0.16491640  0.52938819  0.39407569
   0.00501986  0.27300761  0.65079502
   0.44954369  0.39573154  0.28877385
   0.55100421  0.98229855  0.52408724
   0.66285943  0.45618288  0.56050573
   0.94140870  0.71702328  0.09173128
   0.29420177  0.46336015  0.32047192
   0.46629460  0.40988301  0.22963571
   0.20177480  0.94073096  0.28190903
   0.15366690  0.49178406  0.74056552
   0.70301233  0.06627980  0.35783175
   0.58767754  0.36186421  0.78064491
   0.00155857  0.41032679  0.12118187
   0.93985955  0.52578093  0.57325969
   0.59501958  0.30915346  0.13449237
   0.95720689  0.26897418  0.63650547
   0.31645535  0.17973058  0.01091472
   0.52770695  0.23933024  0.67661071
   0.72182726  0.10607269  0.19681822
   0.34053773  0.44029175  0.31801533
   0.66273233  0.53284028  0.01464841
   0.72403725  0.08863264  0.39050298
   0.16426633  0.00695742  0.63185869
   0.98767496  0.60378984  0.00298672
   0.67894305  0.67584078  0.32499628
   0.02489879  0.22619399  0.99671919
   0.64189217  0.40327959  0.53220624
   0.57152730  0.32418747  0.80652137
   0.62258536  0.30352175  0.09994126
   0.12533643  0.49107926  0.77700971
   0.50941678  0.85838518  0.88367223
   0.94431680  0.77795806  0.06497734
   0.01053701  0.35325114  0.07953970
   0.01966080  0.28409115  0.03580408
   0.15253374  0.97937268  0.28983784
   0.58442349  0.25032201  0.67529022
   0.65594951  0.70967099  0.26339343
   0.13456907  0.99459707  0.69657091
 
 position of ions in cartesian coordinates  (Angst):
  15.51077940 12.68731755 10.15143150
  16.35120100 14.27573520 11.47886265
  18.93906260  0.27856755  5.65459590
   4.44883600  7.66312440  5.03170455
  13.72754940  0.43132485  2.21847825
   3.29832800  7.94082285  5.91113535
   0.10039720  4.09511415  9.76192530
   8.99087380  5.93597310  4.33160775
  11.02008420 14.73447825  7.86130860
  13.25718860  6.84274320  8.40758595
  18.82817400 10.75534920  1.37596920
   5.88403540  6.95040225  4.80707880
   9.32589200  6.14824515  3.44453565
   4.03549600 14.11096440  4.22863545
   3.07333800  7.37676090 11.10848280
  14.06024660  0.99419700  5.36747625
  11.75355080  5.42796315 11.70967365
   0.03117140  6.15490185  1.81772805
  18.79719100  7.88671395  8.59889535
  11.90039160  4.63730190  2.01738555
  19.14413780  4.03461270  9.54758205
   6.32910700  2.69595870  0.16372080
  10.55413900  3.58995360 10.14916065
  14.43654520  1.59109035  2.95227330
   6.81075460  6.60437625  4.77022995
  13.25464660  7.99260420  0.21972615
  14.48074500  1.32948960  5.85754470
   3.28532660  0.10436130  9.47788035
  19.75349920  9.05684760  0.04480080
  13.57886100 10.13761170  4.87494420
   0.49797580  3.39290985 14.95078785
  12.83784340  6.04919385  7.98309360
  11.43054600  4.86281205 12.09782055
  12.45170720  4.55282625  1.49911890
   2.50672860  7.36618890 11.65514565
  10.18833560 12.87577770 13.25508345
  18.88633600 11.66937090  0.97466010
   0.21074020  5.29876710  1.19309550
   0.39321600  4.26136725  0.53706120
   3.05067480 14.69059020  4.34756760
  11.68846980  3.75483015 10.12935330
  13.11899020 10.64506485  3.95090145
   2.69138140 14.91895605 10.44856365
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   81909

 maximum and minimum number of plane-waves per node :     81909    81909

 maximum number of plane-waves:     81909
 maximum index in each direction: 
   IXMAX=   32   IYMAX=   24   IZMAX=   24
   IXMIN=  -32   IYMIN=  -24   IZMIN=  -24

