vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.10.21  20:23:53
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.32 0.77
   NPAR = 4

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  4       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.711  0.186  0.567-  39 1.87
   2  0.431  0.687  0.903-
   3  0.546  0.076  0.515-  14 1.58  39 1.91
   4  0.700  0.355  0.986-   8 1.46  35 1.67
   5  0.188  0.708  0.369-   6 1.53
   6  0.125  0.650  0.371-   5 1.53
   7  0.027  0.313  0.479-  26 0.99  43 1.19
   8  0.683  0.446  0.011-   4 1.46
   9  0.230  0.149  0.145-
  10  0.295  0.920  0.103-
  11  0.288  0.167  0.683-  27 1.00  40 1.29
  12  0.299  0.847  0.409-
  13  0.491  0.384  0.448-  41 1.06
  14  0.571  0.976  0.508-   3 1.58
  15  0.223  0.392  0.653-
  16  0.309  0.781  0.146-  42 1.12
  17  0.605  0.100  0.596-  39 1.18
  18  0.789  0.699  0.900-  32 0.75
  19  0.027  0.316  0.180-  31 0.74
  20  0.894  0.459  0.725-
  21  0.811  0.743  0.448-
  22  0.216  0.261  0.761-
  23  0.583  0.743  0.436-  25 0.74
  24  0.748  0.280  0.453-
  25  0.555  0.712  0.424-  23 0.74
  26  0.022  0.289  0.541-   7 0.99
  27  0.251  0.128  0.660-  11 1.00
  28  0.890  0.742  0.123-
  29  0.211  0.311  0.752-
  30  0.677  0.077  0.513-  39 1.15
  31  0.025  0.347  0.218-  19 0.74
  32  0.817  0.667  0.893-  18 0.75
  33  0.957  0.575  0.140-
  34  0.975  0.993  0.070-
  35  0.718  0.318  0.884-   4 1.67
  36  0.254  0.350  0.131-
  37  0.048  0.437  0.924-
  38  0.413  0.474  0.377-  41 1.29
  39  0.634  0.124  0.532-  30 1.15  17 1.18   1 1.87   3 1.91
  40  0.348  0.134  0.676-  11 1.29
  41  0.453  0.415  0.409-  13 1.06  38 1.29
  42  0.286  0.745  0.204-  16 1.12
  43  0.981  0.353  0.447-   7 1.19
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =    15.0000000000
 C/A-ratio  =     1.3333333333
  
  Lattice vectors:
  
 A1 = (   0.0000000000,  15.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  15.0000000000)
 A3 = (  20.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    4500.0000

  direct lattice vectors                    reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667

  position of ions in fractional coordinates (direct lattice)
     0.711152620  0.185780860  0.566845690
     0.431327670  0.687448710  0.903133360
     0.546464640  0.075971960  0.514672780
     0.700459610  0.354509870  0.985860960
     0.188019390  0.707981900  0.369444900
     0.124783090  0.650337960  0.370748980
     0.026629160  0.313270680  0.479256520
     0.682807190  0.445502720  0.011383300
     0.230476440  0.148876720  0.144831720
     0.294533340  0.920151150  0.103236310
     0.288297050  0.166950130  0.682719570
     0.299024030  0.846837960  0.408546390
     0.490983980  0.383940210  0.447863480
     0.570507930  0.975854690  0.508422500
     0.222783100  0.391973620  0.653397680
     0.309114930  0.780570340  0.145989750
     0.605372890  0.100467490  0.596433860
     0.788801890  0.698564600  0.899830340
     0.026506010  0.316227720  0.179508300
     0.893569770  0.458507500  0.725254130
     0.811144330  0.742562570  0.447976500
     0.216417190  0.260700710  0.760657400
     0.582839540  0.742869320  0.436036330
     0.747661900  0.279958080  0.453143810
     0.555386280  0.711859010  0.423724660
     0.021709720  0.289299920  0.540567140
     0.251217900  0.128043040  0.660118790
     0.889765050  0.741942190  0.123093820
     0.211220630  0.310962450  0.752082250
     0.677104660  0.077009130  0.513208770
     0.025378140  0.347477860  0.217790550
     0.817312170  0.666731090  0.893231770
     0.957327890  0.575444100  0.139609190
     0.975480310  0.993126120  0.070168360
     0.718412560  0.317830680  0.883709680
     0.254405270  0.349666230  0.131091140
     0.048385800  0.437149790  0.924216960
     0.412734210  0.474271100  0.377235910
     0.633879620  0.124308880  0.531837070
     0.347917930  0.134198760  0.676351520
     0.452958960  0.414754630  0.409228100
     0.286367650  0.745092640  0.203911640
     0.981057670  0.352722860  0.447357810

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34
                35          35
                36          36
                37          37
                38          38
                39          39
                40          40
                41          41
                42          42
                43          43

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    1    1    1

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     1.000000000  0.000000000  0.000000000
     0.000000000  0.066666667  0.000000000     0.000000000  1.000000000  0.000000000
     0.000000000  0.000000000  0.066666667     0.000000000  0.000000000  1.000000000

