vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.10.21  20:23:53
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.32 0.77
   NPAR = 4

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  4       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.338  0.404  0.952-  30 1.58
   2  0.255  0.593  0.536-  37 1.48  29 1.48  32 1.48
   3  0.187  0.744  0.059-  42 1.62
   4  0.598  0.510  0.462-  17 1.49  31 1.49  12 1.63
   5  0.639  0.802  0.375-  16 1.50  43 1.62
   6  0.081  0.295  0.406-
   7  0.093  0.881  0.106-  38 1.23  42 1.32
   8  0.049  0.611  0.755-  11 1.22
   9  0.389  0.136  0.686-  15 0.97
  10  0.743  0.047  0.866-  28 1.00  41 1.24
  11  0.101  0.652  0.763-   8 1.22
  12  0.643  0.440  0.404-  25 1.04   4 1.63
  13  0.579  0.175  0.904-
  14  0.738  0.818  0.276-  43 1.08
  15  0.410  0.190  0.663-   9 0.97
  16  0.584  0.757  0.427-   5 1.50
  17  0.612  0.497  0.558-   4 1.49
  18  0.312  0.096  0.991-
  19  0.950  0.269  0.044-
  20  0.094  0.274  0.742-
  21  0.552  0.946  0.024-  26 0.76
  22  0.083  0.003  0.091-  38 1.09
  23  0.991  0.870  0.601-
  24  0.471  0.586  0.731-  27 0.76
  25  0.695  0.441  0.399-  12 1.04
  26  0.528  0.985  0.024-  21 0.76
  27  0.438  0.577  0.754-  24 0.76
  28  0.722  0.106  0.854-  10 1.00
  29  0.258  0.627  0.444-   2 1.48
  30  0.395  0.452  0.008-   1 1.58
  31  0.527  0.508  0.431-   4 1.49
  32  0.195  0.539  0.558-   2 1.48
  33  0.008  0.827  0.582-
  34  0.923  0.750  0.518-
  35  0.800  0.400  0.307-  40 1.14
  36  0.590  0.147  0.945-
  37  0.319  0.557  0.570-   2 1.48
  38  0.060  0.947  0.126-  22 1.09   7 1.23
  39  0.936  0.157  0.267-
  40  0.769  0.461  0.324-  35 1.14
  41  0.804  0.038  0.880-  10 1.24
  42  0.140  0.831  0.068-   7 1.32   3 1.62
  43  0.703  0.779  0.314-  14 1.08   5 1.62
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =    15.0000000000
 C/A-ratio  =     1.3333333333
  
  Lattice vectors:
  
 A1 = (   0.0000000000,  15.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  15.0000000000)
 A3 = (  20.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    4500.0000

  direct lattice vectors                    reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667

  position of ions in fractional coordinates (direct lattice)
     0.337624800  0.404449690  0.952234850
     0.254704840  0.592980850  0.536211370
     0.186983310  0.743864830  0.059085550
     0.598315110  0.509848260  0.461600480
     0.638950450  0.801781930  0.375300830
     0.081249470  0.295416400  0.406093660
     0.092911830  0.880935210  0.105980090
     0.049235200  0.610532270  0.755130420
     0.389371320  0.135591150  0.686436670
     0.743220050  0.046532640  0.866290100
     0.101275300  0.652380290  0.762865740
     0.643147250  0.439708420  0.404260540
     0.578892310  0.174845180  0.903800010
     0.738335840  0.818012720  0.275602750
     0.409826250  0.189635220  0.662892050
     0.584145210  0.757045550  0.426777960
     0.611869760  0.497045020  0.558353710
     0.311788020  0.096471560  0.991169270
     0.949519640  0.268567660  0.044048480
     0.094260460  0.274254820  0.742033370
     0.552172150  0.945664990  0.023583980
     0.083278480  0.003232790  0.091395170
     0.991479070  0.869746670  0.601056480
     0.471103750  0.586198040  0.730661390
     0.695182990  0.440872470  0.398984610
     0.528052530  0.984531730  0.024393370
     0.437950670  0.577366010  0.753815030
     0.722090590  0.106000460  0.854098420
     0.258106150  0.627483720  0.444148210
     0.394665670  0.452204260  0.007581670
     0.527394580  0.507651090  0.430667070
     0.194894780  0.538756800  0.558260920
     0.007981030  0.827273210  0.582157070
     0.922619230  0.749521550  0.518385470
     0.800033670  0.399738800  0.307060270
     0.589912050  0.146682530  0.944968820
     0.318619280  0.557216310  0.569935760
     0.060213020  0.947473460  0.125957700
     0.936115420  0.157172400  0.266951440
     0.768932000  0.461416400  0.323771940
     0.804057810  0.038371670  0.879730580
     0.139791740  0.831406020  0.068154440
     0.703184790  0.778658280  0.313924370

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34
                35          35
                36          36
                37          37
                38          38
                39          39
                40          40
                41          41
                42          42
                43          43

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    1    1    1

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     1.000000000  0.000000000  0.000000000
     0.000000000  0.066666667  0.000000000     0.000000000  1.000000000  0.000000000
     0.000000000  0.000000000  0.066666667     0.000000000  0.000000000  1.000000000