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to   140 to avoid them
 WARNING: aliasing errors must be expected set NGY to    98 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    98 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   222019. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       4015. kBytes
   fftplans  :      45166. kBytes
   grid      :     116408. kBytes
   one-center:        132. kBytes
   wavefun   :      26298. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 65   NGY = 49   NGZ = 49
  (NGX  =196   NGY  =160   NGZ  =160)
  gives a total of 156065 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron     111.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1494
 Maximum index for augmentation-charges         1154 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.107
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.6666416E+03  (-0.2630899E+04)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3617.36175582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       258.08905967
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.00012772
  eigenvalues    EBANDS =      -626.27511609
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       666.64159201 eV

  energy without entropy =      666.64171973  energy(sigma->0) =      666.64163459


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   264
 total energy-change (2. order) :-0.5834499E+03  (-0.5619913E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3617.36175582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       258.08905967
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.00057057
  eigenvalues    EBANDS =     -1209.72569545
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        83.19171095 eV

  energy without entropy =       83.19114038  energy(sigma->0) =       83.19152076


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.2323099E+03  (-0.2094727E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3617.36175582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       258.08905967
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.10308611
  eigenvalues    EBANDS =     -1442.13812949
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -149.11820755 eV

  energy without entropy =     -149.22129366  energy(sigma->0) =     -149.15256959


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.2790411E+02  (-0.2696032E+02)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3617.36175582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       258.08905967
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.15043090
  eigenvalues    EBANDS =     -1470.08958806
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -177.02232134 eV

  energy without entropy =     -177.17275224  energy(sigma->0) =     -177.07246497


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.5927339E+00  (-0.5871642E+00)
 number of electron     110.9999981 magnetization 
 augmentation part        5.2973595 magnetization 

 Broyden mixing:
  rms(total) = 0.34813E+01    rms(broyden)= 0.34780E+01
  rms(prec ) = 0.41294E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3617.36175582
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       258.08905967
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.12299375
  eigenvalues    EBANDS =     -1470.65488477
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -177.61505519 eV

  energy without entropy =     -177.73804894  energy(sigma->0) =     -177.65605311


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.3935961E+02  (-0.2042623E+02)
 number of electron     110.9999969 magnetization 
 augmentation part        0.7119453 magnetization 

 Broyden mixing:
  rms(total) = 0.66358E+01    rms(broyden)= 0.66271E+01
  rms(prec ) = 0.81002E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3159
  0.3159

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3873.53884405
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.35565250
  PAW double counting   =      4740.20352391    -4671.05763833
  entropy T*S    EENTRO =        -0.00190633
  eigenvalues    EBANDS =     -1267.38765167
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -216.97466702 eV

  energy without entropy =     -216.97276068  energy(sigma->0) =     -216.97403157


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) : 0.5631250E+02  (-0.4457821E+01)
 number of electron     110.9999982 magnetization 
 augmentation part        4.2723882 magnetization 

 Broyden mixing:
  rms(total) = 0.25611E+01    rms(broyden)= 0.25450E+01
  rms(prec ) = 0.32054E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4244
  0.6110  0.2378

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3778.83631249
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       270.19271258
  PAW double counting   =      4802.88003371    -4732.81368243
  entropy T*S    EENTRO =        -0.00142111
  eigenvalues    EBANDS =     -1302.53569689
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -160.66216966 eV

  energy without entropy =     -160.66074855  energy(sigma->0) =     -160.66169596


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.8596596E+01  (-0.8704210E+00)
 number of electron     111.0000002 magnetization 
 augmentation part        3.2911414 magnetization 

 Broyden mixing:
  rms(total) = 0.33949E+01    rms(broyden)= 0.33931E+01
  rms(prec ) = 0.41636E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3416
  0.6671  0.2523  0.1055

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3812.86972161
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       271.31802343
  PAW double counting   =      5103.73656589    -5034.02153486
  entropy T*S    EENTRO =         0.06329345
  eigenvalues    EBANDS =     -1260.74439699
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.06557372 eV

  energy without entropy =     -152.12886718  energy(sigma->0) =     -152.08667154


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.3694466E+01  (-0.3698769E+00)
 number of electron     110.9999998 magnetization 
 augmentation part        4.4853234 magnetization 

 Broyden mixing:
  rms(total) = 0.21022E+01    rms(broyden)= 0.20995E+01
  rms(prec ) = 0.26721E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3738
  0.8642  0.2663  0.2663  0.0983

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3813.88595028
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       271.59785196
  PAW double counting   =      5178.49006724    -5108.72826483
  entropy T*S    EENTRO =        -0.32759170
  eigenvalues    EBANDS =     -1255.96941667
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.37110731 eV

  energy without entropy =     -148.04351561  energy(sigma->0) =     -148.26191008


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3555939E+01  (-0.2397375E+01)
 number of electron     110.9999979 magnetization 
 augmentation part        4.1979222 magnetization 