  Length of vectors
     0.050000000  0.066666667  0.066666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      1 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      1   k-points in BZ     NKDIM =      1   number of bands    NBANDS=     80
   number of dos      NEDOS =    301   number of ions     NIONS =     43
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 627200
   max r-space proj   IRMAX =   1586   max aug-charges    IRDMAX=   4859
   dimension x,y,z NGX =    98 NGY =   80 NGZ =   80
   dimension x,y,z NGXF=   196 NGYF=  160 NGZF=  160
   support grid    NGXF=   196 NGYF=  160 NGZF=  160
   ions per type =               5   7  25   6
   NGX,Y,Z   is equivalent  to a cutoff of   8.15,  8.87,  8.87 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.29, 17.73, 17.73 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  32.61 24.46 24.46*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.914E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00  1.00 12.01
  Ionic Valenz
   ZVAL   =   4.00  6.00  1.00  4.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.32  0.77
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =     111.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.31E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =     104.65       706.22
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.476553  0.900556  3.089927  0.227103
  Thomas-Fermi vector in A             =   1.472006
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           24
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     4500.00
      direct lattice vectors                 reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 position of ions in fractional coordinates (direct lattice) 
   0.71115262  0.18578086  0.56684569
   0.43132767  0.68744871  0.90313336
   0.54646464  0.07597196  0.51467278
   0.70045961  0.35450987  0.98586096
   0.18801939  0.70798190  0.36944490
   0.12478309  0.65033796  0.37074898
   0.02662916  0.31327068  0.47925652
   0.68280719  0.44550272  0.01138330
   0.23047644  0.14887672  0.14483172
   0.29453334  0.92015115  0.10323631
   0.28829705  0.16695013  0.68271957
   0.29902403  0.84683796  0.40854639
   0.49098398  0.38394021  0.44786348
   0.57050793  0.97585469  0.50842250
   0.22278310  0.39197362  0.65339768
   0.30911493  0.78057034  0.14598975
   0.60537289  0.10046749  0.59643386
   0.78880189  0.69856460  0.89983034
   0.02650601  0.31622772  0.17950830
   0.89356977  0.45850750  0.72525413
   0.81114433  0.74256257  0.44797650
   0.21641719  0.26070071  0.76065740
   0.58283954  0.74286932  0.43603633
   0.74766190  0.27995808  0.45314381
   0.55538628  0.71185901  0.42372466
   0.02170972  0.28929992  0.54056714
   0.25121790  0.12804304  0.66011879
   0.88976505  0.74194219  0.12309382
   0.21122063  0.31096245  0.75208225
   0.67710466  0.07700913  0.51320877
   0.02537814  0.34747786  0.21779055
   0.81731217  0.66673109  0.89323177
   0.95732789  0.57544410  0.13960919
   0.97548031  0.99312612  0.07016836
   0.71841256  0.31783068  0.88370968
   0.25440527  0.34966623  0.13109114
   0.04838580  0.43714979  0.92421696
   0.41273421  0.47427110  0.37723591
   0.63387962  0.12430888  0.53183707
   0.34791793  0.13419876  0.67635152
   0.45295896  0.41475463  0.40922810
   0.28636765  0.74509264  0.20391164
   0.98105767  0.35272286  0.44735781
 
 position of ions in cartesian coordinates  (Angst):
  14.22305240  2.78671290  8.50268535
   8.62655340 10.31173065 13.54700040
  10.92929280  1.13957940  7.72009170
  14.00919220  5.31764805 14.78791440
   3.76038780 10.61972850  5.54167350
   2.49566180  9.75506940  5.56123470
   0.53258320  4.69906020  7.18884780
  13.65614380  6.68254080  0.17074950
   4.60952880  2.23315080  2.17247580
   5.89066680 13.80226725  1.54854465
   5.76594100  2.50425195 10.24079355
   5.98048060 12.70256940  6.12819585
   9.81967960  5.75910315  6.71795220
  11.41015860 14.63782035  7.62633750
   4.45566200  5.87960430  9.80096520
   6.18229860 11.70855510  2.18984625
  12.10745780  1.50701235  8.94650790
  15.77603780 10.47846900 13.49745510
   0.53012020  4.74341580  2.69262450
  17.87139540  6.87761250 10.87881195
  16.22288660 11.13843855  6.71964750
   4.32834380  3.91051065 11.40986100
  11.65679080 11.14303980  6.54054495
  14.95323800  4.19937120  6.79715715
  11.10772560 10.67788515  6.35586990
   0.43419440  4.33949880  8.10850710
   5.02435800  1.92064560  9.90178185
  17.79530100 11.12913285  1.84640730
   4.22441260  4.66443675 11.28123375
  13.54209320  1.15513695  7.69813155
   0.50756280  5.21216790  3.26685825
  16.34624340 10.00096635 13.39847655
  19.14655780  8.63166150  2.09413785
  19.50960620 14.89689180  1.05252540
  14.36825120  4.76746020 13.25564520
   5.08810540  5.24499345  1.96636710
   0.96771600  6.55724685 13.86325440
   8.25468420  7.11406650  5.65853865
  12.67759240  1.86463320  7.97755605
   6.95835860  2.01298140 10.14527280
   9.05917920  6.22131945  6.13842150
   5.72735300 11.17638960  3.05867460
  19.62115340  5.29084290  6.71036715
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   81909

 maximum and minimum number of plane-waves per node :     81909    81909

 maximum number of plane-waves:     81909
 maximum index in each direction: 
   IXMAX=   32   IYMAX=   24   IZMAX=   24
   IXMIN=  -32   IYMIN=  -24   IZMIN=  -24

