vasp.6.2.1 16May21 (build Apr 11 2022 11:03:26) complex                        
  
 MD_VERSION_INFO: Compiled 2022-04-11T18:25:55-UTC in devlin.sd.materialsdesign.
 com:/home/medea2/data/build/vasp6.2.1/16685/x86_64/src/src/build/gpu from svn 1
 6685
 
 This VASP executable licensed from Materials Design, Inc.
 
 executed on                        Lin64 date 2025.10.21  20:23:51
 running on    4 total cores
 distrk:  each k-point on    4 cores,    1 groups
 distr:  one band on NCORE=   1 cores,    4 groups


--------------------------------------------------------------------------------------------------------


 INCAR:
   SYSTEM = No title
   PREC = Normal
   ENCUT = 400.000
   IBRION = -1
   NSW = 0
   ISIF = 2
   NELMIN = 2
   EDIFF = 1.0e-05
   EDIFFG = -0.02
   VOSKOWN = 1
   NBLOCK = 1
   NWRITE = 1
   NELM = 200
   ALGO = Normal (blocked Davidson)
   ISPIN = 1
   INIWAV = 1
   ISTART = 0
   ICHARG = 2
   LWAVE = .FALSE.
   LCHARG = .FALSE.
   ADDGRID = .FALSE.
   ISMEAR = 1
   SIGMA = 0.2
   LREAL = Auto
   LSCALAPACK = .FALSE.
   RWIGS = 1.11 0.73 0.32 0.77
   NPAR = 4

 POTCAR:    PAW_PBE Si 05Jan2001                  
 POTCAR:    PAW_PBE O 08Apr2002                   
 POTCAR:    PAW_PBE H 15Jun2001                   
 POTCAR:    PAW_PBE C 08Apr2002                   
 POTCAR:    PAW_PBE Si 05Jan2001                  
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE O 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  kinetic energy density of atom read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 POTCAR:    PAW_PBE H 15Jun2001                   
  local pseudopotential read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           3
   number of lm-projection operators is LMMAX =           5
 
 POTCAR:    PAW_PBE C 08Apr2002                   
  local pseudopotential read in
  partial core-charges read in
  partial kinetic energy density read in
  atomic valenz-charges read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           0  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
  non local Contribution for L=           1  read in
    real space projection operators read in
    PAW grid and wavefunctions read in
 
   number of l-projection  operators is LMAX  =           4
   number of lm-projection operators is LMMAX =           8
 
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 19.84
 optimisation between [QCUT,QGAM] = [ 10.12, 20.44] = [ 28.68,116.96] Ry 
 Optimized for a Real-space Cutoff    1.23 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      7    10.119   159.560    0.56E-04    0.22E-03    0.45E-07
   0      7    10.119   115.863    0.56E-04    0.21E-03    0.45E-07
   1      7    10.119    88.339    0.34E-03    0.49E-03    0.11E-06
   1      7    10.119    48.592    0.33E-03    0.48E-03    0.11E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 24.76
 optimisation between [QCUT,QGAM] = [ 10.15, 20.30] = [ 28.85,115.39] Ry 
 Optimized for a Real-space Cutoff    1.38 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.150    20.381    0.22E-03    0.32E-03    0.29E-06
   0      8    10.150    15.268    0.23E-03    0.35E-03    0.30E-06
   1      8    10.150     5.964    0.46E-03    0.53E-03    0.21E-06
   1      8    10.150     5.382    0.38E-03    0.45E-03    0.19E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 34.20
 optimisation between [QCUT,QGAM] = [  9.92, 20.18] = [ 27.55,114.04] Ry 
 Optimized for a Real-space Cutoff    1.26 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8     9.919    19.460    0.50E-03    0.23E-03    0.29E-06
   0      8     9.919    12.209    0.48E-03    0.23E-03    0.28E-06
   1      7     9.919     4.655    0.17E-03    0.75E-03    0.30E-06
 Optimization of the real space projectors (new method)

 maximal supplied QI-value         = 25.13
 optimisation between [QCUT,QGAM] = [ 10.05, 20.36] = [ 28.30,116.06] Ry 
 Optimized for a Real-space Cutoff    1.30 Angstroem

   l    n(q)    QCUT    max X(q) W(low)/X(q) W(high)/X(q)  e(spline) 
   0      8    10.053   115.676    0.49E-03    0.72E-03    0.18E-06
   0      8    10.053    87.132    0.49E-03    0.71E-03    0.18E-06
   1      7    10.053     4.429    0.32E-03    0.31E-03    0.18E-06
   1      7    10.053     2.733    0.23E-03    0.19E-03    0.20E-06
  PAW_PBE Si 05Jan2001                  :
 energy of atom  1       EATOM= -103.0669
 kinetic energy error for atom=    0.0012 (will be added to EATOM!!)
  PAW_PBE O 08Apr2002                   :
 energy of atom  2       EATOM= -432.3788
 kinetic energy error for atom=    0.1156 (will be added to EATOM!!)
  PAW_PBE H 15Jun2001                   :
 energy of atom  3       EATOM=  -12.4884
 kinetic energy error for atom=    0.0098 (will be added to EATOM!!)
  PAW_PBE C 08Apr2002                   :
 energy of atom  4       EATOM= -147.1560
 kinetic energy error for atom=    0.0288 (will be added to EATOM!!)
 
 
 POSCAR: No title
  positions in direct lattice
  No initial velocities read in
 exchange correlation table for  LEXCH =        8
   RHO(1)=    0.500       N(1)  =     2000
   RHO(2)=  100.500       N(2)  =     4000
 


--------------------------------------------------------------------------------------------------------


 ion  position               nearest neighbor table
   1  0.605  0.001  0.847-  22 1.50  29 1.51  33 1.59
   2  0.167  0.372  0.881-   9 1.50
   3  0.829  0.937  0.525-  19 1.52  41 1.76
   4  0.787  0.229  0.120-  39 1.67
   5  0.582  0.140  0.021-  17 1.58
   6  0.318  0.562  0.658-  11 1.28
   7  0.976  0.598  0.280-   8 1.36
   8  0.954  0.613  0.365-  18 1.03   7 1.36
   9  0.176  0.300  0.949-   2 1.50
  10  0.180  0.422  0.412-  21 0.99  34 1.03
  11  0.376  0.579  0.625-  43 1.20   6 1.28
  12  0.417  0.997  0.241-  30 0.99
  13  0.931  0.507  0.739-  32 0.71
  14  0.479  0.760  0.193-  38 1.16
  15  0.244  0.578  0.286-
  16  0.813  0.211  0.983-
  17  0.510  0.168  0.987-   5 1.58
  18  0.907  0.583  0.369-   8 1.03
  19  0.823  0.873  0.446-   3 1.52
  20  0.797  0.261  0.591-
  21  0.216  0.443  0.372-  10 0.99
  22  0.573  0.911  0.855-   1 1.50
  23  0.577  0.863  0.495-  31 0.76
  24  0.125  0.526  0.045-  40 1.13
  25  0.193  0.872  0.438-  27 0.75
  26  0.056  0.156  0.212-
  27  0.213  0.834  0.458-  25 0.75
  28  0.736  0.575  0.240-
  29  0.564  0.060  0.787-   1 1.51
  30  0.391  0.012  0.295-  12 0.99
  31  0.560  0.820  0.511-  23 0.76
  32  0.935  0.544  0.711-  13 0.71
  33  0.615  0.050  0.941-   1 1.59
  34  0.159  0.476  0.442-  10 1.03
  35  0.246  0.541  0.325-
  36  0.033  0.140  0.173-
  37  0.178  0.548  0.954-  40 1.13
  38  0.509  0.813  0.154-  14 1.16
  39  0.715  0.234  0.175-   4 1.67
  40  0.164  0.575  0.022-  24 1.13  37 1.13
  41  0.791  0.934  0.630-   3 1.76
  42  0.450  0.571  0.414-
  43  0.433  0.588  0.603-  11 1.20
 
  LATTYP: Found a simple tetragonal cell.
 ALAT       =    15.0000000000
 C/A-ratio  =     1.3333333333
  
  Lattice vectors:
  
 A1 = (   0.0000000000,  15.0000000000,   0.0000000000)
 A2 = (   0.0000000000,   0.0000000000,  15.0000000000)
 A3 = (  20.0000000000,   0.0000000000,   0.0000000000)


Analysis of symmetry for initial positions (statically):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The static configuration has the point symmetry C_1 .