 Broyden mixing:
  rms(total) = 0.17950E+01    rms(broyden)= 0.17940E+01
  rms(prec ) = 0.22746E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3927
  1.0271  0.3306  0.3306  0.1665  0.1088

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3836.04300814
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       273.12661163
  PAW double counting   =      5404.30449256    -5334.59732064
  entropy T*S    EENTRO =        -0.24349903
  eigenvalues    EBANDS =     -1231.81464118
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -144.81516784 eV

  energy without entropy =     -144.57166881  energy(sigma->0) =     -144.73400150


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.4162781E+00  (-0.2357460E+01)
 number of electron     110.9999991 magnetization 
 augmentation part        3.6463426 magnetization 

 Broyden mixing:
  rms(total) = 0.19572E+01    rms(broyden)= 0.19556E+01
  rms(prec ) = 0.26490E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4245
  1.3472  0.3662  0.3662  0.2375  0.1149  0.1149

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3858.64855347
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.24223250
  PAW double counting   =      5609.90739870    -5540.23550918
  entropy T*S    EENTRO =        -0.11744676
  eigenvalues    EBANDS =     -1209.99920854
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -144.39888977 eV

  energy without entropy =     -144.28144302  energy(sigma->0) =     -144.35974085


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1171016E+01  (-0.2005634E+01)
 number of electron     110.9999952 magnetization 
 augmentation part        2.2479880 magnetization 

 Broyden mixing:
  rms(total) = 0.35192E+01    rms(broyden)= 0.35113E+01
  rms(prec ) = 0.43780E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3781
  1.4061  0.3859  0.2724  0.2724  0.1165  0.1165  0.0768

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3877.43361643
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.42049138
  PAW double counting   =      5866.73889169    -5797.02889856
  entropy T*S    EENTRO =        -0.25734093
  eigenvalues    EBANDS =     -1193.46162982
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -145.56990570 eV

  energy without entropy =     -145.31256477  energy(sigma->0) =     -145.48412539


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.4870431E+01  (-0.1465085E+01)
 number of electron     110.9999971 magnetization 
 augmentation part        2.6781767 magnetization 

 Broyden mixing:
  rms(total) = 0.31697E+01    rms(broyden)= 0.31627E+01
  rms(prec ) = 0.39040E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3678
  1.5011  0.4388  0.2482  0.2482  0.1693  0.1693  0.0837  0.0837

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3870.95052570
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.45930259
  PAW double counting   =      5932.90470498    -5863.07888317
  entropy T*S    EENTRO =        -0.06126608
  eigenvalues    EBANDS =     -1195.42500405
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.69947447 eV

  energy without entropy =     -140.63820839  energy(sigma->0) =     -140.67905245


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.5604540E+00  (-0.1763887E+01)
 number of electron     110.9999977 magnetization 
 augmentation part        3.4924711 magnetization 

 Broyden mixing:
  rms(total) = 0.20562E+01    rms(broyden)= 0.20508E+01
  rms(prec ) = 0.26956E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3579
  1.5428  0.4790  0.2912  0.2912  0.2119  0.1515  0.1003  0.1003  0.0531

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3873.15694628
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.45684276
  PAW double counting   =      6014.78076695    -5944.87944521
  entropy T*S    EENTRO =        -0.32497329
  eigenvalues    EBANDS =     -1192.46746239
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.13902049 eV

  energy without entropy =     -139.81404721  energy(sigma->0) =     -140.03069607


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.8350245E+00  (-0.5101354E+00)
 number of electron     110.9999962 magnetization 
 augmentation part        3.3131573 magnetization 

 Broyden mixing:
  rms(total) = 0.27579E+01    rms(broyden)= 0.27524E+01
  rms(prec ) = 0.34020E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3838
  1.6078  0.7278  0.3925  0.3925  0.2524  0.1284  0.1284  0.0953  0.0622  0.0507

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3875.55855058
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.52826403
  PAW double counting   =      6067.06472327    -5997.12028888
  entropy T*S    EENTRO =        -0.30972542
  eigenvalues    EBANDS =     -1191.03066441
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.97404502 eV

  energy without entropy =     -140.66431960  energy(sigma->0) =     -140.87080321


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.1268291E+01  (-0.1790119E+00)
 number of electron     110.9999983 magnetization 
 augmentation part        3.9451048 magnetization 