  Length of vectors
     0.050000000  0.066666667  0.066666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      1 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      1   k-points in BZ     NKDIM =      1   number of bands    NBANDS=     80
   number of dos      NEDOS =    301   number of ions     NIONS =     43
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 627200
   max r-space proj   IRMAX =   1586   max aug-charges    IRDMAX=   4859
   dimension x,y,z NGX =    98 NGY =   80 NGZ =   80
   dimension x,y,z NGXF=   196 NGYF=  160 NGZF=  160
   support grid    NGXF=   196 NGYF=  160 NGZF=  160
   ions per type =               5   7  25   6
   NGX,Y,Z   is equivalent  to a cutoff of   8.15,  8.87,  8.87 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.29, 17.73, 17.73 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  32.61 24.46 24.46*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.914E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00  1.00 12.01
  Ionic Valenz
   ZVAL   =   4.00  6.00  1.00  4.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.32  0.77
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =     111.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.31E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =     104.65       706.22
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.476553  0.900556  3.089927  0.227103
  Thomas-Fermi vector in A             =   1.472006
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           24
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     4500.00
      direct lattice vectors                 reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 position of ions in fractional coordinates (direct lattice) 
   0.33762480  0.40444969  0.95223485
   0.25470484  0.59298085  0.53621137
   0.18698331  0.74386483  0.05908555
   0.59831511  0.50984826  0.46160048
   0.63895045  0.80178193  0.37530083
   0.08124947  0.29541640  0.40609366
   0.09291183  0.88093521  0.10598009
   0.04923520  0.61053227  0.75513042
   0.38937132  0.13559115  0.68643667
   0.74322005  0.04653264  0.86629010
   0.10127530  0.65238029  0.76286574
   0.64314725  0.43970842  0.40426054
   0.57889231  0.17484518  0.90380001
   0.73833584  0.81801272  0.27560275
   0.40982625  0.18963522  0.66289205
   0.58414521  0.75704555  0.42677796
   0.61186976  0.49704502  0.55835371
   0.31178802  0.09647156  0.99116927
   0.94951964  0.26856766  0.04404848
   0.09426046  0.27425482  0.74203337
   0.55217215  0.94566499  0.02358398
   0.08327848  0.00323279  0.09139517
   0.99147907  0.86974667  0.60105648
   0.47110375  0.58619804  0.73066139
   0.69518299  0.44087247  0.39898461
   0.52805253  0.98453173  0.02439337
   0.43795067  0.57736601  0.75381503
   0.72209059  0.10600046  0.85409842
   0.25810615  0.62748372  0.44414821
   0.39466567  0.45220426  0.00758167
   0.52739458  0.50765109  0.43066707
   0.19489478  0.53875680  0.55826092
   0.00798103  0.82727321  0.58215707
   0.92261923  0.74952155  0.51838547
   0.80003367  0.39973880  0.30706027
   0.58991205  0.14668253  0.94496882
   0.31861928  0.55721631  0.56993576
   0.06021302  0.94747346  0.12595770
   0.93611542  0.15717240  0.26695144
   0.76893200  0.46141640  0.32377194
   0.80405781  0.03837167  0.87973058
   0.13979174  0.83140602  0.06815444
   0.70318479  0.77865828  0.31392437
 
 position of ions in cartesian coordinates  (Angst):
   6.75249600  6.06674535 14.28352275
   5.09409680  8.89471275  8.04317055
   3.73966620 11.15797245  0.88628325
  11.96630220  7.64772390  6.92400720
  12.77900900 12.02672895  5.62951245
   1.62498940  4.43124600  6.09140490
   1.85823660 13.21402815  1.58970135
   0.98470400  9.15798405 11.32695630
   7.78742640  2.03386725 10.29655005
  14.86440100  0.69798960 12.99435150
   2.02550600  9.78570435 11.44298610
  12.86294500  6.59562630  6.06390810
  11.57784620  2.62267770 13.55700015
  14.76671680 12.27019080  4.13404125
   8.19652500  2.84452830  9.94338075
  11.68290420 11.35568325  6.40166940
  12.23739520  7.45567530  8.37530565
   6.23576040  1.44707340 14.86753905
  18.99039280  4.02851490  0.66072720
   1.88520920  4.11382230 11.13050055
  11.04344300 14.18497485  0.35375970
   1.66556960  0.04849185  1.37092755
  19.82958140 13.04620005  9.01584720
   9.42207500  8.79297060 10.95992085
  13.90365980  6.61308705  5.98476915
  10.56105060 14.76797595  0.36590055
   8.75901340  8.66049015 11.30722545
  14.44181180  1.59000690 12.81147630
   5.16212300  9.41225580  6.66222315
   7.89331340  6.78306390  0.11372505
  10.54789160  7.61476635  6.46000605
   3.89789560  8.08135200  8.37391380
   0.15962060 12.40909815  8.73235605
  18.45238460 11.24282325  7.77578205
  16.00067340  5.99608200  4.60590405
  11.79824100  2.20023795 14.17453230
   6.37238560  8.35824465  8.54903640
   1.20426040 14.21210190  1.88936550
  18.72230840  2.35758600  4.00427160
  15.37864000  6.92124600  4.85657910
  16.08115620  0.57557505 13.19595870
   2.79583480 12.47109030  1.02231660
  14.06369580 11.67987420  4.70886555
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   81909

 maximum and minimum number of plane-waves per node :     81909    81909

 maximum number of plane-waves:     81909
 maximum index in each direction: 
   IXMAX=   32   IYMAX=   24   IZMAX=   24
   IXMIN=  -32   IYMIN=  -24   IZMIN=  -24