Analysis of symmetry for dynamics (positions and initial velocities):
=====================================================================
 Subroutine PRICEL returns:
 Original cell was already a primitive cell.
 

 Routine SETGRP: Setting up the symmetry group for a 
 simple tetragonal supercell.


 Subroutine GETGRP returns: Found  1 space group operations
 (whereof  1 operations were pure point group operations)
 out of a pool of 16 trial point group operations.


The dynamic configuration has the point symmetry C_1 .


 Subroutine INISYM returns: Found  1 space group operations
 (whereof  1 operations are pure point group operations),
 and found     1 'primitive' translations


----------------------------------------------------------------------------------------

                                     Primitive cell                                     

  volume of cell :    4500.0000

  direct lattice vectors                    reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667

  position of ions in fractional coordinates (direct lattice)
     0.605425670  0.001189610  0.847400230
     0.167232490  0.372131370  0.880535290
     0.829261390  0.936627910  0.524788520
     0.787266190  0.229490370  0.120467880
     0.582123710  0.140305150  0.021156380
     0.318310420  0.562197050  0.657845840
     0.976242910  0.598143190  0.280106460
     0.954173020  0.612621270  0.364923710
     0.176038170  0.299702610  0.948964900
     0.180045870  0.421558710  0.411521900
     0.375850460  0.579221920  0.624987180
     0.417158520  0.996679740  0.240637710
     0.930914730  0.506525230  0.739394900
     0.478982940  0.759562990  0.192985220
     0.243862160  0.577870330  0.285507750
     0.812678720  0.210983780  0.982774410
     0.510166720  0.168083180  0.987097360
     0.907480940  0.583483570  0.369231610
     0.823104410  0.872890550  0.446405140
     0.797195520  0.261006880  0.591028710
     0.216276830  0.442733140  0.372124360
     0.572744790  0.911335990  0.855032170
     0.576647510  0.862675430  0.495137410
     0.124863090  0.525978840  0.045030180
     0.193067090  0.871785190  0.438344690
     0.056019510  0.156465520  0.211848550
     0.213024470  0.834335890  0.458411320
     0.735871330  0.574736070  0.240269850
     0.564015070  0.060139730  0.786920950
     0.391019200  0.011713830  0.294865510
     0.560152620  0.819713140  0.511430220
     0.935045340  0.543897080  0.711300710
     0.614695290  0.050257600  0.940700330
     0.158771420  0.475992700  0.442133210
     0.246427180  0.541330950  0.324904990
     0.032932550  0.140094370  0.172914710
     0.178344860  0.547588210  0.953835220
     0.508830010  0.812605320  0.153830960
     0.714898530  0.233976460  0.175294970
     0.164027730  0.574994820  0.021647040
     0.791199050  0.934450520  0.630257180
     0.449888940  0.570661570  0.413877330
     0.433333060  0.588415480  0.603492440

  ion indices of the primitive-cell ions
   primitive index   ion index
                 1           1
                 2           2
                 3           3
                 4           4
                 5           5
                 6           6
                 7           7
                 8           8
                 9           9
                10          10
                11          11
                12          12
                13          13
                14          14
                15          15
                16          16
                17          17
                18          18
                19          19
                20          20
                21          21
                22          22
                23          23
                24          24
                25          25
                26          26
                27          27
                28          28
                29          29
                30          30
                31          31
                32          32
                33          33
                34          34
                35          35
                36          36
                37          37
                38          38
                39          39
                40          40
                41          41
                42          42
                43          43

----------------------------------------------------------------------------------------

 
 
 KPOINTS: Automatic mesh                          

Automatic generation of k-mesh.
 Grid dimensions read from file:
 generate k-points for:    1    1    1

 Generating k-lattice:

  Cartesian coordinates                     Fractional coordinates (reciprocal lattice)
     0.050000000  0.000000000  0.000000000     1.000000000  0.000000000  0.000000000
     0.000000000  0.066666667  0.000000000     0.000000000  1.000000000  0.000000000
     0.000000000  0.000000000  0.066666667     0.000000000  0.000000000  1.000000000

  Length of vectors
     0.050000000  0.066666667  0.066666667

  Shift w.r.t. Gamma in fractional coordinates (k-lattice)
     0.000000000  0.000000000  0.000000000

 
 Subroutine IBZKPT returns following result:
 ===========================================
 
 Found      1 irreducible k-points:
 
 Following reciprocal coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 
 Following cartesian coordinates:
            Coordinates               Weight
  0.000000  0.000000  0.000000      1.000000
 


--------------------------------------------------------------------------------------------------------




 Dimension of arrays:
   k-points           NKPTS =      1   k-points in BZ     NKDIM =      1   number of bands    NBANDS=     80
   number of dos      NEDOS =    301   number of ions     NIONS =     43
   non local maximal  LDIM  =      4   non local SUM 2l+1 LMDIM =      8
   total plane-waves  NPLWV = 627200
   max r-space proj   IRMAX =   1586   max aug-charges    IRDMAX=   4859
   dimension x,y,z NGX =    98 NGY =   80 NGZ =   80
   dimension x,y,z NGXF=   196 NGYF=  160 NGZF=  160
   support grid    NGXF=   196 NGYF=  160 NGZF=  160
   ions per type =               5   7  25   6
   NGX,Y,Z   is equivalent  to a cutoff of   8.15,  8.87,  8.87 a.u.
   NGXF,Y,Z  is equivalent  to a cutoff of  16.29, 17.73, 17.73 a.u.