 Broyden mixing:
  rms(total) = 0.15836E+01    rms(broyden)= 0.15786E+01
  rms(prec ) = 0.20635E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4040
  1.5909  1.1270  0.4796  0.3065  0.3065  0.1504  0.1504  0.1216  0.0984  0.0608
  0.0517

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3869.90207440
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.38874654
  PAW double counting   =      6150.91607654    -6080.78213021
  entropy T*S    EENTRO =        -0.09001528
  eigenvalues    EBANDS =     -1195.68855440
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -139.70575426 eV

  energy without entropy =     -139.61573897  energy(sigma->0) =     -139.67574916


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.1575092E+00  (-0.6079364E+00)
 number of electron     110.9999985 magnetization 
 augmentation part        4.3735216 magnetization 

 Broyden mixing:
  rms(total) = 0.19297E+01    rms(broyden)= 0.19285E+01
  rms(prec ) = 0.25292E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4244
  1.9392  1.1657  0.5589  0.3261  0.3261  0.2074  0.1381  0.1381  0.1003  0.0807
  0.0599  0.0520

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3865.81145872
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.12641020
  PAW double counting   =      6187.97491191    -6117.75299755
  entropy T*S    EENTRO =        -0.32655780
  eigenvalues    EBANDS =     -1199.52576845
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -139.86326344 eV

  energy without entropy =     -139.53670564  energy(sigma->0) =     -139.75441084


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.3255847E+00  (-0.1260964E+01)
 number of electron     110.9999958 magnetization 
 augmentation part        3.7589002 magnetization 

 Broyden mixing:
  rms(total) = 0.23802E+01    rms(broyden)= 0.23760E+01
  rms(prec ) = 0.30571E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4069
  2.0733  1.1076  0.5591  0.3437  0.3437  0.2382  0.1298  0.1298  0.1015  0.0811
  0.0719  0.0591  0.0514

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3873.22563303
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.53035766
  PAW double counting   =      6268.00540645    -6197.77834616
  entropy T*S    EENTRO =        -0.27605723
  eigenvalues    EBANDS =     -1192.89677281
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.18884816 eV

  energy without entropy =     -139.91279093  energy(sigma->0) =     -140.09682909


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.1629938E+01  (-0.5520790E+00)
 number of electron     110.9999988 magnetization 
 augmentation part        3.3849233 magnetization 

 Broyden mixing:
  rms(total) = 0.20894E+01    rms(broyden)= 0.20857E+01
  rms(prec ) = 0.26872E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3873
  2.1371  1.1239  0.5084  0.3602  0.3602  0.2485  0.1285  0.1285  0.0970  0.0826
  0.0826  0.0572  0.0572  0.0501

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3878.09483900
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.84787259
  PAW double counting   =      6307.76953239    -6237.54896291
  entropy T*S    EENTRO =        -0.30878586
  eigenvalues    EBANDS =     -1186.67592475
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -138.55891057 eV

  energy without entropy =     -138.25012472  energy(sigma->0) =     -138.45598195


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.8663310E+00  (-0.7457582E-01)
 number of electron     110.9999979 magnetization 
 augmentation part        3.3785801 magnetization 

 Broyden mixing:
  rms(total) = 0.97492E+00    rms(broyden)= 0.97325E+00
  rms(prec ) = 0.12667E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3782
  2.1555  1.1722  0.5224  0.3671  0.3671  0.2407  0.1367  0.1367  0.1140  0.1140
  0.0892  0.0892  0.0597  0.0597  0.0498

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.94019508
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.83903317
  PAW double counting   =      6330.27230432    -6260.05125368
  entropy T*S    EENTRO =        -0.73540377
  eigenvalues    EBANDS =     -1182.52926154
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.69257961 eV

  energy without entropy =     -136.95717584  energy(sigma->0) =     -137.44744502


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1070663E+00  (-0.7974029E-01)
 number of electron     110.9999990 magnetization 
 augmentation part        2.8720740 magnetization 

 Broyden mixing:
  rms(total) = 0.19368E+01    rms(broyden)= 0.19353E+01
  rms(prec ) = 0.23799E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3608
  2.1544  1.1831  0.5091  0.3766  0.3766  0.2423  0.1599  0.1599  0.1175  0.1175
  0.0886  0.0886  0.0611  0.0611  0.0501  0.0257