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to   140 to avoid them
 WARNING: aliasing errors must be expected set NGY to    98 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    98 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   222025. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       4021. kBytes
   fftplans  :      45166. kBytes
   grid      :     116408. kBytes
   one-center:        132. kBytes
   wavefun   :      26298. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 65   NGY = 49   NGZ = 49
  (NGX  =196   NGY  =160   NGZ  =160)
  gives a total of 156065 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron     111.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1497
 Maximum index for augmentation-charges         1146 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.107
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.7265715E+03  (-0.2568899E+04)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4167.36941237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       259.93141731
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.03140475
  eigenvalues    EBANDS =      -578.63913134
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       726.57150274 eV

  energy without entropy =      726.60290749  energy(sigma->0) =      726.58197099


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   248
 total energy-change (2. order) :-0.6208885E+03  (-0.6004731E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4167.36941237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       259.93141731
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.02675147
  eigenvalues    EBANDS =     -1199.58578502
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       105.68300529 eV

  energy without entropy =      105.65625382  energy(sigma->0) =      105.67408813


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) :-0.2496857E+03  (-0.2293041E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4167.36941237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       259.93141731
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.12310781
  eigenvalues    EBANDS =     -1449.12166078
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -144.00272976 eV

  energy without entropy =     -143.87962195  energy(sigma->0) =     -143.96169382


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.2923250E+02  (-0.2809547E+02)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4167.36941237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       259.93141731
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.16068152
  eigenvalues    EBANDS =     -1478.31658731
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -173.23523000 eV

  energy without entropy =     -173.07454848  energy(sigma->0) =     -173.18166949


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   216
 total energy-change (2. order) :-0.7400182E+00  (-0.7235400E+00)
 number of electron     110.9999985 magnetization 
 augmentation part        5.2447866 magnetization 

 Broyden mixing:
  rms(total) = 0.33338E+01    rms(broyden)= 0.33321E+01
  rms(prec ) = 0.38838E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4167.36941237
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       259.93141731
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.15793200
  eigenvalues    EBANDS =     -1479.05935498
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -173.97524816 eV

  energy without entropy =     -173.81731615  energy(sigma->0) =     -173.92260415


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.4436574E+02  (-0.2236829E+02)
 number of electron     110.9999933 magnetization 
 augmentation part        1.3985697 magnetization 

 Broyden mixing:
  rms(total) = 0.59461E+01    rms(broyden)= 0.59427E+01
  rms(prec ) = 0.71034E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3244
  0.3244

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4423.68621996
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.70677767
  PAW double counting   =      4931.09990097    -4862.07106481
  entropy T*S    EENTRO =        -0.16248093
  eigenvalues    EBANDS =     -1279.17060408
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -218.34099225 eV

  energy without entropy =     -218.17851132  energy(sigma->0) =     -218.28683194


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.7373420E+02  (-0.3608165E+01)
 number of electron     110.9999996 magnetization 
 augmentation part        4.2607161 magnetization 

 Broyden mixing:
  rms(total) = 0.23188E+01    rms(broyden)= 0.23134E+01
  rms(prec ) = 0.29212E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5060
  0.7662  0.2459

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4333.43153736
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       271.15949077
  PAW double counting   =      5058.26696860    -4988.20702265
  entropy T*S    EENTRO =        -0.11384033
  eigenvalues    EBANDS =     -1293.22354707
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -144.60678915 eV

  energy without entropy =     -144.49294882  energy(sigma->0) =     -144.56884237


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1108487E+01  (-0.2539803E+01)
 number of electron     110.9999992 magnetization 
 augmentation part        2.4470125 magnetization 

 Broyden mixing:
  rms(total) = 0.34571E+01    rms(broyden)= 0.34546E+01
  rms(prec ) = 0.43363E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4245
  0.8266  0.3074  0.1394

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4366.60926894
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       272.93621376
  PAW double counting   =      5537.29483034    -5467.37103421
  entropy T*S    EENTRO =        -0.17492638
  eigenvalues    EBANDS =     -1262.73378984
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -145.71527639 eV

  energy without entropy =     -145.54035000  energy(sigma->0) =     -145.65696759


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.4285830E+01  (-0.5379842E+01)
 number of electron     110.9999919 magnetization 
 augmentation part        2.5957994 magnetization 

 Broyden mixing:
  rms(total) = 0.42482E+01    rms(broyden)= 0.42451E+01
  rms(prec ) = 0.51230E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4457
  1.0444  0.4661  0.1500  0.1223

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4355.33286471
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       272.74520890
  PAW double counting   =      5653.81394644    -5583.78042598
  entropy T*S    EENTRO =         0.10699361
  eigenvalues    EBANDS =     -1278.49666363
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -150.00110648 eV

  energy without entropy =     -150.10810009  energy(sigma->0) =     -150.03677102


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.9688658E+01  (-0.5085620E+00)
 number of electron     110.9999990 magnetization 
 augmentation part        4.1387678 magnetization 