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to   140 to avoid them
 WARNING: aliasing errors must be expected set NGY to    98 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    98 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   222024. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       4020. kBytes
   fftplans  :      45166. kBytes
   grid      :     116408. kBytes
   one-center:        132. kBytes
   wavefun   :      26298. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 65   NGY = 49   NGZ = 49
  (NGX  =196   NGY  =160   NGZ  =160)
  gives a total of 156065 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron     111.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1497
 Maximum index for augmentation-charges         1149 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.107
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.6876874E+03  (-0.2662986E+04)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4241.95089577
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       263.91405269
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =         0.01535978
  eigenvalues    EBANDS =      -651.60067657
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       687.68741827 eV

  energy without entropy =      687.67205850  energy(sigma->0) =      687.68229835


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   256
 total energy-change (2. order) :-0.6098359E+03  (-0.5910308E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4241.95089577
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       263.91405269
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.05202809
  eigenvalues    EBANDS =     -1261.36922479
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =        77.85148218 eV

  energy without entropy =       77.90351028  energy(sigma->0) =       77.86882488


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.2319652E+03  (-0.2172651E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4241.95089577
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       263.91405269
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.04226175
  eigenvalues    EBANDS =     -1493.34418151
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -154.11370819 eV

  energy without entropy =     -154.07144644  energy(sigma->0) =     -154.09962094


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.2393243E+02  (-0.2303580E+02)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4241.95089577
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       263.91405269
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.05890889
  eigenvalues    EBANDS =     -1517.25996856
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -178.04614239 eV

  energy without entropy =     -177.98723350  energy(sigma->0) =     -178.02650609


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   232
 total energy-change (2. order) :-0.9472867E+00  (-0.6371176E+00)
 number of electron     110.9999976 magnetization 
 augmentation part        4.9137698 magnetization 

 Broyden mixing:
  rms(total) = 0.30900E+01    rms(broyden)= 0.30871E+01
  rms(prec ) = 0.35429E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4241.95089577
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       263.91405269
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.26422429
  eigenvalues    EBANDS =     -1518.00193989
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -178.99342912 eV

  energy without entropy =     -178.72920483  energy(sigma->0) =     -178.90535435


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.2070063E+02  (-0.1995609E+02)
 number of electron     111.0000026 magnetization 
 augmentation part        2.0276013 magnetization 

 Broyden mixing:
  rms(total) = 0.50482E+01    rms(broyden)= 0.50433E+01
  rms(prec ) = 0.60260E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3408
  0.3408

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4442.76036015
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       276.60286610
  PAW double counting   =      4958.26675166    -4888.70850894
  entropy T*S    EENTRO =        -0.02387104
  eigenvalues    EBANDS =     -1348.64317558
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -199.69405482 eV

  energy without entropy =     -199.67018378  energy(sigma->0) =     -199.68609781


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.3806587E+02  (-0.7014161E+01)
 number of electron     110.9999965 magnetization 
 augmentation part        4.3937284 magnetization 

 Broyden mixing:
  rms(total) = 0.23897E+01    rms(broyden)= 0.23798E+01
  rms(prec ) = 0.29286E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4647
  0.6846  0.2447

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4371.92201873
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.25573504
  PAW double counting   =      5164.44442960    -5094.20230671
  entropy T*S    EENTRO =         0.03663081
  eigenvalues    EBANDS =     -1379.81290150
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -161.62818835 eV

  energy without entropy =     -161.66481916  energy(sigma->0) =     -161.64039862


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.1257472E+01  (-0.2369903E+01)
 number of electron     110.9999981 magnetization 
 augmentation part        3.7153508 magnetization 

 Broyden mixing:
  rms(total) = 0.22806E+01    rms(broyden)= 0.22756E+01
  rms(prec ) = 0.28809E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5110
  1.0592  0.2630  0.2107

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4397.34442859
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       276.18537203
  PAW double counting   =      5590.84583794    -5520.98894659
  entropy T*S    EENTRO =        -0.14373387
  eigenvalues    EBANDS =     -1354.49706007
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -160.37071600 eV

  energy without entropy =     -160.22698213  energy(sigma->0) =     -160.32280471


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.6739368E+00  (-0.3261874E+01)
 number of electron     110.9999968 magnetization 
 augmentation part        3.3653770 magnetization 

 Broyden mixing:
  rms(total) = 0.33735E+01    rms(broyden)= 0.33694E+01
  rms(prec ) = 0.42195E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4321
  1.1168  0.3148  0.1997  0.0970