 SYSTEM =  No title                                
 POSCAR =  No title                                

 Startparameter for this run:
   NWRITE =      1    write-flag & timer
   PREC   = normal    normal or accurate (medium, high low for compatibility)
   ISTART =      0    job   : 0-new  1-cont  2-samecut
   ICHARG =      2    charge: 1-file 2-atom 10-const
   ISPIN  =      1    spin polarized calculation?
   LNONCOLLINEAR =      F non collinear calculations
   LSORBIT =      F    spin-orbit coupling
   INIWAV =      1    electr: 0-lowe 1-rand  2-diag
   LASPH  =      F    aspherical Exc in radial PAW
 Electronic Relaxation 1
   ENCUT  =  400.0 eV  29.40 Ry    5.42 a.u.  32.61 24.46 24.46*2*pi/ulx,y,z
   ENINI  =  400.0     initial cutoff
   ENAUG  =  644.9 eV  augmentation charge cutoff
   NELM   =    200;   NELMIN=  2; NELMDL= -5     # of ELM steps 
   EDIFF  = 0.1E-04   stopping-criterion for ELM
   LREAL  =      T    real-space projection
   NLSPLINE    = F    spline interpolate recip. space projectors
   LCOMPAT=      F    compatible to vasp.4.4
   GGA_COMPAT  = T    GGA compatible to vasp.4.4-vasp.4.6
   LMAXPAW     = -100 max onsite density
   LMAXMIX     =    2 max onsite mixed and CHGCAR
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   ROPT   =   -0.00050  -0.00050  -0.00050  -0.00050
 Ionic relaxation
   EDIFFG = -.2E-01   stopping-criterion for IOM
   NSW    =      0    number of steps for IOM
   NBLOCK =      1;   KBLOCK =      1    inner block; outer block 
   IBRION =     -1    ionic relax: 0-MD 1-quasi-New 2-CG
   NFREE  =      0    steps in history (QN), initial steepest desc. (CG)
   ISIF   =      2    stress and relaxation
   IWAVPR =     10    prediction:  0-non 1-charg 2-wave 3-comb
   ISYM   =      2    0-nonsym 1-usesym 2-fastsym
   LCORR  =      T    Harris-Foulkes like correction to forces

   POTIM  = 0.5000    time-step for ionic-motion
   TEIN   =    0.0    initial temperature
   TEBEG  =    0.0;   TEEND  =   0.0 temperature during run
   SMASS  =  -3.00    Nose mass-parameter (am)
   estimated Nose-frequenzy (Omega)   =  0.10E-29 period in steps = 0.13E+47 mass=  -0.914E-26a.u.
   SCALEE = 1.0000    scale energy and forces
   NPACO  =    256;   APACO  = 16.0  distance and # of slots for P.C.
   PSTRESS=    0.0 pullay stress

  Mass of Ions in am
   POMASS =  28.09 16.00  1.00 12.01
  Ionic Valenz
   ZVAL   =   4.00  6.00  1.00  4.00
  Atomic Wigner-Seitz radii
   RWIGS  =   1.11  0.73  0.32  0.77
  virtual crystal weights 
   VCA    =   1.00  1.00  1.00  1.00
   NELECT =     111.0000    total number of electrons
   NUPDOWN=      -1.0000    fix difference up-down

 DOS related values:
   EMIN   =  10.00;   EMAX   =-10.00  energy-range for DOS
   EFERMI =   0.00
   ISMEAR =     1;   SIGMA  =   0.20  broadening in eV -4-tet -1-fermi 0-gaus

 Electronic relaxation 2 (details)
   IALGO  =     38    algorithm
   LDIAG  =      T    sub-space diagonalisation (order eigenvalues)
   LSUBROT=      F    optimize rotation matrix (better conditioning)
   TURBO    =      0    0=normal 1=particle mesh
   IRESTART =      0    0=no restart 2=restart with 2 vectors
   NREBOOT  =      0    no. of reboots
   NMIN     =      0    reboot dimension
   EREF     =   0.00    reference energy to select bands
   IMIX   =      4    mixing-type and parameters
     AMIX     =   0.40;   BMIX     =  1.00
     AMIX_MAG =   1.60;   BMIX_MAG =  1.00
     AMIN     =   0.10
     WC   =   100.;   INIMIX=   1;  MIXPRE=   1;  MAXMIX= -45

 Intra band minimization:
   WEIMIN = 0.0000     energy-eigenvalue tresh-hold
   EBREAK =  0.31E-07  absolut break condition
   DEPER  =   0.30     relativ break condition  

   TIME   =   0.40     timestep for ELM

  volume/ion in A,a.u.               =     104.65       706.22
  Fermi-wavevector in a.u.,A,eV,Ry     =   0.476553  0.900556  3.089927  0.227103
  Thomas-Fermi vector in A             =   1.472006
 
 Write flags
   LWAVE        =      F    write WAVECAR
   LDOWNSAMPLE  =      F    k-point downsampling of WAVECAR
   LCHARG       =      F    write CHGCAR
   LVTOT        =      F    write LOCPOT, total local potential
   LVHAR        =      F    write LOCPOT, Hartree potential only
   LELF         =      F    write electronic localiz. function (ELF)
   LORBIT       =      0    0 simple, 1 ext, 2 COOP (PROOUT), +10 PAW based schemes


 Dipole corrections
   LMONO  =      F    monopole corrections only (constant potential shift)
   LDIPOL =      F    correct potential (dipole corrections)
   IDIPOL =      0    1-x, 2-y, 3-z, 4-all directions 
   EPSILON=  1.0000000 bulk dielectric constant

 Exchange correlation treatment:
   GGA     =    --    GGA type
   LEXCH   =     8    internal setting for exchange type
   VOSKOWN=      1    Vosko Wilk Nusair interpolation
   LHFCALC =     F    Hartree Fock is set to
   LHFONE  =     F    Hartree Fock one center treatment
   AEXX    =    0.0000 exact exchange contribution

 Linear response parameters
   LEPSILON=     F    determine dielectric tensor
   LRPA    =     F    only Hartree local field effects (RPA)
   LNABLA  =     F    use nabla operator in PAW spheres
   LVEL    =     F    velocity operator in full k-point grid
   LINTERFAST=   F  fast interpolation
   KINTER  =     0    interpolate to denser k-point grid
   CSHIFT  =0.1000    complex shift for real part using Kramers Kronig
   OMEGAMAX=  -1.0    maximum frequency
   DEG_THRESHOLD= 0.2000000E-02 threshold for treating states as degnerate
   RTIME   =   -0.100 relaxation time in fs
  (WPLASMAI=    0.000 imaginary part of plasma frequency in eV, 0.658/RTIME)
   DFIELD  = 0.0000000 0.0000000 0.0000000 field for delta impulse in time
 
 Orbital magnetization related:
   ORBITALMAG=     F  switch on orbital magnetization
   LCHIMAG   =     F  perturbation theory with respect to B field
   DQ        =  0.001000  dq finite difference perturbation B field
   LLRAUG    =     F  two centre corrections for induced B field



--------------------------------------------------------------------------------------------------------


 Static calculation
 charge density and potential will be updated during run
 non-spin polarized calculation
 Variant of blocked Davidson
 Davidson routine will perform the subspace rotation
 perform sub-space diagonalisation
    after iterative eigenvector-optimisation
 modified Broyden-mixing scheme, WC =      100.0
 initial mixing is a Kerker type mixing with AMIX =  0.4000 and BMIX =      1.0000
 Hartree-type preconditioning will be used
 using additional bands           24
 real space projection scheme for non local part
 use partial core corrections
 calculate Harris-corrections to forces 
   (improved forces if not selfconsistent)
 use gradient corrections 
 use of overlap-Matrix (Vanderbilt PP)
 Methfessel and Paxton  Order N= 1 SIGMA  =   0.20