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.87297877
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.84991058
  PAW double counting   =      6339.17641477    -6268.94216366
  entropy T*S    EENTRO =        -0.89432426
  eigenvalues    EBANDS =     -1181.56870150
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.79964588 eV

  energy without entropy =     -136.90532161  energy(sigma->0) =     -137.50153779


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.3321839E+00  (-0.6215583E-01)
 number of electron     110.9999975 magnetization 
 augmentation part        2.9846088 magnetization 

 Broyden mixing:
  rms(total) = 0.10770E+01    rms(broyden)= 0.10761E+01
  rms(prec ) = 0.13245E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3609
  2.1780  1.2515  0.5634  0.3640  0.3640  0.2499  0.2499  0.1642  0.1368  0.1368
  0.1017  0.0809  0.0809  0.0637  0.0637  0.0504  0.0358

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.73878942
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.89082425
  PAW double counting   =      6339.77985879    -6269.52941202
  entropy T*S    EENTRO =        -0.94267360
  eigenvalues    EBANDS =     -1181.37946691
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.46746194 eV

  energy without entropy =     -136.52478834  energy(sigma->0) =     -137.15323741


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3255953E-02  (-0.1239241E+00)
 number of electron     110.9999980 magnetization 
 augmentation part        3.4645533 magnetization 

 Broyden mixing:
  rms(total) = 0.83930E+00    rms(broyden)= 0.83786E+00
  rms(prec ) = 0.10366E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3565
  2.1740  1.2017  0.7395  0.3428  0.3428  0.2906  0.2906  0.1954  0.1419  0.1419
  0.1117  0.0823  0.0823  0.0691  0.0634  0.0634  0.0503  0.0340

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.78346824
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.72408644
  PAW double counting   =      6342.09640691    -6271.81418841
  entropy T*S    EENTRO =        -0.87750350
  eigenvalues    EBANDS =     -1182.26173616
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.46420599 eV

  energy without entropy =     -136.58670249  energy(sigma->0) =     -137.17170482


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.2702130E+00  (-0.1437983E+00)
 number of electron     110.9999986 magnetization 
 augmentation part        3.9183868 magnetization 

 Broyden mixing:
  rms(total) = 0.12241E+01    rms(broyden)= 0.12205E+01
  rms(prec ) = 0.15827E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3584
  2.1444  1.0170  1.0170  0.4089  0.4089  0.3025  0.2969  0.2969  0.1350  0.1350
  0.1145  0.0903  0.0903  0.0883  0.0502  0.0599  0.0599  0.0595  0.0344

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3879.24729742
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.63148577
  PAW double counting   =      6338.20265451    -6267.90414428
  entropy T*S    EENTRO =        -0.54707855
  eigenvalues    EBANDS =     -1184.32223598
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.73441899 eV

  energy without entropy =     -137.18734044  energy(sigma->0) =     -137.55205948


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.1149194E+00  (-0.8774384E-01)
 number of electron     110.9999992 magnetization 
 augmentation part        3.5729750 magnetization 

 Broyden mixing:
  rms(total) = 0.16050E+01    rms(broyden)= 0.16042E+01
  rms(prec ) = 0.20364E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3729
  2.1467  1.0982  1.0982  0.7625  0.3594  0.3594  0.2877  0.2877  0.1498  0.1498
  0.1211  0.1211  0.0846  0.0846  0.0807  0.0610  0.0610  0.0504  0.0588  0.0342

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3879.37547019
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.63895773
  PAW double counting   =      6334.17424998    -6263.87717409
  entropy T*S    EENTRO =        -0.51877416
  eigenvalues    EBANDS =     -1184.34332463
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.84933839 eV

  energy without entropy =     -137.33056423  energy(sigma->0) =     -137.67641367


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.3309751E+00  (-0.1601275E+00)
 number of electron     110.9999979 magnetization 
 augmentation part        3.1239459 magnetization 

 Broyden mixing:
  rms(total) = 0.12259E+01    rms(broyden)= 0.12238E+01
  rms(prec ) = 0.15104E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3872
  2.1560  1.7483  0.8913  0.8913  0.3620  0.3620  0.2749  0.2749  0.1603  0.1603
  0.1301  0.1301  0.0898  0.0850  0.0850  0.0659  0.0618  0.0618  0.0504  0.0556
  0.0342