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4405.67632306
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       277.54964287
  PAW double counting   =      6011.79078984    -5941.96757550
  entropy T*S    EENTRO =        -0.12300947
  eigenvalues    EBANDS =     -1346.84254703
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -159.69677921 eV

  energy without entropy =     -159.57376974  energy(sigma->0) =     -159.65577605


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) : 0.7159663E+01  (-0.7205285E+00)
 number of electron     110.9999979 magnetization 
 augmentation part        4.3714426 magnetization 

 Broyden mixing:
  rms(total) = 0.21141E+01    rms(broyden)= 0.21113E+01
  rms(prec ) = 0.27815E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4090
  1.1709  0.3962  0.2395  0.1533  0.0848

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4411.54764122
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       277.87931118
  PAW double counting   =      6131.65196006    -6061.87901055
  entropy T*S    EENTRO =        -0.02568280
  eigenvalues    EBANDS =     -1334.18829651
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.53711670 eV

  energy without entropy =     -152.51143391  energy(sigma->0) =     -152.52855577


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.6110094E+00  (-0.2008185E+01)
 number of electron     110.9999975 magnetization 
 augmentation part        3.7526762 magnetization 

 Broyden mixing:
  rms(total) = 0.17905E+01    rms(broyden)= 0.17876E+01
  rms(prec ) = 0.22568E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4389
  1.4624  0.5067  0.3060  0.1862  0.0997  0.0723

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4423.61570292
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       278.49103721
  PAW double counting   =      6242.27398523    -6172.59052685
  entropy T*S    EENTRO =        -0.07757862
  eigenvalues    EBANDS =     -1321.97956444
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -151.92610725 eV

  energy without entropy =     -151.84852863  energy(sigma->0) =     -151.90024771


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.1853096E+01  (-0.7257778E+00)
 number of electron     110.9999998 magnetization 
 augmentation part        3.0243043 magnetization 

 Broyden mixing:
  rms(total) = 0.33759E+01    rms(broyden)= 0.33697E+01
  rms(prec ) = 0.41227E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4423
  1.7089  0.6383  0.2332  0.2332  0.1349  0.0740  0.0740

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4427.48810486
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.27865056
  PAW double counting   =      6490.96615304    -6421.23033792
  entropy T*S    EENTRO =        -0.25771461
  eigenvalues    EBANDS =     -1320.62009212
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -153.77920276 eV

  energy without entropy =     -153.52148816  energy(sigma->0) =     -153.69329789


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3335975E+01  (-0.6751168E+00)
 number of electron     110.9999981 magnetization 
 augmentation part        3.2862864 magnetization 

 Broyden mixing:
  rms(total) = 0.29803E+01    rms(broyden)= 0.29768E+01
  rms(prec ) = 0.36472E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4500
  1.9022  0.7200  0.2660  0.2660  0.1841  0.0934  0.0934  0.0749

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4437.50812034
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.18001534
  PAW double counting   =      6757.90822418    -6688.19090071
  entropy T*S    EENTRO =        -0.17033057
  eigenvalues    EBANDS =     -1308.23435930
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -150.44322826 eV

  energy without entropy =     -150.27289769  energy(sigma->0) =     -150.38645140


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.3306273E+00  (-0.1046171E+01)
 number of electron     110.9999984 magnetization 
 augmentation part        3.2839872 magnetization 

 Broyden mixing:
  rms(total) = 0.20385E+01    rms(broyden)= 0.20314E+01
  rms(prec ) = 0.26701E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4210
  1.9145  0.7551  0.2903  0.2903  0.1913  0.1240  0.0790  0.0790  0.0658

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4445.97943829
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.72804861
  PAW double counting   =      6914.75041318    -6845.02095303
  entropy T*S    EENTRO =        -0.03003431
  eigenvalues    EBANDS =     -1300.79413484
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -150.77385554 eV

  energy without entropy =     -150.74382123  energy(sigma->0) =     -150.76384410


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.9230101E+00  (-0.2677574E+00)
 number of electron     110.9999980 magnetization 
 augmentation part        3.8291277 magnetization 

 Broyden mixing:
  rms(total) = 0.20361E+01    rms(broyden)= 0.20323E+01
  rms(prec ) = 0.25111E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3959
  1.9365  0.6955  0.3817  0.2573  0.2573  0.1400  0.0716  0.0716  0.0736  0.0736

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4442.84621163
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.49855976
  PAW double counting   =      6950.83202836    -6881.07172949
  entropy T*S    EENTRO =        -0.13100665
  eigenvalues    EBANDS =     -1302.70472891
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -149.85084541 eV

  energy without entropy =     -149.71983876  energy(sigma->0) =     -149.80717653


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.5783786E+00  (-0.3840907E+00)
 number of electron     110.9999976 magnetization 
 augmentation part        3.5837554 magnetization 

 Broyden mixing:
  rms(total) = 0.16546E+01    rms(broyden)= 0.16499E+01
  rms(prec ) = 0.20683E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3806
  1.9921  0.5373  0.5373  0.2748  0.2748  0.1717  0.1100  0.0829  0.0829  0.0641
  0.0588

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4443.56297985
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.59166655
  PAW double counting   =      6971.92463127    -6902.16443037
  entropy T*S    EENTRO =        -0.02251190
  eigenvalues    EBANDS =     -1301.61108564
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -149.27246679 eV

  energy without entropy =     -149.24995489  energy(sigma->0) =     -149.26496282


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.4701787E+00  (-0.3289418E+00)
 number of electron     110.9999981 magnetization 
 augmentation part        3.7887157 magnetization 