--------------------------------------------------------------------------------------------------------


  energy-cutoff  :      400.00
  volume of cell :     4500.00
      direct lattice vectors                 reciprocal lattice vectors
    20.000000000  0.000000000  0.000000000     0.050000000  0.000000000  0.000000000
     0.000000000 15.000000000  0.000000000     0.000000000  0.066666667  0.000000000
     0.000000000  0.000000000 15.000000000     0.000000000  0.000000000  0.066666667

  length of vectors
    20.000000000 15.000000000 15.000000000     0.050000000  0.066666667  0.066666667


 
 k-points in units of 2pi/SCALE and weight: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 k-points in reciprocal lattice and weights: Automatic mesh                          
   0.00000000  0.00000000  0.00000000       1.000
 
 position of ions in fractional coordinates (direct lattice) 
   0.60542567  0.00118961  0.84740023
   0.16723249  0.37213137  0.88053529
   0.82926139  0.93662791  0.52478852
   0.78726619  0.22949037  0.12046788
   0.58212371  0.14030515  0.02115638
   0.31831042  0.56219705  0.65784584
   0.97624291  0.59814319  0.28010646
   0.95417302  0.61262127  0.36492371
   0.17603817  0.29970261  0.94896490
   0.18004587  0.42155871  0.41152190
   0.37585046  0.57922192  0.62498718
   0.41715852  0.99667974  0.24063771
   0.93091473  0.50652523  0.73939490
   0.47898294  0.75956299  0.19298522
   0.24386216  0.57787033  0.28550775
   0.81267872  0.21098378  0.98277441
   0.51016672  0.16808318  0.98709736
   0.90748094  0.58348357  0.36923161
   0.82310441  0.87289055  0.44640514
   0.79719552  0.26100688  0.59102871
   0.21627683  0.44273314  0.37212436
   0.57274479  0.91133599  0.85503217
   0.57664751  0.86267543  0.49513741
   0.12486309  0.52597884  0.04503018
   0.19306709  0.87178519  0.43834469
   0.05601951  0.15646552  0.21184855
   0.21302447  0.83433589  0.45841132
   0.73587133  0.57473607  0.24026985
   0.56401507  0.06013973  0.78692095
   0.39101920  0.01171383  0.29486551
   0.56015262  0.81971314  0.51143022
   0.93504534  0.54389708  0.71130071
   0.61469529  0.05025760  0.94070033
   0.15877142  0.47599270  0.44213321
   0.24642718  0.54133095  0.32490499
   0.03293255  0.14009437  0.17291471
   0.17834486  0.54758821  0.95383522
   0.50883001  0.81260532  0.15383096
   0.71489853  0.23397646  0.17529497
   0.16402773  0.57499482  0.02164704
   0.79119905  0.93445052  0.63025718
   0.44988894  0.57066157  0.41387733
   0.43333306  0.58841548  0.60349244
 
 position of ions in cartesian coordinates  (Angst):
  12.10851340  0.01784415 12.71100345
   3.34464980  5.58197055 13.20802935
  16.58522780 14.04941865  7.87182780
  15.74532380  3.44235555  1.80701820
  11.64247420  2.10457725  0.31734570
   6.36620840  8.43295575  9.86768760
  19.52485820  8.97214785  4.20159690
  19.08346040  9.18931905  5.47385565
   3.52076340  4.49553915 14.23447350
   3.60091740  6.32338065  6.17282850
   7.51700920  8.68832880  9.37480770
   8.34317040 14.95019610  3.60956565
  18.61829460  7.59787845 11.09092350
   9.57965880 11.39344485  2.89477830
   4.87724320  8.66805495  4.28261625
  16.25357440  3.16475670 14.74161615
  10.20333440  2.52124770 14.80646040
  18.14961880  8.75225355  5.53847415
  16.46208820 13.09335825  6.69607710
  15.94391040  3.91510320  8.86543065
   4.32553660  6.64099710  5.58186540
  11.45489580 13.67003985 12.82548255
  11.53295020 12.94013145  7.42706115
   2.49726180  7.88968260  0.67545270
   3.86134180 13.07677785  6.57517035
   1.12039020  2.34698280  3.17772825
   4.26048940 12.51503835  6.87616980
  14.71742660  8.62104105  3.60404775
  11.28030140  0.90209595 11.80381425
   7.82038400  0.17570745  4.42298265
  11.20305240 12.29569710  7.67145330
  18.70090680  8.15845620 10.66951065
  12.29390580  0.75386400 14.11050495
   3.17542840  7.13989050  6.63199815
   4.92854360  8.11996425  4.87357485
   0.65865100  2.10141555  2.59372065
   3.56689720  8.21382315 14.30752830
  10.17660020 12.18907980  2.30746440
  14.29797060  3.50964690  2.62942455
   3.28055460  8.62492230  0.32470560
  15.82398100 14.01675780  9.45385770
   8.99777880  8.55992355  6.20815995
   8.66666120  8.82623220  9.05238660
 


--------------------------------------------------------------------------------------------------------


 k-point  1 :   0.0000 0.0000 0.0000  plane waves:   81909

 maximum and minimum number of plane-waves per node :     81909    81909

 maximum number of plane-waves:     81909
 maximum index in each direction: 
   IXMAX=   32   IYMAX=   24   IZMAX=   24
   IXMIN=  -32   IYMIN=  -24   IZMIN=  -24

 The following grids will avoid any aliasing or wrap around errors in the Hartre
 e energy
  - symmetry arguments have not been applied
  - exchange correlation energies might require even more grid points
  - we recommend to set PREC=Normal or Accurate and rely on VASP defaults
 WARNING: aliasing errors must be expected set NGX to   140 to avoid them
 WARNING: aliasing errors must be expected set NGY to    98 to avoid them
 WARNING: aliasing errors must be expected set NGZ to    98 to avoid them

 serial   3D FFT for wavefunctions
 parallel 3D FFT for charge:
    minimum data exchange during FFTs selected (reduces bandwidth)


 total amount of memory used by VASP MPI-rank0   222026. kBytes
=======================================================================

   base      :      30000. kBytes
   nonlr-proj:       4022. kBytes
   fftplans  :      45166. kBytes
   grid      :     116408. kBytes
   one-center:        132. kBytes
   wavefun   :      26298. kBytes
 
 Broyden mixing: mesh for mixing (old mesh)
   NGX = 65   NGY = 49   NGZ = 49
  (NGX  =196   NGY  =160   NGZ  =160)
  gives a total of 156065 points

 initial charge density was supplied:
 charge density of overlapping atoms calculated
 number of electron     111.0000000 magnetization 
 keeping initial charge density in first step


--------------------------------------------------------------------------------------------------------


 Maximum index for non-local projection operator         1505
 Maximum index for augmentation-charges         1143 (set IRDMAX)


--------------------------------------------------------------------------------------------------------


 First call to EWALD:  gamma=   0.107
 Maximum number of real-space cells 2x 3x 3
 Maximum number of reciprocal cells 3x 3x 3



----------------------------------------- Iteration    1(   1)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.7433629E+03  (-0.2569713E+04)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4297.49012227
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       262.03477443
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.00663945
  eigenvalues    EBANDS =      -568.11465063
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       743.36288028 eV

  energy without entropy =      743.36951973  energy(sigma->0) =      743.36509343


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   2)  ---------------------------------------



 eigenvalue-minimisations  :   264
 total energy-change (2. order) :-0.6431911E+03  (-0.6188178E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4297.49012227
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       262.03477443
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.00360344
  eigenvalues    EBANDS =     -1211.30877793
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =       100.17178899 eV

  energy without entropy =      100.17539243  energy(sigma->0) =      100.17299014


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   3)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) :-0.2478162E+03  (-0.2350562E+03)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4297.49012227
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       262.03477443
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.03356534
  eigenvalues    EBANDS =     -1459.09505789
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -147.64445286 eV

  energy without entropy =     -147.61088752  energy(sigma->0) =     -147.63326442


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   4)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.3240439E+02  (-0.2926051E+02)
 number of electron     111.0000000 magnetization 
 augmentation part      111.0000000 magnetization 