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.32173892
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.70961910
  PAW double counting   =      6340.60788761    -6270.29443630
  entropy T*S    EENTRO =        -0.76640426
  eigenvalues    EBANDS =     -1181.90548750
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.51836330 eV

  energy without entropy =     -136.75195904  energy(sigma->0) =     -137.26289521


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.5525874E-02  (-0.6169974E-01)
 number of electron     110.9999974 magnetization 
 augmentation part        3.4551574 magnetization 

 Broyden mixing:
  rms(total) = 0.61543E+00    rms(broyden)= 0.61456E+00
  rms(prec ) = 0.79796E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3831
  2.1173  1.8751  0.9361  0.9361  0.3653  0.3653  0.3076  0.2227  0.2227  0.1433
  0.1318  0.1318  0.0958  0.0848  0.0848  0.0765  0.0701  0.0618  0.0618  0.0504
  0.0536  0.0343

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.32741261
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.57114194
  PAW double counting   =      6339.66035202    -6269.32072225
  entropy T*S    EENTRO =        -0.84521747
  eigenvalues    EBANDS =     -1182.71422775
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.52388917 eV

  energy without entropy =     -136.67867170  energy(sigma->0) =     -137.24215001


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.1018475E-01  (-0.4408234E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.5637349 magnetization 

 Broyden mixing:
  rms(total) = 0.82156E+00    rms(broyden)= 0.82009E+00
  rms(prec ) = 0.10158E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3708
  2.1556  1.7800  1.1059  0.6654  0.4206  0.3594  0.3594  0.2389  0.2389  0.1500
  0.1500  0.1295  0.1295  0.0894  0.0843  0.0843  0.0794  0.0617  0.0617  0.0543
  0.0504  0.0342  0.0454

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.81554533
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.55996743
  PAW double counting   =      6340.26290756    -6269.91972507
  entropy T*S    EENTRO =        -0.66900943
  eigenvalues    EBANDS =     -1182.40486605
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.53407392 eV

  energy without entropy =     -136.86506449  energy(sigma->0) =     -137.31107078


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.6021692E-01  (-0.3165215E-01)
 number of electron     110.9999979 magnetization 
 augmentation part        3.6552851 magnetization 

 Broyden mixing:
  rms(total) = 0.39729E+00    rms(broyden)= 0.39596E+00
  rms(prec ) = 0.52534E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3614
  2.2430  1.3864  1.3864  0.5388  0.5388  0.3536  0.3536  0.2680  0.2267  0.2267
  0.1359  0.1359  0.1207  0.1207  0.0891  0.0845  0.0845  0.0706  0.0626  0.0626
  0.0342  0.0505  0.0505  0.0500

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.16554940
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.54679362
  PAW double counting   =      6337.31781733    -6266.97377541
  entropy T*S    EENTRO =        -0.69073166
  eigenvalues    EBANDS =     -1182.96060844
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.47385700 eV

  energy without entropy =     -136.78312534  energy(sigma->0) =     -137.24361311


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1464458E-01  (-0.3883969E-02)
 number of electron     110.9999980 magnetization 
 augmentation part        3.5469738 magnetization 

 Broyden mixing:
  rms(total) = 0.30236E+00    rms(broyden)= 0.30208E+00
  rms(prec ) = 0.40634E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3869
  2.2486  1.9329  0.9729  0.9729  0.5200  0.5200  0.3510  0.3510  0.2661  0.2661
  0.1512  0.1512  0.1279  0.1279  0.0902  0.0834  0.0834  0.0807  0.0666  0.0621
  0.0621  0.0342  0.0521  0.0504  0.0480

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.82833747
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.55446845
  PAW double counting   =      6340.58367885    -6270.24373306
  entropy T*S    EENTRO =        -0.77602918
  eigenvalues    EBANDS =     -1182.23074613
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.48850158 eV

  energy without entropy =     -136.71247239  energy(sigma->0) =     -137.22982518


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.2579335E-01  (-0.2796421E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.2300068 magnetization 

 Broyden mixing:
  rms(total) = 0.51729E+00    rms(broyden)= 0.51582E+00
  rms(prec ) = 0.62817E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4121
  2.0043  2.0043  1.4231  1.2274  0.5524  0.5524  0.4475  0.3647  0.3647  0.2479
  0.2479  0.1511  0.1511  0.1294  0.1294  0.0939  0.0838  0.0838  0.0802  0.0670
  0.0621  0.0621  0.0342  0.0520  0.0505  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.66747677
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.54658301
  PAW double counting   =      6340.57548597    -6270.22606721
  entropy T*S    EENTRO =        -0.94060686
  eigenvalues    EBANDS =     -1181.25441005
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.51429493 eV

  energy without entropy =     -136.57368807  energy(sigma->0) =     -137.20075931


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.1432100E+00  (-0.4825048E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.7685927 magnetization 