 Broyden mixing:
  rms(total) = 0.13363E+01    rms(broyden)= 0.13347E+01
  rms(prec ) = 0.16628E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3722
  2.0038  0.5962  0.5962  0.2937  0.2937  0.1998  0.1321  0.0831  0.0831  0.0644
  0.0603  0.0603

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4443.75842764
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.65292777
  PAW double counting   =      7012.90948618    -6943.12858981
  entropy T*S    EENTRO =        -0.26057226
  eigenvalues    EBANDS =     -1300.78935547
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.80228809 eV

  energy without entropy =     -148.54171583  energy(sigma->0) =     -148.71543067


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.1130591E+00  (-0.1441651E+00)
 number of electron     110.9999982 magnetization 
 augmentation part        3.2809644 magnetization 

 Broyden mixing:
  rms(total) = 0.12924E+01    rms(broyden)= 0.12908E+01
  rms(prec ) = 0.15985E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4197
  2.0056  0.8637  0.8637  0.5951  0.2534  0.2534  0.1673  0.0845  0.0845  0.0966
  0.0748  0.0565  0.0565

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4446.17266288
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.71811549
  PAW double counting   =      7032.78887724    -6963.01214841
  entropy T*S    EENTRO =        -0.54693078
  eigenvalues    EBANDS =     -1298.03672276
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.68922896 eV

  energy without entropy =     -148.14229818  energy(sigma->0) =     -148.50691870


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.4915245E+00  (-0.3824730E+00)
 number of electron     110.9999973 magnetization 
 augmentation part        4.3402331 magnetization 

 Broyden mixing:
  rms(total) = 0.14988E+01    rms(broyden)= 0.14958E+01
  rms(prec ) = 0.18477E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4248
  2.1035  1.2018  0.8020  0.5716  0.2587  0.2587  0.1794  0.1092  0.1092  0.0838
  0.0838  0.0723  0.0606  0.0518

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4440.49121078
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.48434217
  PAW double counting   =      7063.91442574    -6994.01284983
  entropy T*S    EENTRO =        -0.15266893
  eigenvalues    EBANDS =     -1304.49503497
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -149.18075346 eV

  energy without entropy =     -149.02808454  energy(sigma->0) =     -149.12986382


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.3684573E+00  (-0.1881617E+00)
 number of electron     110.9999984 magnetization 
 augmentation part        3.8250145 magnetization 

 Broyden mixing:
  rms(total) = 0.13906E+01    rms(broyden)= 0.13894E+01
  rms(prec ) = 0.17713E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4053
  2.1648  1.1171  0.7027  0.7027  0.2584  0.2584  0.1841  0.1457  0.1152  0.0829
  0.0829  0.0766  0.0766  0.0578  0.0534

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4444.10035902
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.67037440
  PAW double counting   =      7114.30456136    -7044.39022835
  entropy T*S    EENTRO =        -0.45608563
  eigenvalues    EBANDS =     -1300.41280205
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.81229617 eV

  energy without entropy =     -148.35621053  energy(sigma->0) =     -148.66026762


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.1876417E+00  (-0.1206131E+00)
 number of electron     110.9999987 magnetization 
 augmentation part        3.7621630 magnetization 

 Broyden mixing:
  rms(total) = 0.13353E+01    rms(broyden)= 0.13337E+01
  rms(prec ) = 0.16685E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3867
  2.1586  1.1416  0.7142  0.7142  0.2598  0.2598  0.1727  0.1727  0.0834  0.0834
  0.1059  0.0958  0.0734  0.0561  0.0561  0.0399

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4444.46235063
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.72584180
  PAW double counting   =      7127.21631088    -7057.29837329
  entropy T*S    EENTRO =        -0.62754233
  eigenvalues    EBANDS =     -1299.75078400
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.62465443 eV

  energy without entropy =     -147.99711210  energy(sigma->0) =     -148.41547366


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.1784926E+00  (-0.3401362E-01)
 number of electron     110.9999980 magnetization 
 augmentation part        3.9203655 magnetization 

 Broyden mixing:
  rms(total) = 0.78650E+00    rms(broyden)= 0.78566E+00
  rms(prec ) = 0.97927E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4212
  2.2065  1.5392  0.6958  0.6958  0.3949  0.2914  0.2914  0.2076  0.2076  0.1078
  0.1078  0.0836  0.0836  0.0683  0.0683  0.0588  0.0520

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4444.51326219
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.73372195
  PAW double counting   =      7129.29535991    -7059.36428174
  entropy T*S    EENTRO =        -0.59054851
  eigenvalues    EBANDS =     -1299.57939437
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.44616180 eV

  energy without entropy =     -147.85561329  energy(sigma->0) =     -148.24931230


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.3022513E+00  (-0.1299138E+00)
 number of electron     110.9999996 magnetization 
 augmentation part        3.1599490 magnetization 