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4297.49012227
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       262.03477443
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.07030184
  eigenvalues    EBANDS =     -1491.46271454
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -180.04884602 eV

  energy without entropy =     -179.97854418  energy(sigma->0) =     -180.02541207


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   5)  ---------------------------------------



 eigenvalue-minimisations  :   224
 total energy-change (2. order) :-0.1458692E+01  (-0.1440525E+01)
 number of electron     110.9999935 magnetization 
 augmentation part        4.7479773 magnetization 

 Broyden mixing:
  rms(total) = 0.31847E+01    rms(broyden)= 0.31797E+01
  rms(prec ) = 0.37221E+01
  weight for this iteration     100.00

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4297.49012227
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       262.03477443
  PAW double counting   =      3570.94830049    -3499.21096548
  entropy T*S    EENTRO =        -0.06882198
  eigenvalues    EBANDS =     -1492.92288617
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -181.50753779 eV

  energy without entropy =     -181.43871580  energy(sigma->0) =     -181.48459713


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   6)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.2485700E+02  (-0.2104796E+02)
 number of electron     110.9999929 magnetization 
 augmentation part        2.4949657 magnetization 

 Broyden mixing:
  rms(total) = 0.46067E+01    rms(broyden)= 0.46013E+01
  rms(prec ) = 0.56465E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.3826
  0.3826

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4502.23080862
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.82035138
  PAW double counting   =      4813.17245855    -4743.51141433
  entropy T*S    EENTRO =        -0.12030936
  eigenvalues    EBANDS =     -1323.69700302
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -206.36454221 eV

  energy without entropy =     -206.24423284  energy(sigma->0) =     -206.32443908


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   7)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.4255446E+02  (-0.4802427E+01)
 number of electron     110.9999955 magnetization 
 augmentation part        3.6862454 magnetization 

 Broyden mixing:
  rms(total) = 0.21401E+01    rms(broyden)= 0.21319E+01
  rms(prec ) = 0.26044E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4453
  0.5990  0.2916

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4441.94836623
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       273.19843980
  PAW double counting   =      5012.80893993    -4942.56374114
  entropy T*S    EENTRO =        -0.04959114
  eigenvalues    EBANDS =     -1340.45794498
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -163.81008056 eV

  energy without entropy =     -163.76048942  energy(sigma->0) =     -163.79355018


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   8)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) : 0.4130445E+01  (-0.1545181E+01)
 number of electron     110.9999950 magnetization 
 augmentation part        3.8554458 magnetization 

 Broyden mixing:
  rms(total) = 0.21780E+01    rms(broyden)= 0.21763E+01
  rms(prec ) = 0.27853E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4153
  0.7213  0.3313  0.1934

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4448.32880772
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       274.05224055
  PAW double counting   =      5282.25401718    -5212.10657787
  entropy T*S    EENTRO =        -0.19790338
  eigenvalues    EBANDS =     -1330.55478761
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -159.67963566 eV

  energy without entropy =     -159.48173228  energy(sigma->0) =     -159.61366787


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(   9)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.2600779E+01  (-0.4066992E+01)
 number of electron     110.9999958 magnetization 
 augmentation part        3.3410366 magnetization 

 Broyden mixing:
  rms(total) = 0.17468E+01    rms(broyden)= 0.17438E+01
  rms(prec ) = 0.21641E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4264
  0.9339  0.3067  0.3067  0.1583

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4468.05897099
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       275.24145043
  PAW double counting   =      5458.22341084    -5388.18846218
  entropy T*S    EENTRO =        -0.06314152
  eigenvalues    EBANDS =     -1309.43532653
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -157.07885677 eV

  energy without entropy =     -157.01571525  energy(sigma->0) =     -157.05780959


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  10)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.1083266E+01  (-0.5767695E+00)
 number of electron     110.9999912 magnetization 
 augmentation part        3.0778882 magnetization 

 Broyden mixing:
  rms(total) = 0.28402E+01    rms(broyden)= 0.28337E+01
  rms(prec ) = 0.35213E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4259
  1.1909  0.3742  0.2649  0.1497  0.1497

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4475.38959129
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       276.03357876
  PAW double counting   =      5697.02499562    -5626.94406894
  entropy T*S    EENTRO =         0.10492855
  eigenvalues    EBANDS =     -1304.19414846
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -158.16212256 eV

  energy without entropy =     -158.26705111  energy(sigma->0) =     -158.19709874


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  11)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.2981706E+01  (-0.4066408E+00)
 number of electron     110.9999954 magnetization 
 augmentation part        3.7671320 magnetization 

 Broyden mixing:
  rms(total) = 0.13531E+01    rms(broyden)= 0.13467E+01
  rms(prec ) = 0.16595E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4693
  1.3600  0.5691  0.4082  0.1747  0.1517  0.1517

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4477.71588436
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       276.63627587
  PAW double counting   =      5908.52788927    -5838.37437585
  entropy T*S    EENTRO =        -0.25372571
  eigenvalues    EBANDS =     -1299.20277918
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -155.18041677 eV

  energy without entropy =     -154.92669107  energy(sigma->0) =     -155.09584154


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  12)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.1501531E+01  (-0.1029010E+01)
 number of electron     110.9999957 magnetization 
 augmentation part        3.5318979 magnetization 

 Broyden mixing:
  rms(total) = 0.95386E+00    rms(broyden)= 0.94948E+00
  rms(prec ) = 0.11938E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4842
  1.5524  0.5527  0.5527  0.2722  0.1672  0.1459  0.1459

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4489.64937298
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       277.58451730
  PAW double counting   =      6075.75650545    -6005.60019297
  entropy T*S    EENTRO =        -0.27092033
  eigenvalues    EBANDS =     -1286.70160591
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -153.67888626 eV

  energy without entropy =     -153.40796592  energy(sigma->0) =     -153.58857948


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  13)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.6500603E+00  (-0.7886100E+00)
 number of electron     110.9999951 magnetization 
 augmentation part        3.9192809 magnetization 

 Broyden mixing:
  rms(total) = 0.17949E+01    rms(broyden)= 0.17921E+01
  rms(prec ) = 0.23641E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5308
  1.9740  0.6741  0.6741  0.3500  0.1495  0.1495  0.1684  0.1065

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4491.51707499
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       278.03968424
  PAW double counting   =      6215.18683654    -6144.93663894
  entropy T*S    EENTRO =        -0.26628027
  eigenvalues    EBANDS =     -1286.03765635
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -154.32894658 eV

  energy without entropy =     -154.06266631  energy(sigma->0) =     -154.24018649


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  14)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.4528382E+00  (-0.1384657E+01)
 number of electron     110.9999947 magnetization 
 augmentation part        3.4104611 magnetization 

 Broyden mixing:
  rms(total) = 0.19580E+01    rms(broyden)= 0.19535E+01
  rms(prec ) = 0.26249E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5158
  2.0794  0.8668  0.4838  0.4540  0.1787  0.1787  0.1520  0.1520  0.0966

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4510.15367831
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.26979571
  PAW double counting   =      6425.69224096    -6355.48695414
  entropy T*S    EENTRO =        -0.05945194
  eigenvalues    EBANDS =     -1268.34024381
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -153.87610834 eV

  energy without entropy =     -153.81665640  energy(sigma->0) =     -153.85629103


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  15)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.1011421E+01  (-0.3351428E+00)
 number of electron     110.9999956 magnetization 
 augmentation part        3.3739517 magnetization 