 Broyden mixing:
  rms(total) = 0.99633E+00    rms(broyden)= 0.99526E+00
  rms(prec ) = 0.12420E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4185
  2.3046  2.3046  1.3297  0.9072  0.6344  0.6344  0.3615  0.3615  0.3446  0.3446
  0.2433  0.2433  0.1539  0.1539  0.1300  0.1300  0.0938  0.0838  0.0838  0.0801
  0.0670  0.0621  0.0621  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3880.07024773
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.46918147
  PAW double counting   =      6334.35124747    -6263.98261073
  entropy T*S    EENTRO =        -0.58425329
  eigenvalues    EBANDS =     -1183.29301911
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.65750496 eV

  energy without entropy =     -137.07325166  energy(sigma->0) =     -137.46275386


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.1652494E+00  (-0.4060231E-01)
 number of electron     110.9999978 magnetization 
 augmentation part        3.4937639 magnetization 

 Broyden mixing:
  rms(total) = 0.17927E+00    rms(broyden)= 0.17739E+00
  rms(prec ) = 0.24246E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4243
  2.3237  2.3237  1.5053  0.9306  0.5757  0.5757  0.4284  0.4284  0.3690  0.3690
  0.2734  0.2734  0.2176  0.1548  0.1548  0.1299  0.1299  0.0939  0.0838  0.0838
  0.0801  0.0670  0.0621  0.0621  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.20550681
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.50407354
  PAW double counting   =      6337.17563062    -6266.81735081
  entropy T*S    EENTRO =        -0.84848268
  eigenvalues    EBANDS =     -1181.75281637
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.49225556 eV

  energy without entropy =     -136.64377288  energy(sigma->0) =     -137.20942800


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.6952606E-01  (-0.1675813E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.6278357 magnetization 

 Broyden mixing:
  rms(total) = 0.71324E+00    rms(broyden)= 0.71290E+00
  rms(prec ) = 0.87300E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4382
  2.4971  2.4971  1.5089  0.7799  0.7799  0.5675  0.4672  0.4672  0.3688  0.3688
  0.3310  0.3310  0.2275  0.2275  0.1550  0.1550  0.1300  0.1300  0.0939  0.0838
  0.0838  0.0801  0.0670  0.0621  0.0621  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.02243002
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.47528519
  PAW double counting   =      6336.01170622    -6265.65004976
  entropy T*S    EENTRO =        -0.75846074
  eigenvalues    EBANDS =     -1182.07002948
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.56178162 eV

  energy without entropy =     -136.80332088  energy(sigma->0) =     -137.30896137


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.4135055E-01  (-0.1025778E-01)
 number of electron     110.9999978 magnetization 
 augmentation part        3.5546749 magnetization 

 Broyden mixing:
  rms(total) = 0.20505E+00    rms(broyden)= 0.20372E+00
  rms(prec ) = 0.25431E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4432
  2.3369  2.3369  1.6466  0.8719  0.8719  0.7074  0.7074  0.3728  0.3728  0.3825
  0.3825  0.2831  0.2831  0.2256  0.2256  0.1551  0.1551  0.1300  0.1300  0.0939
  0.0838  0.0838  0.0801  0.0670  0.0621  0.0621  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.11773301
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.47139281
  PAW double counting   =      6334.53127390    -6264.17021665
  entropy T*S    EENTRO =        -0.78575394
  eigenvalues    EBANDS =     -1181.90159115
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.52043107 eV

  energy without entropy =     -136.73467713  energy(sigma->0) =     -137.25851309


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1171068E-01  (-0.3393296E-02)
 number of electron     110.9999977 magnetization 
 augmentation part        3.4107109 magnetization 

 Broyden mixing:
  rms(total) = 0.18656E+00    rms(broyden)= 0.18578E+00
  rms(prec ) = 0.24585E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4809
  2.9825  2.5798  1.9483  1.0909  0.7522  0.7522  0.5608  0.5608  0.3762  0.3762
  0.3691  0.3691  0.2659  0.2659  0.1894  0.1812  0.1553  0.1553  0.1300  0.1300
  0.0939  0.0838  0.0838  0.0801  0.0670  0.0621  0.0621  0.0342  0.0520  0.0504
  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.52256773
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.48330967
  PAW double counting   =      6336.53166629    -6266.17145288
  entropy T*S    EENTRO =        -0.88793784
  eigenvalues    EBANDS =     -1181.41735622
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.53214175 eV

  energy without entropy =     -136.64420391  energy(sigma->0) =     -137.23616247


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.6896695E-02  (-0.7712047E-02)
 number of electron     110.9999978 magnetization 
 augmentation part        3.5501456 magnetization 