 Broyden mixing:
  rms(total) = 0.18466E+01    rms(broyden)= 0.18449E+01
  rms(prec ) = 0.22473E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4241
  2.2085  1.7253  0.7489  0.6250  0.4568  0.4568  0.2429  0.2429  0.1980  0.1123
  0.1123  0.0836  0.0836  0.0904  0.0676  0.0676  0.0588  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4447.00574518
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.77475012
  PAW double counting   =      7152.63876993    -7082.69397161
  entropy T*S    EENTRO =        -0.65709546
  eigenvalues    EBANDS =     -1297.37736399
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.74841305 eV

  energy without entropy =     -148.09131759  energy(sigma->0) =     -148.52938123


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3473024E+00  (-0.1277772E+00)
 number of electron     110.9999979 magnetization 
 augmentation part        3.6123661 magnetization 

 Broyden mixing:
  rms(total) = 0.78359E+00    rms(broyden)= 0.77528E+00
  rms(prec ) = 0.94660E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4055
  2.2186  1.6592  0.7220  0.6659  0.4480  0.4480  0.2485  0.2485  0.2000  0.1203
  0.1203  0.0837  0.0837  0.0950  0.0950  0.0679  0.0679  0.0591  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4446.33915086
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.76761144
  PAW double counting   =      7150.33061995    -7080.35699827
  entropy T*S    EENTRO =        -0.53011228
  eigenvalues    EBANDS =     -1297.84532380
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.40111069 eV

  energy without entropy =     -147.87099841  energy(sigma->0) =     -148.22440659


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) :-0.8522574E-01  (-0.9997684E-02)
 number of electron     110.9999980 magnetization 
 augmentation part        3.7249482 magnetization 

 Broyden mixing:
  rms(total) = 0.44870E+00    rms(broyden)= 0.44835E+00
  rms(prec ) = 0.55575E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4176
  2.2111  1.3766  0.9491  0.9491  0.4911  0.4911  0.3760  0.2385  0.2385  0.1922
  0.0836  0.0836  0.1132  0.1132  0.0990  0.0990  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4446.22445973
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.66332934
  PAW double counting   =      7151.61750957    -7081.64821863
  entropy T*S    EENTRO =        -0.57795531
  eigenvalues    EBANDS =     -1297.88878482
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.48633643 eV

  energy without entropy =     -147.90838112  energy(sigma->0) =     -148.29368466


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.2552980E-01  (-0.1630663E-01)
 number of electron     110.9999978 magnetization 
 augmentation part        3.8691797 magnetization 

 Broyden mixing:
  rms(total) = 0.45128E+00    rms(broyden)= 0.44998E+00
  rms(prec ) = 0.56023E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4473
  2.1871  1.5302  1.5302  0.8462  0.5461  0.4654  0.4654  0.3418  0.2279  0.2279
  0.2038  0.1196  0.0836  0.0836  0.1014  0.1014  0.0860  0.0678  0.0678  0.0589
  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4445.96897968
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.65852392
  PAW double counting   =      7153.04120368    -7083.07044427
  entropy T*S    EENTRO =        -0.58504910
  eigenvalues    EBANDS =     -1298.15936391
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.51186623 eV

  energy without entropy =     -147.92681713  energy(sigma->0) =     -148.31684986


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.1124794E+00  (-0.6165543E-01)
 number of electron     110.9999979 magnetization 
 augmentation part        3.5768641 magnetization 

 Broyden mixing:
  rms(total) = 0.92847E+00    rms(broyden)= 0.92670E+00
  rms(prec ) = 0.11448E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4694
  2.2558  1.7378  1.7378  0.7413  0.7413  0.5316  0.5316  0.2939  0.2939  0.2171
  0.2171  0.2054  0.0836  0.0836  0.1167  0.1019  0.1019  0.0890  0.0678  0.0678
  0.0589  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4447.35745729
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.69017718
  PAW double counting   =      7153.68503903    -7083.72089922
  entropy T*S    EENTRO =        -0.51625167
  eigenvalues    EBANDS =     -1296.97719676
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.62434559 eV

  energy without entropy =     -148.10809392  energy(sigma->0) =     -148.45226170


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) : 0.1225799E+00  (-0.7828510E-01)
 number of electron     110.9999986 magnetization 
 augmentation part        3.5060212 magnetization 

 Broyden mixing:
  rms(total) = 0.65129E+00    rms(broyden)= 0.64743E+00
  rms(prec ) = 0.78570E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4811
  2.2053  2.2053  1.6864  0.7612  0.7612  0.6392  0.4012  0.4012  0.3526  0.2328
  0.2328  0.1944  0.1701  0.0836  0.0836  0.1141  0.1023  0.1023  0.0893  0.0678
  0.0678  0.0589  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.04168720
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.75145903
  PAW double counting   =      7161.81731412    -7091.85470472
  entropy T*S    EENTRO =        -0.71311995
  eigenvalues    EBANDS =     -1296.03327011
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.50176570 eV

  energy without entropy =     -147.78864574  energy(sigma->0) =     -148.26405905


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.7620612E-01  (-0.4511856E-01)
 number of electron     110.9999976 magnetization 
 augmentation part        3.9185009 magnetization 