 Broyden mixing:
  rms(total) = 0.17225E+01    rms(broyden)= 0.17167E+01
  rms(prec ) = 0.22224E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4631
  1.2592  0.3970  0.3970  0.1312  0.1312

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4349.51853444
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       272.94340735
  PAW double counting   =      5880.22010275    -5809.99369773
  entropy T*S    EENTRO =         0.00522685
  eigenvalues    EBANDS =     -1274.91165204
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.31244837 eV

  energy without entropy =     -140.31767522  energy(sigma->0) =     -140.31419066


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3191990E+01  (-0.3835878E+00)
 number of electron     110.9999980 magnetization 
 augmentation part        3.2937777 magnetization 

 Broyden mixing:
  rms(total) = 0.13759E+01    rms(broyden)= 0.13741E+01
  rms(prec ) = 0.17588E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4611
  1.4181  0.4616  0.4616  0.1866  0.1192  0.1192

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4362.52318269
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       273.63294653
  PAW double counting   =      6100.05259716    -6029.82586389
  entropy T*S    EENTRO =        -0.34499991
  eigenvalues    EBANDS =     -1259.05465450
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.12045840 eV

  energy without entropy =     -136.77545850  energy(sigma->0) =     -137.00545843


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   216
 total energy-change (2. order) :-0.3343234E+01  (-0.1553559E+01)
 number of electron     110.9999965 magnetization 
 augmentation part        3.1020962 magnetization 

 Broyden mixing:
  rms(total) = 0.33376E+01    rms(broyden)= 0.33349E+01
  rms(prec ) = 0.42420E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4848
  1.7278  0.5827  0.5827  0.1945  0.1134  0.1134  0.0795

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4368.51567773
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       273.93836199
  PAW double counting   =      6249.82470607    -6179.58616827
  entropy T*S    EENTRO =         0.00979589
  eigenvalues    EBANDS =     -1257.07740878
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.46369196 eV

  energy without entropy =     -140.47348785  energy(sigma->0) =     -140.46695725


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.3805924E+00  (-0.9682087E+00)
 number of electron     110.9999966 magnetization 
 augmentation part        2.0531347 magnetization 

 Broyden mixing:
  rms(total) = 0.36927E+01    rms(broyden)= 0.36887E+01
  rms(prec ) = 0.45800E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4491
  1.7756  0.7333  0.4315  0.2391  0.1271  0.1271  0.1031  0.0564

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.20567074
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.74938967
  PAW double counting   =      6474.50824464    -6404.25218502
  entropy T*S    EENTRO =        -0.19409435
  eigenvalues    EBANDS =     -1248.63148265
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -140.08309956 eV

  energy without entropy =     -139.88900521  energy(sigma->0) =     -140.01840144


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.3169415E+01  (-0.8110665E+00)
 number of electron     110.9999980 magnetization 
 augmentation part        3.1757707 magnetization 

 Broyden mixing:
  rms(total) = 0.25528E+01    rms(broyden)= 0.25499E+01
  rms(prec ) = 0.30788E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4402
  1.9261  0.7721  0.3547  0.3547  0.1515  0.1515  0.0978  0.0978  0.0556

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4371.62969129
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.55801331
  PAW double counting   =      6498.51899503    -6428.19213917
  entropy T*S    EENTRO =        -0.21155514
  eigenvalues    EBANDS =     -1250.90000601
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -136.91368439 eV

  energy without entropy =     -136.70212924  energy(sigma->0) =     -136.84316600


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.9863853E+00  (-0.4338439E+00)
 number of electron     110.9999988 magnetization 
 augmentation part        4.0832484 magnetization 

 Broyden mixing:
  rms(total) = 0.19227E+01    rms(broyden)= 0.19177E+01
  rms(prec ) = 0.24764E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4218
  1.9513  0.7961  0.3877  0.3877  0.1857  0.1297  0.1297  0.0982  0.0982  0.0533

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4369.11079282
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.51532556
  PAW double counting   =      6564.86107498    -6494.42650462
  entropy T*S    EENTRO =        -0.17915525
  eigenvalues    EBANDS =     -1254.50271644
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.90006971 eV

  energy without entropy =     -137.72091446  energy(sigma->0) =     -137.84035130


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.7815142E+00  (-0.5063216E+00)
 number of electron     110.9999991 magnetization 
 augmentation part        4.1666275 magnetization 

 Broyden mixing:
  rms(total) = 0.16946E+01    rms(broyden)= 0.16938E+01
  rms(prec ) = 0.21470E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4065
  2.0180  0.7728  0.4247  0.4247  0.2077  0.1280  0.1280  0.1179  0.0980  0.0980
  0.0534

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4371.92264840
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.47749983
  PAW double counting   =      6602.06633489    -6531.66640505
  entropy T*S    EENTRO =         0.05920119
  eigenvalues    EBANDS =     -1251.07523681
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -137.11855546 eV

  energy without entropy =     -137.17775665  energy(sigma->0) =     -137.13828919


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.8618262E+00  (-0.1478009E+00)
 number of electron     110.9999990 magnetization 
 augmentation part        3.9677049 magnetization 