 Broyden mixing:
  rms(total) = 0.11297E+01    rms(broyden)= 0.11289E+01
  rms(prec ) = 0.15136E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4948
  2.1252  0.9845  0.4674  0.4674  0.1952  0.1952  0.1498  0.1498  0.1067  0.1067

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.71604855
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.41637706
  PAW double counting   =      6479.35629191    -6409.11835673
  entropy T*S    EENTRO =        -0.26112126
  eigenvalues    EBANDS =     -1265.74401306
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.86468744 eV

  energy without entropy =     -152.60356617  energy(sigma->0) =     -152.77764702


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  16)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.2798438E+00  (-0.2405003E+00)
 number of electron     110.9999945 magnetization 
 augmentation part        3.4152897 magnetization 

 Broyden mixing:
  rms(total) = 0.10337E+01    rms(broyden)= 0.10278E+01
  rms(prec ) = 0.13663E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4737
  2.1525  1.0505  0.4470  0.4470  0.3183  0.1561  0.1561  0.1529  0.1183  0.1183
  0.0939

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.43045877
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.41217137
  PAW double counting   =      6505.90144365    -6435.62721384
  entropy T*S    EENTRO =        -0.20468829
  eigenvalues    EBANDS =     -1265.83828098
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.58484366 eV

  energy without entropy =     -152.38015538  energy(sigma->0) =     -152.51661423


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  17)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.3086313E+00  (-0.1720789E+00)
 number of electron     110.9999949 magnetization 
 augmentation part        3.2132979 magnetization 

 Broyden mixing:
  rms(total) = 0.77004E+00    rms(broyden)= 0.76744E+00
  rms(prec ) = 0.10160E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4755
  2.1807  1.2235  0.4734  0.4734  0.2163  0.2163  0.2124  0.2124  0.1507  0.1507
  0.0981  0.0981

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.63602845
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.43194916
  PAW double counting   =      6516.86603018    -6446.59087236
  entropy T*S    EENTRO =        -0.20322703
  eigenvalues    EBANDS =     -1264.34624704
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.27621235 eV

  energy without entropy =     -152.07298532  energy(sigma->0) =     -152.20847000


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  18)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.8168266E-01  (-0.1895340E+00)
 number of electron     110.9999954 magnetization 
 augmentation part        3.5200762 magnetization 

 Broyden mixing:
  rms(total) = 0.85475E+00    rms(broyden)= 0.85322E+00
  rms(prec ) = 0.11080E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4690
  2.1942  1.3269  0.4663  0.4663  0.3525  0.3525  0.1558  0.1558  0.1648  0.1648
  0.1066  0.1066  0.0834

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.06726135
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.39627254
  PAW double counting   =      6528.06212120    -6457.73751345
  entropy T*S    EENTRO =        -0.12320556
  eigenvalues    EBANDS =     -1266.09049157
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.35789500 eV

  energy without entropy =     -152.23468945  energy(sigma->0) =     -152.31682648


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  19)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.4881485E-01  (-0.1268252E+00)
 number of electron     110.9999948 magnetization 
 augmentation part        3.6516235 magnetization 

 Broyden mixing:
  rms(total) = 0.10048E+01    rms(broyden)= 0.10040E+01
  rms(prec ) = 0.12800E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4688
  2.1946  1.3393  0.6030  0.6030  0.4139  0.3055  0.1912  0.1912  0.1491  0.1491
  0.1511  0.0995  0.0995  0.0736

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4510.33094855
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35189429
  PAW double counting   =      6535.33978017    -6464.98902098
  entropy T*S    EENTRO =        -0.30173513
  eigenvalues    EBANDS =     -1266.58123315
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.30908015 eV

  energy without entropy =     -152.00734502  energy(sigma->0) =     -152.20850177


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  20)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.2743675E+00  (-0.1167144E+00)
 number of electron     110.9999947 magnetization 
 augmentation part        3.5124614 magnetization 

 Broyden mixing:
  rms(total) = 0.48660E+00    rms(broyden)= 0.48469E+00
  rms(prec ) = 0.63634E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4613
  2.2469  1.4009  0.6271  0.6271  0.3451  0.3451  0.2611  0.1745  0.1745  0.1522
  0.1522  0.1466  0.0985  0.0985  0.0696

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4510.85912502
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.34383212
  PAW double counting   =      6540.48537054    -6470.14155601
  entropy T*S    EENTRO =        -0.46829630
  eigenvalues    EBANDS =     -1265.59712113
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.03471261 eV

  energy without entropy =     -151.56641631  energy(sigma->0) =     -151.87861384


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  21)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.6120599E-01  (-0.6894987E-01)
 number of electron     110.9999950 magnetization 
 augmentation part        3.4594510 magnetization 

 Broyden mixing:
  rms(total) = 0.64251E+00    rms(broyden)= 0.64219E+00
  rms(prec ) = 0.85787E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4570
  2.2503  1.3843  0.5809  0.5809  0.5423  0.4257  0.2270  0.2270  0.1867  0.1867
  0.1510  0.1510  0.1525  0.0976  0.0976  0.0698

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.44033053
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35455884
  PAW double counting   =      6542.33873235    -6471.97980030
  entropy T*S    EENTRO =        -0.28509134
  eigenvalues    EBANDS =     -1265.28617082
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.09591860 eV

  energy without entropy =     -151.81082726  energy(sigma->0) =     -152.00088815


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  22)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) : 0.1770947E-01  (-0.1288595E+00)
 number of electron     110.9999942 magnetization 
 augmentation part        3.3668704 magnetization 

 Broyden mixing:
  rms(total) = 0.78083E+00    rms(broyden)= 0.77930E+00
  rms(prec ) = 0.99622E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4497
  2.2676  1.4661  0.6254  0.6254  0.5773  0.4124  0.2607  0.2607  0.1746  0.1746
  0.1510  0.1510  0.1394  0.0971  0.0971  0.0946  0.0692

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.62441897
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.37948275
  PAW double counting   =      6544.65022484    -6474.28640281
  entropy T*S    EENTRO =        -0.48324180
  eigenvalues    EBANDS =     -1264.91603634
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.07820913 eV

  energy without entropy =     -151.59496733  energy(sigma->0) =     -151.91712853


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  23)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.5653548E-01  (-0.5593859E-01)
 number of electron     110.9999950 magnetization 
 augmentation part        3.5842074 magnetization 

 Broyden mixing:
  rms(total) = 0.38861E+00    rms(broyden)= 0.38617E+00
  rms(prec ) = 0.48466E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4950
  2.3077  1.6898  0.8295  0.8295  0.5966  0.4887  0.4319  0.2759  0.2759  0.1816
  0.1816  0.1501  0.1501  0.1390  0.1167  0.0979  0.0979  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4510.98220878
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35075428
  PAW double counting   =      6547.22472101    -6476.84456365
  entropy T*S    EENTRO =        -0.44840478
  eigenvalues    EBANDS =     -1265.52415493
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.02167365 eV

  energy without entropy =     -151.57326887  energy(sigma->0) =     -151.87220539


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  24)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.2638676E+00  (-0.1928526E+00)
 number of electron     110.9999945 magnetization 
 augmentation part        3.4326757 magnetization 