 Broyden mixing:
  rms(total) = 0.61845E+00    rms(broyden)= 0.61643E+00
  rms(prec ) = 0.77042E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4994
  2.5117  2.3369  1.5858  0.8494  0.8494  0.7229  0.4210  0.4210  0.3213  0.3213
  0.2288  0.2288  0.2101  0.1537  0.0836  0.0836  0.1160  0.1019  0.1019  0.0892
  0.0678  0.0678  0.0589  0.0519

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4446.79830855
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.65378007
  PAW double counting   =      7155.99852149    -7086.01776965
  entropy T*S    EENTRO =        -0.53274092
  eigenvalues    EBANDS =     -1297.45369739
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.57797181 eV

  energy without entropy =     -148.04523089  energy(sigma->0) =     -148.40039151


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3033204E-01  (-0.5072936E-01)
 number of electron     110.9999983 magnetization 
 augmentation part        3.4571373 magnetization 

 Broyden mixing:
  rms(total) = 0.66109E+00    rms(broyden)= 0.65911E+00
  rms(prec ) = 0.80678E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5284
  3.1044  2.3453  1.3589  1.3589  0.7659  0.7659  0.5664  0.4146  0.4146  0.2746
  0.2336  0.2336  0.2064  0.2064  0.1378  0.0836  0.0836  0.1164  0.1019  0.1019
  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.31926073
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.71719678
  PAW double counting   =      7159.21085936    -7089.23725229
  entropy T*S    EENTRO =        -0.68126549
  eigenvalues    EBANDS =     -1295.81016054
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.54763978 eV

  energy without entropy =     -147.86637429  energy(sigma->0) =     -148.32055128


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :   216
 total energy-change (2. order) :-0.3749549E-01  (-0.6009799E-01)
 number of electron     110.9999978 magnetization 
 augmentation part        3.8399930 magnetization 

 Broyden mixing:
  rms(total) = 0.70984E+00    rms(broyden)= 0.70883E+00
  rms(prec ) = 0.86801E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5258
  3.2991  2.3206  1.2923  1.2923  0.8131  0.8131  0.5275  0.4235  0.4235  0.3866
  0.2414  0.2414  0.2141  0.2103  0.2103  0.1383  0.0836  0.0836  0.1161  0.1019
  0.1019  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4447.46586776
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.65277924
  PAW double counting   =      7154.67526771    -7084.68716491
  entropy T*S    EENTRO =        -0.54298152
  eigenvalues    EBANDS =     -1296.78941116
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.58513527 eV

  energy without entropy =     -148.04215375  energy(sigma->0) =     -148.40414143


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) : 0.2586564E-01  (-0.1700069E-01)
 number of electron     110.9999983 magnetization 
 augmentation part        3.6018222 magnetization 

 Broyden mixing:
  rms(total) = 0.34110E+00    rms(broyden)= 0.34025E+00
  rms(prec ) = 0.42791E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5561
  3.5304  2.3104  1.5820  1.1987  1.1987  0.7132  0.5412  0.5412  0.4375  0.4375
  0.4279  0.2689  0.2311  0.2311  0.2034  0.2034  0.1354  0.0836  0.0836  0.1162
  0.1019  0.1019  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.18273483
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.67279912
  PAW double counting   =      7157.47047969    -7087.48959397
  entropy T*S    EENTRO =        -0.68748081
  eigenvalues    EBANDS =     -1295.91498197
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.55926963 eV

  energy without entropy =     -147.87178882  energy(sigma->0) =     -148.33010936


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.6644840E-03  (-0.3893704E-02)
 number of electron     110.9999982 magnetization 
 augmentation part        3.6687918 magnetization 

 Broyden mixing:
  rms(total) = 0.19502E+00    rms(broyden)= 0.19426E+00
  rms(prec ) = 0.23634E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6045
  4.1772  2.3129  1.9452  1.2956  1.2956  0.7322  0.7322  0.6626  0.4463  0.4463
  0.4094  0.3626  0.2774  0.2308  0.2308  0.2044  0.2044  0.1358  0.0836  0.0836
  0.1162  0.1019  0.1019  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.11087357
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.66163407
  PAW double counting   =      7157.02137375    -7087.03904055
  entropy T*S    EENTRO =        -0.68611474
  eigenvalues    EBANDS =     -1295.97782723
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.55860514 eV

  energy without entropy =     -147.87249040  energy(sigma->0) =     -148.32990023


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.4947262E-02  (-0.1749859E-02)
 number of electron     110.9999981 magnetization 
 augmentation part        3.6968397 magnetization 

 Broyden mixing:
  rms(total) = 0.11864E+00    rms(broyden)= 0.11836E+00
  rms(prec ) = 0.14692E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6370
  4.9254  2.4811  2.1515  1.2305  1.2305  0.8030  0.8030  0.6176  0.4733  0.4733
  0.4024  0.4024  0.3786  0.2711  0.2311  0.2311  0.2045  0.2045  0.1358  0.0836
  0.0836  0.1162  0.1019  0.1019  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.06803566
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.64893854
  PAW double counting   =      7155.84808889    -7085.86304996
  entropy T*S    EENTRO =        -0.65880388
  eigenvalues    EBANDS =     -1296.04293347
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.56355241 eV

  energy without entropy =     -147.90474853  energy(sigma->0) =     -148.34395111


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.6385799E-02  (-0.2403264E-03)
 number of electron     110.9999981 magnetization 
 augmentation part        3.6884430 magnetization 