 Broyden mixing:
  rms(total) = 0.14699E+01    rms(broyden)= 0.14691E+01
  rms(prec ) = 0.18575E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4085
  2.1044  0.8367  0.6358  0.2822  0.2822  0.1574  0.1574  0.1211  0.0990  0.0990
  0.0734  0.0534

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4375.23828596
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.65755982
  PAW double counting   =      6650.18150169    -6579.78169869
  entropy T*S    EENTRO =        -0.09841415
  eigenvalues    EBANDS =     -1246.92009089
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -136.25672929 eV

  energy without entropy =     -136.15831514  energy(sigma->0) =     -136.22392457


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.6570269E+00  (-0.1674188E+00)
 number of electron     110.9999977 magnetization 
 augmentation part        3.2905853 magnetization 

 Broyden mixing:
  rms(total) = 0.13735E+01    rms(broyden)= 0.13706E+01
  rms(prec ) = 0.16603E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3921
  2.1427  0.9062  0.4806  0.4806  0.1921  0.1921  0.1503  0.1503  0.1077  0.1077
  0.0532  0.0666  0.0666

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.23717868
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.81331496
  PAW double counting   =      6698.88544244    -6628.47837772
  entropy T*S    EENTRO =        -0.53021157
  eigenvalues    EBANDS =     -1243.99539072
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.59970241 eV

  energy without entropy =     -135.06949084  energy(sigma->0) =     -135.42296522


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.6837810E-01  (-0.3283180E+00)
 number of electron     110.9999992 magnetization 
 augmentation part        3.9707482 magnetization 

 Broyden mixing:
  rms(total) = 0.13902E+01    rms(broyden)= 0.13882E+01
  rms(prec ) = 0.17849E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3764
  2.1522  0.9634  0.5603  0.4208  0.1914  0.1914  0.1651  0.1651  0.1090  0.1090
  0.0690  0.0690  0.0548  0.0497

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4375.22909452
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.77283931
  PAW double counting   =      6711.49394850    -6641.04878174
  entropy T*S    EENTRO =        -0.46246126
  eigenvalues    EBANDS =     -1246.13722968
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.66808051 eV

  energy without entropy =     -135.20561925  energy(sigma->0) =     -135.51392675


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.1886178E+00  (-0.2816638E+00)
 number of electron     110.9999974 magnetization 
 augmentation part        3.4468610 magnetization 

 Broyden mixing:
  rms(total) = 0.13408E+01    rms(broyden)= 0.13393E+01
  rms(prec ) = 0.16241E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3630
  2.1556  0.9381  0.5110  0.5110  0.2046  0.2046  0.2107  0.1533  0.1043  0.1043
  0.0948  0.0948  0.0667  0.0539  0.0370

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4376.09223421
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.76774199
  PAW double counting   =      6721.80551449    -6651.36176236
  entropy T*S    EENTRO =        -0.53795937
  eigenvalues    EBANDS =     -1245.00346218
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.47946274 eV

  energy without entropy =     -134.94150337  energy(sigma->0) =     -135.30014295


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.5690312E-01  (-0.5922500E-01)
 number of electron     110.9999982 magnetization 
 augmentation part        3.6666890 magnetization 

 Broyden mixing:
  rms(total) = 0.86948E+00    rms(broyden)= 0.86865E+00
  rms(prec ) = 0.10709E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3625
  2.1515  0.9254  0.5118  0.5118  0.3331  0.3331  0.2141  0.1395  0.1395  0.1028
  0.1028  0.1040  0.0699  0.0699  0.0541  0.0369

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4376.66296153
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.77110872
  PAW double counting   =      6727.53326413    -6657.07826478
  entropy T*S    EENTRO =        -0.54488024
  eigenvalues    EBANDS =     -1244.38352480
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.42255962 eV

  energy without entropy =     -134.87767937  energy(sigma->0) =     -135.24093287


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.6119071E-01  (-0.9461845E-01)
 number of electron     110.9999989 magnetization 
 augmentation part        3.7787099 magnetization 

 Broyden mixing:
  rms(total) = 0.86764E+00    rms(broyden)= 0.86691E+00
  rms(prec ) = 0.10968E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3679
  2.1512  1.0307  0.4874  0.4874  0.4797  0.4797  0.1919  0.1647  0.1647  0.1117
  0.1036  0.1036  0.0731  0.0731  0.0542  0.0611  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4375.85812228
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.71978706
  PAW double counting   =      6731.14388363    -6660.67193941
  entropy T*S    EENTRO =        -0.47714890
  eigenvalues    EBANDS =     -1245.28290932
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.48375033 eV

  energy without entropy =     -135.00660143  energy(sigma->0) =     -135.32470069


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.8787900E-01  (-0.6652234E-01)
 number of electron     110.9999980 magnetization 
 augmentation part        3.4969334 magnetization 