 Broyden mixing:
  rms(total) = 0.16220E+00    rms(broyden)= 0.16160E+00
  rms(prec ) = 0.21680E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5057
  3.8593  2.3479  1.8840  1.1601  0.8199  0.8199  0.8447  0.4167  0.4167  0.3752
  0.3752  0.3486  0.3486  0.2600  0.2600  0.1842  0.1737  0.1555  0.1555  0.1300
  0.1300  0.0939  0.0838  0.0838  0.0801  0.0670  0.0621  0.0621  0.0342  0.0520
  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.25668753
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.44949997
  PAW double counting   =      6335.66564271    -6265.30165132
  entropy T*S    EENTRO =        -0.82613739
  eigenvalues    EBANDS =     -1181.72190186
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.53903845 eV

  energy without entropy =     -136.71290105  energy(sigma->0) =     -137.26365931


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.2116241E-02  (-0.3769537E-02)
 number of electron     110.9999979 magnetization 
 augmentation part        3.5015743 magnetization 

 Broyden mixing:
  rms(total) = 0.11279E+00    rms(broyden)= 0.11262E+00
  rms(prec ) = 0.14178E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5096
  3.9866  2.3397  1.8582  1.3263  0.7979  0.7512  0.7512  0.4506  0.4506  0.4440
  0.4440  0.3699  0.3699  0.2855  0.2855  0.2561  0.2042  0.1554  0.1554  0.1572
  0.1300  0.1300  0.0939  0.0838  0.0838  0.0801  0.0670  0.0621  0.0621  0.0342
  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.32171822
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.44481798
  PAW double counting   =      6335.33276361    -6264.96655458
  entropy T*S    EENTRO =        -0.83134925
  eigenvalues    EBANDS =     -1181.65131119
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.54115469 eV

  energy without entropy =     -136.70980544  energy(sigma->0) =     -137.26403827


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.1378469E-02  (-0.1716023E-02)
 number of electron     110.9999978 magnetization 
 augmentation part        3.4723150 magnetization 

 Broyden mixing:
  rms(total) = 0.10579E+00    rms(broyden)= 0.10534E+00
  rms(prec ) = 0.13511E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5386
  4.1462  2.4641  2.1118  1.2070  0.9870  0.9870  0.6760  0.6760  0.6494  0.4048
  0.3741  0.3741  0.3947  0.3947  0.2871  0.2871  0.2421  0.2008  0.1554  0.1554
  0.1601  0.1300  0.1300  0.0939  0.0838  0.0838  0.0801  0.0670  0.0621  0.0621
  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.50776225
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.44749494
  PAW double counting   =      6336.03250411    -6265.66886461
  entropy T*S    EENTRO =        -0.85375423
  eigenvalues    EBANDS =     -1181.44434808
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.54253316 eV

  energy without entropy =     -136.68877892  energy(sigma->0) =     -137.25794841


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.4005037E-02  (-0.8500965E-03)
 number of electron     110.9999978 magnetization 
 augmentation part        3.4627487 magnetization 

 Broyden mixing:
  rms(total) = 0.58103E-01    rms(broyden)= 0.57856E-01
  rms(prec ) = 0.71771E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5794
  4.8323  2.6935  2.2630  1.2565  1.2565  1.1329  0.6816  0.6380  0.6380  0.4265
  0.4265  0.4110  0.4110  0.3731  0.3731  0.2858  0.2858  0.2445  0.2007  0.1554
  0.1554  0.1600  0.1300  0.1300  0.0939  0.0838  0.0838  0.0801  0.0670  0.0621
  0.0621  0.0342  0.0520  0.0504  0.0481

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =      -165.02654505
  -Hartree energ DENC   =     -3881.50394001
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.44043418
  PAW double counting   =      6336.45113054    -6266.08673503
  entropy T*S    EENTRO =        -0.86266704
  eigenvalues    EBANDS =     -1181.43695781
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.54653819 eV

  energy without entropy =     -136.68387116  energy(sigma->0) =     -137.25898251


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  41)  ---------------------------------------