 Broyden mixing:
  rms(total) = 0.10173E+01    rms(broyden)= 0.10164E+01
  rms(prec ) = 0.13332E+01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5017
  2.3424  1.6593  0.9975  0.9975  0.5841  0.5841  0.3587  0.3587  0.2302  0.2302
  0.1860  0.1860  0.1501  0.1501  0.1429  0.0979  0.0979  0.1099  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.19079093
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36013750
  PAW double counting   =      6548.60892948    -6478.21502229
  entropy T*S    EENTRO =        -0.28660251
  eigenvalues    EBANDS =     -1264.76437566
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.28554121 eV

  energy without entropy =     -151.99893871  energy(sigma->0) =     -152.19000704


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  25)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.2625037E+00  (-0.9177492E-01)
 number of electron     110.9999950 magnetization 
 augmentation part        3.6024277 magnetization 

 Broyden mixing:
  rms(total) = 0.53126E+00    rms(broyden)= 0.52925E+00
  rms(prec ) = 0.69624E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.4989
  2.3418  1.6455  1.1033  1.1033  0.5382  0.5382  0.4122  0.4122  0.2454  0.2454
  0.2028  0.1843  0.1843  0.1498  0.1498  0.1452  0.0980  0.0980  0.1099  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.27876722
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.38969636
  PAW double counting   =      6545.88783763    -6475.48350240
  entropy T*S    EENTRO =        -0.49823000
  eigenvalues    EBANDS =     -1265.24225507
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.02303751 eV

  energy without entropy =     -151.52480751  energy(sigma->0) =     -151.85696084


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  26)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.3522590E-01  (-0.2116637E-01)
 number of electron     110.9999952 magnetization 
 augmentation part        3.5737176 magnetization 

 Broyden mixing:
  rms(total) = 0.41490E+00    rms(broyden)= 0.41465E+00
  rms(prec ) = 0.50842E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5574
  2.1504  2.1504  1.7145  0.8276  0.7062  0.7062  0.5719  0.5719  0.3280  0.2840
  0.2509  0.2509  0.1866  0.1866  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101
  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4511.53820845
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35278784
  PAW double counting   =      6543.97751850    -6473.57174736
  entropy T*S    EENTRO =        -0.40012514
  eigenvalues    EBANDS =     -1265.08067199
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.05826340 eV

  energy without entropy =     -151.65813826  energy(sigma->0) =     -151.92488836


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  27)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) : 0.1262586E-01  (-0.1050787E-01)
 number of electron     110.9999951 magnetization 
 augmentation part        3.4374442 magnetization 

 Broyden mixing:
  rms(total) = 0.32332E+00    rms(broyden)= 0.32238E+00
  rms(prec ) = 0.43153E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5539
  2.3256  2.3256  1.3457  0.8860  0.8860  0.5653  0.5653  0.5728  0.4349  0.2935
  0.2935  0.2493  0.2493  0.1867  0.1867  0.1499  0.1499  0.1438  0.0980  0.0980
  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.66912869
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.39243494
  PAW double counting   =      6541.56007841    -6471.15601381
  entropy T*S    EENTRO =        -0.41078255
  eigenvalues    EBANDS =     -1263.96440904
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.04563754 eV

  energy without entropy =     -151.63485500  energy(sigma->0) =     -151.90871003


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  28)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.3627572E-02  (-0.9027409E-02)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4597583 magnetization 

 Broyden mixing:
  rms(total) = 0.61324E-01    rms(broyden)= 0.60410E-01
  rms(prec ) = 0.82848E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5537
  2.3362  2.3362  1.1599  0.9991  0.9991  0.5511  0.5511  0.5455  0.4725  0.4725
  0.3253  0.2961  0.2494  0.2494  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980
  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.42380264
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36385727
  PAW double counting   =      6539.04044997    -6468.63082342
  entropy T*S    EENTRO =        -0.45460524
  eigenvalues    EBANDS =     -1264.14652424
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.04926511 eV

  energy without entropy =     -151.59465987  energy(sigma->0) =     -151.89773003


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  29)  ---------------------------------------



 eigenvalue-minimisations  :   208
 total energy-change (2. order) :-0.1475596E-01  (-0.1577289E-02)
 number of electron     110.9999948 magnetization 
 augmentation part        3.4287375 magnetization 

 Broyden mixing:
  rms(total) = 0.18053E+00    rms(broyden)= 0.18025E+00
  rms(prec ) = 0.22907E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.5947
  2.5951  2.3817  1.2263  1.0797  1.0797  0.6544  0.6544  0.5997  0.5997  0.5497
  0.5497  0.3052  0.3052  0.2498  0.2498  0.1867  0.1867  0.1499  0.1499  0.1439
  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.58904841
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36026173
  PAW double counting   =      6538.76157102    -6468.35087278
  entropy T*S    EENTRO =        -0.43168050
  eigenvalues    EBANDS =     -1264.01643533
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.06402108 eV

  energy without entropy =     -151.63234058  energy(sigma->0) =     -151.92012758


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  30)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) : 0.2368643E-02  (-0.5266492E-03)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4271924 magnetization 

 Broyden mixing:
  rms(total) = 0.13098E+00    rms(broyden)= 0.13083E+00
  rms(prec ) = 0.17575E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6446
  3.2310  2.2317  1.3505  1.3505  1.3225  0.7990  0.7990  0.5825  0.5825  0.5692
  0.4959  0.4959  0.3064  0.3064  0.2497  0.2497  0.1867  0.1867  0.1499  0.1499
  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.75009813
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36713253
  PAW double counting   =      6538.25417732    -6467.83939497
  entropy T*S    EENTRO =        -0.41362773
  eigenvalues    EBANDS =     -1263.88202465
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.06165243 eV

  energy without entropy =     -151.64802470  energy(sigma->0) =     -151.92377652


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  31)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.7846943E-02  (-0.1659062E-02)
 number of electron     110.9999948 magnetization 
 augmentation part        3.4351953 magnetization 

 Broyden mixing:
  rms(total) = 0.93289E-01    rms(broyden)= 0.93190E-01
  rms(prec ) = 0.11657E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.6756
  3.6514  2.3310  1.6678  1.2444  1.2444  0.9943  0.6913  0.6913  0.5812  0.5812
  0.5561  0.5139  0.5139  0.3062  0.3062  0.2497  0.2497  0.1867  0.1867  0.1499
  0.1499  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.79014065
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36746795
  PAW double counting   =      6537.08322594    -6466.66631166
  entropy T*S    EENTRO =        -0.42294513
  eigenvalues    EBANDS =     -1263.84297902
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.06949938 eV

  energy without entropy =     -151.64655424  energy(sigma->0) =     -151.92851766


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  32)  ---------------------------------------



 eigenvalue-minimisations  :   184
 total energy-change (2. order) :-0.3094427E-02  (-0.1535807E-02)
 number of electron     110.9999950 magnetization 
 augmentation part        3.4449084 magnetization 

 Broyden mixing:
  rms(total) = 0.86920E-01    rms(broyden)= 0.86504E-01
  rms(prec ) = 0.10986E+00
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7074
  3.9518  2.4532  2.0379  1.2879  1.2879  0.9308  0.8884  0.8884  0.5807  0.5807
  0.5443  0.4883  0.4883  0.3869  0.3060  0.3060  0.2497  0.2497  0.1867  0.1867
  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.90179033
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36450473
  PAW double counting   =      6535.97982498    -6465.56414648
  entropy T*S    EENTRO =        -0.40980338
  eigenvalues    EBANDS =     -1263.74336651
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.07259380 eV

  energy without entropy =     -151.66279042  energy(sigma->0) =     -151.93599267


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  33)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.2637668E-02  (-0.3082152E-03)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4442298 magnetization 