 Broyden mixing:
  rms(total) = 0.47389E+00    rms(broyden)= 0.47261E+00
  rms(prec ) = 0.62754E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3764
  2.1969  1.1155  0.7272  0.5479  0.5479  0.3690  0.1809  0.1809  0.1645  0.1445
  0.1071  0.1071  0.0809  0.0809  0.0724  0.0541  0.0606  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.01516217
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.72806948
  PAW double counting   =      6742.21933244    -6671.73975755
  entropy T*S    EENTRO =        -0.61761849
  eigenvalues    EBANDS =     -1243.91343392
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.39587132 eV

  energy without entropy =     -134.77825283  energy(sigma->0) =     -135.18999849


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.7378938E-01  (-0.5021669E-01)
 number of electron     110.9999980 magnetization 
 augmentation part        3.2630618 magnetization 

 Broyden mixing:
  rms(total) = 0.97063E+00    rms(broyden)= 0.96976E+00
  rms(prec ) = 0.12029E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3845
  2.2590  0.9751  0.9751  0.6319  0.6319  0.3264  0.3264  0.1744  0.1590  0.1590
  0.1065  0.1065  0.0940  0.0940  0.0695  0.0695  0.0549  0.0549  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.31792894
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.73827539
  PAW double counting   =      6757.58687205    -6687.09961251
  entropy T*S    EENTRO =        -0.70261974
  eigenvalues    EBANDS =     -1242.61734584
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.46966070 eV

  energy without entropy =     -134.76704096  energy(sigma->0) =     -135.23545412


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) : 0.3272290E-01  (-0.5983152E-01)
 number of electron     110.9999969 magnetization 
 augmentation part        3.0075117 magnetization 

 Broyden mixing:
  rms(total) = 0.10774E+01    rms(broyden)= 0.10764E+01
  rms(prec ) = 0.13190E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3730
  2.2486  1.0213  1.0213  0.6235  0.6235  0.3366  0.3366  0.1757  0.1606  0.1606
  0.1063  0.1063  0.0994  0.0994  0.0702  0.0702  0.0543  0.0542  0.0542  0.0370

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.95497252
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.75936711
  PAW double counting   =      6765.54917005    -6695.05130641
  entropy T*S    EENTRO =        -0.81455132
  eigenvalues    EBANDS =     -1242.86734359
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.43693780 eV

  energy without entropy =     -134.62238648  energy(sigma->0) =     -135.16542069


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.1370511E+00  (-0.2980621E-01)
 number of electron     110.9999975 magnetization 
 augmentation part        3.2848101 magnetization 

 Broyden mixing:
  rms(total) = 0.40673E+00    rms(broyden)= 0.40567E+00
  rms(prec ) = 0.49588E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3817
  2.2756  1.1561  0.9048  0.6929  0.6929  0.3785  0.3785  0.2265  0.1726  0.1726
  0.1803  0.1135  0.1065  0.1065  0.0857  0.0857  0.0694  0.0694  0.0547  0.0555
  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.45778469
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.73865088
  PAW double counting   =      6760.41947963    -6689.90622619
  entropy T*S    EENTRO =        -0.76270821
  eigenvalues    EBANDS =     -1243.27399703
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.29988672 eV

  energy without entropy =     -134.53717852  energy(sigma->0) =     -135.04565066


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.1182764E+00  (-0.2408413E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.2215528 magnetization 

 Broyden mixing:
  rms(total) = 0.72153E+00    rms(broyden)= 0.72116E+00
  rms(prec ) = 0.88617E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3908
  2.2933  1.3600  0.9470  0.7410  0.7410  0.4255  0.4255  0.2355  0.2076  0.1715
  0.1715  0.1227  0.1067  0.1067  0.0914  0.0914  0.0712  0.0712  0.0694  0.0549
  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.48169361
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.68903930
  PAW double counting   =      6763.61656671    -6693.09242973
  entropy T*S    EENTRO =        -0.73935727
  eigenvalues    EBANDS =     -1243.35298745
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.41816316 eV

  energy without entropy =     -134.67880589  energy(sigma->0) =     -135.17171074


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.1014567E+00  (-0.2502539E-01)
 number of electron     110.9999972 magnetization 
 augmentation part        2.8711487 magnetization 

 Broyden mixing:
  rms(total) = 0.13507E+01    rms(broyden)= 0.13502E+01
  rms(prec ) = 0.16558E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4007
  2.2401  1.2142  1.2142  0.8166  0.8166  0.4962  0.4962  0.2924  0.2924  0.1626
  0.1626  0.1698  0.1063  0.1063  0.1058  0.0842  0.0842  0.0689  0.0689  0.0698
  0.0548  0.0556  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.83858474
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.72545959
  PAW double counting   =      6767.10835002    -6696.58008458
  entropy T*S    EENTRO =        -0.73973660
  eigenvalues    EBANDS =     -1242.13772245
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.51961987 eV

  energy without entropy =     -134.77988327  energy(sigma->0) =     -135.27304100


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.1993087E+00  (-0.7633394E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.4494141 magnetization 