 Broyden mixing:
  rms(total) = 0.16901E+00    rms(broyden)= 0.16874E+00
  rms(prec ) = 0.20552E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6448
  5.2064  2.5342  2.1546  1.2884  1.2884  0.7133  0.7133  0.6491  0.5585  0.5585
  0.4287  0.4287  0.3826  0.3396  0.2708  0.2311  0.2311  0.2045  0.2045  0.1358
  0.0836  0.0836  0.1162  0.1019  0.1019  0.0892  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.14198105
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.64425743
  PAW double counting   =      7155.14976695    -7085.16556779
  entropy T*S    EENTRO =        -0.64520215
  eigenvalues    EBANDS =     -1295.98345473
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.56993820 eV

  energy without entropy =     -147.92473606  energy(sigma->0) =     -148.35487082


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.6107142E-03  (-0.1419112E-03)
 number of electron     110.9999981 magnetization 
 augmentation part        3.6824111 magnetization 

 Broyden mixing:
  rms(total) = 0.92901E-01    rms(broyden)= 0.92851E-01
  rms(prec ) = 0.11329E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6618
  5.3690  2.5583  2.1888  1.2872  1.2872  0.7973  0.7973  0.7412  0.7412  0.5727
  0.4644  0.4644  0.4049  0.4049  0.3367  0.2716  0.2311  0.2311  0.2045  0.2045
  0.1358  0.0836  0.0836  0.1162  0.1019  0.1019  0.0892  0.0678  0.0678  0.0519
  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.19335668
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.64440882
  PAW double counting   =      7155.18328255    -7085.20081696
  entropy T*S    EENTRO =        -0.65489587
  eigenvalues    EBANDS =     -1295.92019250
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.56932749 eV

  energy without entropy =     -147.91443162  energy(sigma->0) =     -148.35102887


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :   216
 total energy-change (2. order) :-0.2195135E-02  (-0.2373105E-03)
 number of electron     110.9999982 magnetization 
 augmentation part        3.6493854 magnetization 

 Broyden mixing:
  rms(total) = 0.61859E-01    rms(broyden)= 0.61622E-01
  rms(prec ) = 0.75796E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7172
  5.9455  2.9276  2.2610  1.6935  1.3315  1.3315  0.7785  0.7392  0.7392  0.5489
  0.5147  0.5147  0.4194  0.4194  0.3433  0.3433  0.2707  0.2311  0.2311  0.2045
  0.2045  0.1358  0.0836  0.0836  0.1162  0.1019  0.1019  0.0892  0.0678  0.0678
  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.29602636
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.64399988
  PAW double counting   =      7155.46354220    -7085.48263104
  entropy T*S    EENTRO =        -0.67782954
  eigenvalues    EBANDS =     -1295.79482091
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.57152263 eV

  energy without entropy =     -147.89369309  energy(sigma->0) =     -148.34557945


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.3424007E-02  (-0.1969022E-03)
 number of electron     110.9999982 magnetization 
 augmentation part        3.6761364 magnetization 

 Broyden mixing:
  rms(total) = 0.46016E-01    rms(broyden)= 0.45814E-01
  rms(prec ) = 0.56494E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7316
  6.1855  3.1263  2.3152  1.7691  1.2642  1.2642  0.7637  0.7637  0.7379  0.7379
  0.5107  0.5107  0.5179  0.4297  0.4297  0.3848  0.3305  0.2705  0.2311  0.2311
  0.2045  0.2045  0.1358  0.0836  0.0836  0.1162  0.1019  0.1019  0.0892  0.0678
  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.22182815
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.63531218
  PAW double counting   =      7155.16801079    -7085.18577758
  entropy T*S    EENTRO =        -0.67050096
  eigenvalues    EBANDS =     -1295.87240605
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.57494663 eV

  energy without entropy =     -147.90444567  energy(sigma->0) =     -148.35144631


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.4588827E-03  (-0.4649361E-04)
 number of electron     110.9999981 magnetization 
 augmentation part        3.6673078 magnetization 

 Broyden mixing:
  rms(total) = 0.21035E-01    rms(broyden)= 0.20947E-01
  rms(prec ) = 0.26022E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7568
  6.5416  3.3124  2.3719  1.8607  1.2805  1.1964  1.1964  0.7799  0.7799  0.7436
  0.5840  0.5070  0.5070  0.4404  0.4201  0.4201  0.3539  0.3332  0.2707  0.2311
  0.2311  0.2045  0.2045  0.1358  0.0836  0.0836  0.1162  0.1019  0.1019  0.0892
  0.0678  0.0678  0.0519  0.0589

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       500.09350112
  -Hartree energ DENC   =     -4448.23213841
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       280.63409208
  PAW double counting   =      7155.24357643    -7085.26122980
  entropy T*S    EENTRO =        -0.67114545
  eigenvalues    EBANDS =     -1295.86080350
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -148.57540552 eV

  energy without entropy =     -147.90426006  energy(sigma->0) =     -148.35169036


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------