 Broyden mixing:
  rms(total) = 0.24693E-01    rms(broyden)= 0.24615E-01
  rms(prec ) = 0.30959E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7420
  4.3589  2.4806  1.9440  1.5912  1.3546  1.3546  0.8557  0.7215  0.7215  0.5791
  0.5791  0.5210  0.4900  0.4900  0.4290  0.3059  0.3059  0.2497  0.2497  0.1867
  0.1867  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.91820562
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.36190333
  PAW double counting   =      6535.63980025    -6465.22481503
  entropy T*S    EENTRO =        -0.42660957
  eigenvalues    EBANDS =     -1263.70948802
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.07523147 eV

  energy without entropy =     -151.64862190  energy(sigma->0) =     -151.93302828


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  34)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.3299112E-02  (-0.2459561E-03)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4467956 magnetization 

 Broyden mixing:
  rms(total) = 0.56159E-01    rms(broyden)= 0.56056E-01
  rms(prec ) = 0.75574E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.7594
  4.4507  2.5835  2.1295  1.5283  1.4170  1.4170  0.8208  0.8208  0.7404  0.7404
  0.5794  0.5794  0.4839  0.4839  0.4719  0.4719  0.3060  0.3060  0.2497  0.2497
  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.88968927
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35752200
  PAW double counting   =      6535.77832651    -6465.36373100
  entropy T*S    EENTRO =        -0.42493981
  eigenvalues    EBANDS =     -1263.73820220
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.07853058 eV

  energy without entropy =     -151.65359078  energy(sigma->0) =     -151.93688398


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  35)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.9053961E-03  (-0.4688017E-03)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4536303 magnetization 

 Broyden mixing:
  rms(total) = 0.43788E-01    rms(broyden)= 0.43649E-01
  rms(prec ) = 0.57924E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8133
  5.1983  2.6744  2.1993  1.8626  1.3936  1.3936  1.0710  1.0710  0.7865  0.6786
  0.6786  0.5794  0.5794  0.4804  0.4804  0.4842  0.4842  0.3060  0.3060  0.2497
  0.2497  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.88748612
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35657237
  PAW double counting   =      6536.29820322    -6465.88431651
  entropy T*S    EENTRO =        -0.43901521
  eigenvalues    EBANDS =     -1263.72557693
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.07943598 eV

  energy without entropy =     -151.64042077  energy(sigma->0) =     -151.93309758


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  36)  ---------------------------------------



 eigenvalue-minimisations  :   200
 total energy-change (2. order) :-0.8562031E-03  (-0.7002886E-04)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4539082 magnetization 

 Broyden mixing:
  rms(total) = 0.30355E-01    rms(broyden)= 0.30347E-01
  rms(prec ) = 0.38076E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8470
  5.8288  2.6564  2.6045  1.7807  1.3996  1.3996  1.4854  0.8356  0.8356  0.7498
  0.7498  0.5793  0.5793  0.5913  0.4852  0.4852  0.4539  0.4539  0.3060  0.3060
  0.2497  0.2497  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980  0.0980  0.1101
  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.86500830
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35398532
  PAW double counting   =      6536.41389624    -6466.00003961
  entropy T*S    EENTRO =        -0.43248536
  eigenvalues    EBANDS =     -1263.75282366
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.08029218 eV

  energy without entropy =     -151.64780682  energy(sigma->0) =     -151.93613040


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  37)  ---------------------------------------



 eigenvalue-minimisations  :   192
 total energy-change (2. order) :-0.4464845E-03  (-0.3995939E-04)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4489217 magnetization 

 Broyden mixing:
  rms(total) = 0.12421E-01    rms(broyden)= 0.12384E-01
  rms(prec ) = 0.15835E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.8816
  6.3229  3.2523  2.3298  2.0366  1.4343  1.4343  1.3730  0.9034  0.9034  0.7562
  0.7562  0.7702  0.5791  0.5791  0.5801  0.4836  0.4836  0.4648  0.4648  0.3060
  0.3060  0.2497  0.2497  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980  0.0980
  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.89838533
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35330239
  PAW double counting   =      6536.71602231    -6466.30245249
  entropy T*S    EENTRO =        -0.43378937
  eigenvalues    EBANDS =     -1263.71761937
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.08073867 eV

  energy without entropy =     -151.64694929  energy(sigma->0) =     -151.93614221


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  38)  ---------------------------------------



 eigenvalue-minimisations  :   176
 total energy-change (2. order) :-0.6338076E-03  (-0.1579584E-04)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4484010 magnetization 

 Broyden mixing:
  rms(total) = 0.10433E-01    rms(broyden)= 0.10403E-01
  rms(prec ) = 0.13568E-01
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9085
  6.8414  3.4359  2.2364  2.2364  1.4398  1.4398  1.2230  1.2230  0.9810  0.7891
  0.7891  0.7072  0.7072  0.5790  0.5790  0.5643  0.4841  0.4841  0.4678  0.4678
  0.3060  0.3060  0.2497  0.2497  0.1867  0.1867  0.1499  0.1499  0.1439  0.0980
  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.88638149
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.35045256
  PAW double counting   =      6536.78145018    -6466.36778394
  entropy T*S    EENTRO =        -0.43290046
  eigenvalues    EBANDS =     -1263.72839252
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.08137247 eV

  energy without entropy =     -151.64847201  energy(sigma->0) =     -151.93707232


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  39)  ---------------------------------------



 eigenvalue-minimisations  :   168
 total energy-change (2. order) :-0.2204275E-03  (-0.7285024E-05)
 number of electron     110.9999949 magnetization 
 augmentation part        3.4477089 magnetization 

 Broyden mixing:
  rms(total) = 0.38646E-02    rms(broyden)= 0.38301E-02
  rms(prec ) = 0.50365E-02
  weight for this iteration     100.00

 eigenvalues of (default mixing * dielectric matrix)
  average eigenvalue GAMMA=   0.9505
  7.3160  3.7218  2.2702  2.2702  1.7029  1.4351  1.4351  1.1797  1.1797  0.7754
  0.7754  0.8220  0.8220  0.5790  0.5790  0.6693  0.5758  0.4843  0.4843  0.4687
  0.4687  0.3060  0.3060  0.2497  0.2497  0.1867  0.1867  0.1499  0.1499  0.1439
  0.0980  0.0980  0.1101  0.0695

 Free energy of the ion-electron system (eV)
  ---------------------------------------------------
  alpha Z        PSCENC =         9.57847877
  Ewald energy   TEWEN  =       529.72344117
  -Hartree energ DENC   =     -4512.88291730
  -exchange      EXHF   =         0.00000000
  -V(xc)+E(xc)   XCENC  =       279.34995993
  PAW double counting   =      6536.74478623    -6466.33101111
  entropy T*S    EENTRO =        -0.43381601
  eigenvalues    EBANDS =     -1263.73077782
  atomic energy  EATOM  =      4735.90026324
  Solvation  Ediel_sol  =         0.00000000
  ---------------------------------------------------
  free energy    TOTEN  =      -152.08159290 eV

  energy without entropy =     -151.64777689  energy(sigma->0) =     -151.93698757


--------------------------------------------------------------------------------------------------------




----------------------------------------- Iteration    1(  40)  ---------------------------------------