 Broyden mixing:
  rms(total) = 0.38335E+00    rms(broyden)= 0.37615E+00
  rms(prec ) = 0.46406E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4134
  2.0893  2.0893  0.8717  0.8717  0.6819  0.6819  0.4049  0.4049  0.2488  0.2488
  0.1602  0.1602  0.1657  0.1064  0.1064  0.1099  0.0847  0.0847  0.0689  0.0689
  0.0645  0.0548  0.0555  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.70469476
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.70308010
  PAW double counting   =      6759.40747904    -6688.86510340
  entropy T*S    EENTRO =        -0.66560906
  eigenvalues    EBANDS =     -1243.13816201
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.32031120 eV

  energy without entropy =     -134.65470214  energy(sigma->0) =     -135.09844151


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.3713331E+00  (-0.1145322E+00)
 number of electron     110.9999987 magnetization 
 augmentation part        4.0485261 magnetization 

 Broyden mixing:
  rms(total) = 0.13222E+01    rms(broyden)= 0.13212E+01
  rms(prec ) = 0.16384E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4181
  2.2081  2.2081  0.8612  0.8612  0.6337  0.6337  0.4970  0.4970  0.2614  0.2230
  0.2230  0.1812  0.1604  0.1604  0.1065  0.1065  0.1079  0.0851  0.0851  0.0690
  0.0690  0.0656  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4375.73280468
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.52867245
  PAW double counting   =      6745.78969823    -6675.20685393
  entropy T*S    EENTRO =        -0.37321357
  eigenvalues    EBANDS =     -1245.63984165
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.69164427 eV

  energy without entropy =     -135.31843070  energy(sigma->0) =     -135.56723974


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) : 0.3144802E+00  (-0.4890146E-01)
 number of electron     110.9999981 magnetization 
 augmentation part        3.6054958 magnetization 

 Broyden mixing:
  rms(total) = 0.56958E+00    rms(broyden)= 0.56879E+00
  rms(prec ) = 0.69866E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4401
  2.3187  2.3187  1.2079  0.7706  0.7023  0.7023  0.4712  0.4329  0.4329  0.2579
  0.2579  0.2281  0.1778  0.1607  0.1607  0.1064  0.1064  0.1085  0.0850  0.0850
  0.0690  0.0690  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4377.85874674
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.64312471
  PAW double counting   =      6754.82842454    -6684.26965161
  entropy T*S    EENTRO =        -0.65143725
  eigenvalues    EBANDS =     -1243.01157662
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.37716409 eV

  energy without entropy =     -134.72572684  energy(sigma->0) =     -135.16001834


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.6181931E-02  (-0.2411771E-01)
 number of electron     110.9999980 magnetization 
 augmentation part        3.4686369 magnetization 

 Broyden mixing:
  rms(total) = 0.15912E+00    rms(broyden)= 0.15584E+00
  rms(prec ) = 0.19094E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4497
  2.4698  2.4698  1.1980  0.7472  0.7472  0.6230  0.6230  0.4769  0.4769  0.2664
  0.2521  0.2521  0.1969  0.1799  0.1605  0.1605  0.1064  0.1064  0.1084  0.0850
  0.0850  0.0690  0.0690  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.36668744
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.64037448
  PAW double counting   =      6754.94998552    -6684.39076390
  entropy T*S    EENTRO =        -0.69844383
  eigenvalues    EBANDS =     -1242.46050974
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.38334602 eV

  energy without entropy =     -134.68490219  energy(sigma->0) =     -135.15053141


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.3424584E-01  (-0.2912946E-02)
 number of electron     110.9999979 magnetization 
 augmentation part        3.3961062 magnetization 

 Broyden mixing:
  rms(total) = 0.22431E+00    rms(broyden)= 0.22385E+00
  rms(prec ) = 0.27339E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4673
  2.8143  2.4379  1.0752  1.0752  0.7707  0.5831  0.5831  0.5419  0.4492  0.4492
  0.2571  0.2571  0.2233  0.2233  0.1797  0.1604  0.1604  0.1064  0.1064  0.1084
  0.0850  0.0850  0.0690  0.0690  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.60179469
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.62239322
  PAW double counting   =      6755.83845669    -6685.27834403
  entropy T*S    EENTRO =        -0.70860086
  eigenvalues    EBANDS =     -1242.23240107
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.41759187 eV

  energy without entropy =     -134.70899100  energy(sigma->0) =     -135.18139158


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :   160
 total energy-change (2. order) :-0.2431634E-02  (-0.1787300E-02)
 number of electron     110.9999981 magnetization 
 augmentation part        3.4740337 magnetization 

 Broyden mixing:
  rms(total) = 0.13443E+00    rms(broyden)= 0.13418E+00
  rms(prec ) = 0.16773E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4925
  3.1928  2.4672  1.2503  1.2503  0.6898  0.6898  0.6112  0.6112  0.4545  0.4545
  0.3425  0.2466  0.2466  0.2490  0.1605  0.1605  0.1816  0.1816  0.1064  0.1064
  0.1084  0.0850  0.0850  0.0690  0.0690  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.53375938
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.60234591
  PAW double counting   =      6753.63525147    -6683.07068322
  entropy T*S    EENTRO =        -0.69245053
  eigenvalues    EBANDS =     -1242.30342663
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.42002350 eV

  energy without entropy =     -134.72757297  energy(sigma->0) =     -135.18920666


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.1201263E-01  (-0.2641527E-03)
 number of electron     110.9999981 magnetization 
 augmentation part        3.4537432 magnetization 

 Broyden mixing:
  rms(total) = 0.12894E+00    rms(broyden)= 0.12891E+00
  rms(prec ) = 0.15782E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5019
  3.4302  2.3995  1.6427  0.8399  0.8399  0.7834  0.5639  0.5639  0.5627  0.4675
  0.4675  0.2529  0.2529  0.2442  0.2186  0.1605  0.1605  0.1820  0.1820  0.1064
  0.1064  0.1084  0.0850  0.0850  0.0690  0.0690  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.77691601
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.59930054
  PAW double counting   =      6752.54429785    -6681.98043609
  entropy T*S    EENTRO =        -0.69785923
  eigenvalues    EBANDS =     -1242.06312208
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.43203613 eV

  energy without entropy =     -134.73417691  energy(sigma->0) =     -135.19941639


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.1075636E-01  (-0.1900203E-02)
 number of electron     110.9999978 magnetization 
 augmentation part        3.3415985 magnetization 

 Broyden mixing:
  rms(total) = 0.21613E+00    rms(broyden)= 0.21582E+00
  rms(prec ) = 0.26730E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5040
  3.6307  2.3916  1.2633  1.0873  1.0873  0.6928  0.6013  0.6013  0.5806  0.4444
  0.4444  0.3073  0.2519  0.2519  0.2448  0.2233  0.1605  0.1605  0.1792  0.1792
  0.1064  0.1064  0.1084  0.0850  0.0850  0.0690  0.0690  0.0654  0.0548  0.0554
  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4379.20856535
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.61169886
  PAW double counting   =      6754.03292825    -6683.47290951
  entropy T*S    EENTRO =        -0.73505345
  eigenvalues    EBANDS =     -1241.61359017
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.44279249 eV

  energy without entropy =     -134.70773904  energy(sigma->0) =     -135.19777468


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) : 0.1876906E-02  (-0.1548904E-02)
 number of electron     110.9999980 magnetization 
 augmentation part        3.4620652 magnetization 

 Broyden mixing:
  rms(total) = 0.89378E-01    rms(broyden)= 0.88636E-01
  rms(prec ) = 0.10958E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5365
  4.0165  2.4493  1.7883  0.9771  0.9771  0.8561  0.6052  0.6052  0.5742  0.5742
  0.4618  0.4618  0.3494  0.2522  0.2522  0.2293  0.2152  0.1605  0.1605  0.1799
  0.1799  0.1064  0.1064  0.1084  0.0850  0.0850  0.0690  0.0690  0.0654  0.0548
  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4378.96266587
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.59103018
  PAW double counting   =      6751.97066954    -6681.40428466
  entropy T*S    EENTRO =        -0.71313736
  eigenvalues    EBANDS =     -1241.86522630
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.44091559 eV

  energy without entropy =     -134.72777823  energy(sigma->0) =     -135.20320313


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.9999154E-02  (-0.4124481E-03)
 number of electron     110.9999979 magnetization 
 augmentation part        3.4522914 magnetization 

 Broyden mixing:
  rms(total) = 0.85628E-01    rms(broyden)= 0.85484E-01
  rms(prec ) = 0.10402E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5615
  4.3007  2.5406  2.0149  1.2546  1.2546  0.7157  0.6419  0.6419  0.5102  0.5102
  0.4579  0.4579  0.4873  0.2840  0.2512  0.2512  0.2160  0.2160  0.1605  0.1605
  0.1800  0.1800  0.1064  0.1064  0.1084  0.0850  0.0850  0.0690  0.0690  0.0654
  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4379.13644239
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.58585208
  PAW double counting   =      6751.43696133    -6680.87291881
  entropy T*S    EENTRO =        -0.70615803
  eigenvalues    EBANDS =     -1241.70090780
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.45091474 eV

  energy without entropy =     -134.74475671  energy(sigma->0) =     -135.21552873


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) :-0.1944234E-02  (-0.6132862E-03)
 number of electron     110.9999979 magnetization 
 augmentation part        3.4043260 magnetization 

 Broyden mixing:
  rms(total) = 0.86935E-01    rms(broyden)= 0.86516E-01
  rms(prec ) = 0.10588E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5976
  5.2364  2.6185  2.2173  1.1845  1.1845  0.7526  0.7526  0.6144  0.6144  0.5745
  0.5745  0.4505  0.4505  0.3160  0.3160  0.2506  0.2506  0.2181  0.2181  0.1605
  0.1605  0.1801  0.1801  0.1064  0.1064  0.1084  0.0850  0.0850  0.0690  0.0690
  0.0654  0.0548  0.0554  0.0371

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       395.46395687
  -Hartree energ DENC   =     -4379.25677355
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.58875416
  PAW double counting   =      6751.71649564    -6681.15386208
  entropy T*S    EENTRO =        -0.72200853
  eigenvalues    EBANDS =     -1241.56816351
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -135.45285898 eV

  energy without entropy =     -134.73085045  energy(sigma->0) =     -135.21218947